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Thallium Dichromate
Tl2CrO4

13473-75-1
Product Product Code Order or Specifications
(2N) 99% Thallium Chromate TL-CRAT-02 Contact American Elements
(3N) 99.9% Thallium Chromate TL-CRAT-03 Contact American Elements
(4N) 99.99% Thallium Chromate TL-CRAT-04 Contact American Elements
(5N) 99.999% Thallium Chromate TL-CRAT-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Tl2CrO4 13473-75-1 N/A 61626 N/A 236-750-2 dioxido(dioxo)chromium; thallium(1+) N/A [Tl+].[Tl+].[O-][Cr]([O-])(=O)=O InChI=1S/Cr.4O.2Tl/q;;;2*-1;2*+1 ARTWBPXCXWJLPM-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
CrO4Tl2 524.76 N/A N/A 525.868994 525.868994 0 Safety Data Sheet


Chromate IonThallium Chromate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Thallium(Tl) atomic and molecular weight, atomic number and elemental symbolThallium is a Block P, Group 13, Period 6 element. The number of electrons in each of Thallium's shells is 2, 8, 18, 32, 18, 3 and its electronic configuration is [Xe] 4f14 5d10 6s2 6p1. In its elemental form thallium's CAS number is 7440-28-0. The thallium atom has a radius of 170.pm and it's Van der Waals radius is 196.pm. Thallium and its compounds are highly toxic. Thallium is primarily used for its electrical conductivity as thallium sulfide which changes with exposure to infrared light. This ability makes the compound useful in photocells. Thallium bromide-iodide crystals have been used as infrared optical materials. Thallium has been used,Elemental Thallium with sulfur or selenium and arsenic, to produce low melting glasses which becomes fluid between 125 and 150 C. These glasses have properties at room temperatures similar to ordinary glasses and are said to be durable and insoluble in water. Thallium oxide has been used to produce glasses with a high index of refraction, and is also used in the manufacture of photo cells. Thallium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Thallium was first discovered by Sir William Crookes in 1861.

Chromium(Cr) atomic and molecular weight, atomic number and elemental symbolChromium is a Block D, Group 6, Period 4 element. The number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electronic configuration is [Ar] 3d5 4s1. In its elemental form chromium's CAS number is 7440-47-3. The chromium atom has a radius of 124.9.pm and it's Van der Waals radius is 200.pm. Hexavalent chromium is toxic. Chromium is highly resistant to corrosion. This has led to its use in numerous alloying and steel producing applications. When chromium is added to glass or ceramic glazes, it produces a brilliant green. Chromium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used as a paint pigment for this purpose.Although chromium metal is an essential trace element, hexavalent Elemental Chromiumchromium (Cr(VI)) is especially toxic and carcinogenic. Recently, chromites have formed the basis for cathode compositions Chromium Bohr Modelfor oxygen generation and fuel cell applications. Chromium information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Chromium was first discovered by Anders Ekeberg in 1802. Due to its various colorful compounds, Chromium was named after the Greek word 'chroma' meaning color. See Chromium research below.

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Toxicity
Safety & Handling
 
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
N/A N/A N/A N/A N/A N/A N/A N/A

 

Synonyms for Thallium Dichromate Include:


Thallium(I) chromate
dioxido(dioxo)chromium; thallium(1+)

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 

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Recent Research & Development for Thallium

  • Additive effect of dl-penicillamine plus Prussian blue for the antidotal treatment of thallotoxicosis in rats. Montes S, Pérez-Barrón G, Rubio-Osornio M, Ríos C, Diaz-Ruíz A, Altagracia-Martínez M, Monroy-Noyola A. Environ Toxicol Pharmacol. 2011 Nov;32(3):349-55. Epub 2011 Jul 27. PMID: 22004953 [PubMed - in process]

  • Brain SPECT Thallium Using Cadmium Zinc Telluride: A First Experience. Farid K, Queneau M, Guernou M, Lussato D, Petras S, Songy B. Clin Nucl Med. 2011 Nov;36(11):e178-9. PMID: 21975418 [PubMed - in process]

  • Thallium-201 scintigraphy is an effective diagnostic modality to distinguish malignant from benign soft-tissue tumors. Kawakami N, Kunisada T, Sato S, Morimoto Y, Tanaka M, Sasaki T, Sugihara S, Yanai H, Kanazawa S, Ozaki T. Clin Nucl Med. 2011 Nov;36(11):982-6. PMID: 21975384 [PubMed - in process]

  • [One case of acute thallium poisoning]. Yan LL, Wang ZH, Li SH. Zhonghua Lao Dong Wei Sheng Zhi Ye Bing Za Zhi. 2011 May;29(5):393-4. Chinese. No abstract available. PMID: 21972545 [PubMed - in process]

