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Thorium Oxide
ThO2
1314-20-1
Product Product Code Order or Specifications
(2N) 99% Thorium Oxide TH-OX-02 Contact American Elements
(3N) 99.9% Thorium Oxide TH-OX-03 Contact American Elements
(4N) 99.99% Thorium Oxide TH-OX-04 Contact American Elements
(5N) 99.999% Thorium Oxide TH-OX-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
ThO2 1314-20-1 169899   253-453-3 Oxygen(-2)anion; thorium(=4) cation   O=[Th]=O InChI=1S/2O.Th ZCUFMDLYAMJYST-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
O2Th 264.028 g/mol   10 g/cm3 264.028 g/mol 264.027879 Da 0 Safety Data Sheet


Oxide IonThorium Oxide is a highly insoluble thermally stable Thorium source suitable for glass, optic and ceramic applications. Thorium Oxide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. Thorium is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectanceHigh Purity (99.999%) Thorium Oxide (ThO2) Powder at 560 nm. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. Rare Earth oxide compounds are basic anhydrides and can therefore react with acids and with strong reducing agents in redox reactions. They are compounds containingat least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advanced electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic conductivity. Thorium oxide is also available in rod, tubes, wire, slugs, sputtering targets, foil, plate, ribbon, sheet, shot, and Spheres. Additional technical, research and safety (MSDS) information is available.

Thorium(Th) atomic and molecular weight, atomic number and elemental symbol Thorium is a Block F, Group 3, Period 7 element. The number of electrons in each of Thorium's shells is 2, 8, 18, 32, 18, 10, 2 and its electronic configuration is [Rn] 6d2 7s2. In its elemental form thorium's CAS number is 7440-29-1. The thorium atom has a radius of 179.8.pm and it's Van der Waals radius is 200.pm. Thorium is radioactive and can collect in bones which may cause bone cancer several years after exposure. Breathing in substantial amounts of thorium may be lethal. Thorium is a lanthanide (rare earth) material with potential nuclear power applications. Thorium Elemental Thorium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is Thorium Bohr Modelpresently used as a tungsten coating in electronic parts due to its high emission factor. Thorium in the form of its fluoride and oxide is used in advanced optic applications for its high refractive index. It is also used in several other high temperature glass applications, such as in the mantle of lamps and to produce crystal growth crucibles and ampules. Thorium was first discovered by Jons Berzelius in 1828. The name Thorium originates from the Scandinavian god, Thor, the Norse god of war and thunder. See Thorium research below.

Have a Question? Ask a Chemical Engineer or Material Scientist   Request an MSDS or Certificate of Analysis

 
Safety &
Handling
   
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
          XO6950000    

 

Synonyms for Thorium Oxide Include:


Dioxothorium
Thorium(IV) oxide
Thorianite
Thorium anhydride
Thorotrast Umbrathor

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 


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Production Catalog Available in 36 Countries & Languages

 

 

Recent Research & Development for Thorium

  • [The assessment of no adverse effect doses for plant populations under chronic exposure of radionuclides of uranium and thorium decay series]. [No authors listed] Radiats Biol Radioecol. 2010 Jul-Aug;50(4):383-90. Russian. PMID: 20968049 [PubMed - in process]Related citations

  • Thoron and decay products, beyond UNSCEAR 2006 Annex E. Chambers DB. Radiat Prot Dosimetry. 2010;141(4):351-6.PMID: 20966204 [PubMed - in process]Related citations

  • catena-Poly[thorium(IV)-tetrakis(µ(2)-3-carboxyadamantane-1-carboxylato)]: a quadruple helical strand driven by a synergy of coordination and hydrogen bonding. Nazarenko OM, Rusanova JA, Krautscheid H, Domasevitch KV. Acta Crystallogr C. 2010 Oct;66(Pt 10):m276-9. Epub 2010 Sep 4.PMID: 20921602 [PubMed - in process]Related citations

  • Nuclear energy. Grandin K, Jagers P, Kullander S. Ambio. 2010;39 Suppl 1:26-30.PMID: 20873683 [PubMed - indexed for MEDLINE]Related citations

  • An integrated approach for the assessment of the thoron progeny exposures using direct thoron progeny sensors. Mishra R, Prajith R, Sapra BK, Mayya YS. Radiat Prot Dosimetry. 2010;141(4):363-6. Epub 2010 Sep 23.PMID: 20870667 [PubMed - in process]Related citations

  • A comparative study of thorium activity in NORM and high background radiation area. Sahoo SK, Ishikawa T, Tokonami S, Sorimachi A, Kranrod C, Janik M, Hosoda M, Hassan NM, Chanyotha S, Parami VK, Yonehara H, Ramola RC. Radiat Prot Dosimetry. 2010;141(4):416-9. Epub 2010 Sep 16.PMID: 20846972 [PubMed - in process]Related citations

