Scandium(III) Hexafluoroacetylacetonate

CAS #:

Linear Formula:

Sc(C5HF6O2)3

MDL Number:

MFCD00070432

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Scandium(III) Hexafluoroacetylacetonate
SC-FACA-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Scandium(III) Hexafluoroacetylacetonate
SC-FACA-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Scandium(III) Hexafluoroacetylacetonate
SC-FACA-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Scandium(III) Hexafluoroacetylacetonate
SC-FACA-05
Pricing > SDS > Data Sheet >

Scandium(III) Hexafluoroacetylacetonate Properties (Theoretical)

Compound Formula C15H3F18O6Sc
Molecular Weight 666.11
Appearance solid
Melting Point 90°C
Boiling Point 93-96 °C
Density N/A
Solubility in H2O N/A
Exact Mass N/A
Monoisotopic Mass 665.919983
Charge N/A

Scandium(III) Hexafluoroacetylacetonate Health & Safety Information

Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Precautionary Statements P261-P264-P271-P280-P302 + P352-P304 + P340-P305 + P351 + P338-P312-P321-P332 + P313-P337 + P313-P362-P403 + P233-P405-P405-P501
Risk Codes N/A
Safety Statements N/A
Transport Information N/A
WGK Germany 3
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/29/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Scandium(III) Hexafluoroacetylacetonate

Product Number: All applicable American Elements product codes, e.g. SC-FACA-02 , SC-FACA-03 , SC-FACA-04 , SC-FACA-05

CAS #: 18990-42-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Skin irritation(Category 2), H315
Eye irritation(Category 2A), H319
Specific target organ toxicity -single exposure(Category 3), Respiratory system, H335
GHS Label elements, including precautionary statements
Hazard pictograms

Exclamation Mark - GHS07

Signal word
Warning
Hazard statement(s)
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H335
May cause respiratory irritation.
Precautionary statement(s)
P261
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264
Wash skin thoroughly after handling.
P271
Use only outdoors or in a well-ventilated area.
P280
Wear protective gloves/ eye protection/ face protection.
P302 + P352
IF ON SKIN: Wash with plenty of soap and water.
P304 + P340
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312
Call a POISON CENTER/doctor if you feel unwell.
P321
Specific treatment (see supplemental first aid instructions on this label).
P332 + P313
If skin irritation occurs: Get medical advice/ attention.
P337 + P313
If eye irritation persists: Get medical advice/ attention.
P362
Take off contaminated clothing and wash before reuse.
P403 + P233
Store in a well-ventilated place. Keep container tightly closed.
P405
Store locked up.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula: C15H3F18O6Sc
CAS-No.: 18990-42-6


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
Hydrofluoric (HF) acid burns require immediate and specialized first aid and medical treatment. Symptoms may be delayed up to 24 hours depending on the concentration of HF. After decontamination with water, further damage can occur due to penetration/absorption of the fluorideion. Treatment should be directed toward binding the fluoride ion as well as the
effects of exposure. Skin exposures can be treated with a 2.5% calcium gluconate gel repeated until burning ceases. More serious skin exposures may require subcutaneous calcium gluconate except for digital areas unless the physician is experienced in this technique, due to the potential for tissue injury from increased pressure. Absorption can readily occur through the subungual areas and should be considered when undergoing decontamination. Prevention of
absorption of the fluoride ion in cases of ingestion can be obtained by giving milk, chewable calcium carbonate tablets or Milk of Magnesia to conscious victims. Conditions such as hypocalcemia, hypomagnesemia and cardiac arrhythmias should be monitored for, since they can occur after exposure.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
First treatment with calcium gluconate paste.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
No data available
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: solid
Odor
No data available
Odor Threshold
No data available
pH
No data available
Melting point/freezing point
Melting point/range: 93 -96 °C (199 -205 °F)
Initial boiling point and boiling range
93 -96 °C (199 -205 °F)
Flash point
No data available
Evaporation rate
No data available
Flammability (solid, gas)
No data available
Upper/lower flammability or explosive limits
No data available
Vapor pressure
No data available
Vapor density
No data available
Relative density
No data available
Water solubility
No data available
Partition coefficient: n-octanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity
No data available
Explosive properties
No data available
Oxidizing properties
No data available
Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions.-Carbon oxides, Hydrogen fluoride, Scandium oxide
Other decomposition products-No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity -single exposure
Inhalation-May cause respiratory irritation.
Specific target organ toxicity -repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Scandium(III) hexafluoroacetylacetonate
CAS-No.
18990-42-6
Revision Date
New Jersey Right To Know Components
Scandium(III) hexafluoroacetylacetonate
CAS-No.
18990-42-6
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Scandium(III) Hexafluoroacetylacetonate

Scandium Hexafluoroacetylacetonate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Scandium(III) Hexafluoroacetylacetonate Synonyms

Scandium, tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-O,O'-); Scandium hexafluoroacetylacetonate

Chemical Identifiers

Linear Formula Sc(C5HF6O2)3
MDL Number MFCD00070432
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 5829507
IUPAC Name (Z)-1,1,1,5,5,5-hexafluoro-4-hydroxypent-3-en-2-one; scandium
SMILES O=C(\C=C(/O[Sc](O\C(=C/C(=O)C(F)(F)F)C(F)(F)F)O/C(=C\C(=O)C(F)(F)F)C(F)(F)F)C(F)(F)F)C(F)(F)F
InchI Identifier InChI=1S/3C5H2F6O2.Sc/c3*6-4(7,8)2(12)1-3(13)5(9,10)11;/h3*1,12H;/q;;;+3/p-3/b3*2-1-;
InchI Key DWCYUTXXZMNFLG-JVUUZWNBSA-K

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Scandium

See more Scandium products. Scandium (atomic symbol: Sc, atomic number: 21) is a Block D, Group 3, Period 4 element with an atomic weight of 44.955912. The number of electrons in each of Scandium's shells is [2, 8, 9, 2] and its electron configuration is [Ar] 3d1 4s2. Scandium Bohr Model The scandium atom has a radius of 162 pm and a Van der Waals radius of 216 pm.Scandium was predicted by Dmitri Mendeleev in 1871 and actually discovered and isolated by Lars Nilson in 1879. One of the transition metals, scandium has a silvery-white appearance in its elemental form which oxidizes to yellow or pinkish upon contact with air. Elemental ScandiumIt is occasionally included in the classification of the rare earth elements. Scandium is found in concentrated amounts in the minerals euxenite, gadolinite and thortveitite however, due to the difficulties in the preparation of metallic scandium, global trade of the pure metal is very limited. The origin of the name scandium comes from the Latin word 'scandia' meaning Scandinavia.

Fluorine

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

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