Tin(II) Selenideis a crystalline solid used as a semiconductor and in photo optic applications.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Tin is a Block P, Group 14, Period 5 element. The number of electrons in each of Tin's shells is 2, 8, 18, 18, 4 and its electronic configuration is [Kr] 4d10 5s2 5p2. In its elemental form tin's CAS number is 7440-31-5. The tin atom has a radius of 140.5.pm and it's Van der Waals radius is 217.pm. Organometallic compounds of tin are very toxic and tin salts are also considered to be toxic. Tin as single atoms or molecules are not toxic. Tin compounds sprayed onto glass are used to produce electrically conductive coatings. These have been used for panel lighting and for frost-free windshields. Most window glass is now made by floating molten glass on molten tin (float glass) to produce a flat surface. Crystalline tin-niobium alloy is superconductive at very low temperatures. This promises to be important in the construction of superconductive magnets that generate enormous field strengths but use practically no power. Tin is the basis for many eutectic alloys and the discovery by early man that copper could be better formed and crafted if tin were added producing the first bronze and launching what we refer to as the "Bronze Age" and the first Neolithic metal tools, cooking utensils, and jewelry produced from rudimentary bronze. An important tin compound is the chloride, which is used as a reducing agent and as a mordant in calico printing. Tin is also used in various metal alloys (See AE Alloys). Tin was first discovered by Early Man.The origin of the word tin comes from the Latin word Stannum which translates to the Anglo-Saxon word tin.
See Tin research below.
Selenium is a Block P, Group 16, Period 4 element. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electronic configuration is [Ar] 3d10 4s2 4p4. In its elemental form selenium's CAS number is 7782-49-2. The selenium atom has a radius of 116.pm and it's Van der Waals radius is 190.pm. The EPA does not classify selenium as carcinogenic, although selenium sulfide is a probable carcinogen. Selenates and selenites which are compounds of selenium, are highly toxic. Hydrogen selenide gas (SeH2) is the most acutely toxic compound of selenium. Selenium exhibits both photovoltaic action, where light is converted directly into electricity, and photoconductive action, where the electrical resistance decreases with increased illumination. of photocells and exposure meters for photographic use, as well as solar cells. Below its melting point, selenium is a p-type semiconductor and has many uses in electronic and solid-state applications. Selenium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Selenium was first discovered by Jons Berzelius in 1817. The origin of the name Selenium comes from the Greek word "Selênê" meaning moon. See selenium research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
Crystal "pulling" by the Czochaiski method for production of semiconductor materials
Flux growth and gradient freeze
Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
RECONSTRUCTION OF THE THUMB WITH A MODIFIED WRAP-AROUND FLAP IN A PATIENT SUFFERING FROM ?-THALASSEMIA MINOR.
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Structures of medium sized tin cluster anions.
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(4-Chloro-3-nitro-benzoato)triphenyl-tin(IV).
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Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1270-1. Epub 2011 Aug 27.
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fac-(2-Amido-ethyl-?C,O)trichlorido(urea-?O)tin(IV).
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ACS Appl Mater Interfaces. 2011 Nov 7. [Epub ahead of print]
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Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1190. Epub 2011 Aug 2.
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A new langbeinite-type phosphate: K(2)AlSn(PO(4))(3).
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Chemosphere. 2011 Nov 2. [Epub ahead of print]
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22055569
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Allylsilanes in "Tin-free" Oximation, Alkenylation, and Allylation of Alkyl Halides.
Rouquet G, Robert F, Méreau R, Castet F, Landais Y.
Chemistry. 2011 Nov 3. doi: 10.1002/chem.201101842. [Epub ahead of print]
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22052660
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Surface Modification of Indium-Tin-Oxide Via Self-Assembly of a Donor-Acceptor Complex: A Density Functional Theory Study.
Li H, Winget P, Bredas JL.
Adv Mater. 2011 Nov 3. doi: 10.1002/adma.201103009. [Epub ahead of print] No abstract available.
PMID:
22052626
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Minimally invasive video-assisted cardiac surgery: operative techniques, application fields and clinical outcomes.
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Future Cardiol. 2011 Nov;7(6):775-87.
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Toenail selenium status and the risk of Barrett's esophagus: the Netherlands Cohort Study.
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Promotion of Growth in Mungbean (Phaseolus aureus Roxb.) by Selenium is Associated with Stimulation of Carbohydrate Metabolism.
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Transition metal chemistry of cyclodiphosphanes containing phosphine and amide-phosphine functionalities: Formation of a stable dipalladium(II) complex containing a Pd-P s-bond.
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Associations between blood metals and fecundity among women residing in New York State.
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Reprod Toxicol. 2010 Oct 6. [Epub ahead of print]PMID: 20933593 [PubMed - as supplied by publisher]Related citations
The protective role of selenium in recalcitrant Acer saccharium L. seeds subjected to desiccation.
