Ytterbium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.
 Ytterbium is being applied to numerous fiber amplifier and fiber optic technologies and in various lasing applications. Ytterbium is found in monazite sand as well as the ores euxenite and xenotime and is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has a single dominant absorption band at 985 in the infra-red making it useful in silicon photocells to directly convert radiant energy to electricity. Ytterbium metal increases its electrical resistance when subjected to very high stresses. This property is used in stress gauges for monitoring ground deformations from earthquakes and nuclear explosions. It is also used in thermal barrier system bond coatings on nickel, iron and other transitional metal alloy substrates.
The name Ytterbium originates after the name for the Swedish village of Ytterby.
Ytterbium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.
Oxides are available in forms including powders and dense pellets for such uses  as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Ytterbium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.
Ytterbium has 2 valency state, +2 +3. The number of electrons in each of Ytterbium's shells is 2, 8, 18, 32, 8, 2 and its electronic configuration is [Xe]4f14 6s2. In its metallic form Ytterbium's CAS number is 7440-64-4 and its standard state at 20 ºC is a solid. The Ytterbium atom has a radius of 194 pm and it's Van der Waals radius is unknown. Ytterbium is considered to be fairly toxic. On the periodic table, Ytterbium is a Block F, Group 3, Period 6 element.
 All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, thin fillm deposition using sputtering targets and evaporation materials, metallurgy and optical materials and other high technology applications. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Ytterbium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.
Ytterbium was first discovered by Jean de Marignac in 1878.
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Ytterbium Abundance. The following table shows the abundance of Ytterbium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.
| Isotope |
Atomic Mass |
% Abundance on Earth |
| Yb-168 |
167.934 |
100 |
The following table shows the abundance of Ytterbium present in the human body and in the universe scaled to parts per billion (ppb) by weight and by atom:
| |
Typical Human Body |
Universe |
| by Weight |
no data |
2 ppb |
| by Atom |
no data |
0.01 ppb |
Ytterbium Safety Data and Biological Role. The safety data for Ytterbium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin. Ytterbium compounds have no biological role.
Ionization Energy. The ionization energy for Ytterbium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:
| 1st Ionization Energy |
603.44 kJ mol-1 |
| 2nd Ionization Energy |
1174.82 kJ mol-1 |
| 3rd Ionization Energy |
2416.97 kJ mol-1 |
Conductivity. As to Ytterbium's electrical and thermal conductivity, the electrical conductivity measured in terms of electrical resistivity @ 20 ºC is 29 µOcm and its electronegativities (or its ability to draw electrons relative to other elements) is non-detectable. The thermal conductivity of Ytterbium is 34.9 W m-1 K-1.
Thermal Properties of Ytterbium. The melting point and boiling point for Ytterbium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.
| Heat of Fusion |
9.2 kJ mol-1 |
| Heat of Vaporization |
159 kJ mol-1 |
| Heat of Atomization |
152.8 kJ mol-1 |
Recent Research & Development for Ytterbium
Bis(µ(2)-2-phen-oxy-propionato-?O:O')bis-[(1,10-phenanthroline-?N,N')bis-(2-phen-oxy-propionato-?O,O')ytterbium(III)].
Shen JB, Liu JL, Zhao GL.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1361. Epub 2011 Sep 14.
PMID:
22058692
[PubMed]
"Covalency in the 4f Shell of tris-cyclopentadienyl Ytterbium (YbCp3) - a Spectroscopic Evaluation."
Denning RG, Harmer JR, Green JC, Irwin M.
J Am Chem Soc. 2011 Nov 4. [Epub ahead of print]
PMID:
22053917
[PubMed - as supplied by publisher]
Fingermark detection on non-porous and semi-porous surfaces using YVO(4):Er,Yb luminescent upconverting particles.
Ma R, Shimmon R, McDonagh A, Maynard P, Lennard C, Roux C.
Forensic Sci Int. 2011 Oct 31. [Epub ahead of print]
PMID:
22047749
[PubMed - as supplied by publisher]
Synthesis, Structure, and Reactivity of a Supramolecular Ytterbium(III)-Aqua Complex Featuring Infinite Stacks of C?C Bonds for Photocycloaddition Reactions.
Komori-Orisaku K, Yamashita S, Isozaki T, Sugiura K, Koide Y.
Chemistry. 2011 Oct 21. doi: 10.1002/chem.201102292. [Epub ahead of print] No abstract available.
PMID:
22021148
[PubMed - as supplied by publisher]
Label-free in vivo fiber-based optical-resolution photoacoustic microscopy.
Hajireza P, Shi W, Zemp RJ.
Opt Lett. 2011 Oct 15;36(20):4107-9. doi: 10.1364/OL.36.004107.
PMID:
22002401
[PubMed - in process]
Energy transfer and enhanced 1.54 µm emission in Erbium-Ytterbium disilicate thin films.
Miritello M, Cardile P, Lo Savio R, Priolo F.
Opt Express. 2011 Oct 10;19(21):20761-72. doi: 10.1364/OE.19.020761.
