Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate
ClRh(P(C6H4SO3·Na)3)3
Product
Product Code
Order or Specifications
(2N) 99% Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate
RH-OM38-02
(2N5) 99.5% Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate
RH-OM38-025
(3N) 99.9% Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate
RH-OM38-03
(3N5) 99.95% Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate
RH-OM38-035
(4N) 99.99% Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate
RH-OM38-04
(5N) 99.999% Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate
RH-OM38-05
Chlorotris[(3,3',3''-phosphinidynetris(benzenesulfonato)]rhodium(I) Nonasodium Salt Hydrate is one of numerous organo-metallic compounds sold by American Elements under the tradename AE Organo-Metallics™. Additional technical, research and safety information is available.
Rhodium is a Block D, Group 9, Period 5 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 16, 1 and its electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm. Rhodium is not toxic. Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density.
It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Rhodium was first discovered by William Wollaston in 1803. The name Rhodium, originates from the Greek word 'Rhodon' which means rose. See Rhodium research below.
Sodium is a Block S, Group 1, Period 3 element. The number of electrons in each of Sodium's shells is 2, 8, 1 and its electronic configuration is [Ne] 3s1. In its elemental form sodium's CAS number is 7440-23-5. The sodium atom has a radius of 185.8.pm and it's Van der Waalsradius is 227.pm. Sodium is not toxic but skin contact may cause irritation and burns. Sodium is primarily used in its metallic form in the production of chemical esters and in the manufacturing of various other organic compounds. The metal is used in the alloy of tin, nickel and copper for its structural characteristics. Sodium is availableas metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. High purity sodium compounds are used as reducing agents. Sodium compounds are used in low tech applications throughout industry. Sodium was first discovered by Sir Humphrey Davy in 1807. The name Sodium comes from the Latin word "natrium" which means sodium carbonate. See Sodium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Intramolecular Aromatic Carbenoid Insertion of Biaryldiazoacetates for the Regioselective Synthesis of Fluorenes.
Kim J, Ohk Y, Park SH, Jung Y, Chang S.
Chem Asian J. 2011 May 12. doi: 10.1002/asia.201100142. [Epub ahead of print]
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21567971
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Rhodium-Catalyzed Cycloisomerization Involving Cyclopropenes: Efficient Stereoselective Synthesis of Medium-Sized Heterocyclic Scaffolds.
Miege F, Meyer C, Cossy J.
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PMID:
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Allylic C-H bond activation and functionalization mediated by tris(oxazolinyl)borato rhodium(i) and iridium(i) compounds.
Ho HA, Gray TS, Baird B, Ellern A, Sadow AD.
Dalton Trans. 2011 May 12. [Epub ahead of print]
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21566811
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Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system.
Vautravers NR, Regent DD, Breit B.
Chem Commun (Camb). 2011 May 12. [Epub ahead of print]
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21566809
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Carbon Chain Growth by Formyl Insertion on Rhodium and Cobalt Catalysts in Syngas Conversion.
Zhao YH, Sun K, Ma X, Liu J, Sun D, Su HY, Li WX.
Angew Chem Int Ed Engl. 2011 May 6. doi: 10.1002/anie.201100735. [Epub ahead of print] No abstract available.
PMID:
21557417
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Synthesis, Characterisation and Application of Iridium(III) Photosensitisers for Catalytic Water Reduction.
Gärtner F, Cozzula D, Losse S, Boddien A, Anilkumar G, Junge H, Schulz T, Marquet N, Spannenberg A, Gladiali S, Beller M.
Chemistry. 2011 May 6. doi: 10.1002/chem.201100235. [Epub ahead of print]
PMID:
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Analysis of Tertiary Phosphanes, Arsanes, and Stibanes as Bridging Ligands in Dinuclear Group 9 Complexes.
Schinzel S, Müller R, Riedel S, Werner H, Kaupp M.
Chemistry. 2011 May 9. doi: 10.1002/chem.201003438. [Epub ahead of print]
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21557345
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Asymmetric hydrogenation of alkenes lacking coordinating groups.
Woodmansee DH, Pfaltz A.
Chem Commun (Camb). 2011 May 10. [Epub ahead of print]
PMID:
21556431
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Ionic Diamine Rhodium Complex Catalyzed Reductive N-Heterocyclization of 2-Nitrovinylarenes.
Alper H, Okuro K, Gurnham J.
J Org Chem. 2011 May 4. [Epub ahead of print]
PMID:
21542601
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trans-Carbonylchloridobis(ferrocenyldiphenylphosphane-?P)rhodium(I) dichloromethane monosolvate and trans-carbonylchloridobis(ferrocenyldiphenylphosphane-?P)iridium(I) dichloromethane monosolvate.
Muller A, Otto S.
Acta Crystallogr C. 2011 May;67(Pt 5):m165-8. Epub 2011 Apr 28.
