Palladium Sulfate is a moderately water and acid soluble Palladium source for uses compatible with sulfates. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and deposited utilizing sputtering targets and evaporation materials for uses such as solar energy materials and fuel cells. Palladium Sulfate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. We also produce Palladium Sulfate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and dehydrogenation catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
PET study using [(11)C]FTIMD with ultra-high specific activity to evaluate I(2)-imidazoline receptors binding in rat brains.
Kawamura K, Kimura Y, Yui J, Wakizaka H, Yamasaki T, Hatori A, Kumata K, Fujinaga M, Yoshida Y, Ogawa M, Nengaki N, Fukumura T, Zhang MR.
Nucl Med Biol. 2011 Sep 27. [Epub ahead of print]
PMID:
21958848
[PubMed - as supplied by publisher]
Titanocene-Phosphine Derivatives as Precursors to Cytotoxic Heterometallic TiAu(2) and TiM (M = Pd, Pt) Compounds. Studies of Their Interactions with DNA.
González-Pantoja JF, Stern M, Jarzecki AA, Royo E, Robles-Escajeda E, Varela-Ramírez A, Aguilera RJ, Contel M.
Inorg Chem. 2011 Sep 29. [Epub ahead of print]
PMID:
21958150
[PubMed - as supplied by publisher]
Convenient and General Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Amines.
Wu XF, Neumann H, Beller M.
Angew Chem Int Ed Engl. 2011 Sep 28. doi: 10.1002/anie.201104653. [Epub ahead of print] No abstract available.
PMID:
21957031
[PubMed - as supplied by publisher]
A Convenient and General Palladium-Catalyzed Carbonylative Coupling for the Synthesis of 2-Arylbenzoxazinones.
Wu XF, Schranck J, Neumann H, Beller M.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201102254. [Epub ahead of print] No abstract available.
PMID:
21956858
[PubMed - as supplied by publisher]
Palladium Nanoparticles Encapsulated in Metal-Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles.
Huang Y, Lin Z, Cao R.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101705. [Epub ahead of print]
PMID:
21956646
[PubMed - as supplied by publisher]
Palladium-Catalyzed Pentannulation of Polycyclic Aromatic Hydrocarbons.
Lütke Eversloh C, Avlasevich Y, Li C, Müllen K.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101126. [Epub ahead of print]
PMID:
21956345
[PubMed - as supplied by publisher]
Curious Results with Palladium- and Platinum-Carrying Polymers in Mass Cytometry Bioassays and an Unexpected Application as a Dead Cell Stain.
Majonis D, Ornatsky O, Kinach R, Winnik MA.
Biomacromolecules. 2011 Sep 28. [Epub ahead of print]
PMID:
21955116
[PubMed - as supplied by publisher]
Palladium Catalyzed Stereoselective C-Glycosylation of Glycals with Enol Triflates.
Bai Y, Leow M, Zeng J, Liu XW.
Org Lett. 2011 Sep 28. [Epub ahead of print]
PMID:
21954934
[PubMed - as supplied by publisher]
Palladium-Catalyzed Mono-N-allylation of Unprotected Anthranilic Acids with Allylic Alcohols in Aqueous Media.
Hikawa H, Yokoyama Y.
J Org Chem. 2011 Sep 29. [Epub ahead of print]
PMID:
21919524
[PubMed - as supplied by publisher]
Twin Plane Decoration of Silver Nanorods with Palladium by Galvanic Exchange at a Controlled Rate.
Slawinski GW, Ivanova OS, Zamborini FP.
Langmuir. 2011 Sep 28. [Epub ahead of print]
PMID:
21916478
[PubMed - as supplied by publisher]
Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via ?(3)-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization.
Peng B, Zhang S, Yu X, Feng X, Bao M.
Org Lett. 2011 Oct 7;13(19):5402-5. Epub 2011 Sep 13.
PMID:
21910509
[PubMed - in process]
Azadipyrromethene-Based Conjugated Oligomers with Near-IR Absorption and High Electron Affinity.
Gao L, Senevirathna W, Sauvé G.
Org Lett. 2011 Oct 7;13(19):5354-7. Epub 2011 Sep 12.
PMID:
21910458
[PubMed - in process]
Palladium-catalyzed approach to stereodefined ten-membered cycles from 1,5-bisallenes.
Cheng J, Jiang X, Ma S.
Org Lett. 2011 Oct 7;13(19):5200-3. Epub 2011 Sep 12.
PMID:
21910412
[PubMed - in process]
New Heteroannulation Reactions of N-Alkoxybenzamides by Pd(II) Catalyzed C-H Activation.
Wrigglesworth JW, Cox B, Lloyd-Jones GC, Booker-Milburn KI.
