Rhodium Sulfate Solutions are moderate to highly concentrated liquid solutions of Rhodium Sulfate. They are an excellent source of Rhodium Sulfate for applications requiring solubabilzed materials. American Elements can prepare dissolved homogenous solutions at customer specified concentrations or to the maximum stoichiometric concentration. Packaging is available in 55 gallon drums, smaller units and larger liquid totes. American Elements maintains solution production facilities in the United States, Northern Europe (Liverpool, UK), Southern Europe (Milan, Italy), Australia and China to allow for lower freight costs and quicker delivery to our customers. .American Elements metal and rare earth compound solutions have numerous applications, but are commonly used in petrochemical cracking and automotive catalysts, water treatment, plating, textiles, research and in optic, laser, crystal and glass applications. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Rhodium Sulfate Powder. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and deposited utilizing sputtering targets and evaporation materials for uses such as solar energy materials and fuel cells.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Rhodium is a Block D, Group 9, Period 5 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 16, 1 and its electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm. Rhodium is not toxic. Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density.
It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Rhodium was first discovered by William Wollaston in 1803. The name Rhodium, originates from the Greek word 'Rhodon' which means rose. See Rhodium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Intramolecular Aromatic Carbenoid Insertion of Biaryldiazoacetates for the Regioselective Synthesis of Fluorenes.
Kim J, Ohk Y, Park SH, Jung Y, Chang S.
Chem Asian J. 2011 May 12. doi: 10.1002/asia.201100142. [Epub ahead of print]
PMID:
21567971
[PubMed - as supplied by publisher]
Rhodium-Catalyzed Cycloisomerization Involving Cyclopropenes: Efficient Stereoselective Synthesis of Medium-Sized Heterocyclic Scaffolds.
Miege F, Meyer C, Cossy J.
Angew Chem Int Ed Engl. 2011 May 12. doi: 10.1002/anie.201101220. [Epub ahead of print] No abstract available.
PMID:
21567678
[PubMed - as supplied by publisher]
Allylic C-H bond activation and functionalization mediated by tris(oxazolinyl)borato rhodium(i) and iridium(i) compounds.
Ho HA, Gray TS, Baird B, Ellern A, Sadow AD.
Dalton Trans. 2011 May 12. [Epub ahead of print]
PMID:
21566811
[PubMed - as supplied by publisher]
Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system.
Vautravers NR, Regent DD, Breit B.
Chem Commun (Camb). 2011 May 12. [Epub ahead of print]
PMID:
21566809
[PubMed - as supplied by publisher]
Carbon Chain Growth by Formyl Insertion on Rhodium and Cobalt Catalysts in Syngas Conversion.
Zhao YH, Sun K, Ma X, Liu J, Sun D, Su HY, Li WX.
Angew Chem Int Ed Engl. 2011 May 6. doi: 10.1002/anie.201100735. [Epub ahead of print] No abstract available.
PMID:
21557417
[PubMed - as supplied by publisher]
Synthesis, Characterisation and Application of Iridium(III) Photosensitisers for Catalytic Water Reduction.
Gärtner F, Cozzula D, Losse S, Boddien A, Anilkumar G, Junge H, Schulz T, Marquet N, Spannenberg A, Gladiali S, Beller M.
Chemistry. 2011 May 6. doi: 10.1002/chem.201100235. [Epub ahead of print]
PMID:
21557356
[PubMed - as supplied by publisher]
Analysis of Tertiary Phosphanes, Arsanes, and Stibanes as Bridging Ligands in Dinuclear Group 9 Complexes.
Schinzel S, Müller R, Riedel S, Werner H, Kaupp M.
Chemistry. 2011 May 9. doi: 10.1002/chem.201003438. [Epub ahead of print]
PMID:
21557345
[PubMed - as supplied by publisher]
Asymmetric hydrogenation of alkenes lacking coordinating groups.
Woodmansee DH, Pfaltz A.
Chem Commun (Camb). 2011 May 10. [Epub ahead of print]
PMID:
21556431
[PubMed - as supplied by publisher]
Ionic Diamine Rhodium Complex Catalyzed Reductive N-Heterocyclization of 2-Nitrovinylarenes.
Alper H, Okuro K, Gurnham J.
J Org Chem. 2011 May 4. [Epub ahead of print]
PMID:
21542601
[PubMed - as supplied by publisher]
trans-Carbonylchloridobis(ferrocenyldiphenylphosphane-?P)rhodium(I) dichloromethane monosolvate and trans-carbonylchloridobis(ferrocenyldiphenylphosphane-?P)iridium(I) dichloromethane monosolvate.
Muller A, Otto S.
Acta Crystallogr C. 2011 May;67(Pt 5):m165-8. Epub 2011 Apr 28.
