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Praseodymium Fluoride Sputtering Target
Product
Product Code
Order or Specifications
99.9% Praseodymium Fluoride Sputtering Target
PR-F-03ST
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99.99% Praseodymium Fluoride Sputtering Target
PR-F-04ST
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99.999% Praseodymium Fluoride Sputtering Target
PR-F-05ST
Contact American Elements
 
American Elements specializes in producing high purity Praseodymium fluoride sputtering targets with the highest possible density and smallest possible average grain sizes for use in semiconductor, chemical vapor deposition (CVD) and physical vapor deposition (PVD) display and optical applications. Our standard Sputtering Targets for thin film are available monoblock or bonded with dimensions and configurations up to 820 mm with hole drill locations and threading, beveling, grooves and backing designed to work with both older sputtering devises as well as the latest process equipment, such as large area coating for solar energy or fuel cells and flip-chip applications. Research sized targets are also produced as well as custom sizes and alloys. All targets are analyzed using best demonstrated techniques including X-Ray Fluorescence (XRF), Glow Discharge Mass Spectrometry (GDMS), and Inductively Coupled Plasma (ICP). "Sputtering" allows for thin film deposition of an ultra high purity sputtering metallic or oxide material onto another solid substrate by the controlled removal and conversion of the target material into a directed gaseous/plasma phase through ionic bombardment. We can also provide targets outside this range in addition to just about any size rectangular, annular, or oval target. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as other machined shapes and through other processes nanoparticles. We also produce Praseodymium Fluoride as rods, powder and plates. Other shapes are available by request.

Praseodymium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f36s2. In its elemental form praseodymium's CAS number is 7440-10-0. The praseodymium atom has a radius of 182.pm and it's Van der Waals radius is is unknown. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Praseodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Formula CAS No. Appearance Molecular Weight Density Melting Point Boiling Point Solubility Stability
PrF3 13709-46-1 Green 197.90 6300 kg/m³ 1395 °C   Insoluble in water, moderately soluble in strong mineral acids Slightly hygroscopic
PRODUCT CATALOG Praseodymium Research, Properties, & Information Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. MSDS
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Recent Research & Development for Praseodymium

  • New M(3)N@C(2n) Endohedral Metallofullerene Families (M=Nd, Pr, Ce; n=40-53): Expanding the Preferential Templating of the C(88) Cage and Approaching the C(96) Cage. Chemistry. 2008 Apr 9;14(15):4594-4599. [Epub ahead of print]

  • Tuning the self-assembly of lanthanide triple stranded heterobimetallic helicates by ligand design. Dalton Trans. 2008 Feb 28;(8):1027-36. Epub 2007 Dec 4.

  • Luminescence properties of praseodymium- and erbium-doped silver bromide crystals. Appl Opt. 1997 Oct 20;36(30):7708-11.

  • Orthogonal sample design scheme for two-dimensional synchronous spectroscopy and its application in probing intermolecular interactions. Appl Spectrosc. 2007 Dec;61(12):1359-65.

  • Photorefractive two-step recording in a piezoelectric La(3)Ga(5)SiO(14) crystal doped with praseodymium. Opt Lett. 1998 Aug 1;23(15):1164-6.

  • Praseodymium methanesulfonate catalyzed one-pot synthesis of 3,4-dihydropyrimidin-2-(1H)-ones. Prep Biochem Biotechnol. 2008;38(1):105-14.

  • Doping of an absorbent into a Raman crystal for suppression of higher-order Stokes generation. Opt Lett. 2000 May 15;25(10):752-4.

  • Structural basis for the biological effects of Pr(III) ions: alteration of cell membrane permeability. Biol Trace Elem Res. 2007 Winter;120(1-3):141-7.

  • Structural varieties in heterobimetallic lanthanide disiloxanediolates: "inorganic metallocenes" versus in-plane metallacrowns. Inorg Chem. 2007 Nov 26;46(24):10383-9. Epub 2007 Oct 2.

  • High-power GaN diode-pumped continuous wave Pr3+-doped LiYF4 laser. Opt Lett. 2007 Sep 1;32(17):2493-5.

  • Cross-sensitive rare-earth metal sensors based on bidentate neutral organophosphorus compounds and chlorinated cobalt dicarbollide. Anal Chim Acta. 2006 Jul 21;572(2):243-7. Epub 2006 May 27.

  • Crystallographic and vibrational spectroscopic studies of octakis(DMSO)lanthanoid(III) iodides. Inorg Chem. 2007 Sep 17;46(19):7731-41. Epub 2007 Aug 24.

