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Samarium Bromide SmBr2
SmBr2

50801-97-3
Product Product Code Order or Specifications
(2N) 99% Samarium Bromide SM-BR-02 Contact American Elements
(3N) 99.9% Samarium Bromide SM-BR-03 Contact American Elements
(4N) 99.99% Samarium Bromide SM-BR-04 Contact American Elements
(5N) 99.999% Samarium Bromide SM-BR-05 Contact American Elements
Bromide IonSamarium Bromide is a highly water soluble crystalline Samarium source for uses compatible with Bromides and lower (acidic) pH. Metallic Bromides are marketed under the trade name AE Bromides™. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding Samarium disulfide (CS2) and chlorine. Samarium Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Samarium(Sm)atomic and molecular weight, atomic number and elemental symbol Samarium is a Block F, Group 3, Period 6 element. The number of electrons in each of Samarium's shells is 2, 8, 18, 24, 8, 2 and its electronic configuration is [Xe]4f6 6s2. In its elemental form samarium's CAS number is 7440-19-9. The samarium atom has a radius of 180.4.pm and it's Van der Waals radius is unknown. Samarium is somewhat toxic. Samarium is primarily utilized in the production of samarium-cobalt (Sm2Co17) permanent magnets. Samarium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compoundsElemental Samarium as Samarium Bohr Model submicron and nanopowder. It is also used in laser applications and for its dielectric properties. Samarium-cobalt magnets replaced the more expensive platinum-cobalt magnets in the early 1970s. While now overshadowed by the less expensive neodymium-iron-boron magnet, they are still valued for their ability to function at high temperatures. They are utilized in lightweight electronic equipment where size or space is a limiting factor and where functionality at high temperature is a concern. Applications include electronic watches, aeospace equipment, microwave technology and servomotors. Because of its weak spectral absorption band samarium is used in the filter glass on Nd:YAG solid state lasers to surround the laser rod to improve efficiency by absorbing stray emissions. Samarium was first discovered by Paul Emile Lecoq de Boisbaudran in 1879. Samarium is named after the mineral samarskite. See Samarium research below.

Formula CAS No. Appearance Molecular Weight
SmBr2 50801-97-3 Brown or Black Crystalline Solid 310.168
PRODUCT CATALOG Bromide Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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Recent Research & Development for Samarium

  • Catalytic hydrosilylation of olefins with organolanthanide complexes: A DFT study. Part II: Influence of the substitution on olefin and silane. Barros N, Eisenstein O, Maron L. Dalton Trans. 2010 Oct 8. [Epub ahead of print]PMID: 20936209 [PubMed - as supplied by publisher]Related citations

  • Safety and feasibility of percutaneous vertebroplasty with radioactive (153)Sm PMMA in an animal model. Lu J, Deng J, Zhao H, Shi M, Wang J, Zhao L. Eur J Radiol. 2010 Oct 8. [Epub ahead of print]PMID: 20934823 [PubMed - as supplied by publisher]Related citations

  • Chemical and biological evaluation of (153)Sm and (46/47)Sc complexes of indazolebisphosphonates for targeted radiotherapy. Neves M, Teixeira FC, Antunes I, Majkowska A, Gano L, Santos AC. Appl Radiat Isot. 2010 Sep 25. [Epub ahead of print]PMID: 20933431 [PubMed - as supplied by publisher]Related citations

  • Adverse Events in the Long-Term Follow-Up of Patients Treated With Samarium Sm 153 Lexidronam for Osseous Metastases. Paravati AJ, Russo AL, Aitken C. Int J Radiat Oncol Biol Phys. 2010 Sep 30. [Epub ahead of print]PMID: 20888141 [PubMed - as supplied by publisher]Related citations

  • A Short Formal Total Synthesis of Strychnine with a Samarium Diiodide Induced Cascade Reaction as the Key Step. Beemelmanns C, Reissig HU. Angew Chem Int Ed Engl. 2010 Sep 16. [Epub ahead of print] No abstract available. PMID: 20848626 [PubMed - as supplied by publisher]Related citations

