Silicon-Arsenide is a semiconductor and is used in the production of semiconductors as a substitute for direct arsenic usage. Additional technical, research and safety (MSDS) information is available. Silicon is a Block P, Group 14, Period 3 element. The number of electrons in each of Silicon's shells is 2, 8, 4 and its electronic configuration is [Ne] 3s2 3p2. In its elemental form silicon's CAS number is 7440-21-3. The silicon atom has a radius of 117.6.pm and it's Van der Waals radius is 210.pm. Silicon is not toxic but can cause chronic respiratory problems if inhaled as a fine silica or silicate dust. Asbestos silicates are carcinogenic. Silicon is one of man's most useful elements. It makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, being exceeded only by oxygen. The Czochralski process is commonly used to produce single crystals of silicon used for solid-state or semiconductor devices. Silica, as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Silicon is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Ultra high purity silicon can be doped with boron, gallium, phosphorus , or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics and space-age industries. Hydrogenated amorphous silicon has shown promise in producing economical cells for converting solar energy into electricity. Silcones are important products of silicon. They range from liquids to hard, glasslike solids with many useful properties. Silicon was first discovered by Jons Berzelius in 1823. The name Silicon originates from the Latin word "silex" which means flint or hard stone. See Silicon research below.
Arsenic is a Block P, Group 15, Period 4 element. The number of electrons in each of Arsenic's shells is 2, 8, 18, 5 and its electronic configuration is [Ar] 3d10 4s2 4p3. In its elemental form arsenic's CAS number is 1327-53-3. The arsenic atom has a radius of 124.5.pm and it's Van der Waals radius is 185.pm. Arsenic in the organic form is not harmful but in the inorganic form it is extremely toxic even in very small amounts. Arsenic has numerous applications as a semiconductor and other electronic applications as Indium arsenide, silicon arsenide and tin arsenidea. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors. Gallium arsenide is used as a laser material to convert electricity directly into coherent light. Arsenic is used in bronzing and for hardening and improving the sphericity of shot. Arsenic is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Arsenic information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. See Arsenic research below.
An arsenide, an anion with the charge -3, is a rare mineral group consisting of compounds of one or more metals with arsenic (As). Arsenide anions have no existence in solution since they are extremely basic. These solid salts have very high lattice energies and are toxic due to the inherent toxicity of arsenic. Arsenides have applications in semiconductors, laser and light-emitting diodes, quantum dots, and optical and pressure sensors.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
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Crystal "pulling" by the Czochaiski method for production of semiconductor materials
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Flux growth and gradient freeze
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Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES |
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
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Recent Research & Development for Silicon
- RECONSTRUCTION OF THE THUMB WITH A MODIFIED WRAP-AROUND FLAP IN A PATIENT SUFFERING FROM ?-THALASSEMIA MINOR.
Galeano M, Checcucci G, Ceruso M.
Hand Surg. 2011;16(3):361-5.
PMID:
22072476
[PubMed - in process]
- Isolated complete volar dislocation of the capitate: a case report.
Checcucci G, Bigazzi P, Zucchini M, Ceruso M.
Hand Surg. 2011;16(3):353-6.
PMID:
22072474
[PubMed - in process]
- Dielectrophoretic chip with multilayer electrodes and micro-cavity array for trapping and programmably releasing single cells.
Chuang CH, Huang YW, Wu YT.
Biomed Microdevices. 2011 Nov 10. [Epub ahead of print]
PMID:
22072154
[PubMed - as supplied by publisher]
- Structures of medium sized tin cluster anions.
Wiesel A, Drebov N, Rapps T, Ahlrichs R, Schwarz U, Kelting R, Weis P, Kappes MM, Schooss D.
Phys Chem Chem Phys. 2011 Nov 9. [Epub ahead of print]
PMID:
22071636
[PubMed - as supplied by publisher]
- Discrimination task reveals differences in neural bases of tinnitus and hearing impairment.
Husain FT, Pajor NM, Smith JF, Kim HJ, Rudy S, Zalewski C, Brewer C, Horwitz B.
PLoS One. 2011;6(10):e26639. Epub 2011 Oct 31.
PMID:
22066003
[PubMed - in process]
- A suggested technique for the application of the cone beam computed tomography periapical index.
Esposito S, Cardaropoli M, Cotti E.
Dentomaxillofac Radiol. 2011 Dec;40(8):506-12.
PMID:
22065800
[PubMed - in process]
- (4-Chloro-3-nitro-benzoato)triphenyl-tin(IV).
Win YF, Choong CS, Teoh SG, Quah CK, Fun HK.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1270-1. Epub 2011 Aug 27.
PMID:
22065496
[PubMed]
- Bis{2-[(E)-(5-tert-butyl-2-hy-droxy-phen-yl)diazen-yl]benzoato}dimethyl-tin(IV).
Basu Baul TS, Paul A, Tiekink ER.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1383-4. Epub 2011 Sep 14.
PMID:
22065466
[PubMed]
- Chloridodiphen-yl{[1-(1,3-thia-zol-2-yl-?N)ethyl-idene]-4-phenyl-thio-semicarbazidato-?N,S}tin(IV) methanol monosolvate.
