Niobium Aluminide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. As aluminium is near the nonmetals, it bonds with metals differently than other metals, consequently the properties of aluminide compounds are intermediate between those of a metal alloy and an ionic compound.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Niobium is a Block D, Group 5, Period 5 element. The number of electrons in each of Niobium's shells is 2, 8, 18, 12, 1 and its electronic configuration is [Kr] 4d4 5s1. In its elemental form niobium's CAS number is 7440-03-1. The niobium atom has a radius of 142.9.pm and it's Van der Waals radius is 200.pm. Some niobium compounds are considered very toxic. Niobium is the basis for various barium titanate compositions used as dielectric coatings in telecommunications and small advanced electronics, such as cell phones, pagers and laptop computers. Niobium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Niobium has medical research applications. It is alloyed to produce arc-welding rods and in corrosion-resistant steel. Niobium was first discovered by Charles Hatchett in 1801. The word Niobium originates from Niobe, daughter of mythical Greek king Tantalus. See Niobium research below.
Aluminum is a Block P, Group 13, Period 3 element. The number of electrons in each of Aluminum's shells is 2, 8, 3 and its electronic configuration is [Ne] 3s2 3p1. In its elemental form aluminum's CAS number is 7429-90-5. The aluminum atom has a radius of 143.2.pm and it's Van der Waals radius is 200.pm. Aluminum is the most abundant metal in the earth's crust. Aluminum is not known to be harmful but ingestion may cause Alzheimer's disease.Aluminum is a silvery-white metal that possesses many desirable characteristics. It is light, nonmagnetic and nonsparking.
It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Although it's electrical conductivity is only about 60% that of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements impart a variety of useful properties. These alloys are of vital importance in the construction of modern aircraft and rockets. Aluminum, evaporated in a vacuum, forms a highly reflective coating for both visible light and radiant heat. They are used to coat telescope mirrors. Aluminum is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. See Aluminum research below.
An aluminide contains aluminium and one or more electropositive elements. Since aluminum is similar to the nonmetals, it forms compounds with properties intermediate between a metal alloy and an ionic compound. Aluminides have found applications in hydrogen storage technology, the aeronautical industry, and in coatings for furnaces and other high temperature applications.
Assessing the performance and longevity of Nb, Pt, Ta, Ti, Zr, and ZrO(2)-sputtered Havar foils for the high-power production of reactive [(18)F]F(-) by proton irradiation of [(18)O]H(2)O.
Gagnon K, Wilson JS, Sant E, Backhouse CJ, McQuarrie SA.
Appl Radiat Isot. 2011 Oct;69(10):1330-6. Epub 2011 Feb 25.
PMID:
21782460
[PubMed - in process]
SrNbO(2)N as a Water-Splitting Photoanode with a Wide Visible-Light Absorption Band.
Maeda K, Higashi M, Siritanaratkul B, Abe R, Domen K.
J Am Chem Soc. 2011 Jul 26. [Epub ahead of print]
PMID:
21770436
[PubMed - as supplied by publisher]
Oxygen-containing gas-phase diatomic trications and tetracations: ReO(z+), NbO(z+) and HfO(z+) (z = 3, 4).
Brites V, Franzreb K, Harvey JN, Sayres SG, Ross MW, Blumling DE, Castleman AW, Hochlaf M.
Phys Chem Chem Phys. 2011 Jul 15. [Epub ahead of print]
PMID:
21761073
[PubMed - as supplied by publisher]
Li(2)Ca(1.5)Nb(3)O(10) from X-ray powder data.
Zhu BC, Tang KB.
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):i25. Epub 2011 Mar 12.
PMID:
21753922
[PubMed]
Novel borothermal process for the synthesis of nanocrystalline oxides and borides of niobium.
Jha M, Ramanujachary KV, Lofland SE, Gupta G, Ganguli AK.
Dalton Trans. 2011 Aug 21;40(31):7879-88. Epub 2011 Jul 8.
PMID:
21743887
[PubMed - in process]
Tuning of superconducting niobium nitride terahertz metamaterials.
Wu J, Jin B, Xue Y, Zhang C, Dai H, Zhang L, Cao C, Kang L, Xu W, Chen J, Wu P.
Opt Express. 2011 Jun 20;19(13):119221-6.
PMID:
21716533
[PubMed - in process]
Tuning of superconducting niobium nitride terahertz metamaterials.
Wu J, Jin B, Xue Y, Zhang C, Dai H, Zhang L, Cao C, Kang L, Xu W, Chen J, Wu P.
Opt Express. 2011 Jun 20;19(13):12021-6. doi: 10.1364/OE.19.012021.
PMID:
21716437
[PubMed - in process]
Note: Radio frequency surface impedance characterization system for superconducting samples at 7.5 GHz.
Xiao BP, Reece CE, Phillips HL, Geng RL, Wang H, Marhauser F, Kelley MJ.
Rev Sci Instrum. 2011 May;82(5):056104.
