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Nickel Bromide
NiBr2
Product Product Code Order or Specifications
(2N) 99% Nickel Bromide NI-BR-02 Contact American Elements
(3N) 99.9% Nickel Bromide NI-BR-03 Contact American Elements
(4N) 99.99% Nickel Bromide NI-BR-04 Contact American Elements
(5N) 99.999% Nickel Bromide NI-BR-05 Contact American Elements
Bromide IonNickel Bromide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding carbon disulfide (CS2) and chlorine.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Nickel(Ni) atomic and molecular weight, atomic number and elemental symbolNickel is a Block D, Group 4, Period 4 element. The number of electrons in each of Nickel's shells is 2, 8, 16, 2 and its electronic configuration is [Ar]3d8 4s2. In its elemental form nickel's CAS number is 7440-02-0. Nickel is sometimes found free in nature but is more commonly found in ores. The nickel atom has a radius of 149.pm and it's Van der Waals radius is 163.pm. Nickel and its compounds are considered to be carcinogenic. Nickel carbonyl is a very toxic gas. It is extensively alloyed with iron, chromium, molybdenum, tungsten and other metals produce stainless and other anti-corrosive steel and other corrosion-resistant alloys. It is highly electronically conductive and has many applications as a result. It is the basis of the nickel hydride battery. Most recently, its Nickel Bohr Model conductive properties have Elemental Nickelmade it an ideal component for ceramic anode formulations used in oxygen generation and solid oxide fuel cell applications. Catalytic nickel is used to hydrogenate vegetable oils. Nickel additions to glass and ceramic glazes impart a bright green. It is also used in pigments for this purpose. Nickel information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Nickel was first discovered by Alex Constedt in 1751. The name originates from the German word 'kupfernickel' which means false copper from the illusory copper color of the ore. See Nickel research below.

Formula CAS No. Appearance Molecular Weight
NiBr2 13462-88-9 Green Crystals 218.53
PRODUCT CATALOG Bromide Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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Recent Research & Development for Nickel

  • The Role of a Bilayer Interfacial Phase on Liquid Metal Embrittlement. Luo J, Cheng H, Asl KM, Kiely CJ, Harmer MP. Science. 2011 Sep 23;333(6050):1730-1733. PMID: 21940889 [PubMed - as supplied by publisher]

  • Wettability of carbon nanofiber layers on nickel foils. Pacheco Benito S, Lefferts L. J Colloid Interface Sci. 2011 Aug 26. [Epub ahead of print] PMID: 21939980 [PubMed - as supplied by publisher]

  • The Function of UreB in Klebsiella aerogenes Urease. Carter EL, Boer JL, Farrugia MA, Flugga N, Towns CL, Hausinger RP. Biochemistry. 2011 Sep 22. [Epub ahead of print] PMID: 21939280 [PubMed - as supplied by publisher]

  • Combined Experimental and Theoretical Study on Redox-Active d(8) Metal Dithione-Dithiolato Complexes Showing Molecular Second-Order Nonlinear Optical Activity. Pilia L, Espa D, Barsella A, Fort A, Makedonas C, Marchio` L, Mercuri ML, Serpe A, Mitsopoulou CA, Deplano P. Inorg Chem. 2011 Sep 22. [Epub ahead of print] PMID: 21939192 [PubMed - as supplied by publisher]

  • [Heterogeneity of epidermal cells in relation to nickel accumulation in Alyssum hyperaccumulators]. [No authors listed] Tsitologiia. 2011;53(7):572-9. Russian. PMID: 21938929 [PubMed - in process]

  • Homocysteine metabolism in peripheral blood mononuclear cells: evidence for cystathionine beta-synthase activity in resting state. Katko M, Zavaczki E, Jeney V, Paragh G, Balla J, Varga Z. Amino Acids. 2011 Sep 22. [Epub ahead of print] PMID: 21938399 [PubMed - as supplied by publisher]

