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Thallium
Thallium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Thallium is primarily used for its electrical conductivity as thallium sulfide which changes with exposure to infrared light. This ability makes the compound useful in photocells. Thallium bromide-iodide crystals have been used as infrared optical materials. Thallium has been used, with sulfur or selenium and arsenic, to produce low melting glasses which becomes fluid between 125 and 150 C. These glasses have properties at room temperatures similar to ordinary glasses and are said to be durable and insoluble in water. Thallium oxide has been used to produce glasses with a high index of refraction, and is also used in the manufacture of photo cells. Thallium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Thallium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Thallium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Thallium is a Block P, Group 13, Period 6 element. The electronic configuration is [Xe] 4f14 5d10 6s2 6p1. In its elemental form thallium's CAS number is 7440-28-0. The thallium atom has a radius of 170.pm and it's Van der Waals radius is 196.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Thallium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Thallium was first discovered by Sir William Crookes in 1861.

French Thallium German Thallium Italian tallio Portuguese Tálio Spanish talio Swedish Thallium

Abundance. The following table shows the abundance of thallium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Tl-203
202.972329
29.524
Tl-205
204.974412
70.476

Safety Data. The safety data for thallium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for thallium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
589.36 kJ mol-1
2nd Ionization Energy
1971.02 kJ mol-1
3rd Ionization Energy
2878.18 kJ mol-1

Conductivity. As to thallium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 18 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.8. The thermal conductivity of thallium is 46.1 W m-1 K-1.

Thermal Properties. The melting point and boiling point for thallium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
4.31 kJ mol-1
Heat of Vaporization
166.1 kJ mol-1
Heat of Atomization
182.845 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Tl 81 204.383 g.mol -1 1.8 11.71 g.cm-3 at 20 °C 1800 °C 4200 °C 196.pm 0.099 nm (+3) 589.36 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Thallium

  • The study on the effect and mechanism of the second ligands on the luminescence properties of terbium complexes. Thallium Transport and the Evaluation of Olfactory Nerve Connectivity between the Nasal Cavity and Olfactory Bulb. Chem Senses. 2007 Sep 27; [Epub ahead of print]

  • [Diagonal earlobe crease, a sign of coronary artery disease] Medicina (B Aires). 2007;67(4):321-5. Spanish.

  • Military aviators with mitral valve prolapse: long-term follow-up and aeromedical endpoints. Aviat Space Environ Med. 2007 Sep;78(9):845-51.

  • Water-clear cell parathyroid adenoma causing primary hyperparathyroidism in a patient with neurofibromatosis type 1: report of a case. Surg Today. 2007;37(10):884-7. Epub 2007 Sep 26.

  • A Thallium Mediated Route to sigma-Arylalkynyl Complexes of Bipyridyltricarbonylrhenium(I). Inorg Chem. 2007 Sep 15; [Epub ahead of print]

  • Catalysis Design for Ring-Opening Polymerization of Cyclic Esters: 1. Group 1 Metal and Thallium(I) Trispyrazolylborate Complexes with Hemilabile Ligands. Inorg Chem. 2007 Sep 15; [Epub ahead of print]

  • Levels of eight trace elements in edible mushrooms from a rural area. Food Addit Contam. 2007 Jul 6;:1-8 [Epub ahead of print]

  • Significance of copper determination in late onset of Wilson's disease. Clin Toxicol (Phila). 2007 Sep;45(6):688-94.

  • Analytical procedure for the simultaneous voltammetric determination of trace metals in food and environmental matrices. Critical comparison with atomic absorption spectroscopic measurements. Ann Chim. 2007 Mar-Apr;97(3-4):141-51.

  • Determination of atenolol by the micelle-stabilized room-temperature phosphorescence methodology. Luminescence. 2007 Sep 3; [Epub ahead of print]

  • Thallium(I) sandwich, multidecker, and ether complexes stabilized by weakly-coordinating anions: a spectroscopic, structural, and theoretical investigation.
    J Am Chem Soc. 2007 Jan 31;129(4):881-94.

  • [The influence of cadmium and potassium on the level of cytogenetic effects induced by thallium-232 in Allium cepa root meristem]
    Tsitol Genet. 2006 Nov-Dec;40(6):50-8. Ukrainian.

  • The cause and clinical significance of central tumor photopenia on thallium scintigraphy of pediatric osteosarcoma of the extremity.
    AJR Am J Roentgenol. 2007 Feb;188(2):572-8.

  • Concurrent Ewing Sarcoma Family of Tumors and Fibrous Dysplasia: Possible Diagnostic Pitfall.
    J Pediatr Hematol Oncol. 2007 Jan;29(1):15-18.

  • [A case of cavernous angioma at the septum pellucidum]
    No Shinkei Geka. 2007 Jan;35(1):53-8. Japanese.

  • Short-term thallium intoxication: dermatological findings correlated with thallium concentration.
    Arch Dermatol. 2007 Jan;143(1):93-8.

  • High resolution profiles of thallium, manganese and iron assessed by DET and DGT techniques in riverine sediment pore waters.
    Sci Total Environ. 2007 Jan 12; [Epub ahead of print]

  • Characterization of follicular thyroid nodules at fine needle aspiration biopsy using double phase thallium-201 imaging: comparison of visual and semiquantitative analyses.
    Thyroid. 2006 Dec;16(12):1243-9.

  • [Evaluation of therapeutic answer: role of isotopic imaging]
    Bull Cancer. 2006 Dec 1;93(12):1191-9. French.

  • Effect of stress-induced reversible ischemia on serum concentrations of ischemia-modified albumin, natriuretic peptides and placental growth factor.
    Clin Res Cardiol. 2006 Dec 22; [Epub ahead of print]

 

 

 

 

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