Praseodymium Acetate is a moderately water soluble crystalline Praseodymium source that decomposes to Praseodymium oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. Praseodymium is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. We also produce Praseodymium Acetate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Praseodymium is a Block F, Group 3, Period 6 element. The number of electrons in each of Praseodymium's shells is 2, 8, 18, 21, 8, 2 and its electronic configuration is [Xe]4f3 6s2. In its elemental form praseodymium's CAS number is 7440-10-0. The praseodymium atom has a radius of 182.pm and it's Van der Waals radius is is unknown. Praseodymium is somewhat toxic. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Praseodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. The element is found in most all light rare earth derivatives. It is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. Much research is being done on its optical properties for use in amplification of telecommunication systems, including as a doping agent in fluoride fibers. The origin of the element name comes from the Greek words 'prasios didymos' meaning green twin. See Praseodymium research below.
Acetate is an anion used as a ligand in metal complexes. The formula is CH3CO2-, C2H3O2-, or CH3COO-. Metal acetates are used in biology, printing, vinyl acetate in plastic production, volatile organic esters as solvents and cellulose acetate in photographic films and textiles. Cellulose acetate, one of the first synthetic fibers, is often called acetate.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Superbroadband near-IR emission from praseodymium-doped bismuth gallate glasses.
Zhou B, Pun EY.
Opt Lett. 2011 Aug 1;36(15):2958-60. doi: 10.1364/OL.36.002958.
PMID:
21808371
[PubMed - in process]
Pr(16)Mo(21)O(56).
Gougeon P, Gall P.
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):i34-i35. Epub 2011 Apr 29.
PMID:
21754260
[PubMed]
Internal radiotherapy techniques using radiolanthanide praseodymium-142: a review of production routes, brachytherapy, unsealed source therapy.
Bakht MK, Sadeghi M.
Ann Nucl Med. 2011 Jul 1. [Epub ahead of print]
PMID:
21720780
[PubMed - as supplied by publisher]
Fluorescence and DNA-binding properties of neodymium(III) and praseodymium(III) complexes containing 1,10-phenanthroline.
Khorasani-Motlagh M, Noroozifar M, Mirkazehi-Rigi S.
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Sep;79(5):978-84. Epub 2011 May 7.
PMID:
21669548
[PubMed - in process]
Praseodymium(III) sulfate hydroxide, Pr(SO(4))(OH).
Wang XJ, Cheng JW.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):i12.
PMID:
21522810
[PubMed]
Electrical conductivity and defect equilibria of Pr0.1Ce0.9O(2-d).
Bishop SR, Stefanik TS, Tuller HL.
Phys Chem Chem Phys. 2011 Jun 7;13(21):10165-73. Epub 2011 Apr 26.
PMID:
21519609
[PubMed - in process]
Enhanced emission of 2.7 µm pumped by laser diode from Er3+/Pr(3+)-codoped germanate glasses.
Xu R, Tian Y, Hu L, Zhang J.
Opt Lett. 2011 Apr 1;36(7):1173-5. doi: 10.1364/OL.36.001173.
PMID:
21479020
[PubMed - indexed for MEDLINE]
Effect of graded levels of rare earth elements in diets of fattening bulls on growing and slaughtering performance, and on nutrient digestibility of wethers.
Schwabe A, Meyer U, Flachowsky G, Dänicke S.
Arch Anim Nutr. 2011 Feb;65(1):55-73.
PMID:
21452614
[PubMed - indexed for MEDLINE]
Influence of rare-earth ions on SiO2-Na2O-RE2O3 glass structure.
Johnson JA, Benmore CJ, Holland D, Du J, Beuneu B, Mekki A.
J Phys Condens Matter. 2011 Feb 16;23(6):065404. Epub 2011 Jan 27.
PMID:
21406929
[PubMed]
Poly[[tetra-µ3-acetato-hexa-µ2-acetato-diaqua-µ2-oxalato-tetrapraseodymium(III)] dihydrate].
Gutkowski K, Freire E, Baggio R.
Acta Crystallogr C. 2011 Mar;67(Pt 3):m77-80. Epub 2011 Feb 18.
PMID:
21368405
[PubMed]
Metallic and insulating oxide interfaces controlled by electronic correlations.
Jang HW, Felker DA, Bark CW, Wang Y, Niranjan MK, Nelson CT, Zhang Y, Su D, Folkman CM, Baek SH, Lee S, Janicka K, Zhu Y, Pan XQ, Fong DD, Tsymbal EY, Rzchowski MS, Eom CB.
Science. 2011 Feb 18;331(6019):886-9.
PMID:
21330538
[PubMed]
Decrease of liposomal size and retarding effect on fluconazole skin permeation by lysine derivatives.
Schwarz JC, Kählig H, Matsko NB, Kratzel M, Husa M, Valenta C.
J Pharm Sci. 2011 Jul;100(7):2911-9. doi: 10.1002/jps.22513. Epub 2011 Feb 11.
PMID:
21319163
[PubMed - in process]
Interferometric measurement of laser heating in praseodymium-doped YAG crystal.
Farley CW 3rd, Reddy BR.
