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Palladium Phosphide
High Purity PdP
Product Product Code Order or Specifications
(5N) 99.999% Palladium Phosphide Powder PD-P-05-P Contact American Elements
(5N) 99.999% Palladium Phosphide Ingot PD-P-05-I Contact American Elements
(5N) 99.999% Palladium Phosphide Chunk PD-P-05-CK Contact American Elements
(5N) 99.999% Palladium Phosphide Lump PD-P-05-L Contact American Elements
(5N) 99.999% Palladium Phosphide Sputtering Target PD-P-05-ST Contact American Elements
(5N) 99.999% Palladium Phosphide Wafer PD-P-05-WSX Contact American Elements
Phosphide IonPalladium Phosphide is a semiconductor used in high power, high frequency applications and in laser diodes.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Palladium(Pd) atomic and molecular weight, atomic number and elemental symbolPalladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and Elemental PalladiumdehydrogenationPalladium Bohr Model catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.

Phosphorus(P) atomic and molecular weight, atomic number and elemental symbolPhosphorus Bohr ModelPhosphorus is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. In its elemental form Phosphorus's CAS number is 7723-14-0. The Phosphorus atom has a radius of 110.5.pm and it's Van der Waals radius is 180.pm. Although white phosphorus is very toxic, red phosphorus is not considered toxic. Phosphorus information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:

  • Crystal "pulling" by the Czochaiski method for production of semiconductor materials
  • Flux growth and gradient freeze
  • Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
PRODUCT CATALOG News Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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Recent Research & Development for Palladium

  • PET study using [(11)C]FTIMD with ultra-high specific activity to evaluate I(2)-imidazoline receptors binding in rat brains. Kawamura K, Kimura Y, Yui J, Wakizaka H, Yamasaki T, Hatori A, Kumata K, Fujinaga M, Yoshida Y, Ogawa M, Nengaki N, Fukumura T, Zhang MR. Nucl Med Biol. 2011 Sep 27. [Epub ahead of print] PMID: 21958848 [PubMed - as supplied by publisher]

  • Titanocene-Phosphine Derivatives as Precursors to Cytotoxic Heterometallic TiAu(2) and TiM (M = Pd, Pt) Compounds. Studies of Their Interactions with DNA. González-Pantoja JF, Stern M, Jarzecki AA, Royo E, Robles-Escajeda E, Varela-Ramírez A, Aguilera RJ, Contel M. Inorg Chem. 2011 Sep 29. [Epub ahead of print] PMID: 21958150 [PubMed - as supplied by publisher]

  • Convenient and General Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Amines. Wu XF, Neumann H, Beller M. Angew Chem Int Ed Engl. 2011 Sep 28. doi: 10.1002/anie.201104653. [Epub ahead of print] No abstract available. PMID: 21957031 [PubMed - as supplied by publisher]

  • A Convenient and General Palladium-Catalyzed Carbonylative Coupling for the Synthesis of 2-Arylbenzoxazinones. Wu XF, Schranck J, Neumann H, Beller M. Chemistry. 2011 Sep 28. doi: 10.1002/chem.201102254. [Epub ahead of print] No abstract available. PMID: 21956858 [PubMed - as supplied by publisher]

  • Palladium Nanoparticles Encapsulated in Metal-Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles. Huang Y, Lin Z, Cao R. Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101705. [Epub ahead of print] PMID: 21956646 [PubMed - as supplied by publisher]

  • Palladium-Catalyzed Pentannulation of Polycyclic Aromatic Hydrocarbons. Lütke Eversloh C, Avlasevich Y, Li C, Müllen K. Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101126. [Epub ahead of print] PMID: 21956345 [PubMed - as supplied by publisher]

  • Curious Results with Palladium- and Platinum-Carrying Polymers in Mass Cytometry Bioassays and an Unexpected Application as a Dead Cell Stain. Majonis D, Ornatsky O, Kinach R, Winnik MA. Biomacromolecules. 2011 Sep 28. [Epub ahead of print] PMID: 21955116 [PubMed - as supplied by publisher]

  • Palladium Catalyzed Stereoselective C-Glycosylation of Glycals with Enol Triflates. Bai Y, Leow M, Zeng J, Liu XW. Org Lett. 2011 Sep 28. [Epub ahead of print] PMID: 21954934 [PubMed - as supplied by publisher]

  • Palladium-Catalyzed Mono-N-allylation of Unprotected Anthranilic Acids with Allylic Alcohols in Aqueous Media. Hikawa H, Yokoyama Y. J Org Chem. 2011 Sep 29. [Epub ahead of print] PMID: 21919524 [PubMed - as supplied by publisher]

