Tin Bromide is a highly water soluble crystalline Tin source for uses compatible with Bromides and lower (acidic) pH. Metallic Bromides are marketed under the trade name AE Bromides™. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding Tin disulfide (CS2) and chlorine. Tin Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Tin is a Block P, Group 14, Period 5 element. The number of electrons in each of Tin's shells is 2, 8, 18, 18, 4 and its electronic configuration is [Kr] 4d10 5s2 5p2. In its elemental form tin's CAS number is 7440-31-5. The tin atom has a radius of 140.5.pm and it's Van der Waals radius is 217.pm. Organometallic compounds of tin are very toxic and tin salts are also considered to be toxic. Tin as single atoms or molecules are not toxic. Tin compounds sprayed onto glass are used to produce electrically conductive coatings. These have been used for panel lighting and for frost-free windshields. Most window glass is now made by floating molten glass on molten tin (float glass) to produce a flat surface. Crystalline tin-niobium alloy is superconductive at very low temperatures. This promises to be important in the construction of superconductive magnets that generate enormous field strengths but use practically no power. Tin is the basis for many eutectic alloys and the discovery by early man that copper could be better formed and crafted if tin were added producing the first bronze and launching what we refer to as the "Bronze Age" and the first Neolithic metal tools, cooking utensils, and jewelry produced from rudimentary bronze. An important tin compound is the chloride, which is used as a reducing agent and as a mordant in calico printing. Tin is also used in various metal alloys (See AE Alloys). Tin was first discovered by Early Man.The origin of the word tin comes from the Latin word Stannum which translates to the Anglo-Saxon word tin.
See Tin research below.
RECONSTRUCTION OF THE THUMB WITH A MODIFIED WRAP-AROUND FLAP IN A PATIENT SUFFERING FROM ?-THALASSEMIA MINOR.
Galeano M, Checcucci G, Ceruso M.
Hand Surg. 2011;16(3):361-5.
PMID:
22072476
[PubMed - in process]
Isolated complete volar dislocation of the capitate: a case report.
Checcucci G, Bigazzi P, Zucchini M, Ceruso M.
Hand Surg. 2011;16(3):353-6.
PMID:
22072474
[PubMed - in process]
Dielectrophoretic chip with multilayer electrodes and micro-cavity array for trapping and programmably releasing single cells.
Chuang CH, Huang YW, Wu YT.
Biomed Microdevices. 2011 Nov 10. [Epub ahead of print]
PMID:
22072154
[PubMed - as supplied by publisher]
Structures of medium sized tin cluster anions.
Wiesel A, Drebov N, Rapps T, Ahlrichs R, Schwarz U, Kelting R, Weis P, Kappes MM, Schooss D.
Phys Chem Chem Phys. 2011 Nov 9. [Epub ahead of print]
PMID:
22071636
[PubMed - as supplied by publisher]
Discrimination task reveals differences in neural bases of tinnitus and hearing impairment.
Husain FT, Pajor NM, Smith JF, Kim HJ, Rudy S, Zalewski C, Brewer C, Horwitz B.
PLoS One. 2011;6(10):e26639. Epub 2011 Oct 31.
PMID:
22066003
[PubMed - in process]
A suggested technique for the application of the cone beam computed tomography periapical index.
Esposito S, Cardaropoli M, Cotti E.
Dentomaxillofac Radiol. 2011 Dec;40(8):506-12.
PMID:
22065800
[PubMed - in process]
(4-Chloro-3-nitro-benzoato)triphenyl-tin(IV).
Win YF, Choong CS, Teoh SG, Quah CK, Fun HK.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1270-1. Epub 2011 Aug 27.
PMID:
22065496
[PubMed]
Bis{2-[(E)-(5-tert-butyl-2-hy-droxy-phen-yl)diazen-yl]benzoato}dimethyl-tin(IV).
Basu Baul TS, Paul A, Tiekink ER.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1383-4. Epub 2011 Sep 14.
PMID:
22065466
[PubMed]
catena-Poly[[triphenyl-tin(IV)]-?-5-amino-2-nitro-benzoato-?O:O].
Win YF, Choong CS, Teoh SG, Quah CK, Fun HK.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1276-7. Epub 2011 Aug 27.
PMID:
22064934
[PubMed]
Dual detection strategy for electrochemical analysis of glucose and nitrite using a partitionally modified electrode.
Wang J, Diao P, Zhang Q.
Analyst. 2011 Nov 7. [Epub ahead of print]
PMID:
22064849
[PubMed - as supplied by publisher]
fac-(2-Amido-ethyl-?C,O)trichlorido(urea-?O)tin(IV).
Howie RA, de Lima GM, Tiekink ER, Wardell JL, Wardell SM.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1420-1. Epub 2011 Sep 30.
PMID:
22064619
[PubMed]
Highly sensitive nonenzymatic glucose sensor based on electrospun copper oxide-doped nickel oxide composite microfibers.
Cao F, Guo S, Ma H, Yang G, Yang S, Gong J.
Talanta. 2011 Oct 30;86:214-20. Epub 2011 Sep 8.
PMID:
22063533
[PubMed - in process]
Cross-Linked Perylene Diimide-Based n-Type Interfacial Layer for Inverted Organic Photovoltaic Devices.
