Palladium Trifluoromethanesulfonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Dysprosium Trifluoromethanesulfonate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and dehydrogenation catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
Synonyms for Palladium Trifluoromethanesulfonate Include:
Palladium(2+) bis(trifluoromethanesulfonate)
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Coking- and sintering-resistant palladium catalysts achieved through
atomic layer deposition.
Lu J, Fu B, Kung MC, Xiao G, Elam JW, Kung HH, Stair PC.
Science. 2012 Mar 9;335(6073):1205-8.
PMID:
22403386
[PubMed - in process]
Palladium-catalyzed S-benzylation of unprotected mercaptobenzoic acid with
benzyl alcohols in water.
Hikawa H, Yokoyama Y.
Org Biomol Chem. 2012 Mar 8. [Epub ahead of print]
PMID:
22402746
[PubMed - as supplied by publisher]
Kinetics of the sulfur oxidation on palladium: A combined in situ x-ray
photoelectron spectroscopy and density-functional study.
Gotterbarm K, Luckas N, Ho?fert O, Lorenz MP, Streber R, Papp C, Vin~es F,
Steinru?ck HP, Go?rling A.
J Chem Phys. 2012 Mar 7;136(9):094702.
PMID:
22401463
[PubMed - as supplied by publisher]
Structure and magnetic properties of nanostructured Pd-Fe thin films
produced by pulse electrodeposition.
Strukova GK, Strukov GV, Bozhko SI, Kabanov YP, Shmytko IM, Mazilkin AA,
Sobolev NA, Zhiteytsev ER, Sukhanov AA, Voronkova VK, Tagirov LR.
J Nanosci Nanotechnol. 2011 Oct;11(10):8907-11.
PMID:
22400279
[PubMed - in process]
Microbial synthesis of core/shell gold/palladium nanoparticles for
applications in green chemistry.
Deplanche K, Merroun ML, Casadesus M, Tran DT, Mikheenko IP, Bennett JA, Zhu
J, Jones IP, Attard GA, Wood J, Selenska-Pobell S, Macaskie LE.
J R Soc Interface. 2012 Mar 7. [Epub ahead of print]
PMID:
22399790
[PubMed - as supplied by publisher]
Pd(ii)-catalyzed direct C5-arylation of azole-4-carboxylates through
double C-H bond cleavage.
Li Z, Ma L, Xu J, Kong L, Wu X, Yao H.
Chem Commun (Camb). 2012 Mar 8. [Epub ahead of print]
PMID:
22399150
[PubMed - as supplied by publisher]
Palladium(ii) thiocarboxamide complexes: synthesis, characterisation and
application to catalytic Suzuki coupling reactions.
Sindhuja E, Ramesh R, Liu Y.
Dalton Trans. 2012 Mar 8. [Epub ahead of print]
PMID:
22399145
[PubMed - as supplied by publisher]
Effects of a catalytic converter on PCDD/F, chlorophenol and PAH emissions
in residential wood combustion.
Kaivosoja T, Virén A, Tissari J, Ruuskanen J, Tarhanen J, Sippula O, Jokiniemi
J.
Chemosphere. 2012 Mar 5. [Epub ahead of print]
PMID:
22397840
[PubMed - as supplied by publisher]
Engineering Biogenic Magnetite for Sustained Cr(VI) Remediation in Flow-
through Systems.
Crean DE, Coker VS, van der Laan G, Lloyd JR.
Environ Sci Technol. 2012 Mar 7. [Epub ahead of print]
PMID:
22397548
[PubMed - as supplied by publisher]
Palladium-Catalyzed N-Arylation of 2-Aminothiazoles.
McGowan MA, Henderson JL, Buchwald SL.
Org Lett. 2012 Mar 6. [Epub ahead of print]
PMID:
22394197
[PubMed - as supplied by publisher]
Generation of Indeno[1,2-c]pyrroles via a Pd-Catalyzed Reaction of 2-
Alkynylbromobenzene with Propargylic Sulfonamide.
Luo Y, Wu J.
Org Lett. 2012 Mar 5. [Epub ahead of print]
PMID:
22390224
[PubMed - as supplied by publisher]
Heck-Type Cross-Dehydrogenative Coupling Reactions of Indolizines at the
3-Position with Electron-Deficient Alkenes through Palladium-Catalyzed C?H
Activation.
Hu H, Liu Y, Zhong H, Zhu Y, Wang C, Ji M.
Chem Asian J. 2012 Mar 2. doi: 10.1002/asia.201101050. [Epub ahead of print]
PMID:
22389289
[PubMed - as supplied by publisher]
Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed
Silylation of Terminal Olefins: A Silyl-Heck Reaction.
McAtee JR, Martin SE, Ahneman DT, Johnson KA, Watson DA.
