+ American Elements: Thulium Oxide Shot Supplier & Tech Info
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Thulium Oxide Shot
Tm2O3
12036-44-1
Product
Product Code
Order or Specifications
99% Thulium Oxide Shot
TM-OX-02-SH
Contact American Elements
99.9% Thulium Oxide Shot
TM-OX-03-SH
Contact American Elements
99.99% Thulium Oxide Shot
TM-OX-04-SH
Contact American Elements
99.999% Thulium Oxide Shot
TM-OX-05-SH
Contact American Elements

American Elements specializes in producing high purity Thulium Oxide Shot with the highest possible density and smallest possible average grain sizes for use in semiconductor, Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Metallic-Organic and Chemical Vapor Deposition (MOCVD). Our standard Shot sizes range from 1-3mm . We can also provide Shot outside this range for ultra high purity thin film applications, such as fuel cells and solar energy layers. Materials are produced using crystallization , solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form , as well as other machined shapes and through other processes such as nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots ) and in the form of solutions and organometallics. See research below. We also produce Thulium as rod , ingot, powder, pieces, disc, granules, wire, and in compound forms, such as oxide. Other shapes are available by request.

Thulium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f136s2. In its elemental form thulium's CAS number is 7440-30-4. The thulium atom has a radius of 172.4.pm and it's Van der Waals radius is unknown. Thulium is representative of the other lanthanides (rare earths) similar in chemistry to Yttrium. Thulium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Thulium emits blue upon excitation. Flat panel screens depend critically on bright blue emitters. Also, under X-ray bombardment emissions are in both the 375 nm (ultra violet) and 465 (visible blue) wave lengths. This gives the material useful applications in low radiation detection for detection badges and similar uses. It is also used in other luminescence applications, such as halide discharge lamps. Thulium was first discovered by Theodore Cleve in 1879.

Formula CAS No. Appearance Molecular Weight Density Melting Point Boiling Point Solubility Stability
Tm2O3 12036-44-1 White 385.88 8600 kg/m³ 2425 °C   Insoluble in water, moderately soluble in strong mineral acids Slightly hygroscopic
PRODUCT CATALOG Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. MSDS
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Production Catalog Available in 32 Countries
 
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Recent Research & Development for Thulium

  • Kerr-lens mode-locked femtosecond Cr(2+):ZnSe laser at 2420 nm. Cizmeciyan MN, Cankaya H, Kurt A, Sennaroglu A. Opt Lett. 2009 Oct 15;34(20):3056-8. doi: 10.1364/OL.34.003056. PMID: 19838224 [PubMed - in process]

  • Zeeman slowing of thulium atoms. Chebakov K, Sokolov A, Akimov A, Sukachev D, Kanorsky S, Kolachevsky N, Sorokin V. Opt Lett. 2009 Oct 1;34(19):2955-7. doi: 10.1364/OL.34.002955. PMID: 19794780 [PubMed - in process]

  • Optimized MRI contrast for on-resonance proton exchange processes of PARACEST agents in biological systems. Li AX, Suchy M, Jones CK, Hudson RH, Menon RS, Bartha R. Magn Reson Med. 2009 Sep 24. [Epub ahead of print] PMID: 19780147 [PubMed - as supplied by publisher]

  • Laser treatments of the prostate vs TURP/ open prostatectomy: systematic review of urodynamic data. Herrmann TR, Georgiou A, Bach T, Gross AJ, Oelke M. Minerva Urol Nefrol. 2009 Sep;61(3):309-24. PMID: 19773731 [PubMed - in process]

  • Dose response of CaF2:Tm to charged particles of different LET. Moyers MF, Nelson GA. Med Phys. 2009 Aug;36(8):3714-23. PMID: 19746804 [PubMed - indexed for MEDLINE]

  • BaLn2Se4 (Ln = Er, Tm and Yb). Bugaris DE, Ibers JA. Acta Crystallogr C. 2009 Sep;65(Pt 9):i60-2. Epub 2009 Aug 22. PMID: 19726843 [PubMed - in process]

