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Terbium Hydride TbH2
TbH2
13598-54-4
Product Product Code Order or Specifications
(2N) 99% Terbium Hydride TB-HID-02 Contact American Elements
(3N) 99.9% Terbium Hydride TB-HID-03 Contact American Elements
(4N) 99.99% Terbium Hydride TB-HID-04 Contact American Elements
(5N) 99.999% Terbium Hydride TB-HID-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
TbH2 13598-54-4 46240461 166868 N/A 237-071-4 hydride; terbium(3+) N/A [H-].[H-].[H-].[Tb+3] InChI=1S/Tb.3H/q+3;3*-1 WOLWRTFLUVVVTF-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
H2Tb 161.94916 N/A N/A 161.948818 161.948776 Da 0 Safety Data Sheet


Hydride IonTerbium Hydride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Hydride compounds are used often used as portable sources of hydrogen gas.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Terbium(Tb) atomic and molecular weight, atomic number and elemental symbolTerbium is a Block F, Group 3, Period 6 element. The number of electrons in each of Terbium's shells is 2, 8, 18, 27, 8, 2 and its electronic configuration is [Xe]4f9 6s2. In its elemental form terbium's CAS number is 7440-27-9. Terbium is considered to be somewhat toxic.The terbium atom has a radius of 176.3.pm and it's Van der Waals radius is unknown. Terbium is primarily used in phosphors, particularly in Terbium Bohr Modelfluorescent lamps and as the high intensity green emitter used in projection televisions, such as the yttrium-aluminum-garnet (Tb:YAG) variety. Terbium is available as metal and compounds with purities from 99% to 99.999% Elemental Terbium(ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Terbium responds efficiently in x-ray excitation and is, therefore, used as an x-ray phosphor. Terbium alloys are also used in magneto-optic recording films, such as Tb-Fe-Co. Terbium was first discovered by Carl Mosander in 1843. Terbium is named after "Ytterby", a town in Sweden. See Terbium research below.

Hydrogen is a Block S, Group 1, Period 1 element. The electronic configuration is 1s1. In its elemental form hydrogen's CAS number is 1333-74-0. The hydrogen atom has a radius of 37.3.pm and it's Van der Waals radius is 120.pm. Hydrogen is highly flammable. Hydrogen was discovered by Sir Henry Cavendish in 1766.

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Toxicity
Safety & Handling
  Flame-Flammables          
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
Danger N/A N/A N/A N/A N/A N/A N/A

 

Synonyms for Terbium Hydride Include:


Terbium trihydride
hydride; terbium(3+)

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 

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Recent Research & Development for Terbium

  • Cilostazol Determination by the Enhancement of the Green Emission of Tb(3+) Optical Sensor. Attia MS, Mahmoud WH, Youssef AO, Mostafa MS. J Fluoresc. 2011 Aug 5. [Epub ahead of print] PMID: 21818537 [PubMed - as supplied by publisher]

  • [Induction-resonance energy transfer between the terbium-binding peptide and the red fluorescent proteins Dsred2 and TagRFP]. [No authors listed] Biofizika. 2011 May-Jun;56(3):389-95. Russian. PMID: 21786690 [PubMed - in process]

  • Interactions between metal ions and carbohydrates. Syntheses and spectroscopic studies of several lanthanide nitrate-d-galactitol complexes. Yu L, Hua X, Pan Q, Yang L, Xu Y, Zhao G, Wang H, Wang H, Wu J, Liu K, Chen J. Carbohydr Res. 2011 Jun 30. [Epub ahead of print] PMID: 21784418 [PubMed - as supplied by publisher]

  • Characterization of the ß?-crystallin domains of ß?-CAT, a non-lens ß?-crystallin and trefoil factor complex, from the skin of the toad Bombina maxima. Gao Q, Xiang Y, Zeng L, Ma XT, Lee WH, Zhang Y. Biochimie. 2011 Jul 26. [Epub ahead of print] PMID: 21784123 [PubMed - as supplied by publisher]

