Samarium Ribbon

High Purity Sm Ribbon
CAS 7440-19-9


Product Product Code Order or Specifications
(2N) 99% Samarium Ribbon SM-M-02-RI Contact American Elements
(3N) 99.9% Samarium Ribbon SM-M-03-RI Contact American Elements
(4N) 99.99% Samarium Ribbon SM-M-04-RI Contact American Elements
(5N) 99.999% Samarium Ribbon SM-M-05-RI Contact American Elements

CHEMICAL
IDENTIFIER		 Formula CAS No. PubChem SID PubChem CID MDL No. EC No Beilstein
Re. No.		 SMILES
Identifier 		InChI
Identifier		 InChI
Key
Sm 7440-19-9 24855798 23951 MFCD00011233 231-128-7 N/A UN 2910 7 InChI=1S/Sm KZUNJOHGWZRPMI-UHFFFAOYSA-N

PROPERTIES Mol. Wt. Appearance Density Tensile Strength Melting Point Boiling Point Thermal Conductivity Electrical Resistivity Eletronegativity Specific Heat Heat of Vaporization Heat of Fusion MSDS
150.36 Silvery 7353 kg/m³ N/A 1072°C 1803°C 0.133 W/cm/K @ 298.2 K 88.0 microhm-cm @ 25°C 1.2 Paulings 0.043 Cal/g/K @ 25 °C 46 K-cal/gm atom at 1791°C 2.60 Cal/gm mole Safety Data Sheet

American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards.See safety data and research below and pricing/lead time above. American Elements specializes in producing Samarium as ribbon in various thicknesses and sizes. Most ribbon is rolled High Purity Metallic Ribbonfor use in coating and thin film Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Organometallic and Chemical Vapor Deposition (MOCVD) for specific applications such as fuel cells and solar energy. Thicknesses up to 0.02" and widths up to 1" are available for most metals. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as other machined shapes and through other processes such as nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and in the form of solutions and organometallics. We also produce Samarium as rods, powder and plates. Other shapes are available by request.

Samarium(Sm)atomic and molecular weight, atomic number and elemental symbol Samarium is a Block F, Group 3, Period 6 element. The number of electrons in each of Samarium's shells is 2, 8, 18, 24, 8, 2 and its electronic configuration is [Xe]4f6 6s2. In its elemental form samarium's CAS number is 7440-19-9. The samarium atom has a radius of 180.4.pm. Samarium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Samarium is somewhat toxic. Samarium-cobalt magnets replaced the more expensive platinum-cobalt magnets in the early 1970s. While now overshadowed by less expensive neodymium-iron-boron magnets, they are still valued for their ability to function at high temperatures. They are utilized in lightweight electronic equipment where size or space is a limiting factor and where functionality at high temperature is a concern. Samarium Bohr Model Applications include electronic watches, aeospace equipment, microwave technology and servomotors. Because of its weak spectral absorption band, samarium is used in the filter glass on Nd:YAG solid state lasers to Elemental Samarium surround the laser rod to improve efficiency by absorbing stray emissions. In separate December 2012 experiments, researchers at the University of Michigan, the University of Maryland, and the University of California, Irvine found that Samarium hexaboride may have the ability to act as a topological insulator, an insulating substance with surface conductivity whose existence has been predicted by quantum theory but never observed by scientists. Samarium, first discovered by Paul Emile Lecoq de Boisbaudran in 1879, is found in many minerals, including monazite, bastnäsite, cerite, gadolinite and samarskite. Samarium is named after the mineral samarskite. See Samarium research below.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Danger
H228-H261-H373
R
15-33
30
N/A
UN 2910 7
3
Flame-Flammables Health Hazard      

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Request an MSDS or Certificate of Analysis





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Recent Research & Development for Samarium

