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Terbium Oxide Pellets
Tb4O7
12037-01-3
Product
Product Code
Order or Specifications
99% Terbium Oxide Pellets
TB-OX-02-PE
Contact American Elements
99.9% Terbium Oxide Pellets
TB-OX-03-PE
Contact American Elements
99.99% Terbium Oxide Pellets
TB-OX-04-PE
Contact American Elements
99.999% Terbium Oxide Pellets
TB-OX-05-PE
Contact American Elements
American Elements specializes in producing high purity uniform shaped Terbium Oxide Pellets with the highest possible density 99.9+% Ultra High Purity Metallic Pellets and smallest possible average grain sizes for use in semiconductor, Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Metallic-Organic and Chemical Vapor Deposition (MOCVD). Our standard Pellet sizes range from 1/8" x 1/8" to 1/4" x 1/4" and 3 mm diameter. We can also provide Pellets outside this range for ultra high purity thin film applications, such as fuel cells and solar energy layers. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as other machined shapes and through other processes such as nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and in the form of solutions and organometallics.. We also produce Terbium as pieces, tablets, powder, and sputtering target. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. See research below. Other shapes are available by request.

Terbium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f96s2. In its elemental form terbium's CAS number is 7440-27-9. The terbium atom has a radius of 176.3.pm and it's Van der Waals radius is unknown. Terbium is primarily used in phosphors, particularly in fluorescent lamps and as the high intensity green emitter used in projection televisions, such as the yttrium-aluminum-garnet (Tb:YAG) variety. Terbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Terbium responds efficiently in x-ray excitation and is, therefore, used as an x-ray phosphor. Terbium alloys are also used in magneto-optic recording films, such as Tb-Fe-Co. Terbium was first discovered by Carl Mosander in 1843.

Formula CAS No. Appearance Molecular Weight Density Melting Point Boiling Point Solubility Stability
Tb4O7 12037-01-3 Brown 747.69       Insoluble in water, moderately soluble in strong mineral acids Slightly hygroscopic
PRODUCT CATALOG Terbium Research, Properties, & Information Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. MSDS
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Recent Research & Development for Terbium

