Ruthenium Nitrate

Ru(NO)(NO3)3
CAS 34513-98-9


Product Product Code Order or Specifications
(2N) 99% Ruthenium Nitrate RU-NAT-02 Contact American Elements
(3N) 99.9% Ruthenium Nitrate RU-NAT-03 Contact American Elements
(4N) 99.99% Ruthenium Nitrate RU-NAT-04 Contact American Elements
(5N) 99.999% Ruthenium Nitrate RU-NAT-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Ru(NO)(NO3)3 34513-98-9 24863244 16212391 MFCD00016313 N/A Ruthenium(3+) trinitrate N/A [Ru+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O InChI=1S/2NO3.Ru/c2*2-1(3)4;/q2*-1;+2 QNAOTDIPTCVNIM-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
RuN3O9 287.08 Red-brown crystalline powder 1.07 g/cm3 287.868 g/mol 225.88002 Da N/A Safety Data Sheet

Nitrate Ion When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Ruthenium Nitrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. We also produce Ruthenium Nitrate Solution. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Ruthenium (Ru) atomic and molecular weight, atomic number and elemental symbolRuthenium (atomic symbol: Ru, atomic number: 44) is a Block D, Group 8, Period 5 elemen with an atomic weight of 101.07. Ruthenium Bohr ModelThe number of electrons in each of ruthenium's shells is [2, 8, 18, 15, 1] and its electron configuration is [Kr] 4d7 5s1. The ruthenium atom has a radius of 134 pm and a Van der Waals radius of 207 pm. Ruthenium was discovered by Jędrzej Śniadecki in 1807.It was first recognized as a distinct element by Karl Ernst Claus in 1844. Elemental RutheniumIn its elemental form, ruthenium has a silvery white metallic appearance. Ruthenium is a rare transition metal belonging to the platinum group of metals. It is found in pentlandite, pyroxenite, and platinum group metal ores. The name Ruthenium originates from the Latin word "Ruthenia," meaning Russia. For more information on ruthenium, including properties, safety data, research, and American Elements' catalog of ruthenium products, visit the Ruthenium Information Center.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H314
Hazard Codes C
Risk Codes 34
Safety Precautions 26-36/37/39-45
RTECS Number N/A
Transport Information UN 2031 8/PG 2
WGK Germany 2
Globally Harmonized System of
Classification and Labelling (GHS)
Corrosion-Corrosive to metals        

RUTHENIUM NITRATE SYNONYMS
Ruthenium(2+) dinitrate, Ruthenium trinitrate, Ruthenium(III) nitrosyl nitrate, Ruthenium(3+) trinitrate,

