(S,S,S,S)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene
Cyclooctadiene Rhodium(I) Tetrafluoroborate Complex

C28H40BF4P2RhS
CAS 849920-73-6


Product Product Code Order or Specifications
(2N) 99% (S,S,S,S)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene Cyclooctadiene Rhodium(I) Tetrafluoroborate Complex      RH-OM-02 Contact American Elements
(3N) 99.9% (S,S,S,S)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene Cyclooctadiene Rhodium(I) Tetrafluoroborate Complex RH-OM-03 Contact American Elements
(4N) 99.99% (S,S,S,S)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene Cyclooctadiene Rhodium(I) Tetrafluoroborate Complex RH-OM-04 Contact American Elements
(5N) 99.999% (S,S,S,S)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene Cyclooctadiene Rhodium(I) Tetrafluoroborate Complex RH-OM-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
C28H40BF4P2RhS 849920-73-6 162233918 16216974 MFCD08561120 N/A 2,3-bis[(2S,5S)
-2,5-dimethyl
phospholan-
1-yl]-1-benzo
thiophene;
(1Z, 5Z)-cyclo
octa-1,5-diene;
rhodium;
tetrafluoro
borate
N/A [Rh].F[B-](F)(F)F.s2
c1ccccc1c(c2
P3[C@@H](C)
CC[C@@H]3C)
P4[C@@H](C)C
C[C@@H]4C.C
\1=C\CC/C=C\C
C/1
InChI=1S/C20H
28P2S.C8H
12.BF4.Rh/c1-13
-9-10-14(2)21(13)
19-17-7-5-6-8-18
(17)23-20(19)
22-15(3)11-12-
16(22)4;1-2-4-6-8-
7-5-3-1;2-1(3,4)5;
/h5-8,13-16H,
9-12H2,1-4H3;1
-2,7-8H,3-6H2;;
/q;;-1;/b;2-1-,8-7-
;;/t13-,14-,15-,16-
;;;/m0.../s1
ROQCIQND
SCZIGH-KZOF
NLLLSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
C28H40BF4P2RhS- 660.34 Red Powder N/A N/A N/A 660.141018 660.141018 -1 Safety Data Sheet

(S,S,S,S)-2,3-Bis(2,5-dimethyl-phospholanyl)benzo[b]thiophene Cyclooctadiene Rhodium(I) Tetrafluoroborate Complex is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Rhodium (Rh) atomic and molecular weight, atomic number and elemental symbolRhodium (atomic symbol: Rh, atomic number: 45) is a Block D, Group 9, Period 5 element with an atomic weight of 102.90550. Rhodium Bohr ModelThe number of electrons in each of Rhodium's shells is [2, 8, 18, 16, 1] and its electron configuration is [Kr] 4d8 5s1. The rhodium atom has a radius of 134 pm and a Van der Waals radius of 195 pm. Rhodium was discovered and first isolated by William Wollaston in 1804. In its elemental form, rhodium has a silvery white metallic appearance. Elemental RhodiumRhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density. Rhodium is found in ores mixed with other metals such as palladium, silver, platinum, and gold. Rhodium is primarily used as the catalyst in the three-way catalytic converters of automobiles; it is also highly valued in jewelry. The name Rhodium originates from the Greek word 'Rhodon,' which means rose. For more information on rhodium, including properties, safety data, research, and American Elements' catalog of rhodium products, visit the Rhodium Information Center.

Boron(B) atomic and molecular weight, atomic number and elemental symbolBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. Boron Bohr Model The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808. It was first isolated by Humphry Davy, also in 1808. Boron is classified as a metalloid is not found naturally on earth. Elemental Boron Along with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds.Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Boron is found in borates, borax, boric acid, colemanite, kernite, and ulexite.The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax. For more information on boron, including properties, safety data, research, and American Elements' catalog of boron products, visit the Boron Information Center.

