Potassium Hexanitrorhodate(III) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Potassium is a Block S, Group 1, Period 4 element. The number of electrons in each of Potassium's shells is 2, 8, 8, 1 and its electronic configuration is [Ar] 4s1. In its elemental form potassium's CAS number is 7440-09-7. The potassium atom has a radius of 227.2 .pm and it's Van der Waals radius is 275.pm. Potassium is not toxic. Potassium is the seventh most abundant element on earth. In its metallic form it is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other metals of the alkali group, the metal decomposes in water with the evolution of hydrogen. It catches fire spontaneously in water. In high purity, potassium compounds have numerous pharmacological, medical, and electronics applications. Important compounds include the hydroxide, nitrate, carbonate, chloride, bromide, iodide, and sulfate. Lower purity compounds are used in pyrotechnics for its violet color on ignition and in glass and ceramic glazes to produce this color. Potassium also used as a nutrient in plant growth. Potassium was first discovered by Sir Humphrey Davy in 1807. The origin of the element name comes from the English word 'potash' meaning pot ashes and the Arabic word 'qali' which means alkali. The symbol K originates from the Latin word 'kalium'. See Potassium research below.
Rhodium is a Block D, Group 9, Period 5 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 16, 1 and its electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm. Rhodium is not toxic. Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density.
It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Rhodium was first discovered by William Wollaston in 1803. The name Rhodium, originates from the Greek word 'Rhodon' which means rose. See Rhodium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Aluminum potassium sulfate and tannic Acid injection for hemorrhoids.
Lim SW.
J Korean Soc Coloproctol. 2012 Apr;28(2):73-7. Epub 2012 Apr 30.
PMID:
22606645
[PubMed - in process]
Suppression of Ribosomal Function Triggers Innate Immune Signaling through Activation of the NLRP3 Inflammasome.
Vyleta ML, Wong J, Magun BE.
PLoS One. 2012;7(5):e36044. Epub 2012 May 14.
PMID:
22606244
[PubMed - as supplied by publisher]
Stroke preceding autoimmune encephalitis with neuronal potassium channel antibody.
Simal P, Garcia-García AM, Serna-Candel C, Egido JA.
BMJ Case Rep. 2012 May 8;2012. pii: bcr0820114637. doi: 10.1136/bcr.08.2011.4637.
PMID:
22605845
[PubMed - in process]
Life-threatening hyperkalemia - an overlooked acute kidney injury with a serum creatinine rise in the 'normal' range.
Latus J, Braun N, Alscher MD, Kimmel M.
BMJ Case Rep. 2012 May 8;2012. pii: bcr0120125691. doi: 10.1136/bcr.01.2012.5691.
PMID:
22605836
[PubMed - in process]
Ethylene glycol ingestion masked by concomitant ethanol intoxication.
Head JM.
BMJ Case Rep. 2012 Mar 20;2012. pii: bcr1220115326. doi: 10.1136/bcr.12.2011.5326.
PMID:
22605713
[PubMed - in process]
Neuroanatomy of melanocortin-4 receptor pathway in the lateral hypothalamic area.
Cui H, Sohn JW, Gautron L, Funahashi H, Williams KW, Elmquist JK, Lutter M.
J Comp Neurol. 2012 May 17. doi: 10.1002/cne.23145. [Epub ahead of print]
PMID:
22605619
[PubMed - as supplied by publisher]
Microvascular responses to aldosterone in hamster cheek pouch microcirculation.
Lapi D, Emdin M, Mastantuono T, Sapio D, Santillo M, Colantuoni A.
Clin Hemorheol Microcirc. 2012 May 16. [Epub ahead of print]
PMID:
22596229
[PubMed - as supplied by publisher]
Prevalence and Factors Associated with Hyperkalemia in Predialysis Patients Followed in a Low-Clearance Clinic.
Sarafidis PA, Blacklock R, Wood E, Rumjon A, Simmonds S, Fletcher-Rogers J, Ariyanayagam R, Al-Yassin A, Sharpe C, Vinen K.
Clin J Am Soc Nephrol. 2012 May 17. [Epub ahead of print]
PMID:
22595825
[PubMed - as supplied by publisher]
Chemical punch packed in venoms makes centipedes excellent predators.
Yang S, Liu Z, Xiao Y, Li Y, Rong M, Liang S, Zhang Z, Yu H, King GF, Lai R.
Mol Cell Proteomics. 2012 May 17. [Epub ahead of print]
PMID:
22595790
[PubMed - as supplied by publisher]
21 Days head-down bed rest induces weakening of cell-mediated immunity - Some spaceflight findings confirmed in a ground-based analog.
Kelsen J, Bartels LE, Dige A, Hvas CL, Frings-Meuthen P, Boehme G, Thomsen MK, Fenger-Grøn M, Dahlerup JF.
Cytokine. 2012 May 15. [Epub ahead of print]
PMID:
22595648
[PubMed - as supplied by publisher]
Efficient production of ultrapure manganese oxides via electrodeposition.
