Praseodymium Selenide (PrSe) is a crystal grown product generally immediately available in most volumes. Technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Praseodymium is a Block F, Group 3, Period 6 element. The number of electrons in each of Praseodymium's shells is 2, 8, 18, 21, 8, 2 and its electronic configuration is [Xe]4f3 6s2. In its elemental form praseodymium's CAS number is 7440-10-0. The praseodymium atom has a radius of 182.pm and it's Van der Waals radius is is unknown. Praseodymium is somewhat toxic. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Praseodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. The element is found in most all light rare earth derivatives. It is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. Much research is being done on its optical properties for use in amplification of telecommunication systems, including as a doping agent in fluoride fibers. The origin of the element name comes from the Greek words 'prasios didymos' meaning green twin. See Praseodymium research below.
Selenium is a Block P, Group 16, Period 4 element. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electronic configuration is [Ar] 3d10 4s2 4p4. In its elemental form selenium's CAS number is 7782-49-2. The selenium atom has a radius of 116.pm and it's Van der Waals radius is 190.pm. The EPA does not classify selenium as carcinogenic, although selenium sulfide is a probable carcinogen. Selenates and selenites which are compounds of selenium, are highly toxic. Hydrogen selenide gas (SeH2) is the most acutely toxic compound of selenium. Selenium exhibits both photovoltaic action, where light is converted directly into electricity, and photoconductive action, where the electrical resistance decreases with increased illumination. of photocells and exposure meters for photographic use, as well as solar cells. Below its melting point, selenium is a p-type semiconductor and has many uses in electronic and solid-state applications. Selenium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Selenium was first discovered by Jons Berzelius in 1817. The origin of the name Selenium comes from the Greek word "Selênê" meaning moon. See selenium research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
Crystal "pulling" by the Czochaiski method for production of semiconductor materials
Flux growth and gradient freeze
Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Autogenic Synthesis of Green- and
Red-Emitting Single-Phase Pr(2)O(2)CO(3) and PrO(1.833) Luminescent Nanopowders.
Calderon Moreno JM, Pol VG, Suh SH, Popa M. Inorg Chem. 2010 Oct 5. [Epub ahead of print] PubMed PMID: 20923161.
Cationic rare-earth-metal
methyl complexes: a new preparative access exemplified for Y and Pr. Nieland A, Mix A, Neumann B, Stammler HG, Mitzel NW. Dalton
Trans. 2010 Aug 7;39(29):6753-60. Epub 2010 May 4. PubMed PMID: 20442946.
Conversion of orange light into blue
light. Rai N, Jha Y, Kamal KP, Kumar S, Rai VK. Spectrochim Acta A Mol Biomol Spectrosc. 2010 Aug;76(3-4):311-4. Epub 2010
Mar 6. PubMed PMID: 20430692.
Efficient green
continuous-wave lasing of blue-diode-pumped solid-state lasers based on
praseodymium-doped LiYF4. Hansen NO, Bellancourt AR, Weichmann U, Huber G. Appl Opt. 2010 Jul 10;49(20):3864-8. doi:
10.1364/AO.49.003864. PubMed PMID: 20648158.
Praseodymium(III)-based
bis-metallacalix[4]arene with host-guest behaviour. Xu GF, Gamez P, Teat SJ, Tang J. Dalton Trans. 2010 May
14;39(18):4353-7. Epub 2010 Mar 24. PubMed PMID: 20422093.
Evaluation of short-term effects of rare earth and other elements used in
magnesium alloys on primary cells and cell lines. Feyerabend F, Fischer J, Holtz J, Witte F, Willumeit R, Drücker H, Vogt C,
Hort N. Acta Biomater. 2010
May;6(5):1834-42. Epub 2009 Oct 1. PubMed PMID: 19800429.
Carboxymethylated cyclodextrins and their complexes with Pr(III) and Yb(III) as
water-soluble chiral NMR solvating agents for cationic compounds. Provencher KA, Weber MA, Randall LA, Cunningham PR, Dignam CF, Wenzel TJ. Chirality. 2010
Mar;22(3):336-46. PubMed PMID: 19544350.