Arumugam SR, Dasary SS, Venkatraman R, Yu H, Fronczek FR.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1409-10. Epub 2011 Sep 30.
PMID:
22065366
[PubMed]
- catena-Poly[[triphenyl-tin(IV)]-?-5-amino-2-nitro-benzoato-?O:O].
Win YF, Choong CS, Teoh SG, Quah CK, Fun HK.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1276-7. Epub 2011 Aug 27.
PMID:
22064934
[PubMed]
- Dual detection strategy for electrochemical analysis of glucose and nitrite using a partitionally modified electrode.
Wang J, Diao P, Zhang Q.
Analyst. 2011 Nov 7. [Epub ahead of print]
PMID:
22064849
[PubMed - as supplied by publisher]
- fac-(2-Amido-ethyl-?C,O)trichlorido(urea-?O)tin(IV).
Howie RA, de Lima GM, Tiekink ER, Wardell JL, Wardell SM.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1420-1. Epub 2011 Sep 30.
PMID:
22064619
[PubMed]
- Highly sensitive nonenzymatic glucose sensor based on electrospun copper oxide-doped nickel oxide composite microfibers.
Cao F, Guo S, Ma H, Yang G, Yang S, Gong J.
Talanta. 2011 Oct 30;86:214-20. Epub 2011 Sep 8.
PMID:
22063533
[PubMed - in process]
- Cross-Linked Perylene Diimide-Based n-Type Interfacial Layer for Inverted Organic Photovoltaic Devices.
Hains AW, Chen HY, Reilly TH, Gregg BA.
ACS Appl Mater Interfaces. 2011 Nov 7. [Epub ahead of print]
PMID:
22059439
[PubMed - as supplied by publisher]
- Bis-(chloro-acetato-?O)bis(trimethyl-silylmethyl)tin(IV).
Ding RF, Wang QB.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1190. Epub 2011 Aug 2.
PMID:
22058841
[PubMed]
- A new langbeinite-type phosphate: K(2)AlSn(PO(4))(3).
Li HY, Zhao D.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):i56. Epub 2011 Sep 20.
PMID:
22058680
[PubMed]
- Enhanced resistance of yeast mutants deficient in low-affinity iron and zinc transporters to stannous-induced toxicity.
Viau CM, Cardone JM, Guecheva TN, Yoneama ML, Dias JF, Pungartnik C, Brendel M, Saffi J, Henriques JA.
Chemosphere. 2011 Nov 2. [Epub ahead of print]
PMID:
22055569
[PubMed - as supplied by publisher]
- Allylsilanes in "Tin-free" Oximation, Alkenylation, and Allylation of Alkyl Halides.
Rouquet G, Robert F, Méreau R, Castet F, Landais Y.
Chemistry. 2011 Nov 3. doi: 10.1002/chem.201101842. [Epub ahead of print]
PMID:
22052660
[PubMed - as supplied by publisher]
- Surface Modification of Indium-Tin-Oxide Via Self-Assembly of a Donor-Acceptor Complex: A Density Functional Theory Study.
Li H, Winget P, Bredas JL.
Adv Mater. 2011 Nov 3. doi: 10.1002/adma.201103009. [Epub ahead of print] No abstract available.
PMID:
22052626
[PubMed - as supplied by publisher]
- Minimally invasive video-assisted cardiac surgery: operative techniques, application fields and clinical outcomes.
Vistarini N, Aiello M, Viganò M.
Future Cardiol. 2011 Nov;7(6):775-87.
PMID:
22050064
[PubMed - in process]
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Recent Research & Development for Arsenic
- Arsenic trioxide treatment decreases the oxygen consumption rate of tumor cells and radiosensitizes solid tumors.
Diepart C, Karroum O, Magat J, Feron O, Verrax J, Buc Calderon P, Grégoire V, Leveque P, Stockis J, Dauguet N, Jordan BF, Gallez B.
Cancer Res. 2011 Dec 2. [Epub ahead of print]
PMID:
22139377
[PubMed - as supplied by publisher]
- Arsenic-Induced Straighthead: An Impending Threat to Sustainable Rice Production in South and South-East Asia!
Azizur Rahman M, Mamunur Rahman M, Hasegawa H.
Bull Environ Contam Toxicol. 2011 Dec 4. [Epub ahead of print]
PMID:
22139332
[PubMed - as supplied by publisher]
- Comparative Soil Metal Analyses in Sudbury (Ontario, Canada) and Lubumbashi (Katanga, DR-Congo).
Narendrula R, Nkongolo KK, Beckett P.
Bull Environ Contam Toxicol. 2011 Dec 4. [Epub ahead of print]
PMID:
22139330
[PubMed - as supplied by publisher]
- Purification, crystallization and preliminary X-ray diffraction studies of the arsenic repressor ArsR from Corynebacterium glutamicum.
Santha S, Pandaranayaka EP, Rosen BP, Thiyagarajan S.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Dec 1;67(Pt 12):1616-8. Epub 2011 Nov 26.
PMID:
22139180
[PubMed - in process]
- Arsenic contamination and speciation in surrounding waters of three old cinnabar mines.