Hains AW, Chen HY, Reilly TH, Gregg BA.
ACS Appl Mater Interfaces. 2011 Nov 7. [Epub ahead of print]
PMID:
22059439
[PubMed - as supplied by publisher]
Bis-(chloro-acetato-?O)bis(trimethyl-silylmethyl)tin(IV).
Ding RF, Wang QB.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1190. Epub 2011 Aug 2.
PMID:
22058841
[PubMed]
A new langbeinite-type phosphate: K(2)AlSn(PO(4))(3).
Li HY, Zhao D.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):i56. Epub 2011 Sep 20.
PMID:
22058680
[PubMed]
Enhanced resistance of yeast mutants deficient in low-affinity iron and zinc transporters to stannous-induced toxicity.
Viau CM, Cardone JM, Guecheva TN, Yoneama ML, Dias JF, Pungartnik C, Brendel M, Saffi J, Henriques JA.
Chemosphere. 2011 Nov 2. [Epub ahead of print]
PMID:
22055569
[PubMed - as supplied by publisher]
Allylsilanes in "Tin-free" Oximation, Alkenylation, and Allylation of Alkyl Halides.
Rouquet G, Robert F, Méreau R, Castet F, Landais Y.
Chemistry. 2011 Nov 3. doi: 10.1002/chem.201101842. [Epub ahead of print]
PMID:
22052660
[PubMed - as supplied by publisher]
Surface Modification of Indium-Tin-Oxide Via Self-Assembly of a Donor-Acceptor Complex: A Density Functional Theory Study.
Li H, Winget P, Bredas JL.
Adv Mater. 2011 Nov 3. doi: 10.1002/adma.201103009. [Epub ahead of print] No abstract available.
PMID:
22052626
[PubMed - as supplied by publisher]
Minimally invasive video-assisted cardiac surgery: operative techniques, application fields and clinical outcomes.
Vistarini N, Aiello M, Viganň M.
Future Cardiol. 2011 Nov;7(6):775-87.
PMID:
22050064
[PubMed - in process]
Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids.
Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C.
Org Lett. 2010 Jan 5. [Epub ahead of print]
PMID: 19689116 [PubMed - as supplied by publisher]
Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides.
Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL.
Science. 2009 Aug 13. [Epub ahead of print]
PMID: 19679769 [PubMed - as supplied by publisher]
(2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides.
Zhang Q, Wang D, Wang X, Ding K.
J Org Chem. 2009 Aug 12. [Epub ahead of print]
PMID: 19673481 [PubMed - as supplied by publisher]
Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides.
Vechorkin O, Barmaz D, Proust V, Hu X.
J Am Chem Soc. 2009 Aug 11. [Epub ahead of print]
PMID: 19670863 [PubMed - as supplied by publisher]
Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia.
Huang JM, Dong Y.
Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28.
PMID: 19662260 [PubMed - in process]
Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols.
Salvi L, Kim JG, Walsh PJ.
J Am Chem Soc. 2009 Aug 4. [Epub ahead of print]
PMID: 19653691 [PubMed - as supplied by publisher]
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines.
Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J.
J Comb Chem. 2009 Jul 31. [Epub ahead of print]
PMID: 19645499 [PubMed - as supplied by publisher]
Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids.
del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N.
Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29.
PMID: 19641822 [PubMed - in process]
Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides.
Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639999 [PubMed - as supplied by publisher]
Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies.
Snelders DJ, van Koten G, Klein Gebbink RJ.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639941 [PubMed - as supplied by publisher]
Can One Predict Changes from S(N)1 to S(N)2 Mechanisms?
Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H.
J Am Chem Soc. 2009 Jul 27. [Epub ahead of print]
PMID: 19634906 [PubMed - as supplied by publisher]
A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides.
Liao Q, Wang Y, Zhang L, Xi C.
J Org Chem. 2009 Jul 15. [Epub ahead of print]
PMID: 19603753 [PubMed - as supplied by publisher]
Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides.
Shi L, Chu Y, Knochel P, Mayr H.
Org Lett. 2009 Jul 14. [Epub ahead of print]
PMID: 19601592 [PubMed - as supplied by publisher]
C5-Modified nucleosides exhibiting anticancer activity.
Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH.
Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21.
PMID: 19596579 [PubMed - in process]
Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines.
Vo GD, Hartwig JF.
J Am Chem Soc. 2009 Jul 10. [Epub ahead of print]
PMID: 19591470 [PubMed - as supplied by publisher]
New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes.
Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B.
Org Lett. 2009 Jul 2. [Epub ahead of print]
PMID: 19572730 [PubMed - as supplied by publisher]
The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives.
Jo Y, Ju J, Choe J, Song KH, Lee S.
J Org Chem. 2009 Jul 2. [Epub ahead of print]
PMID: 19572571 [PubMed - as supplied by publisher]
Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents.
Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH.
Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8.
PMID: 19557114 [PubMed - in process]
A facile route to C2-substituted imidazolium ionic liquids.
Ennis E, Handy ST.
Molecules. 2009 Jun 19;14(6):2235-45.
PMID: 19553895 [PubMed - in process]
Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines.
McCall WS, Comins DL.
Org Lett. 2009 Jul 2;11(13):2940-2.
PMID: 19552467 [PubMed - indexed for MEDLINE]