  • Homoleptic rare-earth metal(III) tetramethylaluminates: structural chemistry, reactivity, and performance in isoprene polymerization. Chemistry. 2007;13(31):8784-800.

  • Photocatalytic degradation of phenol in aqueous solutions by Pr-doped TiO2 nanoparticles. J Hazard Mater. 2007 Oct 1;149(1):1-7. Epub 2007 Mar 16.

  • Chemically immobilized single-stranded oligonucleotides on praseodymium oxide nanoparticles as an unlabeled DNA sensor probe using impedance. Angew Chem Int Ed Engl. 2007;46(21):3855-9. No abstract available.

  • Frequency upconversion in Pr3+-Li2O-TeO2 binary glass by decay curve analysis. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Nov;68(3):460-2. Epub 2006 Dec 15.

  • Nuclear magnetic resonance and optical absorption spectroscopic studies on paramagnetic praseodymium(III) complexes with beta-diketone and heterocyclic amines. Spectrochim Acta A Mol Biomol Spectrosc. 2007 Sep;68(1):176-83. Epub 2006 Nov 21.

  • Modified rare earth semiconductor oxide as a new nucleotide probe. J Phys Chem B. 2006 Dec 28;110(51):25633-7.

  • Feasibility and safety of intra-coronary Beta irradiation with 144Ce/Pr for prevention of restenosis after percutaneous transluminal coronary angioplasty of in-stent restenotic lesions. Acute Card Care. 2006;8(4):217-23.

  • Studies on the sorption of praseodymium (III), holmium (III) and cobalt (II) from nitrate medium using TVEX-PHOR resin. J Hazard Mater. 2007 May 8;143(1-2):17-23. Epub 2006 Sep 1.

 

 

Material Safety Data Sheet
  • 1 Identification of substance

    • Product details

    • Trade name Praseodymium (III) fluoride
  • 2 Composition/Data on components:

    • Chemical characterization:
                 Designation: (CAS#)                                        
      Praseodymium (III) fluoride, anhydrous (CAS# 13709-46-1),
                   100%
    • Identification number(s):
    • EINECS Number: 237-254-9
  • 3 Hazards identification

    • Hazard designation: Xn Harmful
    • Information pertaining to particular dangers for man and environment
      R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
      R 36/37/38 Irritating to eyes, respiratory system and skin.
  • 4 First aid measures

    • After inhalation
      Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
      Seek immediate medical advice.
    • After skin contact
      Instantly wash with water and soap and rinse thoroughly.
      Seek immediate medical advice.
      Rub in Ca-gluconate solution or Ca-gluconate gel immediately.
    • After eye contact
      Rinse opened eye for several minutes under running water. Then consult doctor.
    • After swallowing Seek immediate medical advice.
  • 5 Fire fighting measures

    • Suitable extinguishing agents
      Use fire fighting measures that suit the environment.
    • Special hazards caused by the material, its products of combustion or
        flue gases:
      Can be released in case of fire:
      Hydrogen fluoride (HF)
    • Protective equipment:
      Wear self-contained breathing apparatus.
      Wear full protective suit.
  • 6 Accidental release measures

    • Person-related safety precautions:
      Wear protective equipment. Keep unprotected persons away.
      Ensure adequate ventilation
    • Measures for environmental protection:
      Do not allow material to be released to the environment without proper governmental permits.
    • Measures for cleaning/collecting:
      Dispose of contaminated material as waste according to item 13.
      Ensure adequate ventilation.
    • Additional information:
      See Section 7 for information on safe handling
      See section 8 for information on personal protection equipment.
      See Section 13 for information on disposal.
  • 7 Handling and storage


    • Handling
    • Information for safe handling:
      Keep containers tightly sealed.
      Store in cool, dry place in tightly closed containers.
      Ensure good ventilation/exhaustion at the workplace.
    • Information about protection against explosions and fires:
      The product is not flammable

    • Storage
    • Requirements to be met by storerooms and containers:
      No special requirements.
    • Information about storage in one common storage facility:
      Do not store together with acids.
    • Further information about storage conditions:
      This product is hygroscopic.
      Protect from humidity and keep away from water.
      Protect from carbon dioxide.
      Keep container tightly sealed.
      Store in cool, dry conditions in well sealed containers.
  • 8 Exposure controls and personal protection

    • Additional information about design of technical systems:
      Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

    • Components with critical values that require monitoring at the
      workplace:                                                             