  • Detection of bacterial endospores in soil by terbium fluorescence. Brandes Ammann A, Kölle L, Brandl H. Int J Microbiol. 2011;2011:435281. Epub 2011 Jul 7. PMID: 21754939 [PubMed]

  • Poly[[tetra-aqua-tris-(µ(3)-hexane-1,6-di-carboxyl-ato)diterbium(III)] 0.25-hydrate]. Li FF, Zhang HJ, Zhang LN. Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m412. Epub 2011 Mar 9. PMID: 21753944 [PubMed]

  • Single-Molecule Magnetic Behavior in a Neutral Terbium(III) Complex of a Picolinate-Based Nitronyl Nitroxide Free Radical. Coronado E, Gime´nez-Saiz C, Recuenco A, Tarazo´n A, Romero FM, Camo´n A, Luis F. Inorg Chem. 2011 Aug 15;50(16):7370-7372. Epub 2011 Jul 13. PMID: 21751792 [PubMed - as supplied by publisher]

  • Effect of terbium(iii) on the binding of aromatic guests with sodium taurocholate aggregates. Pace TC, Souza Júnior SP, Zhang HT, Bohne C. Photochem Photobiol Sci. 2011 Jul 12. [Epub ahead of print] PMID: 21750813 [PubMed - as supplied by publisher]

  • Label-free colorimetric and quantitative detection of cancer marker protein using noncrosslinking aggregation of Au/Ag nanoparticles induced by target-specific peptide probe. Wang X, Wu L, Ren J, Miyoshi D, Sugimoto N, Qu X. Biosens Bioelectron. 2011 Aug 15;26(12):4804-9. Epub 2011 Jun 17. PMID: 21733670 [PubMed - in process]

  • CeF3 and PrF3 as UV-Visible Faraday rotators. Molina P, Vasyliev V, Víllora EG, Shimamura K. Opt Express. 2011 Jun 6;19(12):11786-91. doi: 10.1364/OE.19.011786. PMID: 21716411 [PubMed - in process]

  • A terbium-sensitized spectrofluorimetric method for determination of catecholamines in a serum sample with micelle medium. Kamruzzaman M, Alam AM, Lee SH, Kim YH, Kim SH. Luminescence. 2011 Jun 21. doi: 10.1002/bio.1332. [Epub ahead of print] PMID: 21692167 [PubMed - as supplied by publisher]

  • Terbium(iii) complex as a luminescent sensor for human serum albumin in aqueous solution. Wang X, Wang X, Wang Y, Guo Z. Chem Commun (Camb). 2011 Jul 28;47(28):8127-9. Epub 2011 Jun 20. PMID: 21691617 [PubMed - in process]

  • Efficient inhibition of germination of coat-deficient bacterial spores by multivalent metal cations, including terbium (tb3+). Yi X, Bond C, Sarker MR, Setlow P. Appl Environ Microbiol. 2011 Aug;77(15):5536-9. Epub 2011 Jun 17. PMID: 21685163 [PubMed - in process]

  • Determination of carvedilol by its quenching effect on the luminescence of terbium complex in dosage form. Leonenko I, Aleksandrova D, Yegorova A. Acta Pol Pharm. 2011 May-Jun;68(3):325-30. PMID: 21648186 [PubMed - indexed for MEDLINE]

  • Luminescent Trimethoprim-Polyaminocarboxylate Lanthanide Complex Conjugates for Selective Protein Labeling and Time-Resolved Bioassays. Reddy DR, Pedro´ Rosa LE, Miller LW. Bioconjug Chem. 2011 Jul 20;22(7):1402-1409. Epub 2011 Jun 7. PMID: 21619068 [PubMed - as supplied by publisher]

  • Lanthanide directed self-assembly formations of Tb(III) and Eu(III) luminescent complexes from tryptophan based pyridyl amide ligands. Lincheneau C, Leonard JP, McCabe T, Gunnlaugsson T. Chem Commun (Camb). 2011 Jul 7;47(25):7119-21. Epub 2011 May 26. PMID: 21614366 [PubMed - in process]

