Rhenium 2 - Ethylhexanoate is an Rhenium source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds) as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds). Ethylhexanoates are carboxylates with many commercial applications They are commonly used in various catalysts for oxidation, hydrogenation and polymerization and as an adhesion promoter. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Rhenium 2-Ethylhexanoate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Silver include metallurgy, glass and glass polishing, ceramics, catalysts, and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Rhenium is a Block D, Group 7, Period 6 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 32, 13, 2 and its electronic configuration is [Xe] 4f14 5d5 6s2. In its elemental form rhenium's CAS number is 7440-15-5. The rhenium atom has a radius of 137.1.pm and it's Van der Waals radius is 200.pm. The toxicity of Rhenium has not yet been established . Rhenium is the fourth densestelementexceeded only by that of platinum, iridium, and osmium . It has the second highest melting point exceeded only by tungsten and carbon . Rhenium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Because of this, thermocouples made of Tungsten/Rhenium alloy is are used when temperatures will rise to 2000 C and rhenium wire is used in photoflash lamps for photography. It is widely used as filaments for mass spectrographs and ion gauges. Rhenium was first discovered by Walter Noddack in 1925 in the Rhine region of Germany. The name Rhenium originates from the Latin word 'Rhenus' meaning "Rhine" after the place of discovery. See Rhenium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Mechanism of visible-light photoisomerization of a rhenium(i) carbonyl-diimine complex.
Gindensperger E, Köppel H, Daniel C.
Chem Commun (Camb). 2010 Sep 28. [Epub ahead of print]PMID: 20877849 [PubMed - as supplied by publisher]Related citations
Novel rhenium nitrides.
Friedrich A, Winkler B, Bayarjargal L, Morgenroth W, Juarez-Arellano EA, Milman V, Refson K, Kunz M, Chen K.
Phys Rev Lett. 2010 Aug 20;105(8):085504. Epub 2010 Aug 20.PMID: 20868112 [PubMed - in process]Related citations
Effect of rhenium on the dislocation core structure in tungsten.
Romaner L, Ambrosch-Draxl C, Pippan R.
Phys Rev Lett. 2010 May 14;104(19):195503. Epub 2010 May 13.PMID: 20866976 [PubMed - in process]Related citations
Highly Emitting Concomitant Polymorphic Crystals of a Dinuclear Rhenium Complex.
Quartapelle Procopio E, Mauro M, Panigati M, Donghi D, Mercandelli P, Sironi A, D'Alfonso G, De Cola L.
J Am Chem Soc. 2010 Sep 24. [Epub ahead of print]PMID: 20866093 [PubMed - as supplied by publisher]Related citations
Pyridyl-Cyclopentadiene Re(CO)(2) Complexes as a Compact Core Systems for SPECT Ligand Development.
Ackroyd NC, Katzenellenbogen JA.
Organometallics. 2010 Aug 23;29(16):3669-3671.PMID: 20865134 [PubMed]Related citations.
Postlumpectomy Focal Brachytherapy for Simultaneous Treatment of Surgical Cavity and Draining Lymph Nodes.
Hrycushko BA, Li S, Shi C, Goins B, Liu Y, Phillips WT, Otto PM, Bao A.
Int J Radiat Oncol Biol Phys. 2010 Sep 23. [Epub ahead of print]PMID: 20864271 [PubMed - as supplied by publisher]Related citations
Radioimmunotherapy with antibody to HPV16 E6 oncoprotein is effective in experimental cervical tumor expressing low levels of E6.
Phaeton R, Harris M, Jiang Z, Wang XG, Einstein MH, Goldberg GL, Casadevall A, Dadachova E.
Cancer Biol Ther. 2010 Nov 12;10(10). [Epub ahead of print]PMID: 20861673 [PubMed - as supplied by publisher]Related citations
Correction to Synthesis and Characterization of Luminescent Rhenium(I) Tricarbonyl Diimine Complexes with a Triarylboron Moiety and the Study of Their Fluoride Ion-Binding Properties.
