Vanadium Bromide is a highly water soluble crystalline Vanadium source for uses compatible with Bromides and lower (acidic) pH. Metallic Bromides are marketed under the trade name AE Bromides™. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding carbon disulfide (CS2) and chlorine. Vanadium Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Vanadium is a Block D, Group 5, Period 4 element. The number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electronic configuration is [Ar] 3d3 4s2. In its elemental form vanadium's CAS number is 7440-62-2. The vanadium atom has a radius of 131.1.pm and it's Van der Waals radius is 200.pm. Several vanadium compounds are toxic to some creatures despite the fact that it is an essential trace element. Vanadium is highly resistant to corrosion, so it is commonly used to alloy stainless steel grades. Vanadium compounds are used in advanced ceramics. Vanadium is a petrochemical cracking catalyst. Vanadium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Vanadium information, including Technical Data, Safety Data and its high purity properties , research , applications and other useful facts are discussed here . Scientific facts such as the atomic structure, ionization energy , abundance on Earth , conductivity and thermal properties are included. Vanadium was first discovered in Mexico City by Andres Manuel del Rio, a Spanish born and European educated Mexican mineralogist, in 1801. In honor of its beautiful multi-colored compounds, Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology. See Vanadium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Distorted cubic tetranuclear vanadium(iv) phosphonate cages: double-four-ring (D4R) containing transition metal ion phosphonate cages.
Chandrasekhar V, Dey A, Senapati T, Sañudo EC.
Dalton Trans. 2011 Nov 10. [Epub ahead of print]
PMID:
22071886
[PubMed - as supplied by publisher]
Bioavailability, tissue distribution and hypoglycaemic effect of vanadium in magnesium-deficient rats.
Sánchez C, Torres M, Bermúdez-Peña MC, Aranda P, Montes-Bayón M, Sanz-Medel A, Llopis J.
Magnes Res. 2011 Nov 9. [Epub ahead of print]
PMID:
22068015
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An alternative path for the evolution of biological nitrogen fixation.
Boyd ES, Hamilton TL, Peters JW.
Front Microbiol. 2011;2:205. Epub 2011 Oct 5.
PMID:
22065963
[PubMed]
(4-Bromo-2-{[2-(morpholin-4-yl)ethyl-imino]-meth-yl}phenolato)dioxido-vanadium(V).
Wang CY, Wu X, Cao F, Yuan CJ.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1330. Epub 2011 Sep 14.
PMID:
22065600
[PubMed]
A new mixed group 5 metal selenide, Nb(1.41)V(0.59)Se(9).
Lee E, Yun H.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):i50. Epub 2011 Aug 27.
PMID:
22064790
[PubMed]
Catalytic dehydration of xylose to furfural: vanadyl pyrophosphate as source of active soluble species.
Sádaba I, Lima S, Valente AA, López Granados M.
Carbohydr Res. 2011 Oct 8. [Epub ahead of print]
PMID:
22055820
[PubMed - as supplied by publisher]
Chemical speciation of vanadium in particulate matter emitted from diesel vehicles and urban atmospheric aerosols.
Shafer MM, Toner B, Overdier J, Schauer JJ, Fakra SC, Herner J, Hu S, Ayala A.
Environ Sci Technol. 2011 Nov 3. [Epub ahead of print]
PMID:
22050708
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Chemical Vapor Deposition Synthesis of Tunable Unsubstituted Polythiophene.
Nejati S, Lau KK.
Langmuir. 2011 Nov 2. [Epub ahead of print]
PMID:
22047472
[PubMed - as supplied by publisher]
VCl(3) catalyzed imine-based multicomponent reactions for the facile access of functionalized tetrahydropyridines and ß-amino carbonyls.
Pal S, Choudhury LH, Parvin T.
Mol Divers. 2011 Nov 1. [Epub ahead of print]
PMID:
22042610
[PubMed - as supplied by publisher]
Interplay between the structural and magnetic probes in the elucidation of the structure of a novel 2D layered [V(4)O(4)(OH)(2)(O(2)CC(6)H(4)CO(2))(4)]·DMF.
Djerdj I, Skapin SD, Ceh M, Jaglicic Z, Pajic D, Kozlevcar B, Orel B, Orel ZC.
Dalton Trans. 2011 Oct 31. [Epub ahead of print]
PMID:
22042096
[PubMed - as supplied by publisher]
Interdigitating Organic Bilayers Direct the Short Interlayer Spacing in Hybrid Organic-Inorganic Layered Vanadium Oxide Nanostructures.
Gannon GT, O'Dwyer CP, Larsson JA, Thompson D.
J Phys Chem B. 2011 Oct 31. [Epub ahead of print]
PMID:
22040010
[PubMed - as supplied by publisher]
Hepatic megalocytosis due to vanadium inhalation: participation of oxidative stress.
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Toxicol Ind Health. 2011 Oct 27. [Epub ahead of print]
PMID:
22033424
[PubMed - as supplied by publisher]
Recent perspectives into biochemistry of decavanadate.
Aureliano M, Fct, Algarve UO, Gambelas, Faro 8, Portugal.
World J Biol Chem. 2011 Oct 26;2(10):215-225.
PMID:
22031844
[PubMed - as supplied by publisher]
Association between plate location and plate removal following facial fracture repair.
Kubota Y, Kuroki T, Akita S, Koizumi T, Hasegawa M, Rikihisa N, Mitsukawa N, Satoh K.