  • The mechanism of quenching of the lanthanide excited state for optical probes using sensitised emission. Law GL, Parker D, Richardson SL, Wong KL. Dalton Trans. 2009 Oct 28;(40):8481-4. Epub 2009 Aug 27. PMID: 19809721 [PubMed - in process] Related Articles 2: Anchoring of Rare-Earth-Based Single-Molecule Magnets on Single-Walled Carbon Nanotubes. Kyatskaya S, Mascaro´s JR, Bogani L, Hennrich F, Kappes M, Wernsdorfer W, Ruben M. J Am Chem Soc. 2009 Oct 2. [Epub ahead of print] PMID: 19799421 [PubMed - as supplied by publisher] Related Articles 3: [Synthesis, characterization and fluorescence properties of rare earth complexes RE(TPTZ) Cl3] Zhao YF, Zhao YL, Bai F. Guang Pu Xue Yu Guang Pu Fen Xi. 2009 Jul;29(7):1929-32. Chinese. PMID: 19798974 [PubMed - in process] Related Articles 4: Gadolinium(III) complexes of 1,4,7-triazacyclononane based picolinate ligands: simultaneous optimization of water exchange kinetics and electronic relaxation. Nonat A, Giraud M, Gateau C, Fries PH, Helm L, Mazzanti M. Dalton Trans. 2009 Oct 14;(38):8033-46. Epub 2009 Aug 17. PMID: 19771367 [PubMed - in process] Related Articles 5: Designing Simple Tridentate Ligands for Highly Luminescent Europium Complexes. Shavaleev NM, Eliseeva SV, Scopelliti R, Bünzli JC. Chemistry. 2009 Sep 16. [Epub ahead of print] PMID: 19760733 [PubMed - as supplied by publisher] Related Articles 6: Heterospin Single-Molecule Magnets Based on Terbium Ions and TCNQF(4) Radicals: Interplay between Single-Molecule Magnet and Phonon Bottleneck Phenomena Investigated by Dilution Studies. Lopez N, Prosvirin AV, Zhao H, Wernsdorfer W, Dunbar KR. Chemistry. 2009 Sep 16. [Epub ahead of print] PMID: 19760709 [PubMed - as supplied by publisher] Related Articles 7: Detection of cationic guest molecules by quenching of luminescence of a self-assembled host molecule consisting of terbium(III) and calix[4]arene-p-tetrasulfonates. Horiuchi T, Iki N, Hoshino H. Anal Chim Acta. 2009 Sep 21;650(2):258-63. Epub 2009 Jul 29. PMID: 19720202 [PubMed - in process] Related Articles 8: Effect of humic matter on metal adsorption onto clay materials: testing the linear additive model. Lippold H, Lippmann-Pipke J. J Contam Hydrol. 2009 Oct 13;109(1-4):40-8. Epub 2009 Aug 11. PMID: 19712995 [PubMed - in process] Related Articles 9: Photosynthetic responses to heavy metal terbium stress in horseradish leaves. Wang L, Zhou Q, Huang X. Chemosphere. 2009 Aug 25. [Epub ahead of print] PMID: 19712958 [PubMed - as supplied by publisher] Related Articles 10: An electrochemical biosensor for ultratrace terbium based on Tb3+ promoted conformational change of human telomeric G-quadruplex. Zhang J, Chen J, Chen R, Chen G, Fu F. Biosens Bioelectron. 2009 Oct 15;25(2):378-82. Epub 2009 Aug 3. PMID: 19699077 [PubMed - in process] Related Articles 11: Luminescence spectroscopy of europium(III) and terbium(III) penta-, octa- and nonanuclear clusters with beta-diketonate ligands. Petit S, Baril-Robert F, Pilet G, Reber C, Luneau D. Dalton Trans. 2009 Sep 14;(34):6809-15. Epub 2009 Jul 15. PMID: 19690693 [PubMed - in process] Related Articles 12: A new Tb3+-selective fluorescent sensor based on 2-(5-(dimethylamino)naphthalen-1-ylsulfonyl)-N-henylhydrazinecarbothioamide. Ganjali MR, Veismohammadi B, Hosseini M, Norouzi P. Spectrochim Acta A Mol Biomol Spectrosc. 2009 Oct 1;74(2):575-8. Epub 2009 Jul 24. PMID: 19671495 [PubMed - in process] Related Articles 13: Lanthanide complexes in hybrid halometallate materials: interconversion between a novel 2D microporous framework and a 1D zigzag chain structure of iodoargentates templated by octakis-solvated terbium(III) cation. Mishra S, Jeanneau E, Ledoux G, Daniele S. Dalton Trans. 2009 Jul 7;(25):4954-61. Epub 2009 May 18. PMID: 19662287 [PubMed] Related Articles 14: Circularly polarized luminescence in enantiopure europium and terbium complexes with modular, all-oxygen donor ligands. Seitz M, Do K, Ingram AJ, Moore EG, Muller G, Raymond KN. Inorg Chem. 2009 Sep 7;48(17):8469-79. PMID: 19639983 [PubMed - in process] Related Articles 15: Sensitive determination of protein based on the fluorescence enhancement effect of terbium (III)-epinephrine-protein-sodium dodecylsulfate system. Guo Y, Yang J, Wu X, Mao H. Luminescence. 2009 Jul 9. [Epub ahead of print] PMID: 19591244 [PubMed - as supplied by publisher] Related Articles 16: Selective labeling of tag-fused protein by tryptophan-sensitized luminescence of a terbium complex. Hirayama T, Taki M, Kodan A, Kato H, Yamamoto Y. Chem Commun (Camb). 2009 Jun 14;(22):3196-8. Epub 2009 May 6. PMID: 19587911 [PubMed - indexed for MEDLINE] Related Articles 17: A rapid hydrothermal synthesis of rare earth oxide activated Y (OH)3 and Y2O3 nanotubes. Devaraju MK, Yin S, Sato T. Nanotechnology. 2009 Jul 29;20(30):305302. Epub 2009 Jul 7. PMID: 19581697 [PubMed - indexed for MEDLINE] Related Articles 18: Study of the luminescence properties of a novel rare earth complex Tb(DPC)(2)2H2O. Lv Y, Li Q, Shi C, Liu H, Liu F, Wu L, Wu D, Liu H, Xie J. Spectrochim Acta A Mol Biomol Spectrosc. 2009 Sep 15;74(1):26-9. Epub 2009 Apr 24. PMID: 19577509 [PubMed - in process] Related Articles 19: Development of a rapid and automatic optosensor for the determination of cromolyn in biological samples. Molina-García L, Llorent-Martínez EJ, Fernández-de Córdova ML, Ruiz-Medina A. Talanta. 2009 Aug 15;79(3):627-32. Epub 2009 May 3. PMID: 19576422 [PubMed - indexed for MEDLINE] Related Articles 20: Selective detection of phosphotyrosine in the presence of various phosphate-containing biomolecules with the aid of a terbium(III) complex. Akiba H, Sumaoka J, Komiyama M. Chembiochem. 2009 Jul 20;10(11):1773-6. No abstract available. PMID: 19565595 [PubMed - in process]

