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Terbium Acetylacetonate
Tb(CH3COCHCOCH3)3 • 3H2O
14284-95-8

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Product Code
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99% Terbium Acetylacetonate
TB-ACAC-02
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99.9% Terbium Acetylacetonate
TB-ACAC-03
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99.99% Terbium Acetylacetonate
TB-ACAC-04
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99.999% Terbium Acetylacetonate
TB-ACAC-05
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Terbium Acetylacetonate is a Terbium source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring.Because of this property, Terbium Acetylacetonate is commonly used in various catalysts and catalytic reagents for organic synthesis. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Terbium Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Terbium includephosphors, particularly in fluorescent lamps and as the high intensity green emitter used in projection televisions, such as the yttrium-aluminum-garnet (Tb:YAG) variety. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Terbium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f96s2. In its elemental form terbium's CAS number is 7440-27-9. The terbium atom has a radius of 176.3.pm and it's Van der Waals radius is unknown. Terbium is primarily used in phosphors, particularly in fluorescent lamps and as the high intensity green emitter used in projection televisions, such as the yttrium-aluminum-garnet (Tb:YAG) variety. Terbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Terbium responds efficiently in x-ray excitation and is, therefore, used as an x-ray phosphor. Terbium alloys are also used in magneto-optic recording films, such as Tb-Fe-Co. Terbium was first discovered by Carl Mosander in 1843.

Formula CAS No. Appearance Molecular Weight Density Melting Point Boiling Point Solubility Stability
Tb(CH3COCHCOCH3)3 • 3H2O 14284-95-8 White 456.26   168-170°C   Soluble in organic solvents  
PRODUCT CATALOG Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc.
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Recent Research & Development for Terbium