  • Computational insights into the nature of increased ionic conductivity in concentrated samarium-doped ceria: a genetic algorithm study. Hooper J, Ismail A, Giorgi JB, Woo TK. Phys Chem Chem Phys. 2010 Oct 28;12(40):12969-72. Epub 2010 Sep 8.PMID: 20830388 [PubMed - in process]Related citations

  • Therapeutic nuclear medicine in pediatric malignancy. Schmidt M, Baum RP, Simon T, Howman-Giles R. Q J Nucl Med Mol Imaging. 2010 Aug;54(4):411-28.PMID: 20823809 [PubMed - in process]Related citations

  • Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer. Fukuzumi S, Morimoto Y, Kotani H, Naumov P, Lee YM, Nam W. Nat Chem. 2010 Sep;2(9):756-9. Epub 2010 Jul 11.PMID: 20729896 [PubMed - indexed for MEDLINE]Related citations

  • Molecules containing rare-earth atoms solely bonded by transition metals. Butovskii MV, Döring C, Bezugly V, Wagner FR, Grin Y, Kempe R. Nat Chem. 2010 Sep;2(9):741-4. Epub 2010 Jun 27.PMID: 20729893 [PubMed - indexed for MEDLINE]Related citations

  • Dynamic ligand exchange in reactions of samarium diiodide. Sadasivam DV, Teprovich JA Jr, Procter DJ, Flowers RA 2nd. Org Lett. 2010 Sep 17;12(18):4140-3.PMID: 20722385 [PubMed - in process]Related citations

  • Tandem dosing of samarium-153 ethylenediamine tetramethylene phosphoric acid with stem cell support for patients with high-risk osteosarcoma. Loeb DM, Hobbs RF, Okoli A, Chen AR, Cho S, Srinivasan S, Sgouros G, Shokek O, Wharam MD Jr, Scott T, Schwartz CL. Cancer. 2010 Aug 16. [Epub ahead of print]PMID: 20715156 [PubMed - as supplied by publisher]Related citations

  • Gamma spectrometry and chemical characterization of ceramic seeds with samarium-153 and holmium-166 for brachytherapy proposal. Valente ES, Campos TP. Appl Radiat Isot. 2010 Dec;68(12):2157-62. Epub 2010 Jul 27.PMID: 20685128 [PubMed - in process]Related citations

  • Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium. Concellón JM, Rodríguez-Solla H, Concellón C, Del Amo V. Chem Soc Rev. 2010 Aug 4. [Epub ahead of print]PMID: 20683534 [PubMed - as supplied by publisher]Related citations

  • Grafting of peralkylated Ln(II)Al(III) heterobimetallic complexes onto periodic mesoporous silica KIT-6. Le Roux E, Michel O, Sommerfeldt HM, Liang Y, Maichle-Mössmer C, Törnroos KW, Anwander R. Dalton Trans. 2010 Sep 28;39(36):8552-9. Epub 2010 Aug 4.PMID: 20683527 [PubMed - in process]Related citations

  • Synthesis of 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanaminevia a [4+2] cycloaddition. Karama U, Al-Saidey A, Al-Othman Z, Almansour AR. Molecules. 2010 Jun 9;15(6):4201-6.PMID: 20657434 [PubMed - in process]Related citations

  • [99mTc]-1,4,7,10-Tetraazacyclododecane tetramethylenephosphonic acid. Datta A, Panwar P, Chuttani K, Mishra AK, Chopra A. Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2010. 2009 Mar 31 [updated 2009 Jun 9].PMID: 20641623 [PubMed]Books & DocumentsFree textRelated citations

  • Non-classical divalent lanthanide complexes. Nief F. Dalton Trans. 2010 Aug 7;39(29):6589-98. Epub 2010 Mar 25.PMID: 20631944 [PubMed - in process]Related citations