  • Solubility of uranium and thorium from a healing earth in synthetic gut fluids: A case study for use in dose assessments. Höllriegl V, Li WB, Leopold K, Gerstmann U, Oeh U. Sci Total Environ. 2010 Nov 1;408(23):5794-800. Epub 2010 Sep 15.PMID: 20832099 [PubMed - in process]Related citations

  • Solid thoron source preparation in a porous mineral matrix. Jobbágy V, Bety-Denissa B. Radiat Prot Dosimetry. 2010;141(4):440-3. Epub 2010 Sep 8.PMID: 20829206 [PubMed - in process]Related citations

  • Thoron ((220)Rn) decay products removal in poorly ventilated environments using unipolar ionizers: Dosimetric implications. Joshi M, Sapra BK, Khan A, Kothalkar P, Mayya YS. Sci Total Environ. 2010 Nov 1;408(23):5701-6. Epub 2010 Sep 6.PMID: 20817221 [PubMed - in process]Related citations

  • Discrepancies in thorium oxide solubility values: study of attachment/detachment processes at the solid/solution interface. Vandenborre J, Grambow B, Abdelouas A. Inorg Chem. 2010 Oct 4;49(19):8736-48.PMID: 20804204 [PubMed - in process]Related citations

  • Synthesis, structure, and solid-state transformation studies of phosphonoacetate based hybrid compounds of uranium and thorium. Ramaswamy P, Prabhu R, Natarajan S. Inorg Chem. 2010 Sep 6;49(17):7927-34.PMID: 20799739 [PubMed - in process]Related citations

  • Observations and modelling of thoron and its progeny in the soil-atmosphere-plant system. Baldacci AE, Gattavecchia E, Kirchner G. J Environ Radioact. 2010 Nov;101(11):992-1001. Epub 2010 Aug 19.PMID: 20727629 [PubMed - in process]Related citations

  • Functional sorbents for selective capture of plutonium, americium, uranium, and thorium in blood. Yantasee W, Sangvanich T, Creim JA, Pattamakomsan K, Wiacek RJ, Fryxell GE, Addleman RS, Timchalk C. Health Phys. 2010 Sep;99(3):413-9.PMID: 20699706 [PubMed - indexed for MEDLINE]Related citations

  • The uneven irradiation of a target cell and its dynamic movement can mathematically explain incubation period for the induction of cancer by internally deposited radionuclides. Yamamoto Y, Usuda N, Oghiso Y, Kuwahara Y, Fukumoto M. Health Phys. 2010 Sep;99(3):388-93.PMID: 20699702 [PubMed - indexed for MEDLINE]Related citations

  • Communication: Electric properties of the ThO(X (1)Sigma(+)) molecule. Buchachenko AA. J Chem Phys. 2010 Jul 28;133(4):041102.PMID: 20687626 [PubMed - in process]Related citations

  • Determination of activity concentration levels of (238)U, (232)Th, and (40)K in drinking water in a gold mine in Ghana. Awudu AR, Darko EO, Schandorf C, Hayford EK, Abekoe MK, Ofori-Danson PK. Health Phys. 2010 Aug;99 Suppl 2:S149-53.PMID: 20622563 [PubMed - indexed for MEDLINE]Related citations

  • The particulate 7Be/210Pbxs and 234Th/210Pbxs activity ratios as tracers for tidal-to-seasonal particle dynamics in the Gironde estuary (France): implications for the budget of particle-associated contaminants. Saari HK, Schmidt S, Castaing P, Blanc G, Sautour B, Masson O, Cochran JK. Sci Total Environ. 2010 Sep 15;408(20):4784-94. Epub 2010 Jul 24.PMID: 20659759 [PubMed - indexed for MEDLINE]Related citations

  • A complimentary tool in the determination of activity concentrations of naturally occurring radionuclides. Olise FS, Owoade OK, Olaniyi HB, Obiajunwa EI. J Environ Radioact. 2010 Nov;101(11):910-4. Epub 2010 Jul 16.PMID: 20637532 [PubMed - in process]Related citations

  • A thermally robust di-n-butyl thorium complex with an unstable dimethyl analogue. Cruz CA, Emslie DJ, Jenkins HA, Britten JF. Dalton Trans. 2010 Aug 7;39(29):6626-8. Epub 2010 Mar 16.PMID: 20631945 [PubMed - in process]Related citations

  • Rapid evolution of ritual architecture in central Polynesia indicated by precise 230Th/U coral dating. Sharp WD, Kahn JG, Polito CM, Kirch PV. Proc Natl Acad Sci U S A. 2010 Jul 27;107(30):13234-9. Epub 2010 Jul 7.PMID: 20616079 [PubMed - indexed for MEDLINE]Related citations

 

 

Material Safety Data Sheet
  • 1 Identification of substance

    • Product details

    • Trade name Praseodymium metal
  • 2 Composition/Data on components:

    • Chemical characterization:
                 Designation: (CAS#)                                        
      Praseodymium (CAS# 7440-10-0); 100%
    • Identification number(s):
    • EINECS Number: 231-120-3
  • 3 Hazards identification

