Ytterbium Fluoride Nanoparticles are a water insoluble Ytterbium source for use in oxygen-sensitive applications, such as metal production. In extremely low concentrations (ppm), fluoride compounds are used in health applications. Fluoride compounds also have significant uses in synthetic organic chemistry. They are commonly also used to alloy metal and for optical deposition. Certain fluoride compounds can be produced at nanoscale and in ultra high purity forms. Ytterbium is applied to fiber amplifier and fiber optic technologies and in lasing applications. It has a single dominant absorption band at 985 in the infra-red useful in silicon photocells to convert radiant energy to electricity. Ytterbium Fluoride Nanoparticles are generally immediately available in most volumes. Ultra high purity, high purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Ytterbium has 2 valency state, +2 +3. The number of electrons in each of Ytterbium's shells is 2, 8, 18, 32, 8, 2 and its electronic configuration is [Xe]4f14 6s2. In its metallic form Ytterbium's CAS number is 7440-64-4 and its standard state at 20 ºC is a solid. The Ytterbium atom has a radius of 194 pm and it's Van der Waals radius is unknown. Ytterbium is considered to be fairly toxic. On the periodic table, Ytterbium is a Block F, Group 3, Period 6 element. Ytterbium isbeing applied to numerous fiber amplifier and fiber optic technologies and in various lasing applications. Ytterbium is found in monazite sand as well as the ores euxenite and xenotime and is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has a single dominant absorption band at 985 in the infra-red making it useful in silicon photocells to directly convert radiant energy to electricity. Ytterbium metal increases its electrical resistance when subjected to very high stresses. This property is used in stress gauges for monitoring ground deformations from earthquakes and nuclear explosions.The name Ytterbium originates after the name for the Swedish village of Ytterby. See Ytterbium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Bullion and bar forms are best if purchasing solely for physical possession and risk exposure.
Bis(?(2)-2-phen-oxy-propionato-?O:O')bis-[(1,10-phenanthroline-?N,N')bis-(2-phen-oxy-propionato-?O,O')ytterbium(III)].
Shen JB, Liu JL, Zhao GL.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1361. Epub 2011 Sep 14.
PMID:
22058692
[PubMed]
"Covalency in the 4f Shell of tris-cyclopentadienyl Ytterbium (YbCp3) - a Spectroscopic Evaluation."
Denning RG, Harmer JR, Green JC, Irwin M.
J Am Chem Soc. 2011 Nov 4. [Epub ahead of print]
PMID:
22053917
[PubMed - as supplied by publisher]
Fingermark detection on non-porous and semi-porous surfaces using YVO(4):Er,Yb luminescent upconverting particles.
Ma R, Shimmon R, McDonagh A, Maynard P, Lennard C, Roux C.
Forensic Sci Int. 2011 Oct 31. [Epub ahead of print]
PMID:
22047749
[PubMed - as supplied by publisher]
Synthesis, Structure, and Reactivity of a Supramolecular Ytterbium(III)-Aqua Complex Featuring Infinite Stacks of C?C Bonds for Photocycloaddition Reactions.
Komori-Orisaku K, Yamashita S, Isozaki T, Sugiura K, Koide Y.
Chemistry. 2011 Oct 21. doi: 10.1002/chem.201102292. [Epub ahead of print] No abstract available.
PMID:
22021148
[PubMed - as supplied by publisher]
Label-free in vivo fiber-based optical-resolution photoacoustic microscopy.
Hajireza P, Shi W, Zemp RJ.
Opt Lett. 2011 Oct 15;36(20):4107-9. doi: 10.1364/OL.36.004107.
PMID:
22002401
[PubMed - in process]
Energy transfer and enhanced 1.54 ?m emission in Erbium-Ytterbium disilicate thin films.
Miritello M, Cardile P, Lo Savio R, Priolo F.
Opt Express. 2011 Oct 10;19(21):20761-72. doi: 10.1364/OE.19.020761.
PMID:
21997086
[PubMed - in process]
Photo darkening of rare earth doped silica.
Mattsson KE.
Opt Express. 2011 Oct 10;19(21):19797-812. doi: 10.1364/OE.19.019797.
PMID:
21996988
[PubMed - in process]
Beam quality and noise properties of coherently combined ytterbium doped single frequency fiber amplifiers.
Tünnermann H, Pöld JH, Neumann J, Kracht D, Willke B, Wessels P.
