Praseodymium Hydride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Hydride compounds are used often used as portable sources of hydrogen gas.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Praseodymium is a Block F, Group 3, Period 6 element. The number of electrons in each of Praseodymium's shells is 2, 8, 18, 21, 8, 2 and its electronic configuration is [Xe]4f3 6s2. In its elemental form praseodymium's CAS number is 7440-10-0. The praseodymium atom has a radius of 182.pm and it's Van der Waals radius is is unknown. Praseodymium is somewhat toxic. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Praseodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. The element is found in most all light rare earth derivatives. It is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. Much research is being done on its optical properties for use in amplification of telecommunication systems, including as a doping agent in fluoride fibers. The origin of the element name comes from the Greek words 'prasios didymos' meaning green twin. See Praseodymium research below.
Hydrogen is a Block S, Group 1, Period 1 element. The electronic configuration is 1s1. In its elemental form hydrogen's CAS number is 1333-74-0. The hydrogen atom has a radius of 37.3.pm and it's Van der Waals radius is 120.pm. Hydrogen is highly flammable. Hydrogen was discovered by Sir Henry Cavendish in 1766.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Synthesis mechanism of low-voltage praseodymium oxide doped zinc oxide varistor ceramics prepared through modified citrate gel coating.
Abdullah WR, Zakaria A, Ghazali MS.
Int J Mol Sci. 2012;13(4):5278-89. Epub 2012 Apr 24.
PMID:
22606043
[PubMed - in process]
Inorganic-organic hybrid compounds based on novel lanthanide-antimony oxohalide nanoclusters.
Hu B, Zou GD, Feng ML, Huang XY.
Dalton Trans. 2012 May 2. [Epub ahead of print]
PMID:
22549083
[PubMed - as supplied by publisher]
High pressure luminescence spectra of CaMoO(4):Pr(3+).
Mahlik S, Grinberg M, Cavalli E, Bettinelli M.
J Phys Condens Matter. 2012 May 30;24(21):215402. Epub 2012 Apr 27.
PMID:
22543332
[PubMed - in process]
Bremsstrahlung parameters of praseodymium-142 in different human tissues: a dosimetric perspective for (142)Pr radionuclide therapy.
Bakht MK, Jabal-Ameli H, Ahmadi SJ, Sadeghi M, Sadjadi S, Tenreiro C.
Ann Nucl Med. 2012 Apr 12. [Epub ahead of print]
PMID:
22528970
[PubMed - as supplied by publisher]
Superbroadband near-IR photoluminescence from Pr3+-doped fluorotellurite glasses.
Zhou B, Tao L, Tsang YH, Jin W, Pun EY.
Opt Express. 2012 Feb 13;20(4):3803-13. doi: 10.1364/OE.20.003803.
PMID:
22418137
[PubMed - in process]
Upgrade of the resonance ionization laser ion source at ISOLDE on-line isotope separation facility: new lasers and new ion beams.
Fedosseev VN, Berg LE, Fedorov DV, Fink D, Launila OJ, Losito R, Marsh BA, Rossel RE, Rothe S, Seliverstov MD, Sjödin AM, Wendt KD.
Rev Sci Instrum. 2012 Feb;83(2):02A903.
PMID:
22380244
[PubMed - in process]
Uncovering the global life cycles of the rare Earth elements.
Du X, Graedel TE.
Sci Rep. 2011;1:145. Epub 2011 Nov 4.
PMID:
22355662
[PubMed]
Nonaaqua-praseodymium triiodide-thio-urea (1/2).
Antonenko TA, Alikberova LY, Albov DV.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m110. Epub 2012 Jan 7.
PMID:
22346801
[PubMed - in process]
Di-?-pivalato-?O,O':O';?O:O,O'-bis-[(methanol-?O)bis-(2,2,6,6-tetra-methylhepta-ne-3,5-dionato)praseo-dymium(III)].
Meng Q, Cross AM, May PS, Sykes AG, Berry MT.
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov 1;67(Pt 11):m1514-5. Epub 2011 Oct 12.
PMID:
22219764
[PubMed - in process]
The matlockite-type praseodymium(III) oxide bromide PrOBr.
Talmon-Gros P, Schurz CM, Schleid T.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):i74. Epub 2011 Nov 23.
PMID:
22199472
[PubMed - in process]
Selected trace elements in the sacramento river, california: occurrence and distribution.
Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P.
Arch Environ Contam Toxicol. 2012 May;62(4):557-69. Epub 2011 Dec 23.
PMID:
22193863
[PubMed - in process]
NaYF4:Pr3+ nanocrystals displaying photon cascade emission.
Gusowski MA, Swart HC, Karlsson LS, Trzebiatowska-Gusowska M.
Nanoscale. 2012 Jan 21;4(2):541-6. Epub 2011 Nov 29.
PMID:
22127460
[PubMed - indexed for MEDLINE]
Tetra-kis(?-4-tert-butyl-benzoato)-?O:O,O';?O,O':O';?O:O'-bis-[aqua-bis-(4-tert-butyl-benzoato-?O,O')(4-tert-butyl-benzoic acid-?O)praseodymium(III)].
Dai J, Pan RK, Yang J.
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1160-1. Epub 2011 Jul 30.
PMID:
22090916
[PubMed]
Unusual spectral renormalization in hexaborides.
Patil S, Adhikary G, Balakrishnan G, Maiti K.