  • Microscopic computerized tomographic evaluation of root canal transportation prepared with twisted or ground nickel-titanium rotary instruments. Freire LG, Gavini G, Branco-Barletta F, Sanches-Cunha R, Dos Santos M. Oral Surg Oral Med Oral Pathol Oral Radiol Endod. 2011 Sep 19. [Epub ahead of print] PMID: 21937249 [PubMed - as supplied by publisher]

  • Site-specific immobilization of a (His)6-tagged acetylcholinesterase on nickel nanoparticles for highly sensitive toxicity biosensors. Ganesana M, Istarnboulie G, Marty JL, Noguer T, Andreescu S. Biosens Bioelectron. 2011 Aug 25. [Epub ahead of print] PMID: 21937214 [PubMed - as supplied by publisher]

  • Accumulation of Cu, Pb, Ni and Zn in the halophyte plant Atriplex grown on polluted soil. Kachout SS, Mansoura AB, Mechergui R, Leclerc JC, Rejeb MN, Ouerghi Z. J Sci Food Agric. 2011 Sep 20. doi: 10.1002/jsfa.4581. [Epub ahead of print] PMID: 21935956 [PubMed - as supplied by publisher]

  • Nickel-catalyzed Negishi cross-couplings of 6-chloropurines with organozinc halides at room temperature. Wang DC, Niu HY, Qu GR, Liang L, Wei XJ, Zhang Y, Guo HM. Org Biomol Chem. 2011 Sep 20. [Epub ahead of print] PMID: 21935566 [PubMed - as supplied by publisher]

  • Dipeptide-Based Models of Nickel Superoxide Dismutase: Solvent Effects Highlight a Critical Role to Ni-S Bonding and Active Site Stabilization. Gale EM, Cowart DM, Scott RA, Harrop TC. Inorg Chem. 2011 Sep 20. [Epub ahead of print] PMID: 21932766 [PubMed - as supplied by publisher]

  • A Serendipitous Discovery: Nickel Catalyst for the Cycloaddition of Diynes with Unactivated Nitriles. Kumar P, Prescher S, Louie J. Angew Chem Int Ed Engl. 2011 Sep 20. doi: 10.1002/anie.201104475. [Epub ahead of print] No abstract available. PMID: 21932226 [PubMed - as supplied by publisher]

  • Differential regulation of serine acetyltransferase is involved in nickel hyperaccumulation in thlaspi goesingense. Na G, Salt DE. J Biol Chem. 2011 Sep 19. [Epub ahead of print] PMID: 21930704 [PubMed - as supplied by publisher]

  • Recovery of nickel from spent NiO/Al2O3 catalyst through sulfuric acid leaching, precipitation and solvent extraction. Nazemi MK, Rashchi F. Waste Manag Res. 2011 Sep 18. [Epub ahead of print] PMID: 21930525 [PubMed - as supplied by publisher]

  • New thermodynamic data for CoTiO3, NiTiO3 and CoCO3 based on low-temperature calorimetric measurements. Klemme S, Hermes W, Eul M, Wijbrans CH, Rohrbach A, Pottgen R. Chem Cent J. 2011 Sep 19;5(1):54. [Epub ahead of print] PMID: 21929780 [PubMed - as supplied by publisher]

  • Aortic Valve Replacement in a Patient with Severe Nickel Allergy. Lusini M, Barbato R, Spadaccio C, Chello M. J Card Surg. 2011 Sep 19. doi: 10.1111/j.1540-8191.2011.01320.x. [Epub ahead of print] PMID: 21929741 [PubMed - as supplied by publisher]

  • Nickel skin levels in different occupations and an estimate of the threshold for reacting to a single open application of nickel in nickel-allergic subjects. Gawkrodger DJ, McLeod CW, Dobson K. Br J Dermatol. 2011 Sep 20. doi: 10.1111/j.1365-2133.2011.10644.x. [Epub ahead of print] PMID: 21929529 [PubMed - as supplied by publisher]

