Nickel Selenide (NiSe) is a crystal grown product generally immediately available in most volumes. Technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Nickel is a Block D, Group 4, Period 4 element. The number of electrons in each of Nickel's shells is 2, 8, 16, 2 and its electronic configuration is [Ar]3d8 4s2. In its elemental form nickel's CAS number is 7440-02-0. Nickel is sometimes found free in nature but is more commonly found in ores. The nickel atom has a radius of 149.pm and it's Van der Waals radius is 163.pm. Nickel and its compounds are considered to be carcinogenic. Nickel carbonyl is a very toxic gas. It is extensively alloyed with iron, chromium, molybdenum, tungsten and other metals produce stainless and other anti-corrosive steel and other corrosion-resistant alloys. It is highly electronically conductive and has many applications as a result. It is the basis of the nickel hydride battery. Most recently, its conductive properties have made it an ideal component for ceramic anode formulations used in oxygen generation and solid oxide fuel cell applications. Catalytic nickel is used to hydrogenate vegetable oils. Nickel additions to glass and ceramic glazes impart a bright green. It is also used in pigments for this purpose. Nickel information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Nickel was first discovered by Alex Constedt in 1751. The name originates from the German word 'kupfernickel' which means false copper from the illusory copper color of the ore. See Nickel research below.
Selenium is a Block P, Group 16, Period 4 element. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electronic configuration is [Ar] 3d10 4s2 4p4. In its elemental form selenium's CAS number is 7782-49-2. The selenium atom has a radius of 116.pm and it's Van der Waals radius is 190.pm. The EPA does not classify selenium as carcinogenic, although selenium sulfide is a probable carcinogen. Selenates and selenites which are compounds of selenium, are highly toxic. Hydrogen selenide gas (SeH2) is the most acutely toxic compound of selenium. Selenium exhibits both photovoltaic action, where light is converted directly into electricity, and photoconductive action, where the electrical resistance decreases with increased illumination. of photocells and exposure meters for photographic use, as well as solar cells. Below its melting point, selenium is a p-type semiconductor and has many uses in electronic and solid-state applications. Selenium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Selenium was first discovered by Jons Berzelius in 1817. The origin of the name Selenium comes from the Greek word "Selênê" meaning moon. See selenium research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
Crystal "pulling" by the Czochaiski method for production of semiconductor materials
Flux growth and gradient freeze
Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
The Role of a Bilayer Interfacial Phase on Liquid Metal Embrittlement.
Luo J, Cheng H, Asl KM, Kiely CJ, Harmer MP.
Science. 2011 Sep 23;333(6050):1730-1733.
PMID:
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Wettability of carbon nanofiber layers on nickel foils.
Pacheco Benito S, Lefferts L.
J Colloid Interface Sci. 2011 Aug 26. [Epub ahead of print]
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The Function of UreB in Klebsiella aerogenes Urease.
Carter EL, Boer JL, Farrugia MA, Flugga N, Towns CL, Hausinger RP.
Biochemistry. 2011 Sep 22. [Epub ahead of print]
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21939280
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Combined Experimental and Theoretical Study on Redox-Active d(8) Metal Dithione-Dithiolato Complexes Showing Molecular Second-Order Nonlinear Optical Activity.
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Inorg Chem. 2011 Sep 22. [Epub ahead of print]
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[Heterogeneity of epidermal cells in relation to nickel accumulation in Alyssum hyperaccumulators].
[No authors listed]
Tsitologiia. 2011;53(7):572-9. Russian.
PMID:
21938929
[PubMed - in process]
Homocysteine metabolism in peripheral blood mononuclear cells: evidence for cystathionine beta-synthase activity in resting state.
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Amino Acids. 2011 Sep 22. [Epub ahead of print]
PMID:
21938399
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Microscopic computerized tomographic evaluation of root canal transportation prepared with twisted or ground nickel-titanium rotary instruments.
Freire LG, Gavini G, Branco-Barletta F, Sanches-Cunha R, Dos Santos M.
Oral Surg Oral Med Oral Pathol Oral Radiol Endod. 2011 Sep 19. [Epub ahead of print]
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Site-specific immobilization of a (His)6-tagged acetylcholinesterase on nickel nanoparticles for highly sensitive toxicity biosensors.
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Biosens Bioelectron. 2011 Aug 25. [Epub ahead of print]
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Accumulation of Cu, Pb, Ni and Zn in the halophyte plant Atriplex grown on polluted soil.
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J Sci Food Agric. 2011 Sep 20. doi: 10.1002/jsfa.4581. [Epub ahead of print]
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Nickel-catalyzed Negishi cross-couplings of 6-chloropurines with organozinc halides at room temperature.
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Org Biomol Chem. 2011 Sep 20. [Epub ahead of print]
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21935566
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Dipeptide-Based Models of Nickel Superoxide Dismutase: Solvent Effects Highlight a Critical Role to Ni-S Bonding and Active Site Stabilization.
