Diammonium Sodium Hexanitrorhodate(III) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Sodium is a Block S, Group 1, Period 3 element. The number of electrons in each of Sodium's shells is 2, 8, 1 and its electronic configuration is [Ne] 3s1. In its elemental form sodium's CAS number is 7440-23-5. The sodium atom has a radius of 185.8.pm and it's Van der Waalsradius is 227.pm. Sodium is not toxic but skin contact may cause irritation and burns. Sodium is primarily used in its metallic form in the production of chemical esters and in the manufacturing of various other organic compounds. The metal is used in the alloy of tin, nickel and copper for its structural characteristics. Sodium is availableas metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. High purity sodium compounds are used as reducing agents. Sodium compounds are used in low tech applications throughout industry. Sodium was first discovered by Sir Humphrey Davy in 1807. The name Sodium comes from the Latin word "natrium" which means sodium carbonate. See Sodium research below.
Rhodium is a Block D, Group 9, Period 5 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 16, 1 and its electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm. Rhodium is not toxic. Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, but a lower density.
It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Rhodium was first discovered by William Wollaston in 1803. The name Rhodium, originates from the Greek word 'Rhodon' which means rose. See Rhodium research below.
Synthesis, structure, and reductive elimination in the series Tp'Rh(PR(3))(Ar(F))H; Determination of rhodium-carbon bond energies of fluoroaryl substituents.
Tanabe T, Brennessel WW, Clot E, Eisenstein O, Jones WD.
Dalton Trans. 2010 Oct 5. [Epub ahead of print]PMID: 20924525 [PubMed - as supplied by publisher]Related citations
The CO Formation Reaction Pathway in Steam Methane Reforming by Rhodium (†).
van Grootel PW, Hensen EJ, van Santen RA.
Langmuir. 2010 Oct 4. [Epub ahead of print]PMID: 20919687 [PubMed - as supplied by publisher]Related citations
The complexation of rhodium(iii) with acyclic diaminedithioether (DADTE) ligands.
Akgun Z, Engelbrecht H, Fan KH, Barnes CL, Cutler CS, Jurisson SS, Lever SZ.
Dalton Trans. 2010 Oct 4. [Epub ahead of print]PMID: 20890539 [PubMed - as supplied by publisher]Related citations
Electrochemical absorption and oxidation of hydrogen on palladium alloys with platinum, gold and rhodium.
Lukaszewski M, Hubkowska K, Czerwinski A.
Phys Chem Chem Phys. 2010 Oct 4. [Epub ahead of print]PMID: 20890504 [PubMed - as supplied by publisher]Related citations
Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes.
Pattison G, Piraux G, Lam HW.
J Am Chem Soc. 2010 Sep 29. [Epub ahead of print]PMID: 20879736 [PubMed - as supplied by publisher]Related citations
Rhodium-catalyzed restructuring of carbon frameworks.
Murakami M.
Chem Rec. 2010 Sep 24. [Epub ahead of print]PMID: 20872617 [PubMed - as supplied by publisher]Related citations
N-Methylephedrium Salts as Chiral Surfactants for Asymmetric Hydrogenation in Neat Water with Rhodium(0) Nanocatalysts.
Guyonnet Bilé E, Denicourt-Nowicki A, Sassine R, Beaunier P, Launay F, Roucoux A.
ChemSusChem. 2010 Sep 24. [Epub ahead of print] No abstract available. PMID: 20872403 [PubMed - as supplied by publisher]Related citations
Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon-Hydrogen and Carbon-Hydrogen Bonds.
Ureshino T, Yoshida T, Kuninobu Y, Takai K.
J Am Chem Soc. 2010 Sep 24. [Epub ahead of print]PMID: 20866053 [PubMed - as supplied by publisher]Related citations
Turn-Off-and-On: Chemosensing Ensembles for Sensing Chloride in Water by Fluorescence Spectroscopy.
Riis-Johannessen T, Schenk K, Severin K.
Inorg Chem. 2010 Sep 24. [Epub ahead of print]PMID: 20866035 [PubMed - as supplied by publisher]Related citations
syn-Selective Rhodium(I)-Catalyzed Allylations of Ketimines Proceeding through a Directed C--H Activation/Allene Addition Sequence.
Tran DN, Cramer N.
Angew Chem Int Ed Engl. 2010 Sep 23. [Epub ahead of print] No abstract available. PMID: 20865713 [PubMed - as supplied by publisher]Related citations
Remarkable Levels of Enantioswitching in Catalytic Asymmetric Hydroboration.
Smith SM, Takacs JM.
Org Lett. 2010 Sep 23. [Epub ahead of print]PMID: 20863120 [PubMed - as supplied by publisher]Related citations
A combinatorial approach to the identification of self-assembled ligands for rhodium-catalysed asymmetric hydrogenation.
Wieland J, Breit B.
Nat Chem. 2010 Oct;2(10):832-7. Epub 2010 Aug 22.PMID: 20861898 [PubMed - indexed for MEDLINE]Related citations
Molecular Studies of Model Surfaces of Metals from Single Crystals to Nanoparticles under Catalytic Reaction Conditions. Evolution from Prenatal and Postmortem Studies of Catalysts (†).
Somorjai GA, Aliaga C.
Langmuir. 2010 Jul 16. [Epub ahead of print]PMID: 20860409 [PubMed - as supplied by publisher]Related citations
Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboroxines to Borylalkenes: Asymmetric Synthesis of ß-Arylalkylboranes.
Sasaki K, Hayashi T.
Angew Chem Int Ed Engl. 2010 Sep 20. [Epub ahead of print] No abstract available. PMID: 20857477 [PubMed - as supplied by publisher]Related citations
Electrodeposition of carrier-free (57)Co on rhodium as an approach to the preparation of Mössbauer sources.
Cieszykowska I, Zóltowska M, Mielcarski M.
Appl Radiat Isot. 2010 Sep 8. [Epub ahead of print]PMID: 20855216 [PubMed - as supplied by publisher]Related citations
Treatment of ammonia by catalytic wet oxidation process over platinum-rhodium bimetallic catalyst in a trickle-bed reactor: effect of pH.
Hung CM, Lin WB, Ho CL, Shen YH, Hsia SY.
Water Environ Res. 2010 Aug;82(8):686-95.PMID: 20853747 [PubMed - in process]Related citations
Rhodium-catalyzed domino heterocyclization and [(3+2)+2] carbocyclization: construction of fused tricycloheptadienes.
Zhao W, Zhang J.
Chem Commun (Camb). 2010 Sep 20. [Epub ahead of print]PMID: 20852782 [PubMed - as supplied by publisher]Related citations
Italian network for human biomonitoring of metals: preliminary results from two Regions.
Bocca B, Mattei D, Pino A, Alimonti A.
Ann Ist Super Sanita. 2010;46(3):259-65.PMID: 20847458 [PubMed - in process]Free ArticleRelated citations
Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands.
McDonald RI, Wong GW, Neupane RP, Stahl SS, Landis CR.
J Am Chem Soc. 2010 Sep 16. [Epub ahead of print]PMID: 20845958 [PubMed - as supplied by publisher]Related citations
Synthesis of the Indolizino[7,6-c]quinoline Alkaloid Isaindigotidione.
Hellal M, Cuny GD.
Org Lett. 2010 Sep 16. [Epub ahead of print]PMID: 20845915 [PubMed - as supplied by publisher]Related citations