  • A current global view of environmental and occupational cancers. Yang M. J Environ Sci Health C Environ Carcinog Ecotoxicol Rev. 2011 Jul;29(3):223-49. PMID: 21929381 [PubMed - in process]

  • Differential biochemical response of rat kidney towards low and high doses of NiCl(2) as revealed by NMR spectroscopy. Tyagi R, Rana P, Gupta M, Khan AR, Bhatnagar D, Bhalla PJ, Chaturvedi S, Tripathi RP, Khushu S. J Appl Toxicol. 2011 Sep 16. doi: 10.1002/jat.1730. [Epub ahead of print] PMID: 21928331 [PubMed - as supplied by publisher]

  • Influence of Operational Parameters and Low Nickel Concentrations on Partial Nitrification in a Submerged Biofilter. Aslan S, Gurbuz B. Appl Biochem Biotechnol. 2011 Sep 17. [Epub ahead of print] PMID: 21927858 [PubMed - as supplied by publisher]

 

Recent Research & Development for Bromides

  • Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids. Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C. Org Lett. 2010 Jan 5. [Epub ahead of print] PMID: 19689116 [PubMed - as supplied by publisher]

  • Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides. Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Science. 2009 Aug 13. [Epub ahead of print] PMID: 19679769 [PubMed - as supplied by publisher]

  • (2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides. Zhang Q, Wang D, Wang X, Ding K. J Org Chem. 2009 Aug 12. [Epub ahead of print] PMID: 19673481 [PubMed - as supplied by publisher]

  • Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides. Vechorkin O, Barmaz D, Proust V, Hu X. J Am Chem Soc. 2009 Aug 11. [Epub ahead of print] PMID: 19670863 [PubMed - as supplied by publisher]

  • Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia. Huang JM, Dong Y. Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28. PMID: 19662260 [PubMed - in process]

  • Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols. Salvi L, Kim JG, Walsh PJ. J Am Chem Soc. 2009 Aug 4. [Epub ahead of print] PMID: 19653691 [PubMed - as supplied by publisher]

  • Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines. Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J. J Comb Chem. 2009 Jul 31. [Epub ahead of print] PMID: 19645499 [PubMed - as supplied by publisher]

  • Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids. del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N. Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29. PMID: 19641822 [PubMed - in process]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies. Snelders DJ, van Koten G, Klein Gebbink RJ. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639941 [PubMed - as supplied by publisher]

  • Can One Predict Changes from S(N)1 to S(N)2 Mechanisms? Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. J Am Chem Soc. 2009 Jul 27. [Epub ahead of print] PMID: 19634906 [PubMed - as supplied by publisher]

  • A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides. Liao Q, Wang Y, Zhang L, Xi C. J Org Chem. 2009 Jul 15. [Epub ahead of print] PMID: 19603753 [PubMed - as supplied by publisher]

  • Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides. Shi L, Chu Y, Knochel P, Mayr H. Org Lett. 2009 Jul 14. [Epub ahead of print] PMID: 19601592 [PubMed - as supplied by publisher]

  • C5-Modified nucleosides exhibiting anticancer activity. Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH. Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21. PMID: 19596579 [PubMed - in process]

  • Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. Vo GD, Hartwig JF. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591470 [PubMed - as supplied by publisher]

  • New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes. Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B. Org Lett. 2009 Jul 2. [Epub ahead of print] PMID: 19572730 [PubMed - as supplied by publisher]

  • The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives. Jo Y, Ju J, Choe J, Song KH, Lee S. J Org Chem. 2009 Jul 2. [Epub ahead of print] PMID: 19572571 [PubMed - as supplied by publisher]

  • Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents. Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH. Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8. PMID: 19557114 [PubMed - in process]

  • A facile route to C2-substituted imidazolium ionic liquids. Ennis E, Handy ST. Molecules. 2009 Jun 19;14(6):2235-45. PMID: 19553895 [PubMed - in process]

  • Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines. McCall WS, Comins DL. Org Lett. 2009 Jul 2;11(13):2940-2. PMID: 19552467 [PubMed - indexed for MEDLINE]

     

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