  • Effects of exercise training started within 2 weeks after acute myocardial infarction on myocardial perfusion and left ventricular function: a gated SPECT imaging study. Giallauria F, Acampa W, Ricci F, Vitelli A, Maresca L, Mancini M, Grieco A, Gallicchio R, Xhoxhi E, Spinelli L, Cuocolo A, Vigorito C. Eur J Cardiovasc Prev Rehabil. 2011 Sep 30. [Epub ahead of print] PMID: 21965517 [PubMed - as supplied by publisher]

  • Altered Neuronal Activity Patterns in the Visual Cortex of the Adult Rat after Partial Optic Nerve Crush--A Single-Cell Resolution Metabolic Mapping Study. Macharadze T, Pielot R, Wanger T, Scheich H, Gundelfinger ED, Budinger E, Goldschmidt J, Kreutz MR. Cereb Cortex. 2011 Sep 21. [Epub ahead of print] PMID: 21940702 [PubMed - as supplied by publisher]

  • [Accumulation of sodium and potassium ions in oocytes of the river lamprey Lampetra fluviatilis during prespawning period]. Sherstobitov AO, Lapin AV, Glazunov VV, Nikiforov VA, Nikiforov AA. Zh Evol Biokhim Fiziol. 2011 Jul-Aug;47(4):278-82. Russian. PMID: 21938909 [PubMed - indexed for MEDLINE]

  • Hidden superlattice in Tl2(SC6H4S) and Tl2(SeC6H4Se) solved from powder X-ray diffraction. Stone KH, Turner DL, Singh MP, Vaid TP, Stephens PW. Acta Crystallogr B. 2011 Oct;67(Pt 5):409-15. Epub 2011 Sep 16. PMID: 21931210 [PubMed]

  • Thallium in the hydrosphere of south west England. Law S, Turner A. Environ Pollut. 2011 Dec;159(12):3484-9. Epub 2011 Sep 16. PMID: 21925780 [PubMed - in process]

  • Myocardial Uptake of 7'-(Z)-[123I]Iodorotenone During Vasodilator Stress in Dogs with Critical Coronary Stenoses. Broisat A, Ruiz M, Goodman NC, Hanrahan SM, Reutter BW, Brennan KM, Janabi M, Schaefer S, Watson DD, Beller GA, Vanbrocklin HF, Glover DK. Circ Cardiovasc Imaging. 2011 Sep 14. [Epub ahead of print] PMID: 21917783 [PubMed - as supplied by publisher]

  • Anhydrous thallium hydrogen l-glutamate: polymer networks formed by sandwich layers of oxygen-coordinated thallium ions cores shielded by hydrogen l-glutamate counterions. Bodner T, Wirnsberger B, Albering J, Wiesbrock F. Dalton Trans. 2011 Nov 7;40(41):10885-8. Epub 2011 Sep 14. PMID: 21915430 [PubMed - in process]

  • Biological safety of nasal thallium-201 administration: a preclinical study for olfacto-scintigraphy. Washiyama K, Shiga H, Hirota K, Tsuchida A, Yamamoto J, Yagi S, Yoshizaki T, Furukawa M, Amano R, Miwa T. J Radiat Res (Tokyo). 2011;52(4):450-5. doi: 10.1269/jrr.10153. No abstract available. PMID: 21905306 [PubMed - in process]

  • Evaluation of Naturally Occurring Radioactive Materials (NORMs) in Inorganic and Organic Oilfield Scales from the Middle East. Bassioni G, Abdulla F, Morsy Z, El-Faramawy N. Arch Environ Contam Toxicol. 2011 Sep 3. [Epub ahead of print] PMID: 21892762 [PubMed - as supplied by publisher]

  • Non-invasive Evaluation of Internal Thoracic Artery Anastomosed to the Left Anterior Descending Artery with 320-Detector Row Computed Tomography and Adenosine Thallium-201 Myocardial Perfusion Scintigraphy. Takagi Y, Akita K, Kondo H, Ishida M, Kaneko K, Sato M, Ando M. Ann Thorac Cardiovasc Surg. 2011 Aug 26. [Epub ahead of print] PMID: 21881340 [PubMed - as supplied by publisher]

  • The pathologic cascade of cerebrovascular lesions in SHRSP: is erythrocyte accumulation an early phase? Schreiber S, Bueche CZ, Garz C, Kropf S, Angenstein F, Goldschmidt J, Neumann J, Heinze HJ, Goertler M, Reymann KG, Braun H. J Cereb Blood Flow Metab. 2011 Aug 31. doi: 10.1038/jcbfm.2011.122. [Epub ahead of print] PMID: 21878945 [PubMed - as supplied by publisher]