Org Lett. 2011 Oct 7;13(19):5326-9. Epub 2011 Sep 12.
PMID:
21910404
[PubMed - in process]
Pd(0)-catalyzed iodoalkynation of norbornene scaffolds: the remarkable solvent effect on reaction pathway.
Liu H, Chen C, Wang L, Tong X.
Org Lett. 2011 Oct 7;13(19):5072-5. Epub 2011 Sep 12.
PMID:
21910403
[PubMed - in process]
Palladium Catalyzed 1,8-Conjugate Addition to Heptafulvene via Bis-?-allyl Palladium Complexes.
George SC, Thulasi S, Anas S, Radhakrishnan KV, Yamamoto Y.
Org Lett. 2011 Oct 7;13(19):4984-7. Epub 2011 Sep 7.
PMID:
21899322
[PubMed - in process]
Hydride formation in single palladium and magnesium nanoparticles studied by nanoplasmonic dark-field scattering spectroscopy.
Shegai T, Langhammer C.
Adv Mater. 2011 Oct 11;23(38):4409-14. doi: 10.1002/adma.201101976. Epub 2011 Sep 5. No abstract available.
PMID:
21898608
[PubMed - in process]
Cross-coupling of mesylated phenol derivatives with potassium cyclopropyltrifluoroborate.
Molander GA, Beaumard F, Niethamer TK.
J Org Chem. 2011 Oct 7;76(19):8126-30. Epub 2011 Sep 2.
PMID:
21888362
[PubMed - in process]
Palladium-catalyzed regioselective C-s bond cleavage of thiophenes.
Huang H, Li J, Lescop C, Duan Z.
Org Lett. 2011 Oct 7;13(19):5252-5. Epub 2011 Sep 2.
PMID:
21888338
[PubMed - in process]
Substrate-Directable Heck Reactions with Arenediazonium Salts. The Regio- and Stereoselective Arylation of Allylamine Derivatives and Applications in the Synthesis of Naftifine and Abamines.
Prediger P, Barbosa LF, Ge?nisson Y, Correia CR.
J Org Chem. 2011 Oct 7;76(19):7737-7749. Epub 2011 Sep 15.
PMID:
21877731
[PubMed - as supplied by publisher]
Self-assembly of a sulphur-terminated graphene nanoribbon within a single-walled carbon nanotube.
Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC, Chamberlain TW, Rance GA, Kuganathan N, Biskupek J, Kaiser U, Khlobystov AN.
Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3082. [Epub ahead of print]
PMID:
21822259
[PubMed - as supplied by publisher]
Crystallization and preliminary X-ray analysis of the yeast tRNA-thiouridine modification protein 1 (Tum1p).
Qiu R, Wang F, Liu M, Yang Z, Wu T, Ji C.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Aug 1;67(Pt 8):953-5. Epub 2011 Jul 27.
PMID:
21821903
[PubMed - in process]
Characterization of Bacillus thuringiensis L-isoleucine dioxygenase toward the production of useful amino acids.
Hibi M, Kawashima T, Kodera T, Smirnov SV, Sokolov PM, Sugiyama M, Shimizu S, Yokozeki K, Ogawa J.
Appl Environ Microbiol. 2011 Aug 5. [Epub ahead of print]
PMID:
21821743
[PubMed - as supplied by publisher]
Characterization of the sulfurtransferase family from Oryza sativa L.
Guretzki S, Papenbrock J.
Plant Physiol Biochem. 2011 Jul 23. [Epub ahead of print]
PMID:
21821426
[PubMed - as supplied by publisher]
Development of a small-scale bioreactor method to monitor the molecular diversity and environmental impacts of bacterial biofilm communities from an acid mine drainage impacted creek.
Cole M, Wrubel J, Henegan P, Janzen C, Holt J, Tobin T.
J Microbiol Methods. 2011 Jul 28. [Epub ahead of print]
PMID:
21821067
[PubMed - as supplied by publisher]
In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent-solute interaction and its activity toward adsorptive desulfurization of gas oil.
Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A.
J Hazard Mater. 2011 Jul 6. [Epub ahead of print]
PMID:
21820806
[PubMed - as supplied by publisher]
Stearoyl-CoA desaturase is an essential enzyme for the parasitic protist Trypanosoma brucei.
Alloatti A, Gupta S, Gualdrón-López M, Nguewa PA, Altabe SG, Deumer G, Wallemacq P, Michels PA, Uttaro AD.
Biochem Biophys Res Commun. 2011 Jul 28. [Epub ahead of print]
PMID:
21820408
[PubMed - as supplied by publisher]
The use of multi-element stable isotope analysis to monitor the origin of chondroitin sulfates.