PMID:
21540536
[PubMed - in process]
A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides.
Serna P, Gates BC.
Angew Chem Int Ed Engl. 2011 Apr 29. doi: 10.1002/anie.201008086. [Epub ahead of print] No abstract available.
PMID:
21538737
[PubMed - as supplied by publisher]
Asymmetric polymerizations of chiral 4-benzyl-2-ethynyloxazoline with rhodium catalyst and chiroptical properties of the polymers.
Onimura K, Shintaku K, Rattanatraicharoen P, Yamabuki K, Oishi T.
Chirality. 2011 Apr 28. doi: 10.1002/chir.20959. [Epub ahead of print]
PMID:
21538572
[PubMed - as supplied by publisher]
Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines.
Shintani R, Narui R, Tsutsumi Y, Hayashi S, Hayashi T.
Chem Commun (Camb). 2011 May 3. [Epub ahead of print]
PMID:
21537505
[PubMed - as supplied by publisher]
Synthesis and characterisation of group nine transition metal complexes containing new mesityl and naphthyl based azaindole scorpionate ligands.
Owen GR, Tsoureas N, Hope RF, Kuo YY, Haddow MF.
Dalton Trans. 2011 Apr 28. [Epub ahead of print]
PMID:
21528139
[PubMed - as supplied by publisher]
Screen-printed carbon electrodes modified by rhodium dioxide and glucose dehydrogenase.
Polan V, Soukup J, Vytras K.
Enzyme Res. 2011 Mar 3;2010:324184.
PMID:
21528113
[PubMed - in process]
Computationally Designed and Experimentally Confirmed Diastereoselective Rhodium-Catalyzed Pauson-Khand Reaction at Room Temperature.
Baik MH, Mazumder S, Ricci P, Sawyer JR, Song YG, Wang H, Evans PA.
J Am Chem Soc. 2011 Apr 27. [Epub ahead of print]
PMID:
21524123
[PubMed - as supplied by publisher]
An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes.
Feng JJ, Zhang J.
J Am Chem Soc. 2011 May 18;133(19):7304-7. Epub 2011 Apr 27.
PMID:
21524076
[PubMed - in process]
Supported Rhodium Oxide Nanoparticles as Highly Active CO Oxidation Catalysts.
Ligthart DA, van Santen RA, Hensen EJ.
Angew Chem Int Ed Engl. 2011 Apr 20. doi: 10.1002/anie.201100190. [Epub ahead of print] No abstract available.
PMID:
21509919
[PubMed - as supplied by publisher]
Thermal diffusion of (57)Co into rhodium matrix as a second step in preparing Mössbauer sources.
Cieszykowska I, Zóltowska M, Zachariasz P, Piasecki A, Janiak T, Mielcarski M.
Appl Radiat Isot. 2011 Apr 8. [Epub ahead of print]
PMID:
21507667
[PubMed - as supplied by publisher]
Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch.
González-Rodríguez C, Pawley RJ, Chaplin AB, Thompson AL, Weller AS, Willis MC.
Angew Chem Int Ed Engl. 2011 Apr 19. doi: 10.1002/anie.201100956. [Epub ahead of print] No abstract available.
PMID:
21506226
[PubMed - as supplied by publisher]
Natural history of Christianson syndrome.
Schroer RJ, Holden KR, Tarpey PS, Matheus MG, Griesemer DA, Friez MJ, Fan JZ, Simensen RJ, Strømme P, Stevenson RE, Stratton MR, Schwartz CE.
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Ger MF, Rendon G, Tilson JL, Jakobsson E.
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Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC, Chamberlain TW, Rance GA, Kuganathan N, Biskupek J, Kaiser U, Khlobystov AN.
Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3082. [Epub ahead of print]
PMID:
21822259
[PubMed - as supplied by publisher]
Crystallization and preliminary X-ray analysis of the yeast tRNA-thiouridine modification protein 1 (Tum1p).
Qiu R, Wang F, Liu M, Yang Z, Wu T, Ji C.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Aug 1;67(Pt 8):953-5. Epub 2011 Jul 27.
PMID:
21821903
[PubMed - in process]
Characterization of Bacillus thuringiensis L-isoleucine dioxygenase toward the production of useful amino acids.
Hibi M, Kawashima T, Kodera T, Smirnov SV, Sokolov PM, Sugiyama M, Shimizu S, Yokozeki K, Ogawa J.
Appl Environ Microbiol. 2011 Aug 5. [Epub ahead of print]
PMID:
21821743
[PubMed - as supplied by publisher]
Characterization of the sulfurtransferase family from Oryza sativa L.
Guretzki S, Papenbrock J.
