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Samarium(III) Iodide
SmI3

13813-25-7
Product Product Code Order or Specifications
(2N) 99% Samarium Iodide SM-I-02 Contact American Elements
(2N5) 99.5% Samarium Iodide SM-I-025 Contact American Elements
(3N) 99.9% Samarium Iodide SM-I-03 Contact American Elements
(3N5) 99.95% Samarium Iodide SM-I-035 Contact American Elements
(4N) 99.99% Samarium Iodide SM-I-04 Contact American Elements
(5N) 99.999% Samarium Iodide SM-I-05 Contact American Elements
Iodide IonIodide compounds are water soluble however iodide rich solutions act as better dissolution agents for creating iodide solutions. Samarium Iodide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Samarium(Sm)atomic and molecular weight, atomic number and elemental symbol Samarium is a Block F, Group 3, Period 6 element. The number of electrons in each of Samarium's shells is 2, 8, 18, 24, 8, 2 and its electronic configuration is [Xe]4f6 6s2. In its elemental form samarium's CAS number is 7440-19-9. The samarium atom has a radius of 180.4.pm and it's Van der Waals radius is unknown. Samarium is somewhat toxic. Samarium is primarily utilized in the production of samarium-cobalt (Sm2Co17) permanent magnets. Samarium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compoundsElemental Samarium as Samarium Bohr Model submicron and nanopowder. It is also used in laser applications and for its dielectric properties. Samarium-cobalt magnets replaced the more expensive platinum-cobalt magnets in the early 1970s. While now overshadowed by the less expensive neodymium-iron-boron magnet, they are still valued for their ability to function at high temperatures. They are utilized in lightweight electronic equipment where size or space is a limiting factor and where functionality at high temperature is a concern. Applications include electronic watches, aeospace equipment, microwave technology and servomotors. Because of its weak spectral absorption band samarium is used in the filter glass on Nd:YAG solid state lasers to surround the laser rod to improve efficiency by absorbing stray emissions. Samarium was first discovered by Paul Emile Lecoq de Boisbaudran in 1879. Samarium is named after the mineral samarskite. See Samarium research below.

Iodine(I) atomic and molecular weight, atomic number and elemental symbol Iodine is a Block P, Group 17, Period 5 element. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electronic configuration is [Kr] 4d10 5s2 5p5. In its elemental form iodine's CAS number is 7553-56-2. The iodine atom has a radius of 133.1.pm and it's Van der Waals radius is 198.pm. Iodine in large amounts is poisonous but in small doses is only slightly toxic. Iodine forms compounds with many elements, but is less active than the other halogens, which displace it from iodides. Iodine exhibits some metallic-like properties. It dissolves readily in chloroform, Iodine Bohr Modelcarbon tetrachloride, or carbonElemental Iodine disulfide to form purple solutions. It is only slightly soluble in water. Iodine compounds are important in organic chemistry and very useful in medicine. Potassium iodide finds use in photography. The deep blue color with starch solution is characteristic of the free element.Iodine is available in compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity). See Iodine research below. Iodine it forms compounds with many elements, but is less active than the other halogens, which displace it from iodides. Iodine exhibits some metallic-like properties. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide to form purple solutions. It is only slightly soluble in water. Iodine compounds are important in organic chemistry and very useful in medicine. Iodides, and thyroxine which contains iodine, are used internally in medicine. Potassium iodide finds use in photography. The deep blue color with starch solution is characteristic of the free element.Iodine is available in compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity). See Iodine research below.

Formula CAS No. Appearance Molecular Weight
SmI3 13813-25-7   531.07
PRODUCT CATALOG Iodide Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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Recent Research & Development for Samarium

  • Selective separation of samarium(III) by synergistic extraction with ß-diketone and methylphenylphenanthroline carboxamide. Hasegawa Y, Tamaki S, Yajima H, Hashimoto B, Yaita T. Talanta. 2011 Sep 15;85(3):1543-8. Epub 2011 Jun 21. PMID: 21807220 [PubMed - in process]

  • Integral Stereocontrolled Synthesis of a Spiro-norlignan, Sequosempervirin A: Revision of Absolute Configuration. Ito Y, Takahashi K, Nagase H, Honda T. Org Lett. 2011 Aug 1. [Epub ahead of print] PMID: 21805972 [PubMed - as supplied by publisher]