Gale EM, Cowart DM, Scott RA, Harrop TC.
Inorg Chem. 2011 Sep 20. [Epub ahead of print]
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21932766
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A Serendipitous Discovery: Nickel Catalyst for the Cycloaddition of Diynes with Unactivated Nitriles.
Kumar P, Prescher S, Louie J.
Angew Chem Int Ed Engl. 2011 Sep 20. doi: 10.1002/anie.201104475. [Epub ahead of print] No abstract available.
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Differential regulation of serine acetyltransferase is involved in nickel hyperaccumulation in thlaspi goesingense.
Na G, Salt DE.
J Biol Chem. 2011 Sep 19. [Epub ahead of print]
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Recovery of nickel from spent NiO/Al2O3 catalyst through sulfuric acid leaching, precipitation and solvent extraction.
Nazemi MK, Rashchi F.
Waste Manag Res. 2011 Sep 18. [Epub ahead of print]
PMID:
21930525
[PubMed - as supplied by publisher]
New thermodynamic data for CoTiO3, NiTiO3 and CoCO3 based on low-temperature calorimetric measurements.
Klemme S, Hermes W, Eul M, Wijbrans CH, Rohrbach A, Pottgen R.
Chem Cent J. 2011 Sep 19;5(1):54. [Epub ahead of print]
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21929780
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Aortic Valve Replacement in a Patient with Severe Nickel Allergy.
Lusini M, Barbato R, Spadaccio C, Chello M.
J Card Surg. 2011 Sep 19. doi: 10.1111/j.1540-8191.2011.01320.x. [Epub ahead of print]
PMID:
21929741
[PubMed - as supplied by publisher]
Nickel skin levels in different occupations and an estimate of the threshold for reacting to a single open application of nickel in nickel-allergic subjects.
Gawkrodger DJ, McLeod CW, Dobson K.
Br J Dermatol. 2011 Sep 20. doi: 10.1111/j.1365-2133.2011.10644.x. [Epub ahead of print]
PMID:
21929529
[PubMed - as supplied by publisher]
A current global view of environmental and occupational cancers.
Yang M.
J Environ Sci Health C Environ Carcinog Ecotoxicol Rev. 2011 Jul;29(3):223-49.
PMID:
21929381
[PubMed - in process]
Differential biochemical response of rat kidney towards low and high doses of NiCl(2) as revealed by NMR spectroscopy.
Tyagi R, Rana P, Gupta M, Khan AR, Bhatnagar D, Bhalla PJ, Chaturvedi S, Tripathi RP, Khushu S.
J Appl Toxicol. 2011 Sep 16. doi: 10.1002/jat.1730. [Epub ahead of print]
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Influence of Operational Parameters and Low Nickel Concentrations on Partial Nitrification in a Submerged Biofilter.
Aslan S, Gurbuz B.
Appl Biochem Biotechnol. 2011 Sep 17. [Epub ahead of print]
PMID:
21927858
[PubMed - as supplied by publisher]
Toenail selenium status and the risk of Barrett's esophagus: the Netherlands Cohort Study.
Steevens J, Schouten LJ, Driessen AL, Huysentruyt CJ, Keulemans YC, Goldbohm RA, van den Brandt PA.
Cancer Causes Control. 2010 Oct 10. [Epub ahead of print]PMID: 20936529 [PubMed - as supplied by publisher]Related citations
Promotion of Growth in Mungbean (Phaseolus aureus Roxb.) by Selenium is Associated with Stimulation of Carbohydrate Metabolism.
Malik JA, Kumar S, Thakur P, Sharma S, Kaur N, Kaur R, Pathania D, Bhandhari K, Kaushal N, Singh K, Srivastava A, Nayyar H.
Biol Trace Elem Res. 2010 Oct 9. [Epub ahead of print]PMID: 20936436 [PubMed - as supplied by publisher]Related citations
Transition metal chemistry of cyclodiphosphanes containing phosphine and amide-phosphine functionalities: Formation of a stable dipalladium(II) complex containing a Pd-P s-bond.
Balakrishna MS, Venkateswaran R, Mague JT.
Dalton Trans. 2010 Oct 8. [Epub ahead of print]PMID: 20936211 [PubMed - as supplied by publisher]Related citations
Associations between blood metals and fecundity among women residing in New York State.
Bloom MS, Louis GM, Sundaram R, Kostyniak PJ, Jain J.
Reprod Toxicol. 2010 Oct 6. [Epub ahead of print]PMID: 20933593 [PubMed - as supplied by publisher]Related citations
The protective role of selenium in recalcitrant Acer saccharium L. seeds subjected to desiccation.
Pukacka S, Ratajczak E, Kalemba E.
J Plant Physiol. 2010 Oct 6. [Epub ahead of print]PMID: 20933296 [PubMed - as supplied by publisher]Related citations
Trace element concentrations in nesting flatback turtles (Natator depressus) from Curtis Island, Queensland, Australia.