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Ruthenium

  • Sensitive single-color fluorescence "off-on" switch system for dsDNA detection based on quantum dots-ruthenium assembling dyads. Zhang R, Zhao D, Ding HG, Huang YX, Zhong HZ, Xie HY. Biosens Bioelectron. 2014.
  • Ultrasensitive fluorescence detection of heparin based on quantum dots and a functional ruthenium polypyridyl complex. Cao Y, Shi S, Wang L, Yao J, Yao T. Biosens Bioelectron. 2014 May
  • Preparation and characterization of three dimensional graphene foam supported platinum-ruthenium bimetallic nanocatalysts for hydrogen peroxide based electrochemical biosensors. Kung CC, Lin PY, Buse FJ, Xue Y, Yu X, Dai L, Liu CC. Biosens Bioelectron. 2014 Feb.
  • A label-free electrochemiluminescence aptasensor for thrombin detection based on host-guest recognition between tris(bipyridine)ruthenium(II)-ß-cyclodextrin and aptamer. Chen Q, Chen H, Zhao Y, Zhang F, Yang F, Tang J, He P. Biosens Bioelectron. 2014 Apr.
  • Synthesis of imine and reduced imine compounds containing aromatic sulfonamide: Use as catalyst for in situ generation of ruthenium catalysts in transfer hydrogenation of acetophenone derivatives. Dayan S, Arslan F, Kayaci N, Kalaycioglu NO. Spectrochim Acta A Mol Biomol Spectrosc. 2014 Feb.
  • Ruthenium(II) carbonyl complexes bearing quinoline-based NNO tridentate ligands as catalyst for one-pot conversion of aldehydes to amides and o-allylation of phenols. Manikandan R, Prakash G, Kathirvel R, Viswanathamurthi P. Spectrochim Acta A Mol Biomol Spectrosc. 2013 Dec
  • Spectroscopic and biological approach in the characterization of a novel 14-membered [N4] macrocyclic ligand and its Palladium(II), Platinum(II), Ruthenium(III) and Iridium(III) complexes. Rani S, Kumar S, Chandra S. Spectrochim Acta A Mol Biomol Spectrosc. 2014 Jan.
  • Highly sensitive and selective phosphorescent chemosensors for hypochlorous acid based on ruthenium(II) complexes. Zhang R, Song B, Dai Z, Ye Z, Xiao Y, Liu Y, Yuan J. Biosens Bioelectron.
  • Evaluation of DNA-binding, DNA cleavage, antioxidant and cytotoxic activity of mononuclear ruthenium(II) carbonyl complexes of benzaldehyde 4-phenyl-3-thiosemicarbazones. Sampath K, Sathiyaraj S, Jayabalakrishnan C. Spectrochim Acta A Mol Biomol Spectrosc. 2013 Nov
  • Photoresponse enhancement by mixing of an alcohol-soluble C60 derivative into a ruthenium complex monolayer. Terada K, Oyama M, Kanaizuka K, Haga MA, Ishida T. Phys Chem Chem Phys.
  • Ruthenium(ii) complexes based on tridentate polypyridine ligands that feature long-lived room-temperature luminescence. Ragazzon G, Verwilst P, Denisov SA, Credi A, Jonusauskas G, McClenaghan ND. Chem Commun (Camb).
  • Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes. Zhang J, Song S, Wang X, Jiao J, Shi M. Chem Commun (Camb).
  • Antitumor activity of new enantiopure pybox-ruthenium complexes. Menéndez-Pedregal E, Díez J, Manteca A, Sánchez J, Bento AC, García-Navas R, Mollinedo F, Gamasa MP, Lastra E. Dalton Trans. 2013 Oct 14
  • An efficient ruthenium tris(bipyridine)-based luminescent chemosensor for recognition of Cu(ii) and sulfide anion in water. Li M, Liang Q, Zheng M, Fang C, Peng S, Zhao M. Dalton Trans. 2013 Oct 7
  • Syntheses, structures and properties of ruthenium complexes of tridentate ligands: isolation and characterization of a rare example of ruthenium nitrosyl complex containing {RuNO}(5) moiety. Ghosh K, Kumar R, Kumar S, Meena JS. Dalton Trans. 2013
  • Ruthenium(II) carbonyl complexes containing S-methylisothiosemicarbazone based tetradentate ligand: synthesis, characterization and biological applications. Selvamurugan S, Ramachandran R, Viswanathamurthi P. Biometals. 2013 Oct
  • First polymer "ruthenium-cyclopentadienyl" complex as potential anticancer agent. Valente A, Garcia MH, Marques F, Miao Y, Rousseau C, Zinck P. J Inorg Biochem.
  • Solution equilibria of anticancer ruthenium(II)-(?(6)-p-cymene)-hydroxy(thio)pyr(id)one complexes: Impact of sulfur vs. oxygen donor systems on the speciation and bioactivity. Enyedy EA, Sija E, Jakusch T, Hartinger CG, Kandioller W, Keppler BK, Kiss T. J Inorg Biochem. 2013
  • Cellular uptake mechanisms of an antitumor ruthenium compound: the endosomal/lysosomal system as a target for anticancer metal-based drugs. Côrte-Real L, Matos AP, Alho I, Morais TS, Tomaz AI, Garcia MH, Santos I, Bicho MP, Marques F. Microsc Microanal. 2013.
  • Reactivity of Nitrido Complexes of Ruthenium(VI), Osmium(VI), and Manganese(V) Bearing Schiff Base and Simple Anionic Ligands. Man WL, Lam WW, Lau TC. Acc Chem Res. 2013 Sep.