  • Thulium:YAG laser enucleation (VapoEnucleation) of the prostate: safety and durability during intermediate-term follow-up. Bach T, Netsch C, Haecker A, Michel MS, Herrmann TR, Gross AJ. World J Urol. 2009 Aug 9. [Epub ahead of print] PMID: 19669645 [PubMed - as supplied by publisher]

  • Transurethral 2-mum laser in the treatment of urethral stricture. Guo FF, Lu H, Wang GJ, Tan SF, He XF, Wang JM, Liu HJ, Zhu WB. World J Urol. 2009 Aug 2. [Epub ahead of print] PMID: 19649639 [PubMed - as supplied by publisher]

  • Natural orifice translumenal endoscopic surgery (NOTES) partial nephrectomy in a porcine model. Boylu U, Oommen M, Joshi V, Thomas R, Lee BR. Surg Endosc. 2009 Jul 8. [Epub ahead of print] PMID: 19585068 [PubMed - as supplied by publisher]

  • A rapid hydrothermal synthesis of rare earth oxide activated Y (OH)3 and Y2O3 nanotubes. Devaraju MK, Yin S, Sato T. Nanotechnology. 2009 Jul 29;20(30):305302. Epub 2009 Jul 7. PMID: 19581697 [PubMed - indexed for MEDLINE]

  • Passive mode-locking of a Tm-doped bulk laser near 2 microm using a carbon nanotube saturable absorber. Cho WB, Schmidt A, Yim JH, Choi SY, Lee S, Rotermund F, Griebner U, Steinmeyer G, Petrov V, Mateos X, Pujol MC, Carvajal JJ, Aguiló M, Díaz F. Opt Express. 2009 Jun 22;17(13):11007-12. PMID: 19550500 [PubMed - indexed for MEDLINE]

  • Absolute temperature MR imaging with thulium 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetramethyl-1,4,7,10-tetraacetic acid (TmDOTMA-). James JR, Gao Y, Miller MA, Babsky A, Bansal N. Magn Reson Med. 2009 Aug;62(2):550-6. PMID: 19526494 [PubMed - indexed for MEDLINE]

  • (170)Tm-EDTMP: a potential cost-effective alternative to (89)SrCl(2) for bone pain palliation. Das T, Chakraborty S, Sarma HD, Tandon P, Banerjee S, Venkatesh M, Pillai MR. Nucl Med Biol. 2009 Jul;36(5):561-8. Epub 2009 May 7. PMID: 19520297 [PubMed - indexed for MEDLINE]

  • Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C(3v)-C(94) and Ca@C(3v)-C(94). Che Y, Yang H, Wang Z, Jin H, Liu Z, Lu C, Zuo T, Dorn HC, Beavers CM, Olmstead MM, Balch AL. Inorg Chem. 2009 Jun 9. [Epub ahead of print] PMID: 19507844 [PubMed - as supplied by publisher]

  • Lanthanide Complexes of Triethylenetetramine Tetra-, Penta-, and Hexaacetamide Ligands as Paramagnetic Chemical Exchange-Dependent Saturation Transfer Contrast Agents for Magnetic Resonance Imaging: Nona- versus Decadentate Coordination. Burdinski D, Pikkemaat JA, Lub J, de Peinder P, Nieto Garrido L, Weyhermu¨ller T. Inorg Chem. 2009 Jun 9. [Epub ahead of print] PMID: 19507818 [PubMed - as supplied by publisher]

  • Near-infrared luminescence of Nd3+ and Tm3+ ions doped ZnO nanocrystals. Liu Y, Luo W, Li R, Zhu H, Chen X. Opt Express. 2009 Jun 8;17(12):9748-53. PMID: 19506624 [PubMed - indexed for MEDLINE]

  • [Comparison of holmium and thulium laser in transurethral enucleation of the prostate] Shao Q, Zhang FB, Shang DH, Tian Y. Zhonghua Nan Ke Xue. 2009 Apr;15(4):346-9. Chinese. PMID: 19472910 [PubMed - indexed for MEDLINE]

  • Thulium laser versus standard transurethral resection of the prostate: A randomized prospective trial. Dubey D, Muruganandham K. Indian J Urol. 2008 Jul;24(3):428-9. No abstract available. PMID: 19468488 [PubMed - in process]