Lam ST, Zhu N, Yam VW.
Inorg Chem. 2010 Sep 20. [Epub ahead of print] No abstract available. PMID: 20853863 [PubMed - as supplied by publisher]Related citations
86Y-CHX-A”-Rhenium-cyclized-[Cys3,4,10,D-Phe7,Arg11]a-MSH3-13 .
Leung K.
Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2010.
2009 Aug 20 [updated 2010 Sep 8].PMID: 20845549 [PubMed]Books & DocumentsFree textRelated citations
68Ga-CHX-A”-Rhenium-cyclized-[Cys3,4,10,D-Phe7,Arg11]a-MSH3-13 .
Leung K.
Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2010.
2009 Aug 20 [updated 2010 Sep 8].PMID: 20845548 [PubMed]Books & DocumentsFree textRelated citations
Therapeutic nuclear medicine in pediatric malignancy.
Schmidt M, Baum RP, Simon T, Howman-Giles R.
Q J Nucl Med Mol Imaging. 2010 Aug;54(4):411-28.PMID: 20823809 [PubMed - in process]Related citations
Rhenium(i) and platinum(ii) complexes with diimine ligands bearing acidic phenol substituents: hydrogen-bonding, acid-base chemistry and optical properties.
Liu W, Heinze K.
Dalton Trans. 2010 Oct 28;39(40):9554-64. Epub 2010 Aug 31.PMID: 20820607 [PubMed - in process]Related citations
Chemical Synthesis of Fully Biomass-Based Poly(butylene succinate) from Inedible-Biomass-Based Furfural and Evaluation of Its Biomass Carbon Ratio.
Tachibana Y, Masuda T, Funabashi M, Kunioka M.
Biomacromolecules. 2010 Sep 3. [Epub ahead of print]PMID: 20815381 [PubMed - as supplied by publisher]Related citations
Rhenium-catalyzed diastereoselective synthesis of aminoindanes via the insertion of allenes into a C-H bond.
Kuninobu Y, Yu P, Takai K.
Org Lett. 2010 Oct 1;12(19):4274-6.PMID: 20804169 [PubMed - in process]Related citations
Slow magnetic relaxation and charge-transfer in cyano-bridged coordination clusters incorporating [Re(CN)(7)](3-/4-).
Zadrozny JM, Freedman DE, Jenkins DM, Harris TD, Iavarone AT, Mathonière C, Clérac R, Long JR.
Inorg Chem. 2010 Oct 4;49(19):8886-96.PMID: 20804139 [PubMed - in process]Related citations
Molecules containing rare-earth atoms solely bonded by transition metals.
Butovskii MV, Döring C, Bezugly V, Wagner FR, Grin Y, Kempe R.
Nat Chem. 2010 Sep;2(9):741-4. Epub 2010 Jun 27.PMID: 20729893 [PubMed - indexed for MEDLINE]Related citations
N-heterocyclic carbene embedded in an N-confused porphyrin framework.
Toganoh M, Hihara T, Furuta H.
Inorg Chem. 2010 Sep 20;49(18):8182-4.PMID: 20726565 [PubMed - in process]Related citations
Probing surface sites of TiO2: reactions with [HRe(CO)5] and [CH3Re(CO)5].
Lobo-Lapidus RJ, Gates BC.
Chemistry. 2010 Oct 4;16(37):11386-98.PMID: 20726017 [PubMed - in process]Related citations
Differences between the macroscopic and tracer level chemistry of rhenium and technetium: contrasting cage isomerisation behaviour of Re(I) and Tc(I) carborane complexes.
Armstrong AF, Valliant JF.
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CO releasing properties and cytoprotective effect of cis-trans-[Re(II)(CO)2Br2L2]n complexes.
Zobi F, Degonda A, Schaub MC, Bogdanova AY.
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