Yb:GDVO4is a crystalline solid used as a semiconductor and in photo optic applications.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Ytterbium has 2 valency state, +2 +3. The number of electrons in each of Ytterbium's shells is 2, 8, 18, 32, 8, 2 and its electronic configuration is [Xe]4f14 6s2. In its metallic form Ytterbium's CAS number is 7440-64-4 and its standard state at 20 şC is a solid. The Ytterbium atom has a radius of 194 pm and it's Van der Waals radius is unknown. Ytterbium is considered to be fairly toxic. On the periodic table, Ytterbium is a Block F, Group 3, Period 6 element. Ytterbium isbeing applied to numerous fiber amplifier and fiber optic technologies and in various lasing applications. Ytterbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has a single dominant absorption band at 985 in the infra-red making it useful in silicon photocells to directly convert radiant energy to electricity. Ytterbium metal increases its electrical resistance when subjected to very high stresses. This property is used in stress gauges for monitoring ground deformations from earthquakes and nuclear explosions.The name Ytterbium originates after the name for the Swedish village of Ytterby. See Ytterbium research below.
Gadolinium is a Block F, Group 3, Period 6 element. The number of electrons in each of Gadolinium's shells is 2, 8, 18, 25, 9, 2 and its electronic configuration is [Xe] 4f7 5d1 6s2. In its elemental form gadolinium's CAS number is 7440-54-2. The gadolinium atom has a radius of 178.7.pm and it's Van der Waals radius is unknown. Gadolinium is very toxic. Gadolinium is utilized for both its high magnetic moment (7.94µB) and in phosphors and scintillator material. When complexed with EDTA ligands, it is used as an injectable contrast agent for patients undergoing magnetic resonance imaging. With its high magnetic moment, gadolinium can reduce relaxation times and thereby enhance signal intensity. The extra stable half-full 4f electron shell with no low lying energy levels creates applications as an inert phosphor host. Gadolinium can therefore act as hosts for x-ray cassettes and in scintillator materials for computer tomography. Gadolinium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Gadolinium was first discovered by Jean de Marignac in 1880. The element is named after the Finnish chemist and geologist Johan Gadolin. See Gadolinium research below. Gadolinium is a Block F, Group 3, Period 6 element. The number of electrons in each of Gadolinium's shells is 2, 8, 18, 25, 9, 2 and its electronic configuration is [Xe] 4f7 5d1 6s2. In its elemental form gadolinium's CAS number is 7440-54-2. The gadolinium atom has a radius of 178.7.pm and it's Van der Waals radius is unknown. Gadolinium is very toxic. Gadolinium is utilized for both its high magnetic moment (7.94µB) and in phosphors and scintillator material. When complexed with EDTA ligands, it is used as an injectable contrast agent for patients undergoing magnetic resonance imaging. Gadolinium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Gadolinium was first discovered by Jean de Marignac in 1880. See Gadolinium research below.
Vanadium is a Block D, Group 5, Period 4 element. The number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electronic configuration is [Ar] 3d3 4s2. In its elemental form vanadium's CAS number is 7440-62-2. The vanadium atom has a radius of 131.1.pm and it's Van der Waals radius is 200.pm. Several vanadium compounds are toxic to some creatures despite the fact that it is an essential trace element. Vanadium is highly resistant to corrosion, so it is commonly used to alloy stainless steel grades. Vanadium compounds are used in advanced ceramics. Vanadium is a petrochemical cracking catalyst. Vanadium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Vanadium information, including Technical Data, Safety Data and its high purity properties , research , applications and other useful facts are discussed here . Scientific facts such as the atomic structure, ionization energy , abundance on Earth , conductivity and thermal properties are included. Vanadium was first discovered in Mexico City by Andres Manuel del Rio, a Spanish born and European educated Mexican mineralogist, in 1801. In honor of its beautiful multi-colored compounds, Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology. See Vanadium research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
Crystal "pulling" by the Czochaiski method for production of semiconductor materials
Flux growth and gradient freeze
Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
Controlled excitation of scar modes in passive and active multimode chaotic fiber.
Michel C, Doya V, Tascu S, Blanc W, Legrand O, Mortessagne F.
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High-power nanosecond ytterbium-doped fiber laser passively synchronized with a femtosecond Ti:sapphire laser.
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Femtosecond and picosecond laser drilling of metals at high repetition rates and average powers.
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Ytterbium(III) triflate catalyzed tandem Friedel-Crafts alkylation/hydroarylation of propargylic alcohols with phenols as an expedient route to indenols.
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Complexation of bisphosphonates with ytterbium(III): Application of phosphate and ATP detection assay based on Yb(3+)-pyrocatechol violet.
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Single-frequency 1 W hybrid Brillouin/ytterbium fiber laser.
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Intense green and red upconversion emissions from Ho(3+) in presence of Yb(3+) in Li:TeO(2) glass.