Crystal structure, diffusion path, and
oxygen permeability of a Pr(2)NiO(4)-based mixed conductor
(Pr(0.9)La(0.1))(2)(Ni(0.74)Cu(0.21)Ga(0.05))O(4+delta). Yashima M, Sirikanda N, Ishihara T. J Am Chem Soc. 2010 Feb
24;132(7):2385-92. PubMed PMID: 20121092.
Crystal structure and optical and magnetic properties of
Pr(2)(MoO(4))(3). Logvinovich D, Arakcheeva A, Pattison P, Eliseeva S, Tomes P, Marozau I,
Chapuis G. Inorg Chem. 2010 Feb 15;49(4):1587-94. PubMed PMID: 20067248.
Morphological and
Electrochemical Properties of Crystalline Praseodymium Oxide Nanorods. Shamshi Hassan M, Shaheer Akhtar M, Shim KB, Yang OB. Nanoscale
Res Lett. 2010 Feb 5;5(4):735-740. PubMed PMID: 20672103; PubMed Central PMCID:
PMC2894094.
Demonstration of atomic frequency
comb memory for light with spin-wave storage. Afzelius M, Usmani I, Amari A, Lauritzen B, Walther A, Simon C, Sangouard N,
Minár J, de Riedmatten H, Gisin N, Kröll S. Phys Rev Lett. 2010 Jan
29;104(4):040503. Epub 2010 Jan 27. PubMed PMID: 20366694.
Triggered instability of liposomes bound to hydrophobically modified core-shell
PNIPAM hydrogel beads. MacKinnon N, Guérin G, Liu B, Gradinaru CC, Rubinstein JL, Macdonald PM. Langmuir. 2010 Jan 19;26(2):1081-9. PubMed PMID: 19754070.
Templated assembly
of mu(5)-CO3(2-) decanuclear praseodymium and neodymium clusters through
spontaneous fixation of atmospheric carbon dioxide. Ke H, Zhao L, Xu GF, Guo YN, Tang J, Zhang XY, Zhang HJ. Dalton Trans. 2009 Dec
21;(47):10609-13. Epub 2009 Nov 2. PubMed PMID: 20023886.
Efficacy and safety of lanthanoids as X-ray contrast agents. Pietsch H, Jost G, Frenzel T, Raschke M, Walter J, Schirmer H, Hütter J,
Sieber MA. Eur J
Radiol. [Epub ahead of print] PubMed PMID: 20006455.
The permanent electric dipole moments and
magnetic g(e)-factors of praseodymium monoxide (PrO). Wang H, Linton C, Ma T, Steimle TC. J Phys Chem A. 2009 Nov
26;113(47):13372-8. PubMed PMID: 19921945.
Pr3+-doped fluoro-oxide lithium glass as
scintillator for nuclear fusion diagnostics. Arikawa Y, Yamanoi K, Nakazato T, Estacio ES, Shimizu T, Sarukura N, Nakai M,
Norimatsu T, Azechi H, Murata T, Fujino S, Yoshida H, Kamada K, Usuki Y, Suyama
T, Yoshikawa A, Sato N, Kan H. Rev Sci Instrum. 2009
Nov;80(11):113504. PubMed PMID: 19947728.
Comparative studies of
praseodymium(III) selective sensors based on newly synthesized Schiff's bases.
Gupta VK, Goyal RN, Pal MK, Sharma RA. Anal Chim Acta. 2009 Oct 27;653(2):161-6. Epub 2009 Sep 9. PubMed PMID: 19808108.
Ethanol electrooxidation on Pt/C catalysts
promoted with praseodymium oxide nanorods. Wang Y, Nguyen TS, Wang C, Wang X. Dalton Trans. 2009 Oct 7;(37):7606-9.
Epub 2009 Jul 27. PubMed PMID: 19759930.