  • Pain and non-pain processing during hypnosis: a thulium-YAG event-related fMRI study. Vanhaudenhuyse A, Boly M, Balteau E, Schnakers C, Moonen G, Luxen A, Lamy M, Degueldre C, Brichant JF, Maquet P, Laureys S, Faymonville ME. Neuroimage. 2009 Sep;47(3):1047-54. Epub 2009 May 19. PMID: 19460446 [PubMed - indexed for MEDLINE]

  • Hexanedioic acid mediated surface-ligand-exchange process for transferring NaYF4:Yb/Er (or Yb/Tm) up-converting nanoparticles from hydrophobic to hydrophilic. Zhang Q, Song K, Zhao J, Kong X, Sun Y, Liu X, Zhang Y, Zeng Q, Zhang H. J Colloid Interface Sci. 2009 Aug 1;336(1):171-5. Epub 2009 Apr 14. PMID: 19428023 [PubMed - indexed for MEDLINE]

 

Material Safety Data Sheet
  • 1 Identification of substance

    • Product details

    • Trade name Thulium oxide
  • 2 Composition/Data on components:

    • Chemical characterization:
                 Designation: (CAS#)                                        
      Thulium oxide (CAS# 12036-44-1); 100%
    • Identification number(s):
    • EINECS Number: 234-851-6
  • 3 Hazards identification

    • Hazard designation: · void
    • Information pertaining to particular dangers for man and environment
      Not applicable
  • 4 First aid measures

    • After inhalation
      Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
      Seek immediate medical advice.
    • After skin contact
      Instantly wash with water and soap and rinse thoroughly.
      Seek immediate medical advice.
    • After eye contact
      Rinse opened eye for several minutes under running water. Then consult doctor.
    • After swallowing Seek medical treatment.
  • 5 Fire fighting measures

    • Suitable extinguishing agents
      Use fire fighting measures that suit the environment.
    • Protective equipment:
      Wear self-contained breathing apparatus.
      Wear full protective suit.
  • 6 Accidental release measures

    • Person-related safety precautions:
      Wear protective equipment. Keep unprotected persons away.
      Ensure adequate ventilation
    • Measures for environmental protection:
      Do not allow material to be released to the environment without proper governmental permits.
    • Measures for cleaning/collecting: Collect mechanically.
    • Additional information:
      See Section 7 for information on safe handling
      See section 8 for information on personal protection equipment.
      See Section 13 for information on disposal.
  • 7 Handling and storage


    • Handling
    • Information for safe handling:
      Keep containers tightly sealed.
      Store in cool, dry place in tightly closed containers.
      No special precautions necessary if used correctly.
    • Information about protection against explosions and fires:
      The product is not flammable

    • Storage
    • Requirements to be met by storerooms and containers:
      No special requirements.
    • Information about storage in one common storage facility:
      Do not store together with acids.
    • Further information about storage conditions:
      Keep container tightly sealed.
      Store in cool, dry conditions in well sealed containers.
  • 8 Exposure controls and personal protection

    • Additional information about design of technical systems:
      Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

    • Components with critical values that require monitoring at the
      workplace:                                                             
      Not required.
    • Additional information: No data

    • Personal protective equipment
    • General protective and hygienic measures
      The usual precautionary measures should be adhered to in handling the chemicals.
      Keep away from foodstuffs, beverages and food.
      Instantly remove any soiled and impregnated garments.
      Wash hands during breaks and at the end of the work.
    • Breathing equipment: Use breathing protection with high concentrations.
    • Protection of hands: Impervious gloves
    • Eye protection: Safety glasses
    • Body protection: Protective work clothing.
  • 9 Physical and chemical properties:

    • General Information

    • Form: Lump
    • Colour: Light green
    • Smell: Odourless
    •   Value/Range  Unit    Method      
    • Change in condition
    • Melting point/Melting range:                  2425 ° C
    • Boiling point/Boiling range:       Not determined
    • Sublimation temperature / start:   Not determined

    • Flash point:                       Not applicable

    • Inflammability (solid, gaseous)    Product is not inflammable.