PMID:
21639552
[PubMed - in process]
Mono N,C,N-pincer complexes of titanium, vanadium and niobium. Synthesis, structure and catalytic activity in olefin polymerisation.
Chuchuryukin AV, Huang R, van Faassen EE, van Klink GP, Lutz M, Chadwick JC, Spek AL, van Koten G.
Dalton Trans. 2011 Jun 2. [Epub ahead of print]
PMID:
21637878
[PubMed - as supplied by publisher]
Comment on "Electronic Structures, Vibrational and Thermochemical Properties of Neutral and Charged Niobium Clusters Nb(n), n = 7-12"
Fielicke A, Meijer G.
J Phys Chem A. 2011 Jul 7;115(26):7869-7870. Epub 2011 Jun 7. No abstract available.
PMID:
21627123
[PubMed - as supplied by publisher]
A structural study of the proton conducting B-site ordered perovskite Ba3Ca1.18Ta1.82O8.73.
Verbraeken MC, Viana HA, Wormald P, Irvine JT.
J Phys Condens Matter. 2011 Jun 15;23(23):234111. Epub 2011 May 25.
PMID:
21613698
[PubMed - in process]
Influence of heat treatment and oxygen doping on the mechanical properties and biocompatibility of titanium-niobium binary alloys.
da Silva LM, Claro AP, Donato TA, Arana-Chavez VE, Moraes JC, Buzalaf MA, Grandini CR.
Artif Organs. 2011 May;35(5):516-21. doi: 10.1111/j.1525-1594.2011.01263.x.
PMID:
21595721
[PubMed - in process]
Posterior Condyle Surface Damage on Retrieved Femoral Knee Components.
Burnell CD, Brandt JM, Petrak MJ, Bourne RB.
J Arthroplasty. 2011 May 12. [Epub ahead of print]
PMID:
21570806
[PubMed - as supplied by publisher]
Multiple isomers in the photoelectron spectra of small mono-niobium carbide clusters.
Iordanov I, Sofo JO.
J Chem Phys. 2011 May 14;134(18):184310.
PMID:
21568509
[PubMed - in process]
Metastable p junction between an s(±)-wave and an s-wave superconductor.
Berg E, Lindner NH, Pereg-Barnea T.
Phys Rev Lett. 2011 Apr 8;106(14):147003. Epub 2011 Apr 7.
PMID:
21561215
[PubMed - in process]
Assessment of radionuclide and metal contamination in a thorium rich area in Norway.
Popic JM, Salbu B, Strand T, Skipperud L.
J Environ Monit. 2011 Jun;13(6):1730-8. Epub 2011 May 10.
PMID:
21556423
[PubMed - in process]
Controlling the duality of the mechanism in liquid-phase oxidation of benzyl alcohol catalysed by supported Au-Pd nanoparticles.
Sankar M, Nowicka E, Tiruvalam R, He Q, Taylor SH, Kiely CJ, Bethell D, Knight DW, Hutchings GJ.
Chemistry. 2011 May 27;17(23):6524-32. doi: 10.1002/chem.201003484. Epub 2011 Apr 27.
PMID:
21538605
[PubMed - in process]
Can the provenance of the conflict minerals columbite and tantalite be ascertained by laser-induced breakdown spectroscopy?
Harmon RS, Shughrue KM, Remus JJ, Wise MA, East LJ, Hark RR.
Anal Bioanal Chem. 2011 Jul;400(10):3377-82. Epub 2011 May 3.
PMID:
21537914
[PubMed - in process]
Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and ß-diketiminato ligands.
Tomson NC, Arnold J, Bergman RG.
Dalton Trans. 2011 Aug 14;40(30):7718-29. Epub 2011 Apr 27.
PMID:
21523303
[PubMed - in process]
K(0.12)Na(0.54)Ag(0.34)Nb(4)O(9)AsO(4).
Chérif SF, Zid MF, Driss A.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 12;67(Pt 2):i10.
PMID:
21522808
[PubMed]
Catalytic hydrosilylation of olefins with organolanthanide complexes: A DFT study. Part II: Influence of the substitution on olefin and silane.
Barros N, Eisenstein O, Maron L.
Dalton Trans. 2010 Oct 8. [Epub ahead of print]PMID: 20936209 [PubMed - as supplied by publisher]Related citations
Safety and feasibility of percutaneous vertebroplasty with radioactive (153)Sm PMMA in an animal model.
Lu J, Deng J, Zhao H, Shi M, Wang J, Zhao L.
Eur J Radiol. 2010 Oct 8. [Epub ahead of print]PMID: 20934823 [PubMed - as supplied by publisher]Related citations
Chemical and biological evaluation of (153)Sm and (46/47)Sc complexes of indazolebisphosphonates for targeted radiotherapy.
Neves M, Teixeira FC, Antunes I, Majkowska A, Gano L, Santos AC.
Appl Radiat Isot. 2010 Sep 25. [Epub ahead of print]PMID: 20933431 [PubMed - as supplied by publisher]Related citations
Adverse Events in the Long-Term Follow-Up of Patients Treated With Samarium Sm 153 Lexidronam for Osseous Metastases.