      Fluorides (as F)
                             mg/m3
      ACGIH TLV             2.5
      Austria TWA           2.5
      Belgium TWA           2.5
      Finland TWA           2.5
      France  TWA           2.5
      Germany MAK           2.5
      Hungary TWA           1; 2-STEL
      Netherlands TWA       3.5
      Norway TWA            0.6
      Poland TWA            1; 3-STEL
      Sweden NGV            2
      Switzerland MAK-W     1.5
      United Kingdom TWA    2.5
      Russia TWA            2
      Denmark TWA           2.5
      USA PEL               2.5
    • Additional information: No data

    • Personal protective equipment
    • General protective and hygienic measures
      The usual precautionary measures should be adhered to in handling the chemicals.
      Keep away from foodstuffs, beverages and food.
      Instantly remove any soiled and impregnated garments.
      Wash hands during breaks and at the end of the work.
      Avoid contact with the eyes and skin.
    • Breathing equipment: Use breathing protection with high concentrations.
    • Protection of hands: Impervious gloves
    • Eye protection:
      Safety glasses
      Face protection
    • Body protection: Protective work clothing.
  • 9 Physical and chemical properties:

    • General Information

    • Form: Chunks
    • Colour: Green
    • Smell: Odourless
    •   Value/Range  Unit    Method      
    • Change in condition
    • Melting point/Melting range:                  1395 ° C
    • Boiling point/Boiling range:       Not determined
    • Sublimation temperature / start:   Not determined

    • Flash point:                       Not applicable

    • Ignition temperature:              Not determined

    • Decomposition temperature:         Not determined

    • Danger of explosion:               Product is not explosive.

    • Critical values for explosion:
    • Lower:                             Not determined
    • Upper:                             Not determined

    • Steam pressure:                    Not determined

    • Density                at   20 ° C             6.2 g/cm³

    • Solubility in / Miscibility with
    • Water:                             Insoluble
      Not miscible or difficult to mix
  • 10 Stability and reactivity

    • Thermal decomposition / conditions to be avoided:
      No decomposition if used and stored according to specifications.
    • Materials to be avoided: Acids
    • Dangerous reactions: No dangerous reactions known
    • Dangerous products of decomposition: Hydrogen fluoride
  • 11 Toxicological information

    • Acute toxicity:
    • Primary irritant effect:
    • on the skin: Irritant for skin and mucous membranes.
    • on the eye: Irritant effect.
    • Sensitization: No sensitizing effect known.
    • Additional toxicological information:
      Danger by skin resorption.
      To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
      No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
  • 12 Ecological information:

    • General notes:
      Do not allow material to be released to the environment without proper governmental permits.
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
      Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
  • 13 Disposal considerations


    • Product:
    • Recommendation
      Consult state, local or national regulations for proper disposal.
      Hand over to disposers of hazardous waste.
      Must be specially treated under adherence to official regulations.

    • Uncleaned packagings:
    • Recommendation:
      Disposal must be made according to official regulations.
  • 14 Transport information


    • Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
    • ADR/RID-GGVS/E Class:     6.1 (T5) Toxic substances.
    • Kemler Number:            60
    • UN-Number:                3288
    • Packaging group:          III
    • Label                     6.1
    • Designation of goods:     3288 TOXIC SOLID, INORGANIC, N.O.S.
                                 (praseodymium fluoride)

    • Maritime transport IMDG/GGVSea:
    • IMDG/GGVSea Class:        6.1
    • UN Number:                3288
    • Label                     6.1
    • Packaging group:          III
    • Correct technical name:   TOXIC SOLID, INORGANIC, N.O.S. (praseodymium
                                 fluoride)

    • Air transport ICAO-TI and IATA-DGR:
    • ICAO/IATA Class:          6.1
    • UN/ID Number:             3288
    • Label                     6.1
    • Packaging group:          III
    • Correct technical name:   TOXIC SOLID, INORGANIC, N.O.S. (praseodymium
                                 fluoride)
  • 15 Regulatory information


    • Designation according to EC guidelines:

    • Code letter and hazard designation of product: Xn Harmful

    • Risk phrases:
      20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
      36/37/38 Irritating to eyes, respiratory system and skin.

    • Safety phrases:
      9        Keep container in a well-ventilated place.
      26       In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
      36/37    Wear suitable protective clothing and gloves.

    • National regulations

    • Information about limitation of use:
      For use only by technically qualified individuals.
      Employment restrictions concerning young persons must be observed.

    • Water hazard class:
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
  • 16 Other information:

      Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees.  This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
  •  

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