Neodymium(III) Nitrate Hexahydrate is a highly water soluble crystalline neodymium source for uses compatible with nitrates and lower (acidic) pH. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Primary applications include lasers, glass coloring and tinting, and dielectrics. NdNO3 is generally immediately available in most volumes.Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Neodymium is a Block F, Group 3, Period 6 element. The number of electrons in each of Neodymium's shells is 2, 8, 18, 22, 8, 2 and its electronic configuration is [Xe] 4f4 6s2. In its elemental form neodymium's CAS number is 7440-00-8. The neodymium atom has a radius of 181.4.pm and it's Van der Waals radius is 181.pm. Neodymium is the most abundant of the rare earths after cerium and lanthanum. Neodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Primary applications include lasers, glass coloring and tinting, dielectrics and, most importantly, as the fundamental basis for neodymium-iron-boron permanent magnets. Neodymium has a strong absorption band centered at 580 nm, which is very close to the human eye's maximum level of sensitivity making it useful in protective lenses for welding goggles. It is also used in CRT displays to enhance contrast between reds and greens and highly valued in glass manufacturing for its attractive purple coloring. Neodymium is included in many formulations of barium titanate, used as dielectric coatings and in multi-layer capacitors essential to electronic equipment. Neodymium was first discovered by Carl Aer von Welsbach in 1885. The name originates from the Greek words 'neos didymos', meaning new twin. See Neodymium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Bullion and bar forms are best if purchasing solely for physical possession and risk exposure.
Uncovering the global life cycles of the rare Earth elements.
Du X, Graedel TE.
Sci Rep. 2011;1:145. Epub 2011 Nov 4.
PMID:
22355662
[PubMed - in process]
Magnetic Nanoparticles to Enhance Cell Seeding and Distribution in Tissue Engineering Scaffolds.
Thevenot P, Sohaebuddin S, Poudyal N, Liu JP, Tang L.
Proc IEEE Conf Nanotechnol. 2008 Aug 18;2008:646-649.
PMID:
22348179
[PubMed]
catena-Poly[[[tetra-aqua-neodymium(III)]-di-µ-isonicotinato] chloride].
Xue JH, Hua XH, Li CP, Xu YZ, Wu JG.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m170-1. Epub 2012 Jan 18.
PMID:
22346846
[PubMed - in process]
Neodymium: yttrium-aluminum-garnet laser anterior hyaloidotomy to treat trapped triamcinolone acetonide behind the crystalline lens after intravitreal injection.
Ascaso FJ, de Gopegui ER, Cascante JM.
Middle East Afr J Ophthalmol. 2012 Jan;19(1):163-5.
PMID:
22346134
[PubMed - in process]
Free PMC Article
Epithelial iris cyst after cataract surgery.
Chaudhry M, Grover S, Sood N, Gupta R.
Nepal J Ophthalmol. 2012 Jan;4(7):191-3. doi: 10.3126/nepjoph.v4i1.5876.
PMID:
22344022
[PubMed - in process]
Transient optic disc edema following neodymium: yttrium-aluminum-garnet laser posterior capsulotomy.
Han SB, Yang HK, Hyon JY, Woo SJ, Wee WR.
Can J Ophthalmol. 2012 Feb;47(1):e1-2. Epub 2011 Dec 22. No abstract available.
PMID:
22333862
[PubMed - in process]
Successful Treatment of Multiple Cutaneous Neurofibromas Using a Combination of Shave Excision and Laser Photothermocoagulation with a 1,444-nm Neodymium-Doped Yttrium Aluminum Garnet Laser.
Kim HJ, Lee KG, Yi SM, Kim JH, Kim IH.
Dermatol Surg. 2012 Feb 13. doi: 10.1111/j.1524-4725.2012.02357.x. [Epub ahead of print] No abstract available.
PMID:
22329357
[PubMed - as supplied by publisher]
Late capsular block syndrome presenting with posterior capsule opacification.
Pinarci EY, Bayar SA, Sizmaz S, Canan H, Yilmaz G.
J Cataract Refract Surg. 2012 Feb 10. [Epub ahead of print]
PMID:
22326771
[PubMed - as supplied by publisher]
Susceptibility of the pilot balloon of the disposable laryngeal mask airway to puncture during laser therapy.