PMID:
21540536
[PubMed - in process]
A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides.
Serna P, Gates BC.
Angew Chem Int Ed Engl. 2011 Apr 29. doi: 10.1002/anie.201008086. [Epub ahead of print] No abstract available.
PMID:
21538737
[PubMed - as supplied by publisher]
Asymmetric polymerizations of chiral 4-benzyl-2-ethynyloxazoline with rhodium catalyst and chiroptical properties of the polymers.
Onimura K, Shintaku K, Rattanatraicharoen P, Yamabuki K, Oishi T.
Chirality. 2011 Apr 28. doi: 10.1002/chir.20959. [Epub ahead of print]
PMID:
21538572
[PubMed - as supplied by publisher]
Design and synthesis of new chiral phosphorus-olefin bidentate ligands and their use in the rhodium-catalyzed asymmetric addition of organoboroxines to N-sulfonyl imines.
Shintani R, Narui R, Tsutsumi Y, Hayashi S, Hayashi T.
Chem Commun (Camb). 2011 May 3. [Epub ahead of print]
PMID:
21537505
[PubMed - as supplied by publisher]
Synthesis and characterisation of group nine transition metal complexes containing new mesityl and naphthyl based azaindole scorpionate ligands.
Owen GR, Tsoureas N, Hope RF, Kuo YY, Haddow MF.
Dalton Trans. 2011 Apr 28. [Epub ahead of print]
PMID:
21528139
[PubMed - as supplied by publisher]
Screen-printed carbon electrodes modified by rhodium dioxide and glucose dehydrogenase.
Polan V, Soukup J, Vytras K.
Enzyme Res. 2011 Mar 3;2010:324184.
PMID:
21528113
[PubMed - in process]
Computationally Designed and Experimentally Confirmed Diastereoselective Rhodium-Catalyzed Pauson-Khand Reaction at Room Temperature.
Baik MH, Mazumder S, Ricci P, Sawyer JR, Song YG, Wang H, Evans PA.
J Am Chem Soc. 2011 Apr 27. [Epub ahead of print]
PMID:
21524123
[PubMed - as supplied by publisher]
An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes.
Feng JJ, Zhang J.
J Am Chem Soc. 2011 May 18;133(19):7304-7. Epub 2011 Apr 27.
PMID:
21524076
[PubMed - in process]
Supported Rhodium Oxide Nanoparticles as Highly Active CO Oxidation Catalysts.
Ligthart DA, van Santen RA, Hensen EJ.
Angew Chem Int Ed Engl. 2011 Apr 20. doi: 10.1002/anie.201100190. [Epub ahead of print] No abstract available.
PMID:
21509919
[PubMed - as supplied by publisher]
Thermal diffusion of (57)Co into rhodium matrix as a second step in preparing Mössbauer sources.
Cieszykowska I, Zóltowska M, Zachariasz P, Piasecki A, Janiak T, Mielcarski M.
Appl Radiat Isot. 2011 Apr 8. [Epub ahead of print]
PMID:
21507667
[PubMed - as supplied by publisher]
Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: A Ligand-Controlled Regioselectivity Switch.
González-Rodríguez C, Pawley RJ, Chaplin AB, Thompson AL, Weller AS, Willis MC.
Angew Chem Int Ed Engl. 2011 Apr 19. doi: 10.1002/anie.201100956. [Epub ahead of print] No abstract available.
PMID:
21506226
[PubMed - as supplied by publisher]
Rhodium Sulfate Solutions are moderate to highly concentrated liquid solutions of Rhodium Sulfate. They are an excellent source of Rhodium Sulfate for applications requiring solubabilzed 
materials. American Elements can prepare dissolved homogenous solutions at customer specified concentrations or to the maximum stoichiometric concentration. Packaging is available in 55 gallon drums, smaller units and larger liquid totes. American Elements maintains solution production facilities in the United States, Northern Europe (Liverpool, UK), Southern Europe (Milan, Italy), Australia and China to allow for lower freight costs and quicker delivery to our customers. .American Elements metal and rare earth compound solutions have numerous applications, but are commonly used in petrochemical cracking and automotive catalysts, water treatment, plating, textiles, research and in optic, laser, crystal and glass applications. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Rhodium Sulfate Powder. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and deposited utilizing sputtering targets and evaporation materials for uses such as solar energy materials and fuel cells.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Rhodium is a Block D, Group 9, Period 5 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 16, 1 and its electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm. Rhodium is not toxic. Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower 
density.
It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Rhodium was first discovered by William Wollaston in 1803. The name Rhodium, originates from the Greek word 'Rhodon' which means rose. See Rhodium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine 
and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
