1,1'-Bis(di-tert-butylphosphino)ferrocene palladium Dichloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Iron is a Block D, Group 8, Period 4 element. The number of electrons in each of Iron's shells is 2, 8, 14, 2 and its electronic configuration is [Ar] 3d6 4s2. In its elemental form iron's CAS number is 7439-89-6. The iron atom has a radius of 124.1.pm and it's Van der Waals radius is 200.pm. Iron is not toxic. Iron is the most commonly used metal for commercial applications due to its hardness, historical availability and low cost. Once used on its own, it is now alloyed with nickel and other elements to produce steel and other high strength, non-corrosive structural metals. Iron as a metal and as its many compounds has numerous uses. It is a primary colorant in glass and ceramics. It is a catalyst. It is the basis for low grade magnets and because of its magnetic properties is used extensively in memory tape. Recent applications for Iron nanoparticles include in water treatment of carbon tetrachloride in contaminated groundwater, magnetic data storage and resonance imaging (MRI) and in certain alloy and catalyst applications. Iron can also be introduced into processes using iron foil, pellets, rod and wire by thin film Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Organometallic and Chemical Vapor Deposition (MOCVD) for specific applications such as fuel cells and solar energy. Iron is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Iron was first discovered by Early Man.See Iron research below.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and dehydrogenation catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Combined proteomic and transcriptomic analysis of the response of Bacillus anthracis to oxidative stress.
Pohl S, Tu WY, Aldridge PD, Gillespie C, Hahne H, Mäder U, Read TD, Harwood CR.
Proteomics. 2011 May 23. doi: 10.1002/pmic.201100085. [Epub ahead of print]
PMID:
21726052
[PubMed - as supplied by publisher]
Spectroscopic Characterization of the Isolated Iron-Molybdenum Cofactor (FeMoco) Precursor from the Protein NifEN.
Fay AW, Blank MA, Lee CC, Hu Y, Hodgson KO, Hedman B, Ribbe MW.
Angew Chem Int Ed Engl. 2011 Jul 1. doi: 10.1002/anie.201102724. [Epub ahead of print] No abstract available.
PMID:
21726031
[PubMed - as supplied by publisher]
Conductive carbon tape as a sample platform for microwave-based MALDI MS detection of proteins and phosphoproteins.
Juang YM, Chen CJ, Lai CC.
Anal Bioanal Chem. 2011 Jul 5. [Epub ahead of print]
PMID:
21725904
[PubMed - as supplied by publisher]
Association between heme oxygenase-1 gene promoter polymorphisms and metabolic syndrome in Iranians.
Javanmard SH, Keyhanian K, Loghmani P, Samety AA, Haghdoost F, Rafiei L, Talaei M, Asgari S, Jazi MH, Sarrafzadegan N.
Mol Biol Rep. 2011 Jul 3. [Epub ahead of print]
PMID:
21725851
[PubMed - as supplied by publisher]
Inhibition of tumor growth by recombinant adenovirus containing human lactoferrin through inducing tumor cell apoptosis in mice bearing EMT6 breast cancer.
Wang J, Li Q, Ou Y, Han Z, Li K, Wang P, Zhou S.
Arch Pharm Res. 2011 Jun;34(6):987-95. Epub 2011 Jul 2.
PMID:
21725820
[PubMed - in process]
Thrombin Preconditioning Attenuates Iron-Induced Neuronal Death.
Hu H, Yamashita S, Song S, Hua Y, Keep RF, Xi G.
Acta Neurochir Suppl. 2011;111:259-263.
PMID:
21725765
[PubMed - as supplied by publisher]
Thrombin Preconditioning Reduces Iron-Induced Brain Swelling and Brain Atrophy.
Song S, Hu H, Hua Y, Wang J, Xi G.
Acta Neurochir Suppl. 2011;111:219-223.
PMID:
21725759
[PubMed - as supplied by publisher]
Deferoxamine Affects Heat Shock Protein Expression in Heart after Intracerebral Hemorrhage in Aged Rats.
Hu H, Wang L, Okauchi M, Keep RF, Xi G, Hua Y.
Acta Neurochir Suppl. 2011;111:197-200.
PMID:
21725755
[PubMed - as supplied by publisher]
Deferoxamine Reduces Cavity Size in the Brain After Intracerebral Hemorrhage in Aged Rats.
Hatakeyama T, Okauchi M, Hua Y, Keep RF, Xi G.
Acta Neurochir Suppl. 2011;111:185-190.
PMID:
21725753
[PubMed - as supplied by publisher]
Hemoglobin Expression in Neurons and Glia After Intracerebral Hemorrhage.
He Y, Hua Y, Keep RF, Liu W, Wang MM, Xi G.
Acta Neurochir Suppl. 2011;111:133-137.
PMID:
21725744
[PubMed - as supplied by publisher]
Iron Accumulation and DNA Damage in a Pig Model of Intracerebral Hemorrhage.