  • Interactions between metal ions and carbohydrates. Syntheses and spectroscopic studies of several lanthanide nitrate-d-galactitol complexes. Yu L, Hua X, Pan Q, Yang L, Xu Y, Zhao G, Wang H, Wang H, Wu J, Liu K, Chen J. Carbohydr Res. 2011 Jun 30. [Epub ahead of print] PMID: 21784418 [PubMed - as supplied by publisher]

  • Chemical synthesis and evaluation of 17a-alkylated derivatives of estradiol as inhibitors of steroid sulfatase. Fournier D, Poirier D. Eur J Med Chem. 2011 Jun 28. [Epub ahead of print] PMID: 21782294 [PubMed - as supplied by publisher]

  • Concise Syntheses of Strychnine and Englerin A: the Power of Reductive Cyclizations Triggered by Samarium Iodide. Szostak M, Procter DJ. Angew Chem Int Ed Engl. 2011 Jul 20. doi: 10.1002/anie.201103128. [Epub ahead of print] No abstract available. PMID: 21780264 [PubMed - as supplied by publisher]

  • Preparation and Quality Control of the [Sm]-Samarium Maltolate Complex as a Lanthanide Mobilization Product in Rats. Naseri Z, Hakimi A, Jalilian AR, Nemati Kharat A, Bahrami-Samani A, Ghannadi-Maragheh M. Sci Pharm. 2011 Jun;79(2):265-275. Epub 2011 Feb 24. PMID: 21773065 [PubMed - as supplied by publisher]

  • Synthesis and characterization of heterobimetallic oxo-bridged aluminum-rare Earth metal complexes. Hao J, Li J, Cui C, Roesky HW. Inorg Chem. 2011 Aug 15;50(16):7453-9. Epub 2011 Jul 15. PMID: 21761836 [PubMed - in process]

  • Novel Supramolecular Assemblies Based on Coordination of Samarium Cation to Cucurbit[5]uril. Chen K, Liang LL, Zhang YQ, Zhu QJ, Xue SF, Tao Z. Inorg Chem. 2011 Aug 15;50(16):7754-60. Epub 2011 Jul 15. PMID: 21761833 [PubMed - in process]

  • Total Synthesis of 10-Isocyano-4-cadinene and Its Stereoisomers and Evaluations of Antifouling Activities. Nishikawa K, Nakahara H, Shirokura Y, Nogata Y, Yoshimura E, Umezawa T, Okino T, Matsuda F. J Org Chem. 2011 Jul 26. [Epub ahead of print] PMID: 21755975 [PubMed - as supplied by publisher]

  • Tris[6-meth-oxy-2-(phenyl-iminiometh-yl)phenolato]-?O,O';?O-tris-(thio-cyanato-?N)samarium(III). Ge GD, Shen JB, Zhao GL. Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m706-7. Epub 2011 May 7. PMID: 21754608 [PubMed]

  • {µ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methanylyl-idene)]di-phenolato}dimethano-ltrinitrato-samarium(III)zinc(II) methanol disolvate. Liu F, Zhang F. Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m525. Epub 2011 Apr 7. PMID: 21754267 [PubMed]

  • Samarium Diiodide Induced Cyclizations of ?-, d- and e-Indolyl Ketones: Reductive Coupling, Intermolecular Trapping, and Subsequent Transformations of Indolines. Beemelmanns C, Lentz D, Reissig HU. Chemistry. 2011 Jul 8. doi: 10.1002/chem.201100981. [Epub ahead of print] PMID: 21744405 [PubMed - as supplied by publisher]

  • 177Lu-Labeled methylene diphosphonate. Chopra A. Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011. 2011 May 24 [updated 2011 Jun 30]. PMID: 21735586 [PubMed]

  • Radioisotopes for metastatic bone pain. Roqué I Figuls M, Martinez-Zapata MJ, Scott-Brown M, Alonso-Coello P. Cochrane Database Syst Rev. 2011 Jul 6;(7):CD003347. Review. PMID: 21735393 [PubMed - indexed for MEDLINE]