Angew Chem Int Ed Engl. 2012 Mar 1. doi: 10.1002/anie.201200060. [Epub ahead
of print]
PMID:
22383447
[PubMed - as supplied by publisher]
Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi
Pincerlike Arene to Palladium.
Wang W, Inoue S, Irran E, Driess M.
Angew Chem Int Ed Engl. 2012 Mar 1. doi: 10.1002/anie.201200632. [Epub ahead
of print]
PMID:
22383113
[PubMed - as supplied by publisher]
MOFs as multifunctional catalysts: One-pot synthesis of menthol from
citronellal over a bifunctional MIL-101 catalyst.
Cirujano FG, Llabrés I Xamena FX, Corma A.
Dalton Trans. 2012 Mar 2. [Epub ahead of print]
PMID:
22382815
[PubMed - as supplied by publisher]
A facile route for preparing a mesoporous palladium coordination polymer
as a recyclable heterogeneous catalyst.
Zhang S, Liu Q, Shen M, Hu B, Chen Q, Li H, Amoureux JP.
Dalton Trans. 2012 Mar 1. [Epub ahead of print]
PMID:
22382505
[PubMed - as supplied by publisher]
Development of palladium-catalyzed transformations using propargylic
compounds.
Yoshida M.
Chem Pharm Bull (Tokyo). 2012;60(3):285-99.
PMID:
22382407
[PubMed - in process]
Palladium-Catalyzed Decarboxylative Coupling of Quinolinone-3-Carboxylic
Acids and Related Heterocyclic Carboxylic Acids with (Hetero)aryl Halides.
Messaoudi S, Brion JD, Alami M.
Org Lett. 2012 Mar 1. [Epub ahead of print]
PMID:
22381127
[PubMed - as supplied by publisher]
Elemental Release from CoCr and NiCr Alloys Containing Palladium.
Beck KA, Sarantopoulos DM, Kawashima I, Berzins DW.
J Prosthodont. 2012 Feb;21(2):88-93. doi: 10.1111/j.1532-849X.2011.00800.x.
PMID:
22380645
[PubMed - in process]
Self-assembly of a sulphur-terminated graphene nanoribbon within a single-walled carbon nanotube.
Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC, Chamberlain TW, Rance GA, Kuganathan N, Biskupek J, Kaiser U, Khlobystov AN.
Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3082. [Epub ahead of print]
PMID:
21822259
[PubMed - as supplied by publisher]
Crystallization and preliminary X-ray analysis of the yeast tRNA-thiouridine modification protein 1 (Tum1p).
Qiu R, Wang F, Liu M, Yang Z, Wu T, Ji C.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Aug 1;67(Pt 8):953-5. Epub 2011 Jul 27.
PMID:
21821903
[PubMed - in process]
Characterization of Bacillus thuringiensis L-isoleucine dioxygenase toward the production of useful amino acids.
Hibi M, Kawashima T, Kodera T, Smirnov SV, Sokolov PM, Sugiyama M, Shimizu S, Yokozeki K, Ogawa J.
Appl Environ Microbiol. 2011 Aug 5. [Epub ahead of print]
PMID:
21821743
[PubMed - as supplied by publisher]
Characterization of the sulfurtransferase family from Oryza sativa L.
Guretzki S, Papenbrock J.
Plant Physiol Biochem. 2011 Jul 23. [Epub ahead of print]
PMID:
21821426
[PubMed - as supplied by publisher]
Development of a small-scale bioreactor method to monitor the molecular diversity and environmental impacts of bacterial biofilm communities from an acid mine drainage impacted creek.
Cole M, Wrubel J, Henegan P, Janzen C, Holt J, Tobin T.
J Microbiol Methods. 2011 Jul 28. [Epub ahead of print]
PMID:
21821067
[PubMed - as supplied by publisher]
In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent-solute interaction and its activity toward adsorptive desulfurization of gas oil.
Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A.
J Hazard Mater. 2011 Jul 6. [Epub ahead of print]
PMID:
21820806
[PubMed - as supplied by publisher]
Stearoyl-CoA desaturase is an essential enzyme for the parasitic protist Trypanosoma brucei.
Alloatti A, Gupta S, Gualdrón-López M, Nguewa PA, Altabe SG, Deumer G, Wallemacq P, Michels PA, Uttaro AD.
Biochem Biophys Res Commun. 2011 Jul 28. [Epub ahead of print]
PMID:
21820408
[PubMed - as supplied by publisher]
The use of multi-element stable isotope analysis to monitor the origin of chondroitin sulfates.
Thomas F, Jamin E, Shimoo K, Nagao J, Osaki Y, Granier C.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2533-7. doi: 10.1002/rcm.5159.