  • [(2R,3S)-Butane-1,2,3,4-tetraol-?(3) O (1),O (2),O (3)](ethanol-?O)tris-(nitrato-?(2) O,O')samarium(III). Xue JH, Hua XH, Yang LM, Xu YZ, Wu JG. Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 2;69(Pt 4):m182-3. doi: 10.1107/S1600536813003255.
  • Photocatalytic performance of novel samarium-doped spherical-like ZnO hierarchical nanostructures under visible light irradiation for 2,4-dichlorophenol degradation. Sin JC, Lam SM, Lee KT, Mohamed AR. J Colloid Interface Sci. 2013 Jul 1;401:40-9. doi: 10.1016/j.jcis.2013.03.043.
  • Radioactive synovectomy with 90 yttrium and 153 samarium hydroxyapatite in haemophilic joints: preliminary study on radiation safety. Thomas S, Mendes JD, Souza SA, Lorenzato CS, Assi PE, Pacheco LR, Gabriel MB, Bordim A, Gutfilen B, da Fonseca LM. Haemophilia. 2013 Mar 28. doi: 10.1111/hae.12122.
  • Samarium-153-lexidronam therapy for metastatic bone pain. Ribera H. J Pain Palliat Care Pharmacother. 2013 Mar;27(1):80-1; discussion 81-2. doi: 10.3109/15360288.2012.760705.
  • Poly[tris-(dimethyl-formamide)(µ3-2,4,6-triiodobenzene-1,3,5-tricarboxyl-ato)samarium(III)]. Yan B, Sheng D, Yang Y. Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m149. doi: 10.1107/S1600536813003358.
  • Recent developments in samarium diiodide promoted organic reactions. Gopalaiah K, Kagan HB. Chem Rec. 2013 Apr;13(2):187-208. doi: 10.1002/tcr.201200028.
  • Photoluminescence and visible diffuse-reflection spectroscopic evidence of samarium reduction in air-fired samples of mixed samarium: strontium tetraborate precipitates. Brown TM, Jeffreys MC, Pehaire M, Stump NA. Appl Spectrosc. 2013 Mar;67(3):279-82. doi: 10.1366/12-06705.
  • Preparation and use of samarium diiodide (SmI(2)) in organic synthesis: the mechanistic role of HMPA and Ni(II) salts in the samarium Barbier reaction. Sadasivam DV, Choquette KA, Flowers RA 2nd. J Vis Exp. 2013 Feb 4;(72):e4323. doi: 10.3791/4323.
  • Cathodoluminescence microanalysis of irradiated microcrystalline and nanocrystalline samarium doped BaFCl. Stevens-Kalceff MA, Liu Z, Riesen H. Microsc Microanal. 2012 Dec;18(6):1229-38. doi: 10.1017/S1431927612001559.
  • Cyclizations producing hydrindanones with two methyl groups at the juncture positions mediated by samarium diiodide and electrolysis. Sono M, Ise N, Shoji T, Tori M. Molecules. 2012 Sep 13;17(9):11079-88. doi: 10.3390/molecules170911079.
  • Beyond samarium diiodide: vistas in reductive chemistry mediated by lanthanides(II). Szostak M, Procter DJ. Angew Chem Int Ed Engl. 2012 Sep 10;51(37):9238-56. doi: 10.1002/anie.201201065.
  • Raman spectral analysis of TiO2 thin films doped with rare-earth samarium. Yang CH, Ma ZQ. Appl Opt. 2012 Aug 1;51(22):5438-41. doi: 10.1364/AO.51.005438.
  • A samarium "soluble" anode: a new source of SmI2 reagent for electrosynthetic application. Sahloul K, Sun L, Requet A, Chahine Y, Mellah M. Chemistry. 2012 Sep 3;18(36):11205-9. doi: 10.1002/chem.201201390.
  • Remarkable effect of alkali metal on polymerization of cyclic esters catalyzed by samarium-alkali metal multinuclear alkoxide clusters. Sheng H, Shi J, Feng Y, Wang H, Jiao Y, Sheng H, Zhang Y, Shen Q. Dalton Trans. 2012 Aug 14;41(30):9232-40. doi: 10.1039/c2dt30677h.
  • Use of samarium Sm 153 lexidronam for the treatment of dogs with primary tumors of the skull: 20 cases (1986-2006). Vancil JM, Henry CJ, Milner RJ, McCoig AM, Lattimer JC, Villamil JA, McCaw DL, Bryan JN. J Am Vet Med Assoc. 2012 Jun 1;240(11):1310-5. doi: 10.2460/javma.240.11.1310.
  • Bis(µ-2-{bis-[(2-oxidobenzyl-idene)amino]-meth-yl}phenolato)bis-[(tetra-hydro-furan)-samarium(III)] tetra-hydro-furan disolvate. Li L, Zhou Y, Yuan F. Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m603-4. doi: 10.1107/S1600536812015759.
  • Trichlorido{µ-6,6'-dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}dimethano-l-copper(II)samarium(III). Wang Y, Zhang Q, Yan PF, Hou GF, Li HF. Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m589. doi: 10.1107/S1600536812014523.
  • catena-Poly[[[aqua-[3-(3-hy-droxy-phen-yl)prop-2-enoato]samarium(III)]-bis-[µ(2)-3-(3-hy-droxy-phen-yl)prop-2-enoato]] monohydrate]. Guo JK, Wen YH. Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m543-4. doi: 10.1107/S1600536812013724.
  • Single samarium atoms in large fullerene cages. Characterization of two isomers of Sm@C92 and four isomers of Sm@C94 with the X-ray crystallographic identification of Sm@C1(42)-C92, Sm@C(s)(24)-C92, and Sm@C3v(134)-C94. Jin H, Yang H, Yu M, Liu Z, Beavers CM, Olmstead MM, Balch AL. J Am Chem Soc. 2012 Jul 4;134(26):10933-41. doi: 10.1021/ja302859r.
  • Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-?N,N'}samarium(III). Lei T, Chen W, Chen Y, Hu B, Li Y. Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m344-5. doi: 10.1107/S1600536812008100.