Computation of energy interaction
parameters as well as electric dipole intensity parameters for the absorption
spectral study of the interaction of Pr(III) with l-phenylalanine, l-glycine,
l-alanine and l-aspartic acid in the presence and absence of Ca2+ in organic
solvents. Moaienla T, Singh TD, Singh NR, Devi MI. Spectrochim Acta A Mol Biomol Spectrosc. 2009 Oct 1;74(2):434-40. Epub
2009 Jun 24. PubMed PMID: 19615935.
High dielectric constant PrY(x)O(y) sensing films
electrolyte-insulator-semiconductor pH-sensor for the detection of urea. Wu MH, Lee CD, Pan TM. Anal
Chim Acta. 2009 Sep 28;651(1):36-41. Epub 2009 Aug 18. PubMed PMID: 19733732.
Selenoprotein K binds multi-protein complexes and is involved in the regulation of ER homeostasis.
Shchedrina VA, Everley RA, Zhang Y, Gygi SP, Hatfield DL, Gladyshev VN.
J Biol Chem. 2011 Oct 20. [Epub ahead of print]
PMID:
22016385
[PubMed - as supplied by publisher]
Catalytic activity of selenomethionine in removing amino acid, peptide, and protein hydroperoxides.
Suryo Rahmanto A, Davies MJ.
Free Radic Biol Med. 2011 Oct 1. [Epub ahead of print]
PMID:
22015433
[PubMed - as supplied by publisher]
Combination of chemometrically assisted voltammetry, calorimetry, and circular dichroism as a new method for the study of bioinorganic substances: application to selenocystine metal complexes.
Gusmão R, Prohens R, Díaz-Cruz JM, Ariño C, Esteban M.
J Biol Inorg Chem. 2011 Oct 21. [Epub ahead of print]
PMID:
22015398
[PubMed - as supplied by publisher]
Marine and farmed fish on the Polish market: Comparison of the nutritive value and human exposure to PCDD/Fs and other contaminants.
Szlinder-Richert J, Usydus Z, Malesa-Ciecwierz M, Polak-Juszczak L, Ruczynska W.
Chemosphere. 2011 Oct 17. [Epub ahead of print]
PMID:
22014661
[PubMed - as supplied by publisher]
Dietary selenium reduces retention of methyl mercury in freshwater fish.
Bjerregaard P, Fjordside S, Hansen MG, Petrova MB.
Environ Sci Technol. 2011 Oct 20. [Epub ahead of print]
PMID:
22014184
[PubMed - as supplied by publisher]
Plant and fungal food components with potential activity on the development of microbial oral diseases.
Daglia M, Papetti A, Mascherpa D, Grisoli P, Giusto G, Lingström P, Pratten J, Signoretto C, Spratt DA, Wilson M, Zaura E, Gazzani G.
J Biomed Biotechnol. 2011;2011:274578. Epub 2011 Oct 17.
PMID:
22013381
[PubMed - in process]
Selenium, selenoproteins and the thyroid gland: interactions in health and disease.
Schomburg L.
Nat Rev Endocrinol. 2011 Oct 18. doi: 10.1038/nrendo.2011.174. [Epub ahead of print]
PMID:
22009156
[PubMed - as supplied by publisher]
Selenium inhibits migration of murine melanoma cells via down-modulation of IL-18 expression.
Song H, Kim J, Lee HK, Park HJ, Nam J, Park GB, Kim YS, Cho D, Hur DY.
Int Immunopharmacol. 2011 Oct 15. [Epub ahead of print]
PMID:
22008306
[PubMed - as supplied by publisher]
Detection, Identification, and Quantification of Selenoproteins in a Candidate Human Plasma Standard Reference Material.
Ballihaut G, Kilpatrick LE, Davis WC.
Anal Chem. 2011 Oct 18. [Epub ahead of print]
PMID:
22007999
[PubMed - as supplied by publisher]
Severe pre-eclampsia is associated with abnormal trace elements concentrations in maternal and fetal blood.
Katz O, Paz-Tal O, Lazer T, Aricha-Tamir B, Mazor M, Wiznitzer A, Sheiner E.