Plant Physiol Biochem. 2011 Jul 23. [Epub ahead of print]
PMID:
21821426
[PubMed - as supplied by publisher]
Development of a small-scale bioreactor method to monitor the molecular diversity and environmental impacts of bacterial biofilm communities from an acid mine drainage impacted creek.
Cole M, Wrubel J, Henegan P, Janzen C, Holt J, Tobin T.
J Microbiol Methods. 2011 Jul 28. [Epub ahead of print]
PMID:
21821067
[PubMed - as supplied by publisher]
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Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A.
J Hazard Mater. 2011 Jul 6. [Epub ahead of print]
PMID:
21820806
[PubMed - as supplied by publisher]
Stearoyl-CoA desaturase is an essential enzyme for the parasitic protist Trypanosoma brucei.
Alloatti A, Gupta S, Gualdrón-López M, Nguewa PA, Altabe SG, Deumer G, Wallemacq P, Michels PA, Uttaro AD.
Biochem Biophys Res Commun. 2011 Jul 28. [Epub ahead of print]
PMID:
21820408
[PubMed - as supplied by publisher]
The use of multi-element stable isotope analysis to monitor the origin of chondroitin sulfates.
Thomas F, Jamin E, Shimoo K, Nagao J, Osaki Y, Granier C.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2533-7. doi: 10.1002/rcm.5159.
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21818814
[PubMed - in process]
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21818798
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Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-Like Molecules with Metal-Metal Multiple Bonds.
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21818792
[PubMed - as supplied by publisher]
Rhodovulum phaeolacus sp. nov. a phototrophic alphaproteobacterium isolated from a brown pond.
Venkata Naga Satya Lakshmi K, Sasikala C, Venkata Ramana V, Veera Venkata Ramaprasad E, Venkata Ramana C.
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21817826
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Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources.
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Bioresour Technol. 2011 Jun 21. [Epub ahead of print]
PMID:
21816612
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Target loads of atmospheric sulfur deposition for the protection and recovery of acid-sensitive streams in the Southern Blue Ridge Province.
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J Environ Manage. 2011 Aug 2. [Epub ahead of print]
PMID:
21816535
[PubMed - as supplied by publisher]
Differential effects of a post-anthesis fertilizer regimen on the wheat flour proteome determined by quantitative 2-DE.
Altenbach SB, Tanaka CK, Hurkman WJ, Whitehand LC, Vensel WH, Dupont FM.
Proteome Sci. 2011 Aug 4;9(1):46. [Epub ahead of print]
PMID:
21816081
[PubMed - as supplied by publisher]
Comparative toxicity of arsenic metabolites in human bladder cancer EJ-1 cells.
Naranmandura H, Michael CW, Xu S, Lee J, Leslie E, Weinfeld M, Le XC.
Chem Res Toxicol. 2011 Aug 4. [Epub ahead of print]
PMID:
21815631
[PubMed - as supplied by publisher]
The Effects of Different Garlic-derived Allyl Sulfides on Peroxidative Processes and Anaerobic Sulfur Metabolism in Mouse Liver.
Iciek MB, Kowalczyk-Pachel D, Kwiecien I, Dudek MB.
Phytother Res. 2011 Aug 4. doi: 10.1002/ptr.3572. [Epub ahead of print]
PMID:
21815229
[PubMed - as supplied by publisher]
A combined model of hepatic polyamine and sulfur amino acid metabolism to analyze S-adenosyl methionine availability.
Reyes-Palomares A, Montañez R, Sánchez-Jiménez F, Medina MA.
Amino Acids. 2011 Aug 4. [Epub ahead of print]
PMID:
21814788
[PubMed - as supplied by publisher]
Microbial gene functions enriched in the Deepwater Horizon deep-sea oil plume.
Lu Z, Deng Y, Van Nostrand JD, He Z, Voordeckers J, Zhou A, Lee YJ, Mason OU, Dubinsky EA, Chavarria KL, Tom LM, Fortney JL, Lamendella R, Jansson JK, D'haeseleer P, Hazen TC, Zhou J.
ISME J. 2011 Aug 4. doi: 10.1038/ismej.2011.91. [Epub ahead of print]
PMID:
21814288
[PubMed - as supplied by publisher]
1,1'-(3-Methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a Building Block in Heterocyclic Synthesis. Novel Synthesis of Some Pyrazole and Pyrimidine Derivatives.
Mabkhot YN, Al-Majid AM, Barakat A, Alshahrani S, Siddiqui Y.
Molecules. 2011 Aug 3;16(8):6502-11.
PMID:
21814162
[PubMed - in process]
Towards the Growth of an Aligned Single-Layer MoS2 Film.
Kim D, Sun D, Lu W, Cheng Z, Zhu Y, Le D, Rahman TS, Bartels L.
Langmuir. 2011 Aug 3. [Epub ahead of print]
PMID:
21812475
[PubMed - as supplied by publisher]