Larios R, Fernández-Martínez R, Silva V, Loredo J, Rucandio I.
J Environ Monit. 2011 Dec 5. [Epub ahead of print]
PMID:
22139034
[PubMed - as supplied by publisher]
- Arsenic Exposure and Hypertension: A Systematic Review.
Abhyankar LN, Jones MR, Guallar E, Navas-Acien A.
Environ Health Perspect. 2011 Dec 2. [Epub ahead of print]
PMID:
22138666
[PubMed - as supplied by publisher]
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Metals in biology: defining metalloproteomes.
Yannone SM, Hartung S, Menon AL, Adams MW, Tainer JA.
Curr Opin Biotechnol. 2011 Dec 2. [Epub ahead of print]
PMID:
22138493
[PubMed - as supplied by publisher]
- Total and inorganic arsenic concentrations in different species of economically important algae harvested from coastal zones of Chile.
Díaz O, Tapia Y, Muñoz O, Montoro R, Velez D, Almela C.
Food Chem Toxicol. 2011 Nov 25. [Epub ahead of print]
PMID:
22138359
[PubMed - as supplied by publisher]
- Zamzam water: Concentration of trace elements and other characteristics.
Shomar B.
Chemosphere. 2011 Dec 2. [Epub ahead of print]
PMID:
22138338
[PubMed - as supplied by publisher]
- Removal of methylated arsenic using a nanostructured zirconia-based sorbent: Process performance and adsorption chemistry.
Zheng YM, Yu L, Chen JP.
J Colloid Interface Sci. 2011 Oct 12. [Epub ahead of print]
PMID:
22137855
[PubMed - as supplied by publisher]
- Humans seem to produce arsenobetaine and dimethylarsinate after a bolus dose of seafood.
Molin M, Ulven SM, Dahl L, Telle-Hansen VH, Holck M, Skjegstad G, Ledsaak O, Sloth JJ, Goessler W, Oshaug A, Alexander J, Fliegel D, Ydersbond TA, Meltzer HM.
Environ Res. 2011 Dec 1. [Epub ahead of print]
PMID:
22137101
[PubMed - as supplied by publisher]
- A modified batch reactor system to study equilibrium-reactive transport problems.
Jeppu GP, Clement TP, Barnett MO, Lee KK.
J Contam Hydrol. 2011 Oct 20. [Epub ahead of print]
PMID:
22136983
[PubMed - as supplied by publisher]
- Identification of the GST-T1 and GST-M1 Null Genotypes using High Resolution Melting Analysis.
Drobna Z, Del Razo LM, Garcia-Vargas G, Sanchez-Ramirez B, Gonzalez-Horta C, Ballinas ML, Loomis D, Styblo M.
Chem Res Toxicol. 2011 Dec 2. [Epub ahead of print]
PMID:
22136492
[PubMed - as supplied by publisher]
- Uranium and trace elements in phosphate fertilizers-saudi arabia.
Khater AE.
Health Phys. 2012 Jan;102(1):63-70.
PMID:
22134079
[PubMed - in process]
- Natural attenuation of arsenic in soils near a highly contaminated historical mine waste dump.
Drahota P, Filippi M, Ettler V, Rohovec J, Mihaljevic M, Sebek O.
Sci Total Environ. 2011 Nov 29. [Epub ahead of print]
PMID:
22134035
[PubMed - as supplied by publisher]
- Removing arsenic from synthetic groundwater with iron electrocoagulation: An Fe and As K-edge EXAFS study.
van Genuchten CM, Addy SE, Pena J, Gadgil A.
Environ Sci Technol. 2011 Dec 1. [Epub ahead of print]
PMID:
22132945
[PubMed - as supplied by publisher]
- Embryotoxicity assessment of developmental neurotoxicants using a neuronal endpoint in the embryonic stem cell test.
Baek DH, Kim TG, Lim HK, Kang JW, Seong SK, Choi SE, Lim SY, Park SH, Nam BH, Kim EH, Kim MS, Park KL.
J Appl Toxicol. 2011 Dec 1. doi: 10.1002/jat.1747. [Epub ahead of print]
PMID:
22131109
[PubMed - as supplied by publisher]
- Comparing different means of signal treatment for improving the detection power in HPLC-ICP-MS.
Prikler S, Pick D, Einax JW.
Anal Bioanal Chem. 2011 Dec 1. [Epub ahead of print]
PMID:
22130722
[PubMed - as supplied by publisher]
- Biological monitoring versus air monitoring strategies in assessing environmental-occupational exposure.
Jakubowski M.
J Environ Monit. 2011 Dec 1. [Epub ahead of print]
PMID:
22130625
[PubMed - as supplied by publisher]
- Overexpression of alfalfa mitochondrial HSP23 in prokaryotic and eukaryotic model systems confers enhanced tolerance to salinity and arsenic stress.
Lee KW, Cha JY, Kim KH, Kim YG, Lee BH, Lee SH.
Biotechnol Lett. 2011 Nov 30. [Epub ahead of print]
PMID:
22127759
[PubMed - as supplied by publisher]
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