Appl Opt. 2011 Feb 1;50(4):526-31. doi: 10.1364/AO.50.000526.
PMID:
21283244
[PubMed]
Observation of 2.7 µm emission from diode-pumped Er3+/Pr3+-codoped fluorophosphate glass.
Tian Y, Xu R, Zhang L, Hu L, Zhang J.
Opt Lett. 2011 Jan 15;36(2):109-11. doi: 10.1364/OL.36.000109.
PMID:
21263469
[PubMed - indexed for MEDLINE]
Spectroscopic studies on the interaction between Pr(III) complex of an ofloxacin derivative and bovine serum albumin or DNA.
Xu M, Ma ZR, Huang L, Chen FJ, Zeng ZZ.
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Jan;78(1):503-11. Epub 2010 Nov 23.
PMID:
21156349
[PubMed - indexed for MEDLINE]
Study on fluorescence and DNA-binding of praseodymium(III) complex containing 2,2'-bipyridine.
Khorasani-Motlagh M, Noroozifar M, Khmmarnia S.
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Jan;78(1):389-95. Epub 2010 Oct 30.
PMID:
21130681
[PubMed - indexed for MEDLINE]
The correlation between f-f absorption and sensitized visible light emission of luminescent Pr(III) complexes: role of solvents and ancillary ligands on sensitivity.
Irfanullah M, Iftikhar K.
J Fluoresc. 2011 Mar;21(2):673-86. Epub 2010 Nov 3.
PMID:
21046438
[PubMed - in process]
Synthesis, characterization, antioxidant activities, and DNA-binding studies of (E)-N'-[1-(pyridin-2-yl)ethylidene]isonicotinohydrazide and its Pr(III) and Nd(III) complexes.
Hao ZY, Liu QW, Xu J, Jia L, Li SB.
Chem Pharm Bull (Tokyo). 2010 Oct;58(10):1306-12.
PMID:
20930395
[PubMed - indexed for MEDLINE]
Autogenic synthesis of green- and red-emitting single-phase Pr(2)O(2)CO(3) and PrO(1.833) luminescent nanopowders.
Calderon Moreno JM, Pol VG, Suh SH, Popa M.
Inorg Chem. 2010 Nov 1;49(21):10067-73.
PMID:
20923161
[PubMed]
Morphological and electrochemical properties of crystalline praseodymium oxide nanorods.
Shamshi Hassan M, Shaheer Akhtar M, Shim KB, Yang OB.
Nanoscale Res Lett. 2010 Feb 5;5(4):735-40.
PMID:
20672103
[PubMed]
Information pertaining to particular dangers for man and environment
Not applicable
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek medical treatment.
5 Fire fighting measures
Suitable extinguishing agents
Use fire fighting measures that suit the environment.
Special hazards caused by the material, its products of combustion or flue gases:
Can be released in case of fire:
Carbon monoxide and carbon dioxide
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting: Collect mechanically.
Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
Handling
Information for safe handling:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
No special precautions necessary if used correctly.
Information about protection against explosions and fires:
The product is not flammable
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Do not store together with alkalis (caustic solutions).
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with critical values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Breathing equipment: Use breathing protection with high concentrations.
Protection of hands: Impervious gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Crystalline aggregates
Colour: Green
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicable
Inflammability (solid, gaseous) Product is not inflammable.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Danger of explosion: Product is not explosive.
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density Not determined
Solubility in / Miscibility with
Water: Soluble
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Materials to be avoided:
Acids
Bases
Dangerous reactions: No dangerous reactions known
Dangerous products of decomposition: Carbon monoxide and carbon dioxide
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: May cause irritation
on the eye: May cause irritation
Sensitization: No sensitizing effect known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Recommended cleaning agent: Water, if necessary with cleaning agent.
14 Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
ADR/RID-GGVS/E Class: None
Maritime transport IMDG/GGVSea:
IMDG/GGVSea Class: None
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: None
Transport/Additional information:
Not dangerous according to the above specifications.
15 Regulatory information
Designation according to EC guidelines:
Observe the normal safety regulations when handling chemicals
The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials (GefStoffV).
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Praseodymium Acetate is a moderately water soluble crystalline Praseodymium source that decomposes to Praseodymium oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. Praseodymium is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. We also produce Praseodymium Acetate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Praseodymium is a Block F, Group 3, Period 6 element. The number of electrons in each of Praseodymium's shells is 2, 8, 18, 21, 8, 2 and its electronic configuration is [Xe]4f3 6s2. In its elemental form praseodymium's CAS number is 7440-10-0. The praseodymium atom has a radius of 182.pm and it's Van der Waals radius is is unknown. Praseodymium is somewhat toxic. Praseodymium resembles the typical trivalent rare earths, however, it will
exhibit a +4 state when stabilized in a zirconia host. Praseodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form 
of foil, sputtering target, and rod, and compounds as submicron and nanopowder. The element is found in most all light rare earth derivatives. It is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. Much research is being done on its optical properties for use in amplification of telecommunication systems, including as a doping agent in fluoride fibers. The origin of the element name comes from the Greek words 'prasios didymos' meaning green twin. See Praseodymium research below.