 

 

Material Safety Data Sheet
  • 1 Identification of substance

    • Product details

    • Trade name Terbium (III,IV) oxide
  • 2 Composition/Data on components:

    • Chemical characterization:
                 Designation: (CAS#)                                        
      Terbium (III,IV) oxide (CAS# 12037-01-3), 100%
    • Identification number(s):
    • EINECS Number: 234-856-3
  • 3 Hazards identification

    • Hazard designation: · void
    • Information pertaining to particular dangers for man and environment
      Not applicable
  • 4 First aid measures

    • After inhalation
      Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
      Seek immediate medical advice.
    • After skin contact
      Instantly wash with water and soap and rinse thoroughly.
      Seek immediate medical advice.
    • After eye contact
      Rinse opened eye for several minutes under running water. Then consult doctor.
    • After swallowing Seek medical treatment.
  • 5 Fire fighting measures

    • Suitable extinguishing agents
      Use fire fighting measures that suit the environment.
    • Protective equipment:
      Wear self-contained breathing apparatus.
      Wear full protective suit.
  • 6 Accidental release measures

    • Person-related safety precautions:
      Wear protective equipment. Keep unprotected persons away.
      Ensure adequate ventilation
    • Measures for environmental protection:
      Do not allow material to be released to the environment without proper governmental permits.
    • Measures for cleaning/collecting: Collect mechanically.
    • Additional information:
      See Section 7 for information on safe handling
      See section 8 for information on personal protection equipment.
      See Section 13 for information on disposal.
  • 7 Handling and storage


    • Handling
    • Information for safe handling:
      Keep containers tightly sealed.
      Store in cool, dry place in tightly closed containers.
      No special precautions necessary if used correctly.
    • Information about protection against explosions and fires:
      The product is not flammable

    • Storage
    • Requirements to be met by storerooms and containers:
      No special requirements.
    • Information about storage in one common storage facility:
      Do not store together with acids.
    • Further information about storage conditions:
      This product is hygroscopic.
      Keep container tightly sealed.
      Store in cool, dry conditions in well sealed containers.
  • 8 Exposure controls and personal protection

    • Additional information about design of technical systems:
      Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

    • Components with critical values that require monitoring at the
      workplace:                                                             
      Not required.
    • Additional information: No data

    • Personal protective equipment
    • General protective and hygienic measures
      The usual precautionary measures should be adhered to in handling the chemicals.
      Keep away from foodstuffs, beverages and food.
      Instantly remove any soiled and impregnated garments.
      Wash hands during breaks and at the end of the work.
    • Breathing equipment: Use breathing protection with high concentrations.
    • Protection of hands: Impervious gloves
    • Eye protection: Safety glasses
    • Body protection: Protective work clothing.
  • 9 Physical and chemical properties:

    • General Information

    • Form: Lump
    • Colour: Brown
    • Smell: Odourless
    •   Value/Range  Unit    Method      
    • Change in condition
    • Melting point/Melting range:                  2340 ° C
    • Boiling point/Boiling range:       Not determined
    • Sublimation temperature / start:   Not determined

    • Flash point:                       Not applicable

    • Inflammability (solid, gaseous)    Product is not inflammable.