Phosphorus(P) atomic and molecular weight, atomic number and elemental symbolPhosphorus Bohr ModelPhosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus; its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669; its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation. For more information on phosphorus, including properties, safety data, research, and American Elements' catalog of phosphorus products, visit the Phosphorus Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number N/A
Transport Information N/A
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
N/A        

(S,S,S,S)-2,3-BIS(2,5-DIMETHYL-PHOSPHOLANYL)BENZO[B]THIOPHENE CYCLOOCTADIENE RHODIUM(I) TETRAFLUOROBORATE COMPLEX SYNONYMS
cyclooctane; (2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]benzothiophen-3-yl]-2,5-dimethyl-phospholane; rhodium; tetrafluoroborate

CUSTOMERS FOR (S,S,S,S)-2,3-BIS(2,5-DIMETHYL-PHOSPHOLANYL)BENZO[B]THIOPHENE CYCLOOCTADIENE RHODIUM(I) TETRAFLUOROBORATE COMPLEX HAVE ALSO LOOKED AT
Rhodium Oxide Rhodium Oxide Pellets Rhodium Acetate Rhodium Chloride Rhodium Pellets
Rhodium Rod Rhodium Metal
Rhodium Oxide Nanopowder
Iron Rhodium Rhodium Foil
Rhodium Sulfate Rhodium Sputtering Target Platinum-rhodium alloy Rhodium Acetylacetonate Rhodium Powder
Show Me MORE Forms of Rhodium

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


Have a Question? Ask a Chemical Engineer or Material Scientist
Request an MSDS or Certificate of Analysis





German   Korean   French   Japanese   Spanish   Chinese (Simplified)   Portuguese   Russian   Chinese (Taiwan)  Italian   Turkish   Polish   Dutch   Czech   Swedish   Hungarian   Danish   Hebrew