Recent Research & Development for Nitrates

  • Stable isotope analysis of plant-derived nitrate - novel method for discrimination between organically and conventionally grown vegetables. Mihailova A, Pedentchouk N, Kelly SD. Food Chem. 2014.
  • Screening of assimilatory and dissimilatory denitrifying microbes isolated from nitrate-contaminated water and soil. Seenivasagan R, Rajakumar S, Kasimani R, Ayyasamy PM. Prep Biochem Biotechnol. 2014.
  • Copper, zinc superoxide dismutase and nitrate reductase coimmobilized bienzymatic biosensor for the simultaneous determination of nitrite and nitrate. Madasamy T, Pandiaraj M, Balamurugan M, Bhargava K, Sethy NK, Karunakaran C. Biosens Bioelectron. 2014 Feb.
  • Stable isotope analysis of plant-derived nitrate - Novel method for discrimination between organically and conventionally grown vegetables. Mihailova A, Pedentchouk N, Kelly SD. Food Chem. 2014 July
  • Multicenter, double-blind, parallel group study investigating the non-inferiority of efficacy and safety of a 2% miconazole nitrate shampoo in comparison with a 2% ketoconazole shampoo in the treatment of seborrhoeic dermatitis of the scalp. Buechner SA. J Dermatolog Treat. 2014
  • Effect of nitrate ions on the efficiency of sonophotochemical phenol degradation. Zaviska F, Drogui P, El Hachemi EM, Naffrechoux E. Ultrason Sonochem. 2014 Jan.
  • Photoluminescence studies on the complexation of Eu(III) and Tb(III) with acetohydroxamic acid (AHA) in nitrate medium. Pathak PN, Mohapatra M, Godbole SV. Spectrochim Acta A Mol Biomol Spectrosc. 2013 Nov.
  • A potential carrier based on liquid crystal nanoparticles for ophthalmic delivery of pilocarpine nitrate. Li J, Wu L, Wu W, Wang B, Wang Z, Xin H, Xu Q. Int J Pharm. 2013 Oct.
  • Synthesis, growth and characterization of a nonlinear optical crystal: Bis l-proline hydrogen nitrate. Selvaraju K, Kirubavathi K. Spectrochim Acta A Mol Biomol Spectrosc. 2013 Nov.
  • Nitrate removal from eutrophic wetlands polluted by metal-mine wastes: Effects of liming and plant growth. González-Alcaraz MN, Conesa HM, Alvarez-Rogel J. J Environ Manage. 2013 Oct.
  • Affinity binding via Zinc(II) for controlled orientation and electrochemistry of Histidine-tagged nitrate reductase in self-assembled monolayers. Campbell WH, Henig J, Plumeré N. Bioelectrochemistry. 2013.
  • The nitrate time bomb: a numerical way to investigate nitrate storage and lag time in the unsaturated zone. Wang L, Butcher AS, Stuart ME, Gooddy DC, Bloomfield JP. Environ Geochem Health. 2013.
  • Direct and indirect photodegradation of estriol in the presence of humic acid, nitrate and iron complexes in water solutions. Chen Y, Zhang K, Zuo Y. Sci Total Environ. 2013 Oct.
  • Nitrate source apportionment in a subtropical watershed using Bayesian model. Yang L, Han J, Xue J, Zeng L, Shi J, Wu L, Jiang Y. Sci Total Environ. 2013 Oct.
  • A novel and efficient synthesis of diverse dihydronaphtho[1,2-b]furans using the ceric ammonium nitrate-catalyzed formal [3 + 2] cycloaddition of 1,4-naphthoquinones to olefins and its application to furomollugin. Xia L, Lee YR. Org Biomol Chem. 2013 Sep.
  • Synthesis, spectroscopic (FT-IR/NMR) characterization, X-ray structure and DFT studies on (E)-2-(1-phenylethylidene) hydrazinecarboximidamide nitrate hemimethanol. Ozdemir N, Inkaya E, Saripinar E, Akyüz L, Ilhan IÖ, Aydin S, Dinçer M, Büyükgüngör O. Spectrochim Acta A Mol Biomol Spectrosc. 2013 Oct.
  • Comments on the "Nitrate contamination in ground water of some rural areas of Rajasthan, India" by Suthar et al. Satpathy KK, Padhi RK, Samantara MK. Hazard Mater. 2013 Sep.
  • Nitrate-based niche differentiation by distinct sulfate-reducing bacteria involved in the anaerobic oxidation of methane. Green-Saxena A, Dekas AE, Dalleska NF, Orphan VJ. ISME J. 2013 Sep.
  • Model-Based Integration and Analysis of Biogeochemical and Isotopic Dynamics in a Nitrate-Polluted Pyritic Aquifer. Zhang YC, Prommer H, Broers HP, Slomp CP, Greskowiak J, van der Grift B, Van Cappellen P. Environ Sci Technol. 2013.
  • Nitrogen Oxyanion Dependent Dissociation of a Two-Component Complex that Regulates Bacterial Nitrate Assimilation. Luque-Almagro VM, Lyall VJ, Ferguson SJ, Roldan MD, Richardson DJ, Gates AJ. J Biol Chem. 2013.