    • Hazard designation: · void
    • Information pertaining to particular dangers for man and environment
      Not applicable
  • 4 First aid measures

    • After inhalation
      Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
      Seek immediate medical advice.
    • After skin contact
      Instantly wash with water and soap and rinse thoroughly.
      Seek immediate medical advice.
    • After eye contact
      Rinse opened eye for several minutes under running water. Then consult doctor.
    • After swallowing Seek medical treatment.
  • 5 Fire fighting measures

    • Suitable extinguishing agents
      Special powder for metal fires. Do not use water.
    • For safety reasons unsuitable extinguishing agents Water.
    • Protective equipment:
      Wear self-contained breathing apparatus.
      Wear full protective suit.
  • 6 Accidental release measures

    • Person-related safety precautions:
      Wear protective equipment. Keep unprotected persons away.
      Ensure adequate ventilation
    • Measures for environmental protection:
      Do not allow material to be released to the environment without proper governmental permits.
    • Measures for cleaning/collecting: Collect mechanically.
    • Additional information:
      See Section 7 for information on safe handling
      See section 8 for information on personal protection equipment.
      See Section 13 for information on disposal.
  • 7 Handling and storage


    • Handling
    • Information for safe handling:
      Keep containers tightly sealed.
      Store in cool, dry place in tightly closed containers.
      No special precautions necessary if used correctly.
    • Information about protection against explosions and fires:
      No special measures required.

    • Storage
    • Requirements to be met by storerooms and containers:
      No special requirements.
    • Information about storage in one common storage facility:
      Do not store together with oxidizing and acidic materials.
      Store away from halogens.
    • Further information about storage conditions:
      Store under dry inert gas.
      Keep container tightly sealed.
      Store in cool, dry conditions in well sealed containers.
  • 8 Exposure controls and personal protection

    • Additional information about design of technical systems:
      Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

    • Components with critical values that require monitoring at the
      workplace:                                                             
      Not required.
    • Additional information: No data

    • Personal protective equipment
    • General protective and hygienic measures
      The usual precautionary measures should be adhered to in handling the chemicals.
      Keep away from foodstuffs, beverages and food.
      Instantly remove any soiled and impregnated garments.
      Wash hands during breaks and at the end of the work.
    • Breathing equipment: Use breathing protection with high concentrations.
    • Protection of hands: Impervious gloves
    • Eye protection: Safety glasses
    • Body protection: Protective work clothing.
  • 9 Physical and chemical properties:

    • General Information

    • Form: Solid.
    • Colour: Silver-coloured
    • Smell: Odourless
    •   Value/Range  Unit    Method      
    • Change in condition
    • Melting point/Melting range:                   931 ° C
    • Boiling point/Boiling range:                  3127 ° C
    • Sublimation temperature / start:   Not determined

    • Flash point:                       Not applicable

    • Inflammability (solid, gaseous)    Product is not inflammable.
      Powder: highly flammable

    • Ignition temperature:              Not determined

    • Decomposition temperature:         Not determined

    • Danger of explosion:               Product is not explosive.

    • Critical values for explosion:
    • Lower:                             Not determined
    • Upper:                             Not determined

    • Steam pressure:                    Not determined

    • Density                at   20 ° C           6.773 g/cm³

    • Solubility in / Miscibility with
    • Water:                             Not determined
  • 10 Stability and reactivity

    • Thermal decomposition / conditions to be avoided:
      No decomposition if used and stored according to specifications.
    • Materials to be avoided:
      Oxidizing agents
      Acids
      Halogens
      Water/moisture
      Air
    • Dangerous reactions:
      Powder: contact with water liberates extremely flammable gases.
    • Dangerous products of decomposition: Metal oxide
  • 11 Toxicological information

    • Acute toxicity:
    • Primary irritant effect:
    • on the skin: May cause irritation
    • on the eye: May cause irritation
    • Sensitization: No sensitizing effect known.
    • Additional toxicological information:
      To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
      No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
  • 12 Ecological information:

    • General notes:
      Do not allow material to be released to the environment without proper governmental permits.
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
      Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
  • 13 Disposal considerations


    • Product:
    • Recommendation
      Consult state, local or national regulations for proper disposal.
      Hand over to disposers of hazardous waste.
      Must be specially treated under adherence to official regulations.

    • Uncleaned packagings:
    • Recommendation:
      Disposal must be made according to official regulations.
  • 14 Transport information


    • Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
    • ADR/RID-GGVS/E Class:         None

    • Maritime transport IMDG/GGVSea:
    • IMDG/GGVSea Class:        None

    • Air transport ICAO-TI and IATA-DGR:
    • ICAO/IATA Class:          None

    • Transport/Additional information:
      Not dangerous according to the above specifications.
  • 15 Regulatory information


    • Designation according to EC guidelines:
      Observe the normal safety regulations when handling chemicals
      The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials (GefStoffV).

    • National regulations

    • Information about limitation of use:
      For use only by technically qualified individuals.

    • Water hazard class:
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
  • 16 Other information:

      Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees.  This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.

  •      

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