Production Catalog Available in 36 Countries & Languages


Recent Research & Development for Rhodium

  • Arnab Kumar Maity, Manish Bhattacharjee, Sujit Roy, SnCl2 insertion into Ir–Cl and Rh–Cl bonds: Synthesis, characterization and catalytic activity of three-legged piano-stool trichlorostannyl iridium and rhodium complexes, Journal of Organometallic Chemistry, Volume 768, 1 October 2014
  • Song-Il O, Jun-Min Yan, Hong-Li Wang, Zhi-Li Wang, Qing Jiang, Ni/La2O3 catalyst containing low content platinum–rhodium for the dehydrogenation of N2H4·H2O at room temperature, Journal of Power Sources, Volume 262, 15 September 2014
  • Mahesh Kalidasan, S.H. Forbes, Yurij Mozharivskyj, Mohan Rao Kollipara, Half-sandwich ?6-arene ruthenium and Cp* rhodium/iridium compounds comprising with thioether ligands: Synthesis, spectral and molecular studies, Inorganica Chimica Acta, Volume 421, 1 September 2014
  • Takanori Matsuda, Kohei Mizuno, Shoichi Watanuki, Rhodium-catalyzed arylation of acylsilanes with sodium tetraarylborates, Journal of Organometallic Chemistry, Volume 765, 15 August 2014
  • P. Arzu Akinci, Süleyman Gülcemal, Olga N. Kazheva, Grigorii G. Alexandrov, Oleg A. Dyachenko, Engin Çetinkaya, Bekir Çetinkaya, Perimidin-2-ylidene rhodium(I) complexes; unexpected halogen exchange and catalytic activities in transfer hydrogenation reaction, Journal of Organometallic Chemistry, Volume 765, 15 August 2014
  • Marion Graf, Yvonne Gothe, Nils Metzler-Nolte, Rafal Czerwieniec, Karlheinz Sünkel, Photophysical and biological characterization of new cationic cyclometalated M(III) complexes of rhodium and iridium, Journal of Organometallic Chemistry, Volume 765, 15 August 2014
  • Yisong Xu, Ying Bai, Jiajian Peng, Jiayun Li, Wenjun Xiao, Guoqiao Lai, Hydrosilylation of alkenes catalyzed by rhodium with polyethylene glycol-based ionic liquids as ligands, Journal of Organometallic Chemistry, Volume 765, 15 August 2014
  • Siu Yin Lee, Tsz Ho Lai, Ying Ying Hui, Kin Shing Chan, Hydroxide-promoted selective C(a)–C(ß) bond activation of aliphatic ethers by rhodium(III) porphyrins, Journal of Organometallic Chemistry, Volume 762, 15 July 2014
  • Mark D. Doherty, Steven J. Konezny, Victor S. Batista, Grigorii L. Soloveichik, Electrochemical reactions of pincer rhodium(I) complexes, Journal of Organometallic Chemistry, Volume 762, 15 July 2014
  • Yu. S. Varshavsky, M.R. Galding, V.N. Khrustalev, I.S. Podkorytov, S.N. Smirnov, V.A. Gindin, A.B. Nikolskii, Rhodium(I) dimethyl sulfoxide oxyquinolinato carbonyl complex, [Rh(Oxq)(CO)(DMSO)]. NMR and X-ray structure data, Journal of Organometallic Chemistry, Volume 761, 1 July 2014
  • Ai-Quan Jia, Wai-Hang Chiu, Xiang-Hong Huang, Wa-Hung Leung, Qian-Feng Zhang, Isolation and structures of rhodium(III) complexes with cyclometalated bis(dialkylthiophosphoryl)imides via intramolecular C–H activation, Journal of Organometallic Chemistry, Volume 761, 1 July 2014
  • Yasushi Maeda, Shin-ichi Yamazaki, Masanori Kohyama, Atomic force microscopy on phase-control pulsed force mode in water: Imaging and force analysis on a rhodium-octaethylporphyrin layer on highly oriented pyrolytic graphite, Applied Surface Science, Volume 305, 30 June 2014
  • Srikanth Cheemalapati, Shen-Ming Chen, M. Ajmal Ali, Fahad M.A. Al-Hemaid, Enhanced electrocatalytic oxidation of isoniazid at electrochemically modified rhodium electrode for biological and pharmaceutical analysis, Colloids and Surfaces B: Biointerfaces, Available online 21 June 2014
  • C. Barroo, N. Gilis, S.V. Lambeets, F. Devred, T. Visart de Bocarmé, Oxygen assisted reconstructions of rhodium and platinum nanocrystals and their effects on local catalytic activity of hydrogenation reactions, Applied Surface Science, Volume 304, 15 June 2014
  • Megan K. Pennington-Boggio, Brian L. Conley, Michael G. Richmond, Travis J. Williams, Synthesis, structure, and conformational dynamics of rhodium and iridium complexes of dimethylbis(2-pyridyl)borate, Polyhedron, Available online 29 May 2014
  • James D. Blakemore, Emilia S. Hernandez, Wesley Sattler, Bryan M. Hunter, Lawrence M. Henling, Bruce S. Brunschwig, Harry B. Gray, Pentamethylcyclopentadienyl rhodium complexes, Polyhedron, Available online 20 May 2014
  • Khadichakhan Rafikova, Nurzhamal Kystaubayeva, Murat Aydemir, Cezmi Kayan, Yusuf Selim Ocak, Hamdi Temel, Alexey Zazybin, Nevin Gürbüz, Ismail Özdemir, Transfer hydrogenation of ketones catalyzed by new rhodium and iridium complexes of aminophosphine containing cyclohexyl moiety and photosensing behaviors of rhodium and iridium based devices, Journal of Organometallic Chemistry, Volume 758, 15 May 2014
  • María A. Montero, José L. Fernández, María R. Gennero de Chialvo, Abel C. Chialvo, Characterization and kinetic study of a nanostructured rhodium electrode for the hydrogen oxidation reaction, Journal of Power Sources, Volume 254, 15 May 2014
  • Renshi Luo, Ling Xie, Jianhua Liao, Hu Xin, Albert S.C. Chan, Tunable chiral monophosphines as ligands in enantioselective rhodium-catalyzed ring-opening of oxabenzonorbornadienes with amines, Tetrahedron: Asymmetry, Volume 25, Issue 9, 15 May 2014
  • Nathalie Debono, Jean-Claude Daran, Rinaldo Poli, Agnès Labande, A rhodium(I) dicarbonyl complex with a redox-active ferrocenyl phosphine-NHC ligand: Enhanced reactivity of the metal centre through ferrocene oxidation, Polyhedron, Available online 9 May 2014