  • Synthesis and characterization of thermally stable Sm,N co-doped TiO2 with highly visible light activity. Ma Y, Zhang J, Tian B, Chen F, Wang L. J Hazard Mater. 2010 Oct 15;182(1-3):386-93. Epub 2010 Jun 18.PMID: 20619539 [PubMed - in process]Related citations

  • Steric control of the reduction of carbodiimides by samarium(II) and the synthesis of very crowded samarium(III) complexes. Cole ML, Deacon GB, Forsyth CM, Junk PC, Polo Cerón D, Wang J. Dalton Trans. 2010 Aug 7;39(29):6732-8.PMID: 20614084 [PubMed - in process]Related citations

  • Studies on the biodistribution of dextrin nanoparticles. Gonçalves C, Ferreira MF, Santos AC, Prata MI, Geraldes CF, Martins JA, Gama FM. Nanotechnology. 2010 Jul 23;21(29):295103. Epub 2010 Jul 5.PMID: 20601764 [PubMed - indexed for MEDLINE]Related citations
Recent Research & Development for Bromides

  • Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids. Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C. Org Lett. 2010 Jan 5. [Epub ahead of print] PMID: 19689116 [PubMed - as supplied by publisher]

  • Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides. Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Science. 2009 Aug 13. [Epub ahead of print] PMID: 19679769 [PubMed - as supplied by publisher]

  • (2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides. Zhang Q, Wang D, Wang X, Ding K. J Org Chem. 2009 Aug 12. [Epub ahead of print] PMID: 19673481 [PubMed - as supplied by publisher]

  • Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides. Vechorkin O, Barmaz D, Proust V, Hu X. J Am Chem Soc. 2009 Aug 11. [Epub ahead of print] PMID: 19670863 [PubMed - as supplied by publisher]

  • Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia. Huang JM, Dong Y. Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28. PMID: 19662260 [PubMed - in process]

  • Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols. Salvi L, Kim JG, Walsh PJ. J Am Chem Soc. 2009 Aug 4. [Epub ahead of print] PMID: 19653691 [PubMed - as supplied by publisher]

  • Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines. Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J. J Comb Chem. 2009 Jul 31. [Epub ahead of print] PMID: 19645499 [PubMed - as supplied by publisher]

  • Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids. del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N. Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29. PMID: 19641822 [PubMed - in process]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies. Snelders DJ, van Koten G, Klein Gebbink RJ. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639941 [PubMed - as supplied by publisher]

  • Can One Predict Changes from S(N)1 to S(N)2 Mechanisms? Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. J Am Chem Soc. 2009 Jul 27. [Epub ahead of print] PMID: 19634906 [PubMed - as supplied by publisher]

  • A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides. Liao Q, Wang Y, Zhang L, Xi C. J Org Chem. 2009 Jul 15. [Epub ahead of print] PMID: 19603753 [PubMed - as supplied by publisher]

  • Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides. Shi L, Chu Y, Knochel P, Mayr H. Org Lett. 2009 Jul 14. [Epub ahead of print] PMID: 19601592 [PubMed - as supplied by publisher]

  • C5-Modified nucleosides exhibiting anticancer activity. Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH. Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21. PMID: 19596579 [PubMed - in process]

  • Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. Vo GD, Hartwig JF. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591470 [PubMed - as supplied by publisher]

  • New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes. Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B. Org Lett. 2009 Jul 2. [Epub ahead of print] PMID: 19572730 [PubMed - as supplied by publisher]

  • The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives. Jo Y, Ju J, Choe J, Song KH, Lee S. J Org Chem. 2009 Jul 2. [Epub ahead of print] PMID: 19572571 [PubMed - as supplied by publisher]

  • Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents. Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH. Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8. PMID: 19557114 [PubMed - in process]

  • A facile route to C2-substituted imidazolium ionic liquids. Ennis E, Handy ST. Molecules. 2009 Jun 19;14(6):2235-45. PMID: 19553895 [PubMed - in process]

  • Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines. McCall WS, Comins DL. Org Lett. 2009 Jul 2;11(13):2940-2. PMID: 19552467 [PubMed - indexed for MEDLINE]

 

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