Gu Y, Hua Y, He Y, Wang L, Hu H, Keep RF, Xi G.
Acta Neurochir Suppl. 2011;111:123-128.
PMID:
21725742
[PubMed - as supplied by publisher]
Red Blood Cell Lysis and Brain Tissue-Type Transglutaminase Upregulation in a Hippocampal Model of Intracerebral Hemorrhage.
Zhao F, Song S, Liu W, Keep RF, Xi G, Hua Y.
Acta Neurochir Suppl. 2011;111:101-105.
PMID:
21725738
[PubMed - as supplied by publisher]
The theft of host heme by Gram-positive pathogenic bacteria.
Nobles CL, Maresso AW.
Metallomics. 2011 Jul 4. [Epub ahead of print]
PMID:
21725569
[PubMed - as supplied by publisher]
Iron sulfide-embedded carbon microsphere anode material with high-rate performance for lithium-ion batteries.
Wu B, Song H, Zhou J, Chen X.
Chem Commun (Camb). 2011 Jul 1. [Epub ahead of print]
PMID:
21725544
[PubMed - as supplied by publisher]
CT and MR imaging of hepatocellular carcinoma.
Bolog N, Andreisek G, Oancea I, Mangrau A.
J Gastrointestin Liver Dis. 2011 Jun;20(2):181-9.
PMID:
21725516
[PubMed - in process]
Visualization and biochemical analyses of the emerging mammalian 14-3-3-phosphoproteome.
Johnson C, Tinti M, Wood NT, Campbell DG, Toth R, Dubois F, Geraghty KM, Wong BH, Brown LJ, Tyler J, Gernez A, Chen S, Synowsky S, Mackintosh C.
Mol Cell Proteomics. 2011 Jul 1. [Epub ahead of print]
PMID:
21725060
[PubMed - as supplied by publisher]
A Regulated Shift from Helical to Polar Localization of Listeria monocytogenes Cell Wall-Anchored Proteins.
Bruck S, Personnic N, Prevost MC, Cossart P, Bierne H.
J Bacteriol. 2011 Jul 1. [Epub ahead of print]
PMID:
21725001
[PubMed - as supplied by publisher]
Transcriptional profiling of nitrogen fixation in Azotobacter vinelandii.
Hamilton TL, Ludwig M, Dixon R, Boyd ES, Dos Santos PC, Setubal JC, Bryant DA, Dean DR, Peters JW.
J Bacteriol. 2011 Jul 1. [Epub ahead of print]
PMID:
21724999
[PubMed - as supplied by publisher]
Shewanella arctica sp. nov., an iron-reducing bacterium isolated from Arctic marine sediment.
Kim SJ, Park SJ, Oh YS, Lee SA, Shin KS, Roh DH, Rhee SK.
Int J Syst Evol Microbiol. 2011 Jul 1. [Epub ahead of print]
PMID:
21724958
[PubMed - as supplied by publisher]
The mic Locus in the Phytopathogen Ralstonia solanacearum Encodes the Biosynthesis of a Complex Yersiniabactin-like Natural Product.
Kreutzer MF, Kage H, Gebhardt P, Wackler B, Saluz HP, Hoffmeister D, Nett M.
Appl Environ Microbiol. 2011 Jul 1. [Epub ahead of print]
PMID:
21724891
[PubMed - as supplied by publisher]
Coking- and sintering-resistant palladium catalysts achieved through
atomic layer deposition.
Lu J, Fu B, Kung MC, Xiao G, Elam JW, Kung HH, Stair PC.
Science. 2012 Mar 9;335(6073):1205-8.
PMID:
22403386
[PubMed - in process]
Palladium-catalyzed S-benzylation of unprotected mercaptobenzoic acid with
benzyl alcohols in water.
Hikawa H, Yokoyama Y.
Org Biomol Chem. 2012 Mar 8. [Epub ahead of print]
PMID:
22402746
[PubMed - as supplied by publisher]
Kinetics of the sulfur oxidation on palladium: A combined in situ x-ray
photoelectron spectroscopy and density-functional study.
Gotterbarm K, Luckas N, Ho?fert O, Lorenz MP, Streber R, Papp C, Vin~es F,
Steinru?ck HP, Go?rling A.
J Chem Phys. 2012 Mar 7;136(9):094702.
PMID:
22401463
[PubMed - as supplied by publisher]
Structure and magnetic properties of nanostructured Pd-Fe thin films
produced by pulse electrodeposition.
Strukova GK, Strukov GV, Bozhko SI, Kabanov YP, Shmytko IM, Mazilkin AA,
Sobolev NA, Zhiteytsev ER, Sukhanov AA, Voronkova VK, Tagirov LR.
J Nanosci Nanotechnol. 2011 Oct;11(10):8907-11.
PMID:
22400279
[PubMed - in process]
Microbial synthesis of core/shell gold/palladium nanoparticles for
applications in green chemistry.
Deplanche K, Merroun ML, Casadesus M, Tran DT, Mikheenko IP, Bennett JA, Zhu
J, Jones IP, Attard GA, Wood J, Selenska-Pobell S, Macaskie LE.