Opt Express. 2011 Sep 26;19(20):19600-6. doi: 10.1364/OE.19.019600.
PMID:
21996901
[PubMed - in process]
p-Wave Cold Collisions in an Optical Lattice Clock.
Lemke ND, von Stecher J, Sherman JA, Rey AM, Oates CW, Ludlow AD.
Phys Rev Lett. 2011 Sep 2;107(10):103902. Epub 2011 Aug 30.
PMID:
21981504
[PubMed - in process]
Mode-locked 0.5 ?J fiber laser at 976 nm.
Lhermite J, Lecaplain C, Machinet G, Royon R, Hideur A, Cormier E.
Opt Lett. 2011 Oct 1;36(19):3819-21. doi: 10.1364/OL.36.003819.
PMID:
21964108
[PubMed - in process]
Acid-responsive microcapsules: the loading-unloading processes.
Samanta D, Sankar RM, Jaisankar SN, Alam MS, Mandal AB.
Chem Commun (Camb). 2011 Oct 25;47(43):11975-7. Epub 2011 Sep 30.
PMID:
21963934
[PubMed - in process]
Electrochemical spectroscopic investigations on the interaction of an ytterbium complex with DNA and their analytical applications such as biosensor.
Ilkhani H, Ganjali MR, Arvand M, Hejazi MS, Azimi F, Norouzi P.
Int J Biol Macromol. 2011 Dec 1;49(5):1117-23. Epub 2011 Sep 16.
PMID:
21939686
[PubMed - in process]
A family of 13 tetranuclear zinc(ii)-lanthanide(iii) complexes of a [3 + 3] Schiff-base macrocycle derived from 1,4-diformyl-2,3-dihydroxybenzene.
Feltham HL, Klöwer F, Cameron SA, Larsen DS, Lan Y, Tropiano M, Faulkner S, Powell AK, Brooker S.
Dalton Trans. 2011 Oct 25;40(43):11425-32. Epub 2011 Sep 21.
PMID:
21935549
[PubMed - in process]
Generation of 578-nm yellow light over 10 mW by second harmonic generation of an 1156-nm external-cavity diode laser.
Lee WK, Park CY, Yu DH, Park SE, Lee SB, Kwon TY.
Opt Express. 2011 Aug 29;19(18):17453-61. doi: 10.1364/OE.19.017453.
PMID:
21935111
[PubMed - in process]
In vivo near-realtime volumetric optical-resolution photoacoustic microscopy using a high-repetition-rate nanosecond fiber-laser.
Shi W, Hajireza P, Shao P, Forbrich A, Zemp RJ.
Opt Express. 2011 Aug 29;19(18):17143-50. doi: 10.1364/OE.19.017143.
PMID:
21935076
[PubMed - in process]
Self-referenceable frequency comb from a gigahertz diode-pumped solid-state laser.
Pekarek S, Südmeyer T, Lecomte S, Kundermann S, Dudley JM, Keller U.
Opt Express. 2011 Aug 15;19(17):16491-7. doi: 10.1364/OE.19.016491.
PMID:
21935013
[PubMed - in process]
Thermal effects in kilowatt all-fiber MOPA.
Fan Y, He B, Zhou J, Zheng J, Liu H, Wei Y, Dong J, Lou Q.
Opt Express. 2011 Aug 1;19(16):15162-72. doi: 10.1364/OE.19.015162.
PMID:
21934878
[PubMed - in process]
Background-free broadband CARS spectroscopy from a 1-MHz ytterbium laser.
Kumar V, Osellame R, Ramponi R, Cerullo G, Marangoni M.
Opt Express. 2011 Aug 1;19(16):15143-8. doi: 10.1364/OE.19.015143.
PMID:
21934875
[PubMed - in process]
Fabrication and characterization of new Yb-doped zirconia-germano-alumino silicate phase-separated nano-particles based fibers.
Kir'yanov AV, Paul MC, Barmenkov YO, Das S, Pal M, Bhadra SK, Zarate LE, Guzman-Chavez AD.
Opt Express. 2011 Aug 1;19(16):14823-37. doi: 10.1364/OE.19.014823.
PMID:
21934843
[PubMed - in process]
White emission of lithium ytterbium tetraphosphate nanocrystals.
Strek W, Marciniak L, Bednarkiewicz A, Lukowiak A, Wiglusz R, Hreniak D.
Opt Express. 2011 Jul 18;19(15):14083-92. doi: 10.1364/OE.19.014083.