  • Cubic and doubly-fused cubic samarium clusters from Sm(ii)-mediated reduction of organic azides and azobenzenes. Pan CL, Chen W, Su S, Pan YS, Wang J. Dalton Trans. 2011 Aug 21;40(31):7941-5. Epub 2011 Jun 30. PMID: 21717024 [PubMed - in process]

  • ACR-ASTRO Practice Guideline for the Performance of Therapy With Unsealed Radiopharmaceutical Sources. Henkin RE, Del Rowe JD, Grigsby PW, Hartford AC, Jadvar H, Macklis RM, Parker JA, Wong JY, Rosenthal SA. Clin Nucl Med. 2011 Aug;36(8):e72-e80. PMID: 21716005 [PubMed - as supplied by publisher]

  • Synthesis and molecular structure of piperazidine-bridged bis(phenolate) samarium(ii) complex and its reactivity to carbodiimides. Du Z, Zhang Y, Yao Y, Shen Q. Dalton Trans. 2011 Aug 7;40(29):7639-44. Epub 2011 Jun 24. PMID: 21701733 [PubMed - in process]

  • Theoretical Treatment of Redox Processes Involving Lanthanide(II) Compounds: Reactivity of Organosamarium(II) and Organothulium(II) Complexes with CO(2) and Pyridine. Labouille S, Nief F, Maron L. J Phys Chem A. 2011 Jul 28;115(29):8295-8301. Epub 2011 Jul 6. PMID: 21675778 [PubMed - as supplied by publisher]

  • 177Lu-Labeled ethylenediamine tetramethylene phosphonic acid. Chopra A. Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011. 2011 Apr 28 [updated 2011 May 26]. PMID: 21656987 [PubMed]

  • [170Tm]-Labeled ethylenediamine tetramethylene phosphonic acid. Chopra A. Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011. 2011 Apr 27 [updated 2011 May 26]. PMID: 21656985 [PubMed]

 

  • The role of striatal dopamine D2 receptors in the occurrence of extrapyramidal side effects: Iodine-123-iodobenzamide single photon emission computed tomography study. Corripio I, Ferreira A, Portella MJ, Pérez V, Escartí MJ, Del Valle Camacho M, Sauras RB, Alonso A, Grasa EM, Carrió I, Catafau AM, Alvarez E. Psychiatry Res. 2012 Jan 24. [Epub ahead of print] PMID: 22281201 [PubMed - as supplied by publisher]

  • Adjuvant therapy options following curative treatment of hepatocellular carcinoma: A systematic review of randomized trials. Zhong JH, Li H, Li LQ, You XM, Zhang Y, Zhao YN, Liu JY, Xiang BD, Wu GB. Eur J Surg Oncol. 2012 Jan 24. [Epub ahead of print] PMID: 22281155 [PubMed - as supplied by publisher]

  • Mercury and thyroid autoantibodies in U.S. women, NHANES 2007-2008. Gallagher CM, Meliker JR. Environ Int. 2012 Apr;40:39-43. Epub 2011 Dec 27. PMID: 22280926 [PubMed - in process]

  • Dietary Iodine and Thyroid Cancer Risk in French Polynesia: A Case-Control Study. Cléro E, Doyon F, Chungue V, Rachédi F, Boissin JL, Sebbag J, Shan L, Bost-Bezeaud F, Petitdidier P, Dewailly E, Rubino C, de Vathaire F. Thyroid. 2012 Jan 26. [Epub ahead of print] PMID: 22280227 [PubMed - as supplied by publisher]

  • Highly Enantioselective Copper-Catalyzed Alkylation of ß-Ketoesters and Subsequent Cyclization to Spirolactones/ bi-Spirolactones. Deng QH, Wadepohl H, Gade LH. J Am Chem Soc. 2012 Jan 26. [Epub ahead of print] PMID: 22280225 [PubMed - as supplied by publisher]

  • Mediastinal goiter diagnosed by functional imaging. Michels G, Dietlein M, Kobe C, Pfister R. Libyan J Med. 2012;7. doi: 10.3402/ljm.v7i0.15693. Epub 2012 Jan 19. PMID: 22279494 [PubMed - in process]