  • Twin Plane Decoration of Silver Nanorods with Palladium by Galvanic Exchange at a Controlled Rate. Slawinski GW, Ivanova OS, Zamborini FP. Langmuir. 2011 Sep 28. [Epub ahead of print] PMID: 21916478 [PubMed - as supplied by publisher]

  • Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via ?(3)-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization. Peng B, Zhang S, Yu X, Feng X, Bao M. Org Lett. 2011 Oct 7;13(19):5402-5. Epub 2011 Sep 13. PMID: 21910509 [PubMed - in process]

  • Azadipyrromethene-Based Conjugated Oligomers with Near-IR Absorption and High Electron Affinity. Gao L, Senevirathna W, Sauvé G. Org Lett. 2011 Oct 7;13(19):5354-7. Epub 2011 Sep 12. PMID: 21910458 [PubMed - in process]

  • Palladium-catalyzed approach to stereodefined ten-membered cycles from 1,5-bisallenes. Cheng J, Jiang X, Ma S. Org Lett. 2011 Oct 7;13(19):5200-3. Epub 2011 Sep 12. PMID: 21910412 [PubMed - in process]

  • New Heteroannulation Reactions of N-Alkoxybenzamides by Pd(II) Catalyzed C-H Activation. Wrigglesworth JW, Cox B, Lloyd-Jones GC, Booker-Milburn KI. Org Lett. 2011 Oct 7;13(19):5326-9. Epub 2011 Sep 12. PMID: 21910404 [PubMed - in process]

  • Pd(0)-catalyzed iodoalkynation of norbornene scaffolds: the remarkable solvent effect on reaction pathway. Liu H, Chen C, Wang L, Tong X. Org Lett. 2011 Oct 7;13(19):5072-5. Epub 2011 Sep 12. PMID: 21910403 [PubMed - in process]

  • Palladium Catalyzed 1,8-Conjugate Addition to Heptafulvene via Bis-?-allyl Palladium Complexes. George SC, Thulasi S, Anas S, Radhakrishnan KV, Yamamoto Y. Org Lett. 2011 Oct 7;13(19):4984-7. Epub 2011 Sep 7. PMID: 21899322 [PubMed - in process]

  • Hydride formation in single palladium and magnesium nanoparticles studied by nanoplasmonic dark-field scattering spectroscopy. Shegai T, Langhammer C. Adv Mater. 2011 Oct 11;23(38):4409-14. doi: 10.1002/adma.201101976. Epub 2011 Sep 5. No abstract available. PMID: 21898608 [PubMed - in process]

  • Cross-coupling of mesylated phenol derivatives with potassium cyclopropyltrifluoroborate. Molander GA, Beaumard F, Niethamer TK. J Org Chem. 2011 Oct 7;76(19):8126-30. Epub 2011 Sep 2. PMID: 21888362 [PubMed - in process]

  • Palladium-catalyzed regioselective C-s bond cleavage of thiophenes. Huang H, Li J, Lescop C, Duan Z. Org Lett. 2011 Oct 7;13(19):5252-5. Epub 2011 Sep 2. PMID: 21888338 [PubMed - in process]

  • Substrate-Directable Heck Reactions with Arenediazonium Salts. The Regio- and Stereoselective Arylation of Allylamine Derivatives and Applications in the Synthesis of Naftifine and Abamines. Prediger P, Barbosa LF, Ge?nisson Y, Correia CR. J Org Chem. 2011 Oct 7;76(19):7737-7749. Epub 2011 Sep 15. PMID: 21877731 [PubMed - as supplied by publisher]

Recent Research & Development for Phosphorus

  • Consumption of whole grains is associated with improved diet quality and nutrient intake in children and adolescents: the National Health and Nutrition Examination Survey 1999-2004. O'Neil CE, Nicklas TA, Zanovec M, Cho SS, Kleinman R. Public Health Nutr. 2010 Oct 6:1-9. [Epub ahead of print] PubMed PMID: 20923597.

  • Chemical and microbiological changes during vermicomposting of coffee pulp using exotic (Eudrilus eugeniae) and native earthworm (Perionyx ceylanesis) species. Raphael K, Velmourougane K. Biodegradation. 2010 Oct 5. [Epub ahead of print] PubMed PMID: 20922463.

  • Synthesis, structure, and reductive elimination in the series Tp'Rh(PR(3))(Ar(F))H; Determination of rhodium-carbon bond energies of fluoroaryl substituents. Tanabe T, Brennessel WW, Clot E, Eisenstein O, Jones WD. Dalton Trans. 2010 Oct 5. [Epub ahead of print] PubMed PMID: 20924525.