  • Gold nanoparticles-based fluorescence enhancement of the terbium-levofloxacin system and its application in pharmaceutical preparations. Lee SH, Wabaidur SM, Alothman ZA, Alam SM. Luminescence. 2011 May 24. doi: 10.1002/bio.1311. [Epub ahead of print] PMID: 21608101 [PubMed - as supplied by publisher]

  • Optical properties and luminescence dynamics of Eu3+-doped terbium orthophosphate nanophosphors. Ruan Y, Xiao Q, Luo W, Li R, Chen X. Nanotechnology. 2011 Jul 8;22(27):275701. Epub 2011 May 20. PMID: 21597160 [PubMed - in process]

  • A long-lived luminescence and EPR bimodal lanthanide-based probe for free radicals. Hong J, Zhuang Y, Ji X, Guo X. Analyst. 2011 Jun 21;136(12):2464-70. Epub 2011 May 10. PMID: 21556434 [PubMed - in process]

  • Development of a terbium complex-based luminescent probe for imaging endogenous hydrogen peroxide generation in plant tissues. Ye Z, Chen J, Wang G, Yuan J. Anal Chem. 2011 Jun 1;83(11):4163-9. Epub 2011 May 11. PMID: 21548628 [PubMed - in process]

 

Recent Research & Development for Hydride

  • Diazaphospholenes: N-Heterocyclic Phosphines between Molecules and Lewis Pairs. Gudat D. Acc Chem Res. 2010 Jun 24. [Epub ahead of print] PubMed PMID: 20572668.

  • Thymidylate Synthase Catalyzed H-Transfers: Two Chapters in One Tale. Wang Z, Kohen A. J Am Chem Soc. 2010 Jun 24. [Epub ahead of print] PubMed PMID: 20575541.

  • Cobalt-Mediated Linear 2:1 Co-oligomerization of Alkynes with Enol Ethers to Give 1-Alkoxy-1,3,5-Trienes: A Missing Mode of Reactivity. Lebœuf D, Iannazzo L, Geny A, Malacria M, Vollhardt KP, Aubert C, Gandon V. Chemistry. 2010 Jun 23. [Epub ahead of print] PubMed PMID: 20575116.

  • Synthesis and evaluation of silica hydride-based fluorinated stationary phases. Pesek JJ, Matyska MT, Prajapati KV. J Sep Sci. 2010 Jun 22. [Epub ahead of print] PubMed PMID: 20572267.

  • Kinetics of substituted silylene addition and elimination in silicon nanocluster growth captured by group additivity. Adamczyk AJ, Reyniers MF, Marin GB, Broadbelt LJ. Chemphyschem. 2010 Jun 21;11(9):1978-94. PubMed PMID: 20549662.

  • Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides. Tobisu M, Fujihara H, Koh K, Chatani N. J Org Chem. 2010 Jun 17. [Epub ahead of print] PubMed PMID: 20557065.

  • Thermal Decomposition of Mono- and Bimetallic Magnesium Amidoborane Complexes. Spielmann J, Piesik DF, Harder S. Chemistry. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20564288.

  • Versatile New C(3)-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize Cu(I) and Rh(I) Species and Tune Their Reactivity. Wassenaar J, Siegler MA, Spek AL, de Bruin B, Reek JN, van der Vlugt JI. Inorg Chem. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20552965.

  • Iron-Catalyzed Hydrogen Production from Formic Acid. Boddien A, Loges B, Ga¨rtner F, Torborg C, Fumino K, Junge H, Ludwig R, Beller M. J Am Chem Soc. 2010 Jun 15. [Epub ahead of print] PubMed PMID: 20550131.

  • Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation. Yi CS, Lee DW. Organometallics. 2010 Mar 19;29(8):1883-1885. PubMed PMID: 20567607; PubMed Central PMCID: PMC2887707.

     

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