Tetraamminepalladium(II) Bromide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and dehydrogenation catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
PET study using [(11)C]FTIMD with ultra-high specific activity to evaluate I(2)-imidazoline receptors binding in rat brains.
Kawamura K, Kimura Y, Yui J, Wakizaka H, Yamasaki T, Hatori A, Kumata K, Fujinaga M, Yoshida Y, Ogawa M, Nengaki N, Fukumura T, Zhang MR.
Nucl Med Biol. 2011 Sep 27. [Epub ahead of print]
PMID:
21958848
[PubMed - as supplied by publisher]
Titanocene-Phosphine Derivatives as Precursors to Cytotoxic Heterometallic TiAu(2) and TiM (M = Pd, Pt) Compounds. Studies of Their Interactions with DNA.
González-Pantoja JF, Stern M, Jarzecki AA, Royo E, Robles-Escajeda E, Varela-Ramírez A, Aguilera RJ, Contel M.
Inorg Chem. 2011 Sep 29. [Epub ahead of print]
PMID:
21958150
[PubMed - as supplied by publisher]
Convenient and General Palladium-Catalyzed Carbonylative Sonogashira Coupling of Aryl Amines.
Wu XF, Neumann H, Beller M.
Angew Chem Int Ed Engl. 2011 Sep 28. doi: 10.1002/anie.201104653. [Epub ahead of print] No abstract available.
PMID:
21957031
[PubMed - as supplied by publisher]
A Convenient and General Palladium-Catalyzed Carbonylative Coupling for the Synthesis of 2-Arylbenzoxazinones.
Wu XF, Schranck J, Neumann H, Beller M.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201102254. [Epub ahead of print] No abstract available.
PMID:
21956858
[PubMed - as supplied by publisher]
Palladium Nanoparticles Encapsulated in Metal-Organic Framework as Efficient Heterogeneous Catalysts for Direct C2 Arylation of Indoles.
Huang Y, Lin Z, Cao R.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101705. [Epub ahead of print]
PMID:
21956646
[PubMed - as supplied by publisher]
Palladium-Catalyzed Pentannulation of Polycyclic Aromatic Hydrocarbons.
Lütke Eversloh C, Avlasevich Y, Li C, Müllen K.
Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101126. [Epub ahead of print]
PMID:
21956345
[PubMed - as supplied by publisher]
Curious Results with Palladium- and Platinum-Carrying Polymers in Mass Cytometry Bioassays and an Unexpected Application as a Dead Cell Stain.
Majonis D, Ornatsky O, Kinach R, Winnik MA.
Biomacromolecules. 2011 Sep 28. [Epub ahead of print]
PMID:
21955116
[PubMed - as supplied by publisher]
Palladium Catalyzed Stereoselective C-Glycosylation of Glycals with Enol Triflates.
Bai Y, Leow M, Zeng J, Liu XW.
Org Lett. 2011 Sep 28. [Epub ahead of print]
PMID:
21954934
[PubMed - as supplied by publisher]
Palladium-Catalyzed Mono-N-allylation of Unprotected Anthranilic Acids with Allylic Alcohols in Aqueous Media.
Hikawa H, Yokoyama Y.
J Org Chem. 2011 Sep 29. [Epub ahead of print]
PMID:
21919524
[PubMed - as supplied by publisher]
Twin Plane Decoration of Silver Nanorods with Palladium by Galvanic Exchange at a Controlled Rate.
Slawinski GW, Ivanova OS, Zamborini FP.
Langmuir. 2011 Sep 28. [Epub ahead of print]
PMID:
21916478
[PubMed - as supplied by publisher]
Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via ?(3)-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization.
Peng B, Zhang S, Yu X, Feng X, Bao M.
Org Lett. 2011 Oct 7;13(19):5402-5. Epub 2011 Sep 13.
PMID:
21910509
[PubMed - in process]
Azadipyrromethene-Based Conjugated Oligomers with Near-IR Absorption and High Electron Affinity.
Gao L, Senevirathna W, Sauvé G.
Org Lett. 2011 Oct 7;13(19):5354-7. Epub 2011 Sep 12.
PMID:
21910458
[PubMed - in process]
Palladium-catalyzed approach to stereodefined ten-membered cycles from 1,5-bisallenes.
Cheng J, Jiang X, Ma S.
Org Lett. 2011 Oct 7;13(19):5200-3. Epub 2011 Sep 12.
PMID:
21910412
[PubMed - in process]
New Heteroannulation Reactions of N-Alkoxybenzamides by Pd(II) Catalyzed C-H Activation.
Wrigglesworth JW, Cox B, Lloyd-Jones GC, Booker-Milburn KI.
Org Lett. 2011 Oct 7;13(19):5326-9. Epub 2011 Sep 12.
PMID:
21910404
[PubMed - in process]
Pd(0)-catalyzed iodoalkynation of norbornene scaffolds: the remarkable solvent effect on reaction pathway.
Liu H, Chen C, Wang L, Tong X.
Org Lett. 2011 Oct 7;13(19):5072-5. Epub 2011 Sep 12.
PMID:
21910403
[PubMed - in process]
Palladium Catalyzed 1,8-Conjugate Addition to Heptafulvene via Bis-?-allyl Palladium Complexes.
George SC, Thulasi S, Anas S, Radhakrishnan KV, Yamamoto Y.
Org Lett. 2011 Oct 7;13(19):4984-7. Epub 2011 Sep 7.