  • Nutrient concentrations in Maryland non-tidal streams. Morgan RP 2nd, Kline KM. Environ Monit Assess. 2010 Oct 5. [Epub ahead of print] PubMed PMID: 20890788.

  • Hereditary disorders of renal phosphate wasting. Alizadeh Naderi AS, Reilly RF; Medscape. Nat Rev Nephrol. 2010 Oct 5. [Epub ahead of print] PubMed PMID: 20924400.

  • New Synthesis of 3-Trifluoromethylpyrroles by Condensation of Mesoionic 4-Trifluoroacetyl-1,3-oxazolium-5-olates with Phosphorus Ylides. Saijo R, Hagimoto Y, Kawase M. Org Lett. 2010 Oct 5. [Epub ahead of print] PubMed PMID: 20923166.

  • Structural and electronic properties of luminescent copper(i) halide complexes of bis[2-(diphenylphosphano)phenyl] ether (DPEphos). Crystal structure of [CuCl(DPEphos)(dmpymtH]. Aslanidis P, Cox PJ, Tsipis AC. Dalton Trans. 2010 Oct 4. [Epub ahead of print] PubMed PMID: 20922239.

  • Changes in Microbial Community Structure and Function of Drinking Water Treatment Bioreactors Upon Phosphorus Addition. Li X, Upadhyaya G, Yuen W, Brown J, Morgenroth E, Raskin L. Appl Environ Microbiol. 2010 Oct 1. [Epub ahead of print] PubMed PMID: 20889793.

  • Determination of a set of surrogate parameters to assess urban stormwater quality. Miguntanna NS, Egodawatta P, Kokot S, Goonetilleke A. Sci Total Environ. 2010 Oct 1. [Epub ahead of print] PubMed PMID: 20888615.

  • A review on the effects of environmental conditions on growth and toxin production of Ostreopsis ovata. Pistocchi R, Pezzolesi L, Guerrini F, Vanucci S, Dell'aversano C, Fattorusso E. Toxicon. 2010 Oct 1. [Epub ahead of print] PubMed PMID: 20920514.

  • Tenofovir-associated severe bone pain: I cannot walk! Jhaveri MA, Mawad HW, Thornton AC, Mullen NW, Greenberg RN. J Int Assoc Physicians AIDS Care (Chic Ill). 2010 Sep-Oct;9(5):328-34. PubMed PMID: 20923957.

  • Characteristics of contaminants in water and sediment of a constructed wetland treating piggery wastewater effluent. Lee S, Maniquiz MC, Kim LH. J Environ Sci (China). 2010;22(6):940-5. PubMed PMID: 20923110.

  • Effect of a seasonal diffuse pollution migration on natural organic matter behavior in a stratified dam reservoir. Yu SJ, Lee JY, Ha SR. J Environ Sci (China). 2010;22(6):908-14. PubMed PMID: 20923105.

  • Water-saving irrigation of paddy field to reduce nutrient runoff. Hitomi T, Iwamoto Y, Miura A, Hamada K, Takaki K, Shiratani E. J Environ Sci (China). 2010;22(6):885-91. PubMed PMID: 20923101.

  • Scenario analysis for reduction of pollutant load discharged from a watershed by recycling of treated water for irrigation. Shiratani E, Munakata Y, Yoshinaga I, Kubota T, Hamada K, Hitomi T. J Environ Sci (China). 2010;22(6):878-84. PubMed PMID: 20923100.

  • Modeling the effects of constructed wetland on nonpoint source pollution control and reservoir water quality improvement. Ham J, Yoon CG, Kim HJ, Kim HC. J Environ Sci (China). 2010;22(6):834-9. PubMed PMID: 20923093.

  • Evaluation of non-point source pollution reduction by applying best management practices using a SWAT model and QuickBird high resolution satellite imagery. Lee M, Park G, Park M, Park J, Lee J, Kim S. J Environ Sci (China). 2010;22(6):826-33. PubMed PMID: 20923092.

  • Understanding nutrient build-up on urban road surfaces. Miguntanna NP, Goonetilleke A, Egodowatta P, Kokot S. J Environ Sci (China). 2010;22(6):806-12. PubMed PMID: 20923089.

  • Monitoring of non-point source pollutants load from a mixed forest land use. Yoon SW, Chung SW, Oh DG, Lee JW. J Environ Sci (China). 2010;22(6):801-5. PubMed PMID: 20923088.

  • [Primary hyperparathyroidism: Postoperative long-term evolution.]. Spivacow FR, Martínez C, Polonsky A. Medicina (B Aires). 2010;70(5):408-14. Spanish. PubMed PMID: 20920956.

     

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