PMID:
21934770
[PubMed - in process]
Material Safety Data Sheet
1 Identification of substance
Product details
Trade name Ytterbium Fluoride Nanoparticles
2 Composition/Data on components:
Chemical characterization: Designation: (CAS#)
Ytterbium Fluoride Nanoparticles (CAS# 13860-80-0), 100%
Identification number(s):
EINECS Number: 237-354-2
3 Hazards identification
Hazard designation: Xn Harmful
Information pertaining to particular dangers for man and environment
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
Rub in Ca-gluconate solution or Ca-gluconate gel immediately.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek immediate medical advice.
5 Fire fighting measures
Suitable extinguishing agents
Use fire fighting measures that suit the environment.
Special hazards caused by the material, its products of combustion or flue gases:
Can be released in case of fire:
Hydrogen fluoride (HF)
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting:
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
Handling
Information for safe handling:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with critical values that require monitoring at the workplace:
Fluorides (as F)
mg/m3
ACGIH TLV 2.5
Austria TWA 2.5
Belgium TWA 2.5
Finland TWA 2.5
France TWA 2.5
Germany MAK 2.5
Hungary TWA 1; 2-STEL
Netherlands TWA 3.5
Norway TWA 0.6
Poland TWA 1; 3-STEL
Sweden NGV 2
Switzerland MAK-W 1.5
United Kingdom TWA 2.5
Russia TWA 2
Denmark TWA 2.5
USA PEL 2.5
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Breathing equipment: Use breathing protection with high concentrations.
Protection of hands: Impervious gloves
Eye protection:
Safety glasses
Face protection
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Crystalline
Colour: White
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: 1157 ° C
Boiling point/Boiling range: 2200 ° C
Sublimation temperature / start: Not determined
Flash point: Not applicable
Ignition temperature: Not determined
Decomposition temperature: Not determined
Danger of explosion: Product is not explosive.
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density at 20 ° C 8.168 g/cm³
Solubility in / Miscibility with
Water: Insoluble
Not miscible or difficult to mix
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Materials to be avoided: Acids
Dangerous reactions: No dangerous reactions known
Dangerous products of decomposition: Hydrogen fluoride
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant for skin and mucous membranes.
on the eye: Irritant effect.
Sensitization: No sensitizing effect known.
Additional toxicological information:
Danger by skin resorption.
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
14 Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
Code letter and hazard designation of product: Xn Harmful
Risk phrases:
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases:
9 Keep container in a well-ventilated place.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37 Wear suitable protective clothing and gloves.
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Proud sponsors of Aeromat 2012. Please join us and our customers & co-sponsors Boeing and ATI on
June 18-20, 2012
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Ytterbium Fluoride Nanoparticles are a water insoluble Ytterbium source for use in oxygen-sensitive applications, such as metal production. In extremely low concentrations (ppm), fluoride compounds are used in health applications. Fluoride compounds also have significant uses in synthetic organic chemistry. They are commonly also used to alloy metal and for optical deposition. Certain fluoride compounds can be produced at nanoscale and in ultra high purity forms. Ytterbium is applied to fiber amplifier and fiber optic technologies and in lasing applications. It has a single dominant absorption band at 985 in the infra-red useful in silicon photocells to convert radiant energy to electricity. Ytterbium Fluoride Nanoparticles are generally immediately available in most volumes. Ultra high purity, high purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Ytterbium has 2 valency state, +2 +3. The number of electrons in each of Ytterbium's shells is 2, 8, 18, 32, 8, 2 and its electronic configuration is [Xe]4f14 6s2. In its metallic form Ytterbium's CAS number is 7440-64-4 and its standard state at 20 ºC is a solid. The Ytterbium atom has a radius of 194 pm and it's Van der Waals radius is unknown. Ytterbium is considered to be fairly toxic. On the periodic table, Ytterbium is a Block F, Group 3, Period 6 
element. Ytterbium is
being applied to numerous fiber amplifier and fiber optic technologies and in various lasing applications. Ytterbium is found in monazite sand as well as the ores euxenite and xenotime and is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has a single dominant absorption band at 985 in the infra-red making it useful in silicon photocells to directly convert radiant energy to electricity. Ytterbium metal increases its electrical resistance when subjected to very high stresses. This property is used in stress gauges for monitoring ground deformations from earthquakes and nuclear explosions.The name Ytterbium originates after the name for the Swedish village of Ytterby. See Ytterbium research below.