    • Ignition temperature:              Not determined

    • Decomposition temperature:         Not determined

    • Danger of explosion:               Product is not explosive.

    • Critical values for explosion:
    • Lower:                             Not determined
    • Upper:                             Not determined

    • Steam pressure:                    Not determined

    • Density                            Not determined

    • Solubility in / Miscibility with
    • Water:                             Insoluble
  • 10 Stability and reactivity

    • Thermal decomposition / conditions to be avoided:
      No decomposition if used and stored according to specifications.
    • Materials to be avoided: Acids
    • Dangerous reactions: No dangerous reactions known
    • Dangerous products of decomposition:
      No dangerous decomposition products known
  • 11 Toxicological information

    • Acute toxicity:
    • Primary irritant effect:
    • on the skin: Powder: irritant effect
    • on the eye: Powder: irritant effect
    • Sensitization: No sensitizing effect known.
    • Additional toxicological information:
      To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
      No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
  • 12 Ecological information:

    • General notes:
      Do not allow material to be released to the environment without proper governmental permits.
      Generally not hazardous for water.
  • 13 Disposal considerations


    • Product:
    • Recommendation
      Consult state, local or national regulations for proper disposal.
      Hand over to disposers of hazardous waste.
      Must be specially treated under adherence to official regulations.

    • Uncleaned packagings:
    • Recommendation:
      Disposal must be made according to official regulations.
  • 14 Transport information


    • Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
    • ADR/RID-GGVS/E Class:         None

    • Maritime transport IMDG/GGVSea:
    • IMDG/GGVSea Class:        None

    • Air transport ICAO-TI and IATA-DGR:
    • ICAO/IATA Class:          None

    • Transport/Additional information:
      Not dangerous according to the above specifications.
  • 15 Regulatory information


    • Designation according to EC guidelines:
      Observe the normal safety regulations when handling chemicals
      The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials (GefStoffV).

    • National regulations

    • Information about limitation of use:
      For use only by technically qualified individuals.

    • Water hazard class: Generally not hazardous for water.
  • 16 Other information:

      Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees.  This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
  •  

     

    Recent Research & Development for Thulium Oxide

    • Office-based and microlaryngeal applications of a fiber-based thulium laser.
      Ann Otol Rhinol Laryngol. 2006 Dec;115(12):891-6.

    • Cause of upper urinary-tract essential hematuria: Veno-caliceal fistula or contralateral coexistent upper-tract transitional-cell carcinoma? Case report.
      J Endourol. 2006 Nov;20(11):913-5.

    • 13C direct detected NMR increases the detectability of residual dipolar couplings.
      J Am Chem Soc. 2006 Nov 29;128(47):15042-3. No abstract available.

    • Effect of rare-earth component of the RE/Ni catalyst on the formation and nanostructure of single-walled carbon nanotubes.
      J Phys Chem B Condens Matter Mater Surf Interfaces Biophys. 2006 Aug 10;110(31):15284-90.

    • The electronic and vibrational structure of endohedral Tm3N@C80 (I) fullerene--proof of an encaged Tm3+.
      J Phys Chem A Mol Spectrosc Kinet Environ Gen Theory. 2005 Aug 18;109(32):7088-93.

    • Midinfrared laser source with high power and beam quality.
      Appl Opt. 2006 Jun 1;45(16):3839-45.

    • Electron- and positron-emitting radiolanthanides for therapy: aspects of dosimetry and production.
      J Nucl Med. 2006 May;47(5):807-14.

    • Assignment strategy for fast relaxing signals: complete aminoacid identification in thulium substituted calbindin D 9K.
      J Biomol NMR. 2006 Feb;34(2):63-73.

    • Synthesis of a new stable, neutral organothulium(II) complex by reduction of a thulium(III) precursor.
      Chem Commun (Camb). 2006 Jan 28;(4):426-8.

    • Localization of touch versus heat pain in the human hand: a dissociative effect of temporal parameters on discriminative capacity and decision strategy.
      Pain. 2006 Mar;121(1-2):6-13. Epub 2006 Feb 9.

     

     

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