J Plast Reconstr Aesthet Surg. 2011 Oct 24. [Epub ahead of print]
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22030077
[PubMed - as supplied by publisher]
Vanadium Oxide Nanotube Spherical Clusters Prepared on Carbon Fabrics for Energy Storage Applications.
Perera SD, Patel B, Bonso J, Grunewald M, Ferraris JP, Balkus KJ.
ACS Appl Mater Interfaces. 2011 Nov 4. [Epub ahead of print]
PMID:
22029527
[PubMed - as supplied by publisher]
Exchange Interactions Through p-p Stacking in the Lamellar Compound [{Cu(bipy)(en)}{Cu(bipy)(H(2)O)}{VO(3)}(4)](n).
Venegas-Yazigi D, Brown KA, Vega A, Calvo R, Aliaga C, Santana RC, Cardoso-Gil R, Kniep R, Schnelle W, Spodine E.
Inorg Chem. 2011 Oct 25. [Epub ahead of print]
PMID:
22026723
[PubMed - as supplied by publisher]
MCM-41 supported oxo-vanadium(IV) complex: A highly selective heterogeneous catalyst for bromination of hydroxy aromatic compounds in water.
Bhunia S, Saha D, Koner S.
Langmuir. 2011 Oct 25. [Epub ahead of print]
PMID:
22026477
[PubMed - as supplied by publisher]
Electronic Properties of Vanadium-Doped TiO(2).
Islam MM, Bredow T, Gerson A.
Chemphyschem. 2011 Oct 24. doi: 10.1002/cphc.201100557. [Epub ahead of print]
PMID:
22025455
[PubMed - as supplied by publisher]
Design and Redox Function of Conjugated Complexes with Polyanilines or Quinonediimines.
Moriuchi T, Hirao T.
Acc Chem Res. 2011 Oct 24. [Epub ahead of print]
PMID:
22023138
[PubMed - as supplied by publisher]
The Tetrahydrometalate Species VH2(H2), NbH4, and TaH4: Matrix Infrared Spectra and Quantum Chemical Calculations.
Wang X, Andrews L.
J Phys Chem A. 2011 Oct 24. [Epub ahead of print]
PMID:
22017260
[PubMed - as supplied by publisher]
Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids.
Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C.
Org Lett. 2010 Jan 5. [Epub ahead of print]
PMID: 19689116 [PubMed - as supplied by publisher]
Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides.
Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL.
Science. 2009 Aug 13. [Epub ahead of print]
PMID: 19679769 [PubMed - as supplied by publisher]
(2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides.
Zhang Q, Wang D, Wang X, Ding K.
J Org Chem. 2009 Aug 12. [Epub ahead of print]
PMID: 19673481 [PubMed - as supplied by publisher]
Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides.
Vechorkin O, Barmaz D, Proust V, Hu X.
J Am Chem Soc. 2009 Aug 11. [Epub ahead of print]
PMID: 19670863 [PubMed - as supplied by publisher]
Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia.
Huang JM, Dong Y.
Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28.
PMID: 19662260 [PubMed - in process]
Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols.
Salvi L, Kim JG, Walsh PJ.
J Am Chem Soc. 2009 Aug 4. [Epub ahead of print]
PMID: 19653691 [PubMed - as supplied by publisher]
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines.
Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J.
J Comb Chem. 2009 Jul 31. [Epub ahead of print]
PMID: 19645499 [PubMed - as supplied by publisher]
Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids.
del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N.
Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29.
PMID: 19641822 [PubMed - in process]
Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides.
Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639999 [PubMed - as supplied by publisher]
Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies.
Snelders DJ, van Koten G, Klein Gebbink RJ.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639941 [PubMed - as supplied by publisher]
Can One Predict Changes from S(N)1 to S(N)2 Mechanisms?
Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H.
J Am Chem Soc. 2009 Jul 27. [Epub ahead of print]
PMID: 19634906 [PubMed - as supplied by publisher]
A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides.
Liao Q, Wang Y, Zhang L, Xi C.
J Org Chem. 2009 Jul 15. [Epub ahead of print]
PMID: 19603753 [PubMed - as supplied by publisher]
Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides.
Shi L, Chu Y, Knochel P, Mayr H.
Org Lett. 2009 Jul 14. [Epub ahead of print]
PMID: 19601592 [PubMed - as supplied by publisher]
C5-Modified nucleosides exhibiting anticancer activity.
Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH.
Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21.
PMID: 19596579 [PubMed - in process]
Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines.
Vo GD, Hartwig JF.
J Am Chem Soc. 2009 Jul 10. [Epub ahead of print]
PMID: 19591470 [PubMed - as supplied by publisher]
New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes.
Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B.
Org Lett. 2009 Jul 2. [Epub ahead of print]
PMID: 19572730 [PubMed - as supplied by publisher]
The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives.
Jo Y, Ju J, Choe J, Song KH, Lee S.
J Org Chem. 2009 Jul 2. [Epub ahead of print]
PMID: 19572571 [PubMed - as supplied by publisher]
Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents.
Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH.
Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8.
PMID: 19557114 [PubMed - in process]
A facile route to C2-substituted imidazolium ionic liquids.
Ennis E, Handy ST.
Molecules. 2009 Jun 19;14(6):2235-45.
PMID: 19553895 [PubMed - in process]
Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines.
McCall WS, Comins DL.
Org Lett. 2009 Jul 2;11(13):2940-2.
PMID: 19552467 [PubMed - indexed for MEDLINE]