J Phys Condens Matter. 2011 Dec 14;23(49):495601. Epub 2011 Nov 17.
PMID:
22089641
[PubMed - indexed for MEDLINE]
Novel lanthanide-based polymeric chains and corresponding ultrafast dynamics in solution.
Thielemann DT, Klinger M, Wolf TJ, Lan Y, Wernsdorfer W, Busse M, Roesky PW, Unterreiner AN, Powell AK, Junk PC, Deacon GB.
Inorg Chem. 2011 Dec 5;50(23):11990-2000. Epub 2011 Nov 8.
PMID:
22066577
[PubMed]
catena-Poly[[[bis-(3-amino-pyrazine-2-carboxyl-ato)triaqua-praseodymium(III)]-?-3-amino-pyrazine-2-carboxyl-ato-[(3-amino-pyrazine-2-carboxyl-ato)diaqua-formatopraseodymium(III)]-?-3-amino-pyrazine-2-carboxyl-ato] hexa-hydrate].
Gao S, Ng SW.
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1221-2. Epub 2011 Aug 11.
PMID:
22065704
[PubMed]
Tetra-kis(?-2-phen-oxy-propionato)-?O,O':O';?O:O,O',?O:O'-bis-[(1,10-phenanthroline-?N,N')(2-phen-oxy-propionato-?O,O')praseodymium(III)].
Shen JB, Liu JL, Zhao GL.
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1321. Epub 2011 Aug 31.
PMID:
22058896
[PubMed]
Poly[diaquabis-(?(4)-fumarato-?O:O:O:O)(?(4)-fumarato-?O:O,O:O:O,O)(?(2)-fumaric acid-?O:O)dipraseodymium(III)].
Liu PL, Cao W, Wang J, Zeng RH, Zeng Z.
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1433-4. Epub 2011 Sep 30.
PMID:
22058712
[PubMed]
Spectroscopic properties and upconversion in Pr3+:YF3 nanoparticles.
Pellé F, Dhaouadi M, Michely L, Aschehoug P, Toncelli A, Veronesi S, Tonelli M.
Phys Chem Chem Phys. 2011 Oct 21;13(39):17453-60. Epub 2011 Sep 2.
PMID:
21887443
[PubMed - indexed for MEDLINE]
Signatures of spin-glass behaviour in PrIr2B2 and heavy fermion behaviour in PrIr2B2C.
Anupam, Anand VK, Hossain Z, Adroja DT, Geibel C.
J Phys Condens Matter. 2011 Sep 21;23(37):376001. Epub 2011 Aug 31.
PMID:
21878715
[PubMed - indexed for MEDLINE]
Recent Research & Development for Hydride
Diazaphospholenes: N-Heterocyclic Phosphines between Molecules and
Lewis Pairs. Gudat D. Acc Chem Res. 2010 Jun 24. [Epub ahead of print] PubMed PMID:
20572668.
Thymidylate Synthase Catalyzed H-Transfers: Two Chapters in
One Tale. Wang Z, Kohen A. J Am Chem Soc. 2010 Jun 24. [Epub ahead of print] PubMed PMID:
20575541.
Cobalt-Mediated Linear 2:1 Co-oligomerization of Alkynes with Enol Ethers to Give
1-Alkoxy-1,3,5-Trienes: A Missing Mode of Reactivity. Lebœuf D, Iannazzo L, Geny A, Malacria M, Vollhardt KP, Aubert C, Gandon V. Chemistry. 2010 Jun 23.
[Epub ahead of print] PubMed PMID: 20575116.
Synthesis and evaluation of silica
hydride-based fluorinated stationary phases. Pesek JJ, Matyska MT, Prajapati KV. J Sep Sci. 2010 Jun 22. [Epub ahead
of print] PubMed PMID: 20572267.
Kinetics of substituted
silylene addition and elimination in silicon nanocluster growth captured by group
additivity. Adamczyk AJ, Reyniers MF, Marin GB, Broadbelt LJ. Chemphyschem. 2010 Jun 21;11(9):1978-94. PubMed PMID: 20549662.
Synthesis of 2-Boryl- and Silylindoles
by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl
Isocyanides. Tobisu M, Fujihara H, Koh K, Chatani N. J Org Chem. 2010 Jun 17. [Epub ahead of print] PubMed PMID:
20557065.
Thermal Decomposition of Mono- and
Bimetallic Magnesium Amidoborane Complexes. Spielmann J, Piesik DF, Harder S. Chemistry. 2010 Jun 16. [Epub ahead
of print] PubMed PMID: 20564288.
Versatile New C(3)-Symmetric Tripodal Tetraphosphine Ligands; Structural
Flexibility to Stabilize Cu(I) and Rh(I) Species and Tune Their Reactivity. Wassenaar J, Siegler MA, Spek AL, de Bruin B, Reek JN, van der Vlugt JI. Inorg
Chem. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20552965.
Iron-Catalyzed Hydrogen Production from Formic Acid. Boddien A, Loges B, Ga¨rtner F, Torborg C, Fumino K, Junge H, Ludwig R, Beller
M. J Am Chem Soc. 2010 Jun
15. [Epub ahead of print] PubMed PMID: 20550131.
Intermolecular Dehydrative Coupling Reaction of Arylketones
with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride
Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation.
Yi CS, Lee DW. Organometallics. 2010 Mar 19;29(8):1883-1885. PubMed PMID: 20567607; PubMed
Central PMCID: PMC2887707.
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