  • The mechanism of quenching of the lanthanide excited state for optical probes using sensitised emission. Law GL, Parker D, Richardson SL, Wong KL. Dalton Trans. 2009 Oct 28;(40):8481-4. Epub 2009 Aug 27. PMID: 19809721 [PubMed - in process] Related Articles 2: Anchoring of Rare-Earth-Based Single-Molecule Magnets on Single-Walled Carbon Nanotubes. Kyatskaya S, Mascaro´s JR, Bogani L, Hennrich F, Kappes M, Wernsdorfer W, Ruben M. J Am Chem Soc. 2009 Oct 2. [Epub ahead of print] PMID: 19799421 [PubMed - as supplied by publisher] Related Articles 3: [Synthesis, characterization and fluorescence properties of rare earth complexes RE(TPTZ) Cl3] Zhao YF, Zhao YL, Bai F. Guang Pu Xue Yu Guang Pu Fen Xi. 2009 Jul;29(7):1929-32. Chinese. PMID: 19798974 [PubMed - in process] Related Articles 4: Gadolinium(III) complexes of 1,4,7-triazacyclononane based picolinate ligands: simultaneous optimization of water exchange kinetics and electronic relaxation. Nonat A, Giraud M, Gateau C, Fries PH, Helm L, Mazzanti M. Dalton Trans. 2009 Oct 14;(38):8033-46. Epub 2009 Aug 17. PMID: 19771367 [PubMed - in process] Related Articles 5: Designing Simple Tridentate Ligands for Highly Luminescent Europium Complexes. Shavaleev NM, Eliseeva SV, Scopelliti R, Bünzli JC. Chemistry. 2009 Sep 16. [Epub ahead of print] PMID: 19760733 [PubMed - as supplied by publisher] Related Articles 6: Heterospin Single-Molecule Magnets Based on Terbium Ions and TCNQF(4) Radicals: Interplay between Single-Molecule Magnet and Phonon Bottleneck Phenomena Investigated by Dilution Studies. Lopez N, Prosvirin AV, Zhao H, Wernsdorfer W, Dunbar KR. Chemistry. 2009 Sep 16. [Epub ahead of print] PMID: 19760709 [PubMed - as supplied by publisher] Related Articles 7: Detection of cationic guest molecules by quenching of luminescence of a self-assembled host molecule consisting of terbium(III) and calix[4]arene-p-tetrasulfonates. Horiuchi T, Iki N, Hoshino H. Anal Chim Acta. 2009 Sep 21;650(2):258-63. Epub 2009 Jul 29. PMID: 19720202 [PubMed - in process] Related Articles 8: Effect of humic matter on metal adsorption onto clay materials: testing the linear additive model. Lippold H, Lippmann-Pipke J. J Contam Hydrol. 2009 Oct 13;109(1-4):40-8. Epub 2009 Aug 11. PMID: 19712995 [PubMed - in process] Related Articles 9: Photosynthetic responses to heavy metal terbium stress in horseradish leaves. Wang L, Zhou Q, Huang X. Chemosphere. 2009 Aug 25. [Epub ahead of print] PMID: 19712958 [PubMed - as supplied by publisher] Related Articles 10: An electrochemical biosensor for ultratrace terbium based on Tb3+ promoted conformational change of human telomeric G-quadruplex. Zhang J, Chen J, Chen R, Chen G, Fu F. Biosens Bioelectron. 2009 Oct 15;25(2):378-82. Epub 2009 Aug 3. PMID: 19699077 [PubMed - in process] Related Articles 11: Luminescence spectroscopy of europium(III) and terbium(III) penta-, octa- and nonanuclear clusters with beta-diketonate ligands. Petit S, Baril-Robert F, Pilet G, Reber C, Luneau D. Dalton Trans. 2009 Sep 14;(34):6809-15. Epub 2009 Jul 15. PMID: 19690693 [PubMed - in process] Related Articles 12: A new Tb3+-selective fluorescent sensor based on 2-(5-(dimethylamino)naphthalen-1-ylsulfonyl)-N-henylhydrazinecarbothioamide. Ganjali MR, Veismohammadi B, Hosseini M, Norouzi P. Spectrochim Acta A Mol Biomol Spectrosc. 2009 Oct 1;74(2):575-8. Epub 2009 Jul 24. PMID: 19671495 [PubMed - in process] Related Articles 13: Lanthanide complexes in hybrid halometallate materials: interconversion between a novel 2D microporous framework and a 1D zigzag chain structure of iodoargentates templated by octakis-solvated terbium(III) cation. Mishra S, Jeanneau E, Ledoux G, Daniele S. Dalton Trans. 2009 Jul 7;(25):4954-61. Epub 2009 May 18. PMID: 19662287 [PubMed] Related Articles 14: Circularly polarized luminescence in enantiopure europium and terbium complexes with modular, all-oxygen donor ligands. Seitz M, Do K, Ingram AJ, Moore EG, Muller G, Raymond KN. Inorg Chem. 2009 Sep 7;48(17):8469-79. PMID: 19639983 [PubMed - in process] Related Articles 15: Sensitive determination of protein based on the fluorescence enhancement effect of terbium (III)-epinephrine-protein-sodium dodecylsulfate system. Guo Y, Yang J, Wu X, Mao H. Luminescence. 2009 Jul 9. [Epub ahead of print] PMID: 19591244 [PubMed - as supplied by publisher] Related Articles 16: Selective labeling of tag-fused protein by tryptophan-sensitized luminescence of a terbium complex. Hirayama T, Taki M, Kodan A, Kato H, Yamamoto Y. Chem Commun (Camb). 2009 Jun 14;(22):3196-8. Epub 2009 May 6. PMID: 19587911 [PubMed - indexed for MEDLINE] Related Articles 17: A rapid hydrothermal synthesis of rare earth oxide activated Y (OH)3 and Y2O3 nanotubes. Devaraju MK, Yin S, Sato T. Nanotechnology. 2009 Jul 29;20(30):305302. Epub 2009 Jul 7. PMID: 19581697 [PubMed - indexed for MEDLINE] Related Articles 18: Study of the luminescence properties of a novel rare earth complex Tb(DPC)(2)2H2O. Lv Y, Li Q, Shi C, Liu H, Liu F, Wu L, Wu D, Liu H, Xie J. Spectrochim Acta A Mol Biomol Spectrosc. 2009 Sep 15;74(1):26-9. Epub 2009 Apr 24. PMID: 19577509 [PubMed - in process] Related Articles 19: Development of a rapid and automatic optosensor for the determination of cromolyn in biological samples. Molina-García L, Llorent-Martínez EJ, Fernández-de Córdova ML, Ruiz-Medina A. Talanta. 2009 Aug 15;79(3):627-32. Epub 2009 May 3. PMID: 19576422 [PubMed - indexed for MEDLINE] Related Articles 20: Selective detection of phosphotyrosine in the presence of various phosphate-containing biomolecules with the aid of a terbium(III) complex. Akiba H, Sumaoka J, Komiyama M. Chembiochem. 2009 Jul 20;10(11):1773-6. No abstract available. PMID: 19565595 [PubMed - in process]

 

 

 

 

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