J Matern Fetal Neonatal Med. 2011 Oct 18. [Epub ahead of print]
PMID:
22007865
[PubMed - as supplied by publisher]
Effects of Selenium Supplements on Cancer Prevention: Meta-analysis of Randomized Controlled Trials.
Lee EH, Myung SK, Jeon YJ, Kim Y, Chang YJ, Ju W, Seo HG, Huh BY.
Nutr Cancer. 2011 Oct 17. [Epub ahead of print]
PMID:
22004275
[PubMed - as supplied by publisher]
Study of the correlation of serum selenium level with Behcet's disease.
Esalatmanesh K, Jamshidi A, Shahram F, Davatchi F, Masoud SA, Soleimani Z, Salesi M, Ghaffarpasand I.
Int J Rheum Dis. 2011 Oct;14(4):375-8. doi: 10.1111/j.1756-185X.2011.01649.x. Epub 2011 Sep 5.
PMID:
22004235
[PubMed - in process]
Multi-metal(loid) methylation in methanoarchaea is linked to central intermediates of methanogenesis.
Thomas F, Diaz-Bone RA, Wuerfel O, Huber B, Weidenbach K, Schmitz RA, Hensel R.
Appl Environ Microbiol. 2011 Oct 14. [Epub ahead of print]
PMID:
22003009
[PubMed - as supplied by publisher]
The Effects of Di(2-Ethylhexyl)Phthalate Exposure and Selenium Nutrition on Sertoli Cell Vimentin Structure and Germ-Cell Apoptosis in Rat Testis.
Erkekoglu P, Zeybek ND, Giray B, Asan E, Hincal F.
Arch Environ Contam Toxicol. 2011 Oct 16. [Epub ahead of print]
PMID:
22002783
[PubMed - as supplied by publisher]
A superoxide anion-scavenger, 1,3-selenazolidin-4-one suppresses serum deprivation-induced apoptosis in PC12 cells by activating MAP kinase.
Nishina A, Kimura H, Kozawa K, Sommen G, Nakamura T, Heimgartner H, Koketsu M, Furukawa S.
Toxicol Appl Pharmacol. 2011 Oct 2. [Epub ahead of print]
PMID:
22001386
[PubMed - as supplied by publisher]
Nutrition, dietary supplements and adenocarcinoma of the prostate.
Schultz C, Meier M, Schmid HP.
Maturitas. 2011 Oct 12. [Epub ahead of print]
PMID:
22001108
[PubMed - as supplied by publisher]
Interactions of Cu(I) with Selenium-Containing Amino Acids Determined by NMR, XAS, and DFT Studies.
Wang HC, Riahi M, Pothen J, Bayse CA, Riggs-Gelasco P, Brumaghim JL.
Inorg Chem. 2011 Oct 14. [Epub ahead of print]
PMID:
21999616
[PubMed - as supplied by publisher]
Effects of Basal Media and Supplements on Diethylstilbestrol-Treated Immature Mouse Primary Granulosa Cell Growth and Regulation of Steroidogenesis In Vitro.
Ding T, Luo A, Yang S, Lai Z, Wang Y, Shen W, Jiang J, Lu Y, Ma D, Wang S.
Reprod Domest Anim. 2011 Oct 15. doi: 10.1111/j.1439-0531.2011.01879.x. [Epub ahead of print]
PMID:
21999365
[PubMed - as supplied by publisher]
Demographic and lifestyle factors and selenium levels in men and women in the U.S.
Park K, Rimm E, Siscovick D, Spiegelman D, Morris JS, Mozaffarian D.
Nutr Res Pract. 2011 Aug;5(4):357-64. Epub 2011 Aug 31.
PMID:
21994531
[PubMed - in process]
New group 11 complexes with metal-selenium bonds of methyldiphenylphosphane selenide: a solid state, solution and theoretical investigation.
Pop A, Silvestru A, Gimeno MC, Laguna A, Kulcsar M, Arca M, Lippolis V, Pintus A.
Dalton Trans. 2011 Oct 13. [Epub ahead of print]
PMID:
21993712
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