Thomas F, Jamin E, Shimoo K, Nagao J, Osaki Y, Granier C.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2533-7. doi: 10.1002/rcm.5159.
PMID:
21818814
[PubMed - in process]
Sulphur isotopes in animal hair track distance to sea.
Zazzo A, Monahan FJ, Moloney AP, Green S, Schmidt O.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2371-8. doi: 10.1002/rcm.5131.
PMID:
21818798
[PubMed - in process]
Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-Like Molecules with Metal-Metal Multiple Bonds.
Fang W, He Q, Tan ZF, Liu CY, Lu X, Murillo CA.
Chemistry. 2011 Aug 4. doi: 10.1002/chem.201003693. [Epub ahead of print]
PMID:
21818792
[PubMed - as supplied by publisher]
Rhodovulum phaeolacus sp. nov. a phototrophic alphaproteobacterium isolated from a brown pond.
Venkata Naga Satya Lakshmi K, Sasikala C, Venkata Ramana V, Veera Venkata Ramaprasad E, Venkata Ramana C.
J Gen Appl Microbiol. 2011;57(3):145-51.
PMID:
21817826
[PubMed - in process]
Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources.
Wyman CE, Balan V, Dale BE, Elander RT, Falls M, Hames B, Holtzapple MT, Ladisch MR, Lee YY, Mosier N, Pallapolu VR, Shi J, Thomas SR, Warner RE.
Bioresour Technol. 2011 Jun 21. [Epub ahead of print]
PMID:
21816612
[PubMed - as supplied by publisher]
Target loads of atmospheric sulfur deposition for the protection and recovery of acid-sensitive streams in the Southern Blue Ridge Province.
Sullivan TJ, Cosby BJ, Jackson WA.
J Environ Manage. 2011 Aug 2. [Epub ahead of print]
PMID:
21816535
[PubMed - as supplied by publisher]
Differential effects of a post-anthesis fertilizer regimen on the wheat flour proteome determined by quantitative 2-DE.
Altenbach SB, Tanaka CK, Hurkman WJ, Whitehand LC, Vensel WH, Dupont FM.
Proteome Sci. 2011 Aug 4;9(1):46. [Epub ahead of print]
PMID:
21816081
[PubMed - as supplied by publisher]
Comparative toxicity of arsenic metabolites in human bladder cancer EJ-1 cells.
Naranmandura H, Michael CW, Xu S, Lee J, Leslie E, Weinfeld M, Le XC.
Chem Res Toxicol. 2011 Aug 4. [Epub ahead of print]
PMID:
21815631
[PubMed - as supplied by publisher]
The Effects of Different Garlic-derived Allyl Sulfides on Peroxidative Processes and Anaerobic Sulfur Metabolism in Mouse Liver.
Iciek MB, Kowalczyk-Pachel D, Kwiecien I, Dudek MB.
Phytother Res. 2011 Aug 4. doi: 10.1002/ptr.3572. [Epub ahead of print]
PMID:
21815229
[PubMed - as supplied by publisher]
A combined model of hepatic polyamine and sulfur amino acid metabolism to analyze S-adenosyl methionine availability.
Reyes-Palomares A, Montańez R, Sánchez-Jiménez F, Medina MA.
Amino Acids. 2011 Aug 4. [Epub ahead of print]
PMID:
21814788
[PubMed - as supplied by publisher]
Microbial gene functions enriched in the Deepwater Horizon deep-sea oil plume.
Lu Z, Deng Y, Van Nostrand JD, He Z, Voordeckers J, Zhou A, Lee YJ, Mason OU, Dubinsky EA, Chavarria KL, Tom LM, Fortney JL, Lamendella R, Jansson JK, D'haeseleer P, Hazen TC, Zhou J.
ISME J. 2011 Aug 4. doi: 10.1038/ismej.2011.91. [Epub ahead of print]
PMID:
21814288
[PubMed - as supplied by publisher]
1,1'-(3-Methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a Building Block in Heterocyclic Synthesis. Novel Synthesis of Some Pyrazole and Pyrimidine Derivatives.
Mabkhot YN, Al-Majid AM, Barakat A, Alshahrani S, Siddiqui Y.
Molecules. 2011 Aug 3;16(8):6502-11.
PMID:
21814162
[PubMed - in process]
Towards the Growth of an Aligned Single-Layer MoS2 Film.
Kim D, Sun D, Lu W, Cheng Z, Zhu Y, Le D, Rahman TS, Bartels L.
Langmuir. 2011 Aug 3. [Epub ahead of print]
PMID:
21812475
[PubMed - as supplied by publisher]