Cheney MA, Joo SW, Banerjee A, Min BK.
J Colloid Interface Sci. 2012 Apr 25. [Epub ahead of print]
PMID:
22595552
[PubMed - as supplied by publisher]
Radiolytic formation of non-toxic Cr(III) from toxic Cr(VI) in formate containing aqueous solutions: A system for water treatment.
Djouider F.
J Hazard Mater. 2012 May 3. [Epub ahead of print]
PMID:
22595544
[PubMed - as supplied by publisher]
Comparative effect of angiotensin II type I receptor blockers and calcium channel blockers on laboratory parameters in hypertensive patients with type 2 diabetes.
Nishida Y, Takahashi Y, Nakayama T, Asai S.
Cardiovasc Diabetol. 2012 May 17;11(1):53. [Epub ahead of print]
PMID:
22594344
[PubMed - as supplied by publisher]
Functional significance of M-type potassium channels in nociceptive cutaneous sensory endings.
Passmore GM, Reilly JM, Thakur M, Keasberry VN, Marsh SJ, Dickenson AH, Brown DA.
Front Mol Neurosci. 2012;5:63. Epub 2012 May 14.
PMID:
22593734
[PubMed - in process]
Growth, root formation, and nutrient value of triticale plants fertilized with biosolids.
Rauw WM, Teglas MB, Chandra S, Forister ML.
ScientificWorldJournal. 2012;2012:467052. Epub 2012 Apr 19.
PMID:
22593686
[PubMed - in process]
Electrochemistry/mass spectrometry as a tool in the investigation of the potent skin sensitizer p-phenylenediamine and its reactivity toward nucleophiles.
Jahn S, Faber H, Zazzeroni R, Karst U.
Rapid Commun Mass Spectrom. 2012 Jun 30;26(12):1453-64. doi: 10.1002/rcm.6249.
PMID:
22592989
[PubMed - in process]
One-step sonochemical synthesis of a graphene oxide-manganese oxide nanocomposite for catalytic glycolysis of poly(ethylene terephthalate).
Park G, Bartolome L, Lee KG, Lee SJ, Kim DH, Park TJ.
Nanoscale. 2012 May 16. [Epub ahead of print]
PMID:
22592889
[PubMed - as supplied by publisher]
Interventions for non-oliguric hyperkalaemia in preterm neonates.
Vemgal P, Ohlsson A.
Cochrane Database Syst Rev. 2012 May 16;5:CD005257.
PMID:
22592703
[PubMed - in process]
Ultrasound assisted free radical polymerization of glycidyl methacrylate by a new disite phase-transfer catalyst system: A kinetic study.
Sankar K, Rajendran V.
Ultrason Sonochem. 2012 Feb 22. [Epub ahead of print]
PMID:
22592149
[PubMed - as supplied by publisher]
Comparison of the Effects of Sevoflurane, Isoflurane, and Desflurane on Microcirculation in Coronary Artery Bypass Graft Surgery.
Ozarslan NG, Ayhan B, Kanbak M, Celebiog?lu B, Demircin M, Ince C, Aypar U.
J Cardiothorac Vasc Anesth. 2012 May 14. [Epub ahead of print]
PMID:
22592139
[PubMed - as supplied by publisher]
Intramolecular Aromatic Carbenoid Insertion of Biaryldiazoacetates for the Regioselective Synthesis of Fluorenes.
Kim J, Ohk Y, Park SH, Jung Y, Chang S.
Chem Asian J. 2011 May 12. doi: 10.1002/asia.201100142. [Epub ahead of print]
PMID:
21567971
[PubMed - as supplied by publisher]
Rhodium-Catalyzed Cycloisomerization Involving Cyclopropenes: Efficient Stereoselective Synthesis of Medium-Sized Heterocyclic Scaffolds.
Miege F, Meyer C, Cossy J.
Angew Chem Int Ed Engl. 2011 May 12. doi: 10.1002/anie.201101220. [Epub ahead of print] No abstract available.
PMID:
21567678
[PubMed - as supplied by publisher]
Allylic C-H bond activation and functionalization mediated by tris(oxazolinyl)borato rhodium(i) and iridium(i) compounds.
Ho HA, Gray TS, Baird B, Ellern A, Sadow AD.
Dalton Trans. 2011 May 12. [Epub ahead of print]
PMID:
21566811
[PubMed - as supplied by publisher]
Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system.
Vautravers NR, Regent DD, Breit B.
Chem Commun (Camb). 2011 May 12. [Epub ahead of print]
PMID:
21566809
[PubMed - as supplied by publisher]
Carbon Chain Growth by Formyl Insertion on Rhodium and Cobalt Catalysts in Syngas Conversion.
Zhao YH, Sun K, Ma X, Liu J, Sun D, Su HY, Li WX.
Angew Chem Int Ed Engl. 2011 May 6. doi: 10.1002/anie.201100735. [Epub ahead of print] No abstract available.