    • Ignition temperature:              Not determined

    • Decomposition temperature:         Not determined

    • Danger of explosion:               Product is not explosive.

    • Critical values for explosion:
    • Lower:                             Not determined
    • Upper:                             Not determined

    • Steam pressure:                    Not determined

    • Density                            Not determined

    • Solubility in / Miscibility with
    • Water:                             Insoluble
  • 10 Stability and reactivity

    • Thermal decomposition / conditions to be avoided:
      No decomposition if used and stored according to specifications.
    • Materials to be avoided:
      Acids
      Air
    • Dangerous reactions: No dangerous reactions known
    • Dangerous products of decomposition: Metal oxide
  • 11 Toxicological information

    • Acute toxicity:
    • Primary irritant effect:
    • on the skin: May cause irritation
    • on the eye: May cause irritation
    • Sensitization: No sensitizing effect known.
    • Additional toxicological information:
      To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
      No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
  • 12 Ecological information:

    • General notes:
      Do not allow material to be released to the environment without proper governmental permits.
      Generally not hazardous for water.
  • 13 Disposal considerations


    • Product:
    • Recommendation
      Consult state, local or national regulations for proper disposal.
      Hand over to disposers of hazardous waste.
      Must be specially treated under adherence to official regulations.

    • Uncleaned packagings:
    • Recommendation:
      Disposal must be made according to official regulations.
  • 14 Transport information


    • Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
    • ADR/RID-GGVS/E Class:         None

    • Maritime transport IMDG/GGVSea:
    • IMDG/GGVSea Class:        None

    • Air transport ICAO-TI and IATA-DGR:
    • ICAO/IATA Class:          None

    • Transport/Additional information:
      Not dangerous according to the above specifications.
  • 15 Regulatory information


    • Designation according to EC guidelines:
      Observe the normal safety regulations when handling chemicals
      The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials (GefStoffV).

    • National regulations

    • Information about limitation of use:
      For use only by technically qualified individuals.

    • Water hazard class: Generally not hazardous for water.
  • 16 Other information:

      Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees.  This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
  •  

     

    Recent Research & Development for Terbium Oxide

    • Spectrofluorimetric determination of trace amounts of coenzyme A using a terbium ion-ciprofloxacin complex probe in the presence of periodic acid.
      Anal Bioanal Chem. 2007 Jan 17; [Epub ahead of print]

    • Luminescence dynamics of terbium monodipicolinate in ethyl ammonium nitrate.
      Appl Spectrosc. 2006 Dec;60(12):1453-60.

    • Solvent effect on the luminescent properties of new europium and terbium nitrate complexes with 3,3,7,7-tetra[N-methyl-N-phenyl(acetamide)-2-oxymethyl]-5-oxanonane.
      Spectrochim Acta A Mol Biomol Spectrosc. 2006 Apr 19; [Epub ahead of print]

    • Photoluminescence response of terbium-exchanged MFI-type materials to Si/Al ratio, texture, and hydration state.
      J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Dec 28;110(51):25707-15.

    • Determination of fluoroquinolones in milk samples by postcolumn derivatization liquid chromatography with luminescence detection.
      J Agric Food Chem. 2006 Dec 27;54(26):9670-6.

    • Nonlithographic fabrication of microfluidic devices.
      J Am Chem Soc. 2006 Dec 20;128(50):16062-72.

    • A substrate for deubiquitinating enzymes based on time-resolved fluorescence resonance energy transfer between terbium and yellow fluorescent protein.
      Anal Biochem. 2007 Jan 1;360(1):138-43. Epub 2006 Aug 10.

    • Effect of terbium(III) chloride on the micellization properties of sodium decyl- and dodecyl-sulfate solutions.
      J Colloid Interface Sci. 2007 Feb 1;306(1):166-74. Epub 2006 Oct 27.

    • Improved photoluminescence properties of ternary terbium complexes in mesoporous molecule sieves.
      J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Nov 23;110(46):23164-9.

    • Synthesis of fluorescent analogs of alpha-conotoxin MII.
      Bioconjug Chem. 2006 Nov-Dec;17(6):1612-7.

     

     

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