Ikonomopoulou MP, Olszowy H, Limpus C, Francis R, Whittier J.
Mar Environ Res. 2010 Sep 25. [Epub ahead of print]PMID: 20933265 [PubMed - as supplied by publisher]Related citations
Correlation between serum selenium level and febrile seizures.
Mahyar A, Ayazi P, Fallahi M, Javadi A.
Pediatr Neurol. 2010 Nov;43(5):331-4.PMID: 20933176 [PubMed - in process]Related citations
Anti-Tumor Activity of Aloe vera Against DMBA/Croton Oil-Induced Skin Papillomagenesis in Swiss Albino Mice.
Saini M, Goyal PK, Chaudhary G.
J Environ Pathol Toxicol Oncol. 2010;29(2):127-35.PMID: 20932247 [PubMed - in process]Related citations
Aluminosilicate Relatives: Chalcogenoaluminogermanates Rb(3)(AlQ(2))(3)(GeQ(2))(7) (Q = S, Se).
Rothenberger A, Shafaei-Fallah M, Kanatzidis MG.
Inorg Chem. 2010 Oct 8. [Epub ahead of print]PMID: 20932019 [PubMed - as supplied by publisher]Related citations
A Nutrient Approach to Prostate Cancer Prevention: The Selenium and Vitamin E Cancer Prevention Trial (SELECT).
Dunn BK, Richmond ES, Minasian LM, Ryan AM, Ford LG.
Nutr Cancer. 2010 Oct;62(7):896-918.PMID: 20924966 [PubMed - in process]Related citations
Serum levels of selenium in patients with breast cancer before and after treatment of external beam radiotherapy.
Franca CA, Nogueira CR, Ramalho A, Carvalho AC, Vieira SL, Penna AB.
Ann Oncol. 2010 Oct 5. [Epub ahead of print]PMID: 20924074 [PubMed - as supplied by publisher]Related citations
Kenji Soda--researching enzymes with the spirit of an alpinist.
Yoshimura T, Mihara H, Ohshima T, Tanizawa K.
J Biochem. 2010 Oct;148(4):371-9.PMID: 20924059 [PubMed - in process]Related citations
Inhibitory effect of arsenic on aerobic gut flora in rat.
Choudhry ZK, Misbahuddin M, Hosain AK, Saleh AA.
Bangladesh Med Res Counc Bull. 2009 Dec;35(3):79-83.PMID: 20922909 [PubMed - in process]Related citations
[Endemic and biogeochemical features of the territory of Chuvash Republic]
[No authors listed]
Vestn Ross Akad Med Nauk. 2010;(8):40-6. Russian. PMID: 20922843 [PubMed - in process]Related citations
Interaction of uranyl with Se(IV) and Se(VI) in aqueous acid solutions by means of capillary electrophoresis.
Sladkov V.
Electrophoresis. 2010 Oct 4. [Epub ahead of print]PMID: 20922762 [PubMed - as supplied by publisher]Related citations
Ensemble Modeling Coupled with Six Element Concentrations in Human Blood for Cancer Diagnosis.
Chen H, Tan C, Wu T.
Biol Trace Elem Res. 2010 Oct 5. [Epub ahead of print]PMID: 20922500 [PubMed - as supplied by publisher]Related citations
Use of dietary vitamin E and selenium (Se) to increase the shelf life of modified atmosphere packaged light lamb meat.
Ripoll G, Joy M, Muñoz F.
Meat Sci. 2010 Sep 18. [Epub ahead of print]PMID: 20920835 [PubMed - as supplied by publisher]Related citations
Impacts of maternal selenium and nutritional level on growth, adiposity, and glucose tolerance in female offspring in sheep.
Vonnahme KA, Luther JS, Reynolds LP, Hammer CJ, Carlson DB, Redmer DA, Caton JS.
Domest Anim Endocrinol. 2010 Nov;39(4):240-8. Epub 2010 Jul 25.PMID: 20920781 [PubMed - in process]Related citations
Mutations disrupting selenocysteine formation cause progressive cerebello-cerebral atrophy.
Agamy O, Ben Zeev B, Lev D, Marcus B, Fine D, Su D, Narkis G, Ofir R, Hoffmann C, Leshinsky-Silver E, Flusser H, Sivan S, Söll D, Lerman-Sagie T, Birk OS.
Am J Hum Genet. 2010 Oct 8;87(4):538-44.PMID: 20920667 [PubMed - in process]Related citations
Developmental toxicity of selenium to Dolly Varden char (Salvelinus malma).
McDonald BG, Debruyn AM, Elphick JR, Davies M, Bustard D, Chapman PM.
Environ Toxicol Chem. 2010 Aug 3. [Epub ahead of print]PMID: 20891017 [PubMed - as supplied by publisher]Related citations