PMID:
21557417
[PubMed - as supplied by publisher]
Synthesis, Characterisation and Application of Iridium(III) Photosensitisers for Catalytic Water Reduction.
Gärtner F, Cozzula D, Losse S, Boddien A, Anilkumar G, Junge H, Schulz T, Marquet N, Spannenberg A, Gladiali S, Beller M.
Chemistry. 2011 May 6. doi: 10.1002/chem.201100235. [Epub ahead of print]
PMID:
21557356
[PubMed - as supplied by publisher]
Analysis of Tertiary Phosphanes, Arsanes, and Stibanes as Bridging Ligands in Dinuclear Group 9 Complexes.
Schinzel S, Müller R, Riedel S, Werner H, Kaupp M.
Chemistry. 2011 May 9. doi: 10.1002/chem.201003438. [Epub ahead of print]
PMID:
21557345
[PubMed - as supplied by publisher]
Asymmetric hydrogenation of alkenes lacking coordinating groups.
Woodmansee DH, Pfaltz A.
Chem Commun (Camb). 2011 May 10. [Epub ahead of print]
PMID:
21556431
[PubMed - as supplied by publisher]
Ionic Diamine Rhodium Complex Catalyzed Reductive N-Heterocyclization of 2-Nitrovinylarenes.
Alper H, Okuro K, Gurnham J.
J Org Chem. 2011 May 4. [Epub ahead of print]
PMID:
21542601
[PubMed - as supplied by publisher]
trans-Carbonylchloridobis(ferrocenyldiphenylphosphane-?P)rhodium(I) dichloromethane monosolvate and trans-carbonylchloridobis(ferrocenyldiphenylphosphane-?P)iridium(I) dichloromethane monosolvate.
Muller A, Otto S.
Acta Crystallogr C. 2011 May;67(Pt 5):m165-8. Epub 2011 Apr 28.
PMID:
21540536
[PubMed - in process]
A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides.
Serna P, Gates BC.
Angew Chem Int Ed Engl. 2011 Apr 29. doi: 10.1002/anie.201008086. [Epub ahead of print] No abstract available.
PMID:
21538737
[PubMed - as supplied by publisher]
Asymmetric polymerizations of chiral 4-benzyl-2-ethynyloxazoline with rhodium catalyst and chiroptical properties of the polymers.
Onimura K, Shintaku K, Rattanatraicharoen P, Yamabuki K, Oishi T.
Chirality. 2011 Apr 28. doi: 10.1002/chir.20959. [Epub ahead of print]
PMID:
21538572
[PubMed - as supplied by publisher]
Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines.
Shintani R, Narui R, Tsutsumi Y, Hayashi S, Hayashi T.
Chem Commun (Camb). 2011 May 3. [Epub ahead of print]
PMID:
21537505
[PubMed - as supplied by publisher]
Synthesis and characterisation of group nine transition metal complexes containing new mesityl and naphthyl based azaindole scorpionate ligands.
Owen GR, Tsoureas N, Hope RF, Kuo YY, Haddow MF.
Dalton Trans. 2011 Apr 28. [Epub ahead of print]
PMID:
21528139
[PubMed - as supplied by publisher]
Screen-printed carbon electrodes modified by rhodium dioxide and glucose dehydrogenase.
Polan V, Soukup J, Vytras K.
Enzyme Res. 2011 Mar 3;2010:324184.
PMID:
21528113
[PubMed - in process]
Computationally Designed and Experimentally Confirmed Diastereoselective Rhodium-Catalyzed Pauson-Khand Reaction at Room Temperature.
Baik MH, Mazumder S, Ricci P, Sawyer JR, Song YG, Wang H, Evans PA.
J Am Chem Soc. 2011 Apr 27. [Epub ahead of print]
PMID:
21524123
[PubMed - as supplied by publisher]
An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes.
Feng JJ, Zhang J.
J Am Chem Soc. 2011 May 18;133(19):7304-7. Epub 2011 Apr 27.
PMID:
21524076
[PubMed - in process]
Supported Rhodium Oxide Nanoparticles as Highly Active CO Oxidation Catalysts.
Ligthart DA, van Santen RA, Hensen EJ.
Angew Chem Int Ed Engl. 2011 Apr 20. doi: 10.1002/anie.201100190. [Epub ahead of print] No abstract available.
PMID:
21509919
[PubMed - as supplied by publisher]
Thermal diffusion of (57)Co into rhodium matrix as a second step in preparing Mössbauer sources.
Cieszykowska I, Zóltowska M, Zachariasz P, Piasecki A, Janiak T, Mielcarski M.
Appl Radiat Isot. 2011 Apr 8. [Epub ahead of print]
PMID:
21507667
[PubMed - as supplied by publisher]
Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch.
González-Rodríguez C, Pawley RJ, Chaplin AB, Thompson AL, Weller AS, Willis MC.
Angew Chem Int Ed Engl. 2011 Apr 19. doi: 10.1002/anie.201100956. [Epub ahead of print] No abstract available.
PMID:
21506226
[PubMed - as supplied by publisher]
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