Chilcott A, Lister TS, Geary PM, Wright PA.
Anaesthesia. 2012 Feb 11. doi: 10.1111/j.1365-2044.2011.07025.x. [Epub ahead of print]
PMID:
22325000
[PubMed - as supplied by publisher]
A Case Report of Multiple Eccrine Hydrocystomas Successfully Treated with Subdermal 1,444-nm Micropulsed Neodymium-Doped Yttrium Aluminum Garnet Laser.
Lee SH, Chung KY, Jung JY.
Dermatol Surg. 2012 Feb 6. doi: 10.1111/j.1524-4725.2011.02276.x. [Epub ahead of print] No abstract available.
PMID:
22309039
[PubMed - as supplied by publisher]
Inlaid Nd-substituted bismuth titanate nanoplates for protein immobilization and Nd-controlled electrochemical properties.
Guo H, Ye C, He H, Chen Z, Hu J, Hu G, Li A.
Biosens Bioelectron. 2012 Jan 16. [Epub ahead of print]
PMID:
22305390
[PubMed - as supplied by publisher]
An overview of clinical and experimental treatment modalities for port wine stains.
Chen JK, Ghasri P, Aguilar G, van Drooge AM, Wolkerstorfer A, Kelly KM, Heger M.
J Am Acad Dermatol. 2012 Feb 2. [Epub ahead of print]
PMID:
22305042
[PubMed - as supplied by publisher]
Evaluating Rare Earth Element Availability: A case with revolutionary demand from clean technologies.
Alonso E, Sherman AM, Wallington TJ, Everson MP, Field FR, Roth R, Kirchain RE.
Environ Sci Technol. 2012 Feb 3. [Epub ahead of print]
PMID:
22304002
[PubMed - as supplied by publisher]
Prevention of posterior capsule opacification with 3 intraocular lens models: a prospective, randomized, long-term clinical trial.
Zemaitiene R, Jasinskas V.
Medicina (Kaunas). 2011;47(11):595-9.
PMID:
22286574
[PubMed - in process]
Ultrasensitive determination of human growth hormone (hGH) with a disposable electrochemical magneto-immunosensor.
Serafín V, Ubeda N, Agüí L, Yáñez-Sedeño P, Pingarrón JM.
Anal Bioanal Chem. 2012 Jan 30. [Epub ahead of print]
PMID:
22286079
[PubMed - as supplied by publisher]
Biosorption and desorption of lanthanum(III) and neodymium(III) in fixed-bed columns with Sargassum sp.: Perspectives for separation of rare earth metals.
Oliveira RC, Guibal E, Garcia O.
Biotechnol Prog. 2012 Jan 24. doi: 10.1002/btpr.1525. [Epub ahead of print]
PMID:
22275117
[PubMed - as supplied by publisher]
Pyogenic Granuloma: Treatment with the 1,064-nm Long-Pulsed Neodymium-Doped Yttrium Aluminum Garnet Laser in 20 Patients.
Hammes S, Kaiser K, Pohl L, Metelmann HR, Enk A, Raulin C.
Dermatol Surg. 2012 Jan 24. doi: 10.1111/j.1524-4725.2012.02344.x. [Epub ahead of print]
PMID:
22272571
[PubMed - as supplied by publisher]
Porous YAG:Nd(3+) Fibers with Excitation and Emission in the Human "NIR Optical Window" as Luminescent Drug Carriers.
Ma Z, Ji H, Tan D, Dong G, Teng Y, Zhou J, Qiu J.
Chemistry. 2012 Feb 27;18(9):2609-16. doi: 10.1002/chem.201101262. Epub 2012 Jan 23.
PMID:
22271350
[PubMed - in process]
Topical eflornithine hydrochloride improves the effectiveness of standard laser hair removal for treating pseudofolliculitis barbae: A randomized, double-blinded, placebo-controlled trial.
Xia Y, Cho S, Howard RS, Maggio KL.
J Am Acad Dermatol. 2012 Jan 6. [Epub ahead of print]
PMID:
22226431
[PubMed - as supplied by publisher]
Comparison of Laser Versus Sclerotherapy in the Treatment of Lower Extremity Telangiectases: A Prospective Study.