J R Soc Interface. 2012 Mar 7. [Epub ahead of print]
PMID:
22399790
[PubMed - as supplied by publisher]
Pd(ii)-catalyzed direct C5-arylation of azole-4-carboxylates through
double C-H bond cleavage.
Li Z, Ma L, Xu J, Kong L, Wu X, Yao H.
Chem Commun (Camb). 2012 Mar 8. [Epub ahead of print]
PMID:
22399150
[PubMed - as supplied by publisher]
Palladium(ii) thiocarboxamide complexes: synthesis, characterisation and
application to catalytic Suzuki coupling reactions.
Sindhuja E, Ramesh R, Liu Y.
Dalton Trans. 2012 Mar 8. [Epub ahead of print]
PMID:
22399145
[PubMed - as supplied by publisher]
Effects of a catalytic converter on PCDD/F, chlorophenol and PAH emissions
in residential wood combustion.
Kaivosoja T, Virén A, Tissari J, Ruuskanen J, Tarhanen J, Sippula O, Jokiniemi
J.
Chemosphere. 2012 Mar 5. [Epub ahead of print]
PMID:
22397840
[PubMed - as supplied by publisher]
Engineering Biogenic Magnetite for Sustained Cr(VI) Remediation in Flow-
through Systems.
Crean DE, Coker VS, van der Laan G, Lloyd JR.
Environ Sci Technol. 2012 Mar 7. [Epub ahead of print]
PMID:
22397548
[PubMed - as supplied by publisher]
Palladium-Catalyzed N-Arylation of 2-Aminothiazoles.
McGowan MA, Henderson JL, Buchwald SL.
Org Lett. 2012 Mar 6. [Epub ahead of print]
PMID:
22394197
[PubMed - as supplied by publisher]
Generation of Indeno[1,2-c]pyrroles via a Pd-Catalyzed Reaction of 2-
Alkynylbromobenzene with Propargylic Sulfonamide.
Luo Y, Wu J.
Org Lett. 2012 Mar 5. [Epub ahead of print]
PMID:
22390224
[PubMed - as supplied by publisher]
Heck-Type Cross-Dehydrogenative Coupling Reactions of Indolizines at the
3-Position with Electron-Deficient Alkenes through Palladium-Catalyzed C?H
Activation.
Hu H, Liu Y, Zhong H, Zhu Y, Wang C, Ji M.
Chem Asian J. 2012 Mar 2. doi: 10.1002/asia.201101050. [Epub ahead of print]
PMID:
22389289
[PubMed - as supplied by publisher]
Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed
Silylation of Terminal Olefins: A Silyl-Heck Reaction.
McAtee JR, Martin SE, Ahneman DT, Johnson KA, Watson DA.
Angew Chem Int Ed Engl. 2012 Mar 1. doi: 10.1002/anie.201200060. [Epub ahead
of print]
PMID:
22383447
[PubMed - as supplied by publisher]
Synthesis and Unexpected Coordination of a Silicon(II)-Based SiCSi
Pincerlike Arene to Palladium.
Wang W, Inoue S, Irran E, Driess M.
Angew Chem Int Ed Engl. 2012 Mar 1. doi: 10.1002/anie.201200632. [Epub ahead
of print]
PMID:
22383113
[PubMed - as supplied by publisher]
MOFs as multifunctional catalysts: One-pot synthesis of menthol from
citronellal over a bifunctional MIL-101 catalyst.
Cirujano FG, Llabrés I Xamena FX, Corma A.
Dalton Trans. 2012 Mar 2. [Epub ahead of print]
PMID:
22382815
[PubMed - as supplied by publisher]
A facile route for preparing a mesoporous palladium coordination polymer
as a recyclable heterogeneous catalyst.
Zhang S, Liu Q, Shen M, Hu B, Chen Q, Li H, Amoureux JP.
Dalton Trans. 2012 Mar 1. [Epub ahead of print]
PMID:
22382505
[PubMed - as supplied by publisher]
Development of palladium-catalyzed transformations using propargylic
compounds.
Yoshida M.
Chem Pharm Bull (Tokyo). 2012;60(3):285-99.
PMID:
22382407
[PubMed - in process]
Palladium-Catalyzed Decarboxylative Coupling of Quinolinone-3-Carboxylic
Acids and Related Heterocyclic Carboxylic Acids with (Hetero)aryl Halides.
Messaoudi S, Brion JD, Alami M.
Org Lett. 2012 Mar 1. [Epub ahead of print]
PMID:
22381127
[PubMed - as supplied by publisher]
Elemental Release from CoCr and NiCr Alloys Containing Palladium.
Beck KA, Sarantopoulos DM, Kawashima I, Berzins DW.
J Prosthodont. 2012 Feb;21(2):88-93. doi: 10.1111/j.1532-849X.2011.00800.x.
PMID:
22380645
[PubMed - in process]
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