Paravati AJ, Russo AL, Aitken C.
Int J Radiat Oncol Biol Phys. 2010 Sep 30. [Epub ahead of print]PMID: 20888141 [PubMed - as supplied by publisher]Related citations
A Short Formal Total Synthesis of Strychnine with a Samarium Diiodide Induced Cascade Reaction as the Key Step.
Beemelmanns C, Reissig HU.
Angew Chem Int Ed Engl. 2010 Sep 16. [Epub ahead of print] No abstract available. PMID: 20848626 [PubMed - as supplied by publisher]Related citations
Computational insights into the nature of increased ionic conductivity in concentrated samarium-doped ceria: a genetic algorithm study.
Hooper J, Ismail A, Giorgi JB, Woo TK.
Phys Chem Chem Phys. 2010 Oct 28;12(40):12969-72. Epub 2010 Sep 8.PMID: 20830388 [PubMed - in process]Related citations
Therapeutic nuclear medicine in pediatric malignancy.
Schmidt M, Baum RP, Simon T, Howman-Giles R.
Q J Nucl Med Mol Imaging. 2010 Aug;54(4):411-28.PMID: 20823809 [PubMed - in process]Related citations
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer.
Fukuzumi S, Morimoto Y, Kotani H, Naumov P, Lee YM, Nam W.
Nat Chem. 2010 Sep;2(9):756-9. Epub 2010 Jul 11.PMID: 20729896 [PubMed - indexed for MEDLINE]Related citations
Molecules containing rare-earth atoms solely bonded by transition metals.
Butovskii MV, Döring C, Bezugly V, Wagner FR, Grin Y, Kempe R.
Nat Chem. 2010 Sep;2(9):741-4. Epub 2010 Jun 27.PMID: 20729893 [PubMed - indexed for MEDLINE]Related citations
Dynamic ligand exchange in reactions of samarium diiodide.
Sadasivam DV, Teprovich JA Jr, Procter DJ, Flowers RA 2nd.
Org Lett. 2010 Sep 17;12(18):4140-3.PMID: 20722385 [PubMed - in process]Related citations
Tandem dosing of samarium-153 ethylenediamine tetramethylene phosphoric acid with stem cell support for patients with high-risk osteosarcoma.
Loeb DM, Hobbs RF, Okoli A, Chen AR, Cho S, Srinivasan S, Sgouros G, Shokek O, Wharam MD Jr, Scott T, Schwartz CL.
Cancer. 2010 Aug 16. [Epub ahead of print]PMID: 20715156 [PubMed - as supplied by publisher]Related citations
Gamma spectrometry and chemical characterization of ceramic seeds with samarium-153 and holmium-166 for brachytherapy proposal.
Valente ES, Campos TP.
Appl Radiat Isot. 2010 Dec;68(12):2157-62. Epub 2010 Jul 27.PMID: 20685128 [PubMed - in process]Related citations
Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium.
Concellón JM, Rodríguez-Solla H, Concellón C, Del Amo V.
Chem Soc Rev. 2010 Aug 4. [Epub ahead of print]PMID: 20683534 [PubMed - as supplied by publisher]Related citations
Grafting of peralkylated Ln(II)Al(III) heterobimetallic complexes onto periodic mesoporous silica KIT-6.
Le Roux E, Michel O, Sommerfeldt HM, Liang Y, Maichle-Mössmer C, Törnroos KW, Anwander R.
Dalton Trans. 2010 Sep 28;39(36):8552-9. Epub 2010 Aug 4.PMID: 20683527 [PubMed - in process]Related citations
Synthesis of 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanaminevia a [4+2] cycloaddition.
Karama U, Al-Saidey A, Al-Othman Z, Almansour AR.
Molecules. 2010 Jun 9;15(6):4201-6.PMID: 20657434 [PubMed - in process]Related citations
[99mTc]-1,4,7,10-Tetraazacyclododecane tetramethylenephosphonic acid.
Datta A, Panwar P, Chuttani K, Mishra AK, Chopra A.
Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2010.
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Non-classical divalent lanthanide complexes.
Nief F.
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Synthesis and characterization of thermally stable Sm,N co-doped TiO2 with highly visible light activity.
Ma Y, Zhang J, Tian B, Chen F, Wang L.
J Hazard Mater. 2010 Oct 15;182(1-3):386-93. Epub 2010 Jun 18.PMID: 20619539 [PubMed - in process]Related citations
Steric control of the reduction of carbodiimides by samarium(II) and the synthesis of very crowded samarium(III) complexes.
Cole ML, Deacon GB, Forsyth CM, Junk PC, Polo Cerón D, Wang J.
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Studies on the biodistribution of dextrin nanoparticles.
Gonçalves C, Ferreira MF, Santos AC, Prata MI, Geraldes CF, Martins JA, Gama FM.
Nanotechnology. 2010 Jul 23;21(29):295103. Epub 2010 Jul 5.PMID: 20601764 [PubMed - indexed for MEDLINE]Related citations
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