Vanadium(IV) Oxide Sulfate Hydrate

CAS #:

Linear Formula:

VOSO4 ·xH2O

MDL Number:

MFCD00149933

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Vanadium(IV) Oxide Sulfate Hydrate
V-OXSAT-02.XHYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Vanadium(IV) Oxide Sulfate Hydrate
V-OXSAT-03.XHYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Vanadium(IV) Oxide Sulfate Hydrate
V-OXSAT-04.XHYD
Pricing > SDS > Data Sheet >
(5N) 99.999% Vanadium(IV) Oxide Sulfate Hydrate
V-OXSAT-05.XHYD
Pricing > SDS > Data Sheet >

Vanadium(IV) Oxide Sulfate Hydrate Properties (Theoretical)

Compound Formula O5SV
Molecular Weight 163.00 (anhydrous basis)
Appearance Blue Powder
Melting Point 105 °C
Boiling Point N/A
Density N/A
Solubility in H2O N/A
Exact Mass 180.901168
Monoisotopic Mass 180.901168

Vanadium(IV) Oxide Sulfate Hydrate Health & Safety Information

Signal Word Warning
Hazard Statements H302
Hazard Codes Xn
Risk Codes 22
Safety Statements 36
RTECS Number N/A
Transport Information UN 2931 6.1/PG 2
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/28/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Vanadium(IV) Oxide Sulfate Hydrate

Product Number: All applicable American Elements product codes, e.g. V-OXSAT-02.XHYD , V-OXSAT-03.XHYD , V-OXSAT-04.XHYD , V-OXSAT-05.XHYD

CAS #: 123334-20-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral(Category 4), H302

GHS Label elements, including precautionary statements
Pictogram

Exclamation Mark - GHS07

Signal word
Warning
Hazard statement(s)
H302
Harmful if swallowed.
Precautionary statement(s)
P264
Wash skin thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.
P301 + P312
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P330
Rinse mouth.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Synonyms: Vanadyl sulfate hydrate
Formula: O5SV xH2O
Molecular Weight:163.00 g/mol
CAS-No.: 123334-20-3


SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
Indication of any immediate medical attention and special treatment needed
no data available


SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Sulphur oxides, Vanadium/vanadium oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Handle and store under inert gas.
Hygroscopic.
Keep in a dry place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters
Component
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Value
C
Control parameters
0.05 mg/m3
Basis
USA. NIOSH Recommended Exposure Limits
Remarks
15 minute ceiling value
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: powder
Colour: blue
Odor
no data available
Odor Threshold
no data available
pH
no data available
Melting point/freezing point
Melting point/range: 105 °C (221 °F)-lit.
Initial boiling point and boiling range
no data available
Flash point
not applicable
EVaporation rate
no data available
Flammability (solid, gas)
no data available
Upper/lower flammability or explosive limits
no data available
Vapor pressure
no data available
Vapor density
no data available
Relative density
no data available
Water solubility
no data available
Partition coefficient: n-octanol/water
no data available
Auto-ignition temperature
no data available
Decomposition temperature
no data available
Viscosity
no data available
Explosive properties
no data available
Oxidizing properties
no data available
Other safety information
no data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
Avoid moisture.
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products-no data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
no data available
Inhalation: no data available
Dermal: no data available
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity -single exposure
no data available
Specific target organ toxicity -repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence


SECTION 12. ECOLOGICAL INFORMATION

Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available


SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 2931
Class: 6.1
Packing group: II
Proper shipping name: Vanadyl sulfate
Reportable Quantity
(RQ): 1000 lbs
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2931
Class: 6.1
Packing group: II
EMS-No: F-A, S-A
Proper shipping name: VANADYL SULPHATE
Marine pollutant: No
IATA
UN number:2931
Class: 6.1
Packing group: II
Proper shipping name: Vanadyl sulphate


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Revision Date
1993-04-24
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Revision Date
1993-04-24
Pennsylvania Right To Know Components
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Revision Date
1993-04-24
New Jersey Right To Know Components
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Revision Date
1993-04-24
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Vanadium(IV) Oxide Sulfate Hydrate

Sulfate IonOxide IonVanadium(IV) Oxide Sulfate Hydrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.

Vanadium(IV) Oxide Sulfate Hydrate Synonyms

Basic vanadium(IV) sulfate hydrate; Vanadyl sulfate hydrate; vanadium oxide sulphate; Oxovanadium(2+) sulfate hydrate; oxygen(-2) anion; vanadium(+4) cation; sulfate

Chemical Identifiers

Linear Formula VOSO4 ·xH2O
MDL Number MFCD00149933
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 16211496
IUPAC Name oxovanadium(2+); sulfate; hydrate
SMILES [V+4].[O-2].[O-]S([O-])(=O)=O
InchI Identifier InChI=1S/H2 O4S.O.V/c1- 5(2,3)4;;/h(H2,1 ,2,3 ,4);;/q;-2;+4/p-2
InchI Key RBFRVUKIVGOWND-UHFFFAOYSA-L

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Vanadium products. Vanadium (atomic symbol: V, atomic number: 23) is a Block D, Group 5, Period 4 element with an atomic weight of 50.9415. Vanadium Bohr ModelThe number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electron configuration is [Ar] 3d3 4s2. The vanadium atom has a radius of 134 pm and a Van der Waals radius of 179 pm. Vanadium was discovered by Andres Manuel del Rio in 1801 and first isolated by Nils Gabriel Sefström in 1830. In its elemental form, vanadium has a bluish-silver appearance. Elemental VanadiumIt is a hard, ductile transition metal that is primarily used as a steel additive and in alloys such as Titanium-6AL-4V, which is composed of titanium, aluminum, and vanadium and is the most common titanium alloy commercially produced. Vanadium is found in fossil fuel deposits and 65 different minerals. Vanadium is not found free in nature; however, once isolated it forms an oxide layer that stabilizes the free metal against further oxidation. Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology.

See more Sulfur products. Sulfur (or Sulphur) (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. Sulfur Bohr ModelThe number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne] 3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777, when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound.

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