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Spectrochim Acta A Mol Biomol Spectrosc. 2009 Sep 19. [Epub ahead of print]
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Single-frequency 1060 nm semiconductor-optical-amplifier-based fiber laser with 40 nm tuning range.
Tang M, Tian X, Lu X, Fu S, Shum PP, Zhang Z, Liu M, Cheng Y, Liu J.
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Appl Opt. 2009 Oct 10;48(29):5484-9. doi: 10.1364/AO.48.005484.
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Lewis Acid-Mediated beta-Hydride Abstraction Reactions of Divalent M(C(SiHMe(2))(3))(2)THF(2) (M = Ca, Yb).
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Observation of a large atomic parity violation effect in ytterbium.
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Synthesis and characterization of Sn(II), Pb(II) and Yb(II) complexes supported by [C(Ph(2)P=NSiMe3){6-(2-RC5H3N)}]2- or [CH(Ph2P=NSiMe3){6-(2-RC5H3N)}]- (R = 3,5-dimethyl-1-pyrazolyl or iminophosphoranyl) ligands.
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Observation of extreme temporal events in CW-pumped supercontinuum.
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Synthesis, structure, and reaction chemistry of samarium(II), europium(II), and ytterbium(II) complexes of the unsymmetrical benzamidinate ligand [PhC(NSiMe(3))(NC(6)H(3)Pr(i)(2)-2,6)](-).
Yao S, Chan HS, Lam CK, Lee HK.
Inorg Chem. 2009 Oct 19;48(20):9936-46.
PMID: 19757783 [PubMed - in process]
Broadly tunable carrier envelope phase stable optical parametric amplifier pumped by a monolithic ytterbium fiber amplifier.
Fernández A, Zhu L, Verhoef AJ, Sidorov-Biryukov D, Pugzlys A, Baltuska A, Liao KH, Liu ChH, Galvanauskas A, Kane S, Holzwarth R, Ilday FO.
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Structure and photophysics of near-infrared emissive ytterbium(III) monoporphyrinate acetate complexes having neutral bidentate ligands.
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Dalton Trans. 2009 Sep 28;(36):7454-61. Epub 2009 Jul 27.
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BaLn2Se4 (Ln = Er, Tm and Yb).
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Acta Crystallogr C. 2009 Sep;65(Pt 9):i60-2. Epub 2009 Aug 22.
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Experimental investigation of radiation effect on erbium-ytterbium co-doped fiber amplifier for space optical communication in low-dose radiation environment.
Ma J, Li M, Tan L, Zhou Y, Yu S, Ran Q.
Opt Express. 2009 Aug 31;17(18):15571-7. doi: 10.1364/OE.17.015571.
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Quantum-limited noise performance of a femtosecond all-fiber ytterbium laser.
Prochnow O, Paschotta R, Benkler E, Morgner U, Neumann J, Wandt D, Kracht D.
Opt Express. 2009 Aug 31;17(18):15525-33. doi: 10.1364/OE.17.015525.
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T(1) assessment of hip joint cartilage following intra-articular
gadolinium injection: A pilot study. Bittersohl B, Hosalkar HS, Kim YJ, Werlen S, Trattnig S, Siebenrock KA,
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The
time window of MRI of murine atherosclerotic plaques after administration of CB2
receptor targeted micelles: inter-scan variability and relation between plaque
signal intensity increase and gadolinium content of inversion recovery prepared
versus non-prepared fast spin echo. Te Boekhorst BC, Bovens SM, van de Kolk CW, Cramer MJ, Doevendans PA, Ten Hove
M, van der Weerd L, Poelmann R, Strijkers GJ, Pasterkamp G, van Echteld CJ. NMR Biomed. 2010 Oct;23(8):939-51. PubMed
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Coordination chemistry of amide-functionalised
tetraazamacrocycles: structural, relaxometric and cytotoxicity studies. Martinelli J, Balali-Mood B, Panizzo R, Lythgoe MF, White AJ, Ferretti P,
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Gadolinium released from MR contrast
agents is deposited in brain tumors: in situ demonstration using scanning
electron microscopy with energy dispersive X-ray spectroscopy. Xia D, Davis RL, Crawford JA, Abraham JL. Acta Radiol. 2010
Sep 26. [Epub ahead of print] PubMed PMID: 20868305.
Midregional
pro-atrial natriuretic peptide: a novel marker of myocardial fibrosis in patients
with hypertrophic cardiomyopathy. Elmas E, Doesch C, Fluechter S, Freundt M, Weiss C, Lang S, Kälsch T, Haghi D,
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Translocator Protein PET
Imaging for Glial Activation in Multiple Sclerosis. Oh U, Fujita M, Ikonomidou VN, Evangelou IE, Matsuura E, Harberts E, Ohayon J,
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Influence of small caliber coronary arteries on the diagnostic accuracy of
adenosine stress cardiac magnetic resonance imaging. Pilz G, Heer T, Graw M, Ali E, Klos M, Scheck R, Zeymer U, Höfling B