PMID:
21818814
[PubMed - in process]
Sulphur isotopes in animal hair track distance to sea.
Zazzo A, Monahan FJ, Moloney AP, Green S, Schmidt O.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2371-8. doi: 10.1002/rcm.5131.
PMID:
21818798
[PubMed - in process]
Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-Like Molecules with Metal-Metal Multiple Bonds.
Fang W, He Q, Tan ZF, Liu CY, Lu X, Murillo CA.
Chemistry. 2011 Aug 4. doi: 10.1002/chem.201003693. [Epub ahead of print]
PMID:
21818792
[PubMed - as supplied by publisher]
Rhodovulum phaeolacus sp. nov. a phototrophic alphaproteobacterium isolated from a brown pond.
Venkata Naga Satya Lakshmi K, Sasikala C, Venkata Ramana V, Veera Venkata Ramaprasad E, Venkata Ramana C.
J Gen Appl Microbiol. 2011;57(3):145-51.
PMID:
21817826
[PubMed - in process]
Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources.
Wyman CE, Balan V, Dale BE, Elander RT, Falls M, Hames B, Holtzapple MT, Ladisch MR, Lee YY, Mosier N, Pallapolu VR, Shi J, Thomas SR, Warner RE.
Bioresour Technol. 2011 Jun 21. [Epub ahead of print]
PMID:
21816612
[PubMed - as supplied by publisher]
Target loads of atmospheric sulfur deposition for the protection and recovery of acid-sensitive streams in the Southern Blue Ridge Province.
Sullivan TJ, Cosby BJ, Jackson WA.
J Environ Manage. 2011 Aug 2. [Epub ahead of print]
PMID:
21816535
[PubMed - as supplied by publisher]
Differential effects of a post-anthesis fertilizer regimen on the wheat flour proteome determined by quantitative 2-DE.
Altenbach SB, Tanaka CK, Hurkman WJ, Whitehand LC, Vensel WH, Dupont FM.
Proteome Sci. 2011 Aug 4;9(1):46. [Epub ahead of print]
PMID:
21816081
[PubMed - as supplied by publisher]
Comparative toxicity of arsenic metabolites in human bladder cancer EJ-1 cells.
Naranmandura H, Michael CW, Xu S, Lee J, Leslie E, Weinfeld M, Le XC.
Chem Res Toxicol. 2011 Aug 4. [Epub ahead of print]
PMID:
21815631
[PubMed - as supplied by publisher]
The Effects of Different Garlic-derived Allyl Sulfides on Peroxidative Processes and Anaerobic Sulfur Metabolism in Mouse Liver.
Iciek MB, Kowalczyk-Pachel D, Kwiecien I, Dudek MB.
Phytother Res. 2011 Aug 4. doi: 10.1002/ptr.3572. [Epub ahead of print]
PMID:
21815229
[PubMed - as supplied by publisher]
A combined model of hepatic polyamine and sulfur amino acid metabolism to analyze S-adenosyl methionine availability.
Reyes-Palomares A, Montañez R, Sánchez-Jiménez F, Medina MA.
Amino Acids. 2011 Aug 4. [Epub ahead of print]
PMID:
21814788
[PubMed - as supplied by publisher]
Microbial gene functions enriched in the Deepwater Horizon deep-sea oil plume.
Lu Z, Deng Y, Van Nostrand JD, He Z, Voordeckers J, Zhou A, Lee YJ, Mason OU, Dubinsky EA, Chavarria KL, Tom LM, Fortney JL, Lamendella R, Jansson JK, D'haeseleer P, Hazen TC, Zhou J.
ISME J. 2011 Aug 4. doi: 10.1038/ismej.2011.91. [Epub ahead of print]
PMID:
21814288
[PubMed - as supplied by publisher]
1,1'-(3-Methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a Building Block in Heterocyclic Synthesis. Novel Synthesis of Some Pyrazole and Pyrimidine Derivatives.
Mabkhot YN, Al-Majid AM, Barakat A, Alshahrani S, Siddiqui Y.
Molecules. 2011 Aug 3;16(8):6502-11.
PMID:
21814162
[PubMed - in process]
Towards the Growth of an Aligned Single-Layer MoS2 Film.
Kim D, Sun D, Lu W, Cheng Z, Zhu Y, Le D, Rahman TS, Bartels L.
Langmuir. 2011 Aug 3. [Epub ahead of print]
PMID:
21812475
[PubMed - as supplied by publisher]
Proud sponsors of Aeromat 2012. Please join us and our customers & co-sponsors Boeing and ATI on
June 18-20, 2012
in Charlotte, North Carolina
metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Dysprosium Trifluoromethanesulfonate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and 
dehydrogenation
catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine 
and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