PMID:
21997086
[PubMed - in process]
Photo darkening of rare earth doped silica.
Mattsson KE.
Opt Express. 2011 Oct 10;19(21):19797-812. doi: 10.1364/OE.19.019797.
PMID:
21996988
[PubMed - in process]
Beam quality and noise properties of coherently combined ytterbium doped single frequency fiber amplifiers.
Tünnermann H, Pöld JH, Neumann J, Kracht D, Willke B, Wessels P.
Opt Express. 2011 Sep 26;19(20):19600-6. doi: 10.1364/OE.19.019600.
PMID:
21996901
[PubMed - in process]
p-Wave Cold Collisions in an Optical Lattice Clock.
Lemke ND, von Stecher J, Sherman JA, Rey AM, Oates CW, Ludlow AD.
Phys Rev Lett. 2011 Sep 2;107(10):103902. Epub 2011 Aug 30.
PMID:
21981504
[PubMed - in process]
Mode-locked 0.5 µJ fiber laser at 976 nm.
Lhermite J, Lecaplain C, Machinet G, Royon R, Hideur A, Cormier E.
Opt Lett. 2011 Oct 1;36(19):3819-21. doi: 10.1364/OL.36.003819.
PMID:
21964108
[PubMed - in process]
Acid-responsive microcapsules: the loading-unloading processes.
Samanta D, Sankar RM, Jaisankar SN, Alam MS, Mandal AB.
Chem Commun (Camb). 2011 Oct 25;47(43):11975-7. Epub 2011 Sep 30.
PMID:
21963934
[PubMed - in process]
Electrochemical spectroscopic investigations on the interaction of an ytterbium complex with DNA and their analytical applications such as biosensor.
Ilkhani H, Ganjali MR, Arvand M, Hejazi MS, Azimi F, Norouzi P.
Int J Biol Macromol. 2011 Dec 1;49(5):1117-23. Epub 2011 Sep 16.
PMID:
21939686
[PubMed - in process]
A family of 13 tetranuclear zinc(ii)-lanthanide(iii) complexes of a [3 + 3] Schiff-base macrocycle derived from 1,4-diformyl-2,3-dihydroxybenzene.
Feltham HL, Klöwer F, Cameron SA, Larsen DS, Lan Y, Tropiano M, Faulkner S, Powell AK, Brooker S.
Dalton Trans. 2011 Oct 25;40(43):11425-32. Epub 2011 Sep 21.
PMID:
21935549
[PubMed - in process]
Generation of 578-nm yellow light over 10 mW by second harmonic generation of an 1156-nm external-cavity diode laser.
Lee WK, Park CY, Yu DH, Park SE, Lee SB, Kwon TY.
Opt Express. 2011 Aug 29;19(18):17453-61. doi: 10.1364/OE.19.017453.
PMID:
21935111
[PubMed - in process]
In vivo near-realtime volumetric optical-resolution photoacoustic microscopy using a high-repetition-rate nanosecond fiber-laser.
Shi W, Hajireza P, Shao P, Forbrich A, Zemp RJ.
Opt Express. 2011 Aug 29;19(18):17143-50. doi: 10.1364/OE.19.017143.
PMID:
21935076
[PubMed - in process]
Self-referenceable frequency comb from a gigahertz diode-pumped solid-state laser.
Pekarek S, Südmeyer T, Lecomte S, Kundermann S, Dudley JM, Keller U.
Opt Express. 2011 Aug 15;19(17):16491-7. doi: 10.1364/OE.19.016491.
PMID:
21935013
[PubMed - in process]
Thermal effects in kilowatt all-fiber MOPA.
Fan Y, He B, Zhou J, Zheng J, Liu H, Wei Y, Dong J, Lou Q.
Opt Express. 2011 Aug 1;19(16):15162-72. doi: 10.1364/OE.19.015162.
PMID:
21934878
[PubMed - in process]
Background-free broadband CARS spectroscopy from a 1-MHz ytterbium laser.
Kumar V, Osellame R, Ramponi R, Cerullo G, Marangoni M.
Opt Express. 2011 Aug 1;19(16):15143-8. doi: 10.1364/OE.19.015143.
PMID:
21934875
[PubMed - in process]
Fabrication and characterization of new Yb-doped zirconia-germano-alumino silicate phase-separated nano-particles based fibers.
Kir'yanov AV, Paul MC, Barmenkov YO, Das S, Pal M, Bhadra SK, Zarate LE, Guzman-Chavez AD.
Opt Express. 2011 Aug 1;19(16):14823-37. doi: 10.1364/OE.19.014823.
PMID:
21934843
[PubMed - in process]
White emission of lithium ytterbium tetraphosphate nanocrystals.
Strek W, Marciniak L, Bednarkiewicz A, Lukowiak A, Wiglusz R, Hreniak D.
Opt Express. 2011 Jul 18;19(15):14083-92. doi: 10.1364/OE.19.014083.
PMID:
21934770
[PubMed - in process]
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