PMID:
21899322
[PubMed - in process]
Hydride formation in single palladium and magnesium nanoparticles studied by nanoplasmonic dark-field scattering spectroscopy.
Shegai T, Langhammer C.
Adv Mater. 2011 Oct 11;23(38):4409-14. doi: 10.1002/adma.201101976. Epub 2011 Sep 5. No abstract available.
PMID:
21898608
[PubMed - in process]
Cross-coupling of mesylated phenol derivatives with potassium cyclopropyltrifluoroborate.
Molander GA, Beaumard F, Niethamer TK.
J Org Chem. 2011 Oct 7;76(19):8126-30. Epub 2011 Sep 2.
PMID:
21888362
[PubMed - in process]
Palladium-catalyzed regioselective C-s bond cleavage of thiophenes.
Huang H, Li J, Lescop C, Duan Z.
Org Lett. 2011 Oct 7;13(19):5252-5. Epub 2011 Sep 2.
PMID:
21888338
[PubMed - in process]
Substrate-Directable Heck Reactions with Arenediazonium Salts. The Regio- and Stereoselective Arylation of Allylamine Derivatives and Applications in the Synthesis of Naftifine and Abamines.
Prediger P, Barbosa LF, Ge?nisson Y, Correia CR.
J Org Chem. 2011 Oct 7;76(19):7737-7749. Epub 2011 Sep 15.
PMID:
21877731
[PubMed - as supplied by publisher]
Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids.
Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C.
Org Lett. 2010 Jan 5. [Epub ahead of print]
PMID: 19689116 [PubMed - as supplied by publisher]
Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides.
Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL.
Science. 2009 Aug 13. [Epub ahead of print]
PMID: 19679769 [PubMed - as supplied by publisher]
(2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides.
Zhang Q, Wang D, Wang X, Ding K.
J Org Chem. 2009 Aug 12. [Epub ahead of print]
PMID: 19673481 [PubMed - as supplied by publisher]
Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides.
Vechorkin O, Barmaz D, Proust V, Hu X.
J Am Chem Soc. 2009 Aug 11. [Epub ahead of print]
PMID: 19670863 [PubMed - as supplied by publisher]
Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia.
Huang JM, Dong Y.
Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28.
PMID: 19662260 [PubMed - in process]
Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols.
Salvi L, Kim JG, Walsh PJ.
J Am Chem Soc. 2009 Aug 4. [Epub ahead of print]
PMID: 19653691 [PubMed - as supplied by publisher]
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines.
Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J.
J Comb Chem. 2009 Jul 31. [Epub ahead of print]
PMID: 19645499 [PubMed - as supplied by publisher]
Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids.
del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N.
Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29.
PMID: 19641822 [PubMed - in process]
Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides.
Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639999 [PubMed - as supplied by publisher]
Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies.
Snelders DJ, van Koten G, Klein Gebbink RJ.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639941 [PubMed - as supplied by publisher]
Can One Predict Changes from S(N)1 to S(N)2 Mechanisms?
Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H.
J Am Chem Soc. 2009 Jul 27. [Epub ahead of print]
PMID: 19634906 [PubMed - as supplied by publisher]
A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides.
Liao Q, Wang Y, Zhang L, Xi C.
J Org Chem. 2009 Jul 15. [Epub ahead of print]
PMID: 19603753 [PubMed - as supplied by publisher]
Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides.
Shi L, Chu Y, Knochel P, Mayr H.
Org Lett. 2009 Jul 14. [Epub ahead of print]
PMID: 19601592 [PubMed - as supplied by publisher]
C5-Modified nucleosides exhibiting anticancer activity.
Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH.
Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21.
PMID: 19596579 [PubMed - in process]
Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines.
Vo GD, Hartwig JF.
J Am Chem Soc. 2009 Jul 10. [Epub ahead of print]
PMID: 19591470 [PubMed - as supplied by publisher]
New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes.
Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B.
Org Lett. 2009 Jul 2. [Epub ahead of print]
PMID: 19572730 [PubMed - as supplied by publisher]
The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives.
Jo Y, Ju J, Choe J, Song KH, Lee S.
J Org Chem. 2009 Jul 2. [Epub ahead of print]
PMID: 19572571 [PubMed - as supplied by publisher]
Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents.
Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH.
Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8.
PMID: 19557114 [PubMed - in process]
A facile route to C2-substituted imidazolium ionic liquids.
Ennis E, Handy ST.
Molecules. 2009 Jun 19;14(6):2235-45.
PMID: 19553895 [PubMed - in process]
Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines.
McCall WS, Comins DL.
Org Lett. 2009 Jul 2;11(13):2940-2.
PMID: 19552467 [PubMed - indexed for MEDLINE]
Tetraamminepalladium(II) Bromide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Palladium is a Block D, Group 10, Period 5 element. The number of electrons in each of Palladium's shells is 2, 8, 18, 18 and its electronic configuration is [Kr] 4d10. In its elemental form palladium's CAS number is 7440-05-3. The palladium atom has a radius of 137.6.pm and it's Van der Waals radius is 163.pm. Palladium is a member of the palladium group of metals. It is an excellent hydrogenation and 
dehydrogenation
catalyst and available in many Organo-metallic forms for this purpose. It is alloyed with gold, silver, iridium and other palladium group elements and used in jewelry. The metal is used in dentistry, watch making, and in making surgical instruments and electrical contacts. Palladium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below. Palladium was first discovered by William Hyde Wollaston in 1803. See Palladium research below.