Pukacka S, Ratajczak E, Kalemba E.
J Plant Physiol. 2010 Oct 6. [Epub ahead of print]PMID: 20933296 [PubMed - as supplied by publisher]Related citations
Trace element concentrations in nesting flatback turtles (Natator depressus) from Curtis Island, Queensland, Australia.
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Correlation between serum selenium level and febrile seizures.
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Pediatr Neurol. 2010 Nov;43(5):331-4.PMID: 20933176 [PubMed - in process]Related citations
Anti-Tumor Activity of Aloe vera Against DMBA/Croton Oil-Induced Skin Papillomagenesis in Swiss Albino Mice.
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J Environ Pathol Toxicol Oncol. 2010;29(2):127-35.PMID: 20932247 [PubMed - in process]Related citations
Aluminosilicate Relatives: Chalcogenoaluminogermanates Rb(3)(AlQ(2))(3)(GeQ(2))(7) (Q = S, Se).
Rothenberger A, Shafaei-Fallah M, Kanatzidis MG.
Inorg Chem. 2010 Oct 8. [Epub ahead of print]PMID: 20932019 [PubMed - as supplied by publisher]Related citations
A Nutrient Approach to Prostate Cancer Prevention: The Selenium and Vitamin E Cancer Prevention Trial (SELECT).
Dunn BK, Richmond ES, Minasian LM, Ryan AM, Ford LG.
Nutr Cancer. 2010 Oct;62(7):896-918.PMID: 20924966 [PubMed - in process]Related citations
Serum levels of selenium in patients with breast cancer before and after treatment of external beam radiotherapy.
Franca CA, Nogueira CR, Ramalho A, Carvalho AC, Vieira SL, Penna AB.
Ann Oncol. 2010 Oct 5. [Epub ahead of print]PMID: 20924074 [PubMed - as supplied by publisher]Related citations
Kenji Soda--researching enzymes with the spirit of an alpinist.
Yoshimura T, Mihara H, Ohshima T, Tanizawa K.
J Biochem. 2010 Oct;148(4):371-9.PMID: 20924059 [PubMed - in process]Related citations
Inhibitory effect of arsenic on aerobic gut flora in rat.
Choudhry ZK, Misbahuddin M, Hosain AK, Saleh AA.
Bangladesh Med Res Counc Bull. 2009 Dec;35(3):79-83.PMID: 20922909 [PubMed - in process]Related citations
[Endemic and biogeochemical features of the territory of Chuvash Republic]
[No authors listed]
Vestn Ross Akad Med Nauk. 2010;(8):40-6. Russian. PMID: 20922843 [PubMed - in process]Related citations
Interaction of uranyl with Se(IV) and Se(VI) in aqueous acid solutions by means of capillary electrophoresis.
Sladkov V.
Electrophoresis. 2010 Oct 4. [Epub ahead of print]PMID: 20922762 [PubMed - as supplied by publisher]Related citations
Ensemble Modeling Coupled with Six Element Concentrations in Human Blood for Cancer Diagnosis.
Chen H, Tan C, Wu T.
Biol Trace Elem Res. 2010 Oct 5. [Epub ahead of print]PMID: 20922500 [PubMed - as supplied by publisher]Related citations
Use of dietary vitamin E and selenium (Se) to increase the shelf life of modified atmosphere packaged light lamb meat.
Ripoll G, Joy M, Muñoz F.
Meat Sci. 2010 Sep 18. [Epub ahead of print]PMID: 20920835 [PubMed - as supplied by publisher]Related citations
Impacts of maternal selenium and nutritional level on growth, adiposity, and glucose tolerance in female offspring in sheep.
Vonnahme KA, Luther JS, Reynolds LP, Hammer CJ, Carlson DB, Redmer DA, Caton JS.
Domest Anim Endocrinol. 2010 Nov;39(4):240-8. Epub 2010 Jul 25.PMID: 20920781 [PubMed - in process]Related citations
Mutations disrupting selenocysteine formation cause progressive cerebello-cerebral atrophy.
Agamy O, Ben Zeev B, Lev D, Marcus B, Fine D, Su D, Narkis G, Ofir R, Hoffmann C, Leshinsky-Silver E, Flusser H, Sivan S, Söll D, Lerman-Sagie T, Birk OS.
Am J Hum Genet. 2010 Oct 8;87(4):538-44.PMID: 20920667 [PubMed - in process]Related citations
Developmental toxicity of selenium to Dolly Varden char (Salvelinus malma).
McDonald BG, Debruyn AM, Elphick JR, Davies M, Bustard D, Chapman PM.
Environ Toxicol Chem. 2010 Aug 3. [Epub ahead of print]PMID: 20891017 [PubMed - as supplied by publisher]Related citations