Recent Research & Development for Boron

  • Zhijie Wu, Xikang Mao, Qin Zi, Rongrong Zhang, Tao Dou, Alex C.K. Yip, Mechanism and kinetics of sodium borohydride hydrolysis over crystalline nickel and nickel boride and amorphous nickel–boron nanoparticles, Journal of Power Sources, Volume 268, 5 December 2014
  • Ning Zhang, Huan Liu, Hongmin Kan, Xiaoyang Wang, Haibo Long, Yonghui Zhou, The preparation of high-adsorption, spherical, hexagonal boron nitride by template method, Journal of Alloys and Compounds, Volume 613, 15 November 2014
  • Yikun Zhang, Baijun Yang, Effect of Fe substitution on magnetocaloric effect in metamagnetic boron-carbide ErNi2-xFexB2C compounds, Journal of Alloys and Compounds, Volume 610, 15 October 2014
  • Elena V. Fedorenko, Anatoliy G. Mirochnik, Anton Yu. Beloliptsev, Vladimir V. Isakov, (S2?S0) and (S1?S0) luminescence of dimethylaminostyryl-ß-diketonates of boron difluoride, Dyes and Pigments, Volume 109, October 2014
  • Wenwen Cui, Jingming Shi, Hanyu Liu, Cheng Lu, Hui Wang, Novel high-pressure crystal structures of boron trifluoride, Journal of Physics and Chemistry of Solids, Volume 75, Issue 10, October 2014
  • Joseph W. McGrady, Dimitrios A. Papaconstantopoulos, Michael J. Mehl, Tight-Binding study of Boron structures, Journal of Physics and Chemistry of Solids, Volume 75, Issue 10, October 2014
  • Lingling Zhang, Yulin Ma, Xinqun Cheng, Pengjian Zuo, Yingzhi Cui, Ting Guan, Chunyu Du, Yunzhi Gao, Geping Yin, Enhancement of high voltage cycling performance and thermal stability of LiNi1/3Co1/3Mn1/3O2 cathode by use of boron-based additives, Solid State Ionics, Volume 263, 1 October 2014
  • Manuel Palencia, Myleidi Vera, Bernabé L. Rivas, Modification of ultrafiltration membranes via interpenetrating polymer networks for removal of boron from aqueous solution, Journal of Membrane Science, Volume 466, 15 September 2014
  • A.G. Van Der Geest, A.N. Kolmogorov, Stability of 41 metal–boron systems at 0 GPa and 30 GPa from first principles, Calphad, Volume 46, September 2014
  • Weon Gyu Shin, Hye Jin Jung, Hong Gye Sung, Hyung Soo Hyun, Youngku Sohn, Synergic CO oxidation activities of boron–CeO2 hybrid materials prepared by dry and wet milling methods, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • D. McNamara, D. Carolan, P. Alveen, N. Murphy, A. Ivankovic, The influence of microstructure on the fracture statistics of polycrystalline diamond and polycrystalline cubic boron nitride, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • Chuan Sun, Yunkai Li, Yunfei Wang, Lingbo Zhu, Quanzhen Jiang, Yong Miao, Xuebing Chen, Effect of alumina addition on the densification of boron carbide ceramics prepared by spark plasma sintering technique, Ceramics International, Volume 40, Issue 8, Part B, September 2014
  • W.J. Kelvin Chew, M. Amiriyan, A. Yaghoubi, S. Ramesh, J. Purbolaksono, R. Tolouei, W.D. Teng, D.K. Agrawal, Sintering properties and thermal depletion of boron in zirconia–zirconium diboride conductive ceramic, Ceramics International, Volume 40, Issue 8, Part B, September 2014
  • Yuzheng Wang, Xiangxin Xue, He Yang, Preparation and characterization of carbon or/and boron-doped titania nano-materials with antibacterial activity, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • Mehdi D. Esrafili, Roghaye Nurazar, Potential of C-doped boron nitride fullerene as a catalyst for methanol dehydrogenation, Computational Materials Science, Volume 92, September 2014
  • Poonam Verma, Shiny S. Kumar, R.M. Sawant, B.S. Tomar, K.L. Ramakumar, Synchronous derivative fluorimetric determination of boron in Uranium fuel samples, Journal of Luminescence, Volume 153, September 2014
  • Zs. Rák, C.J. O’Brien, D.W. Brenner, First-principles investigation of boron defects in nickel ferrite spinel, Journal of Nuclear Materials, Volume 452, Issues 1–3, September 2014
  • Glen A. Slack, Kenneth E. Morgan, Some crystallography, chemistry, physics, and thermodynamics of B12O2, B12P2, B12As2, and related alpha-boron type crystals, Journal of Physics and Chemistry of Solids, Volume 75, Issue 9, September 2014
  • Yinsheng Li, Jie Yin, Haibo Wu, Ping Lu, Yongjie Yan, Xuejian Liu, Zhengren Huang, Dongliang Jiang, High thermal conductivity in pressureless densified SiC ceramics with ultra-low contents of additives derived from novel boron–carbon sources, Journal of the European Ceramic Society, Volume 34, Issue 10, September 2014
  • Qiwei Qiao, Rijie Wang, Minglei Gou, Xiaoxia Yang, Catalytic performance of boron and aluminium incorporated ZSM-5 zeolites for isomerization of styrene oxide to phenylacetaldehyde, Microporous and Mesoporous Materials, Volume 195, 1 September 2014