  • An Approach to the Regioselective Diamination of Conjugated Di- and Trienes. Lishchynskyi A, Muñiz K. Chemistry. 2012 Jan 25. doi: 10.1002/chem.201103435. [Epub ahead of print] PMID: 22279008 [PubMed - as supplied by publisher]

  • Highly Stereoselective Metal-Free Oxyaminations Using Chiral Hypervalent Iodine Reagents. Farid U, Wirth T. Angew Chem Int Ed Engl. 2012 Jan 25. doi: 10.1002/anie.201107703. [Epub ahead of print] PMID: 22278888 [PubMed - as supplied by publisher]

  • Scintigraphic Detection of Benign Ovarian Teratoma after Total Thyroidectomy and Radioactive Iodine for Differentiated Thyroid Cancer. van Wijk JP, Broekhuizen-de Gast HS, Smits AJ, Schipper ME, Zelissen PM. J Clin Endocrinol Metab. 2012 Jan 25. [Epub ahead of print] PMID: 22278431 [PubMed - as supplied by publisher]

  • An Operational Study on Implementation of Mobile Primary Healthcare Services for Seasonal Migratory Farmworkers, Turkey. Simsek Z, Koruk I, Doni NY. Matern Child Health J. 2012 Jan 26. [Epub ahead of print] PMID: 22278354 [PubMed - as supplied by publisher]

  • BMI, Diet and Female Reproductive Factors as Risks for Thyroid Cancer: A Systematic Review. Peterson E, De P, Nuttall R. PLoS One. 2012;7(1):e29177. Epub 2012 Jan 19. PMID: 22276106 [PubMed - in process]

  • Report on a cryotherapy service for women with cervical intraepithelial neoplasia in a district hospital in western Kenya. Lewis K, Sellors J, Dawa A, Tsu V, Kidula N. Afr Health Sci. 2011 Sep;11(3):370-6. PMID: 22275926 [PubMed - in process]

  • A comparison of triage methods for Kenyan women who screen positive for cervical intraepithelial neoplasia by visual inspection of the cervix with acetic acid. Lewis K, Tsu V, Dawa A, Kidula N, Chami I, Sellors J. Afr Health Sci. 2011 Sep;11(3):362-9. PMID: 22275925 [PubMed - in process]

  • Coupled simulation of chemical lasers based on intracavity partially coherent light model and 3D CFD model. Wu K, Huai Y, Jia S, Jin Y. Opt Express. 2011 Dec 19;19(27):26295-307. doi: 10.1364/OE.19.026295. PMID: 22274214 [PubMed - in process]

  • Surgical Treatment for Thyrotoxic Hypokalemic Periodic Paralysis: Case Report. Lin YC, Wu CW, Chen HC, Chen HY, Lu IC, Tsai CJ, Kuo WR, Chiang FY. World J Surg Oncol. 2012 Jan 24;10(1):21. [Epub ahead of print] PMID: 22273473 [PubMed - as supplied by publisher]

  • Hofmann-Type Rearrangement of Imides by in Situ Generation of Imide-Hypervalent Iodines(III) from Iodoarenes. Moriyama K, Ishida K, Togo H. Org Lett. 2012 Jan 24. [Epub ahead of print] PMID: 22273472 [PubMed - as supplied by publisher]

  • Recent advances on radionuclide labeled hypoxia-imaging agents. Li Z, Chu T. Curr Pharm Des. 2012 Jan 17. [Epub ahead of print] PMID: 22272826 [PubMed - as supplied by publisher]

  • Predictive modelling of interventions to improve iodine intake in New Zealand. Schiess S, Cressey PJ, Thomson BM. Public Health Nutr. 2012 Jan 25:1-9. [Epub ahead of print] PMID: 22272731 [PubMed - as supplied by publisher]

  • Goiter prevalence and urinary iodine levels. Ozsoylu S. Turk J Pediatr. 2011 Sep-Oct;53(5):595. No abstract available. PMID: 22272468 [PubMed - in process]

  • Collaboration to optimize dietary intakes of salt and iodine: a critical but overlooked public health issue. Campbell N, Dary O, Cappuccio FP, Neufeld LM, Harding KB, Zimmermann MB. Bull World Health Organ. 2012 Jan 1;90(1):73-4. No abstract available. PMID: 22271970 [PubMed - in process]

     

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