Munia MA, Wolosker N, Munia CG, Chao WS, Puech-Leão P.
Dermatol Surg. 2011 Dec 30. doi: 10.1111/j.1524-4725.2011.02226.x. [Epub ahead of print]
PMID:
22221551
[PubMed - as supplied by publisher]
Material Safety Data Sheet
1 Identification of substance
Product details
Trade name Neodymium nitrate
2 Composition/Data on components:
Chemical characterization: Designation: (CAS#)
Neodymium nitrate, hexahydrate (CAS# 16454-60-7), 100%
Identification number(s):
EINECS Number: 233-153-9
3 Hazards identification
Hazard designation:
Xi Irritant
O Oxidising
Information pertaining to particular dangers for man and environment
R 8 Contact with combustible material may cause fire.
R 36/37/38 Irritating to eyes, respiratory system and skin.
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek immediate medical advice.
Information for doctor
The following symptoms may occur: Methaemoglobinaemia
5 Fire fighting measures
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet.
Special hazards caused by the material, its products of combustion or flue gases:
Can be released in case of fire:
Nitrogen oxides (NOx)
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting: Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
Handling
Information for safe handling:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Substance/product can reduce the ignition temperature of flammable substances.
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Store away from flammable substances.
Store away from reducing agents.
Do not store together with acids.
Do not store together with alkalis (caustic solutions).
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with critical values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Breathing equipment: Use breathing protection with high concentrations.
Protection of hands: Impervious gloves
Eye protection:
Safety glasses
Face protection
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Crystalline
Colour: Violet
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: 69-71 ° C
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicable
Inflammability (solid, gaseous)
Contact with combustible material may cause fire.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density Not determined
Solubility in / Miscibility with
Water: at 25 ° C 1529 g/l
pH-value: (200 g/l) at 20 ° C 3.0-4.0
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Materials to be avoided:
Reducing agents, easily oxidized materials
Acids
Bases
Aluminum and aluminum alloys.
Dangerous reactions:
Reacts with reducing agents
Reacts with flammable substances
Dangerous products of decomposition: Nitrous vitriol gases
11 Toxicological information
Acute toxicity: LD/LC50 values that are relevant for classification:
Oral: LD50: 2750 mg/kg (rat)
Primary irritant effect:
on the skin: Irritant for skin and mucous membranes.
on the eye: Irritant effect.
Sensitization: No sensitizing effect known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
14 Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
Code letter and hazard designation of product:
Xi Irritant O Oxidising
Risk phrases:
8 Contact with combustible material may cause fire.
36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases:
17 Keep away from combustible material.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Proud sponsors of Aeromat 2012. Please join us and our customers & co-sponsors Boeing and ATI on
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Neodymium(III) Nitrate Hexahydrate is a highly water soluble crystalline neodymium source for uses compatible with nitrates and lower (acidic) pH. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Primary applications include lasers, glass coloring and tinting, and dielectrics. NdNO3 is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Neodymium is a Block F, Group 3, Period 6 element. The number of electrons in each of Neodymium's shells is 2, 8, 18, 22, 8, 2 and its electronic configuration is [Xe] 4f4 6s2. In its elemental form neodymium's CAS number is 7440-00-8. The neodymium atom has a radius of 181.4.pm and it's Van der Waals radius is 181.pm. Neodymium is the most abundant of the rare earths after cerium and lanthanum. Neodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds
as submicron and nanopowder. Primary
applications include lasers, glass coloring and tinting, dielectrics and, most importantly, as the fundamental basis for neodymium-iron-boron permanent magnets. Neodymium has a strong absorption band centered at 580 nm, which is very close to the human eye's maximum level of sensitivity making it useful in protective lenses for welding goggles. It is also used in CRT displays to enhance contrast between reds and greens and highly valued in glass manufacturing for its attractive purple coloring. Neodymium is included in many formulations of barium titanate, used as dielectric coatings and in multi-layer capacitors essential to electronic equipment. Neodymium was first discovered by Carl Aer von Welsbach in 1885. The name originates from the Greek words 'neos didymos', meaning new twin. See Neodymium research below.