Recent Research & Development for Phosphorus

  • Xinhua Tang, Haoran Li, Zhuwei Du, How Yong Ng, A phosphorus-free anolyte to enhance coulombic efficiency of microbial fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Ziwu Liu, Qianqian Shi, Rufan Zhang, Quande Wang, Guojun Kang, Feng Peng, Phosphorus-doped carbon nanotubes supported low Pt loading catalyst for the oxygen reduction reaction in acidic fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Murat Rakap, Hydrogen generation from the hydrolytic dehydrogenation of ammonia borane using electrolessly deposited cobalt–phosphorus as reusable and cost-effective catalyst, Journal of Power Sources, Volume 265, 1 November 2014
  • Zegao Wang, Pingjian Li, Yuanfu Chen, Jiarui He, Jingbo Liu, Wanli Zhang, Yanrong Li, Phosphorus-doped reduced graphene oxide as an electrocatalyst counter electrode in dye-sensitized solar cells, Journal of Power Sources, Volume 263, 1 October 2014
  • Jun-Bo Zhang, Xiu-Li Wang, Qiu-Xia He, Hai-Bo Zhao, Yu-Zhong Wang, A novel phosphorus-containing poly(1,4-cyclohexylenedimethylene terephthalate) copolyester: Synthesis, thermal stability, flammability and pyrolysis behavior, Polymer Degradation and Stability, Volume 108, October 2014
  • Liqiang Gu, Guoan Chen, Youwei Yao, Two novel phosphorus–nitrogen-containing halogen-free flame retardants of high performance for epoxy resin, Polymer Degradation and Stability, Volume 108, October 2014
  • Ziqing Zhai, Yuichi Miyahara, Hiroshi Abe, Yutaka Watanabe, Segregation behavior of phosphorus in the heat-affected zone of an A533B/A182 dissimilar weld joint before and after simulated thermal aging, Journal of Nuclear Materials, Volume 452, Issues 1–3, September 2014
  • David A. McKeown, Hao Gan, Ian L. Pegg, Raman and X-ray absorption spectroscopy studies of chromium–phosphorus interactions in high-bismuth high-level waste glasses, Journal of Nuclear Materials, Volume 452, Issues 1–3, September 2014
  • Qin Liu, Shuiliang Chen, Yan Zhou, Suqi Zheng, Haoqing Hou, Feng Zhao, Phosphorus-doped carbon derived from cellulose phosphate as efficient catalyst for air-cathode in microbial fuel cells, Journal of Power Sources, Volume 261, 1 September 2014
  • Shaozheng Hu, Lin Ma, Jiguang You, Fayun Li, Zhiping Fan, Guang Lu, Dan Liu, Jianzhou Gui, Enhanced visible light photocatalytic performance of g-C3N4 photocatalysts co-doped with iron and phosphorus, Applied Surface Science, Volume 311, 30 August 2014