  • Head-to-head comparison of contrast-enhanced cardiovascular magnetic resonance and (201)Thallium single photon emission computed tomography for prediction of reversible left ventricular dysfunction in chronic ischaemic heart disease. Regenfus M, Schlundt C, von Erffa J, Schmidt M, Reulbach U, Kuwert T, Daniel WG, Schmid M. Int J Cardiovasc Imaging. 2011 Aug 28. [Epub ahead of print] PMID: 21874571 [PubMed - as supplied by publisher]

  • Selective preconcentration of thallium species as chloro and iodo complexes on Chromosorb 105 resin prior to electrothermal atomic absorption spectrometry. Karatepe A, Soylak M, Elçi L. Talanta. 2011 Sep 30;85(4):1974-9. Epub 2011 Jul 18. PMID: 21872046 [PubMed - in process]

  • Monte Carlo dose enhancement studies in microbeam radiation therapy. Martínez-Rovira I, Prezadoa Y. Med Phys. 2011 Jul;38(7):4430-9. PMID: 21859044 [PubMed - indexed for MEDLINE]

  • The effects of chemical and radioactive properties of Tl-201 on human erythrocyte glutathione reductase activity. Sahin A, Senturk M, Akkemik E, Ciftci M. Nucl Med Biol. 2011 Aug 8. [Epub ahead of print] PMID: 21831653 [PubMed - as supplied by publisher]

  • Comparison of myocardial perfusion imaging using thallium-201 between a new cadmium-zinc-telluride cardiac camera and a conventional SPECT camera. Songy B, Lussato D, Guernou M, Queneau M, Geronazzo R. Clin Nucl Med. 2011 Sep;36(9):776-80. PMID: 21825848 [PubMed - in process]

Recent Research & Development for Chromate

  • Bioremediation of Cr(VI) and Immobilization as Cr(III) by Ochrobactrum anthropi. Cheng Y, Yan F, Huang F, Chu W, Pan D, Chen Z, Zheng J, Yu M, Lin Z, Wu Z. Environ Sci Technol. 2010 Jul 7. [Epub ahead of print] PubMed PMID: 20608725.

  • Proteogenomic and functional analysis of chromate reduction in Acidiphilium cryptum JF-5, an Fe(III)-respiring acidophile. Magnuson TS, Swenson MW, Paszczynski AJ, Deobald LA, Kerk D, Cummings DE. Biometals. 2010 Jul 1. [Epub ahead of print] PubMed PMID: 20593301.

  • Enhanced chromate reduction by resting Escherichia coli cells in the presence of quinone redox mediators. Liu G, Yang H, Wang J, Jin R, Zhou J, Lv H. Bioresour Technol. 2010 Jun 26. [Epub ahead of print] PubMed PMID: 20584598.

  • Tricaesium tris(oxalato-kappa(2)O(1),O(2))chromate(III) dihydrate. Martin L, Christian A, Akutsu H. Acta Crystallogr C. 2010 Jun;66(Pt 6):m157-9. Epub 2010 May 8. PubMed PMID: 20522938.

  • Removal of chromate and phosphate anion from aqueous solutions using calix[4]aren receptors containing proton switchable units. Ertul S, Bayrakci M, Yilmaz M. J Hazard Mater. 2010 Jun 1. [Epub ahead of print] PubMed PMID: 20579808.

  • Leucobacter chromiiresistens sp. nov., a novel chromate-resistant strain in the genus Leucobacter. Sturm G, Jacobs J, Spröer C, Schumann P, Gescher J. Int J Syst Evol Microbiol. 2010 May 28. [Epub ahead of print] PubMed PMID: 20511468.

  • Proteomics reveals a core molecular response of Pseudomonas putida F1 to acute chromate challenge. Thompson DK, Chourey K, Wickham GS, Thieman SB, VerBerkmoes NC, Zhang B, McCarthy AT, Rudisill MA, Shah M, Hettich RL. BMC Genomics. 2010 May 19;11:311. PubMed PMID: 20482812.

  • Microbial products (biosurfactant and extracellular chromate reductase) of marine microorganism are the potential agents reduce the oxidative stress induced by toxic heavy metals. Gnanamani A, Kavitha V, Radhakrishnan N, Suseela Rajakumar G, Sekaran G, Mandal AB. Colloids Surf B Biointerfaces. 2010 Apr 22. [Epub ahead of print] PubMed PMID: 20483569.

  • Removal of selected nuisance anions by Octolig. Martin DF, Lizardi CL, Schulman E, Vo B, Wynn D. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2010 Jan;45(9):1144-9. PubMed PMID: 20560089.

  • Effects of physicochemical factors on Cr(VI) removal from leachate by zero-valent iron and alpha-Fe(2)O(3) nanoparticles. Liu TY, Zhao L, Tan X, Liu SJ, Li JJ, Qi Y, Mao GZ. Water Sci Technol. 2010;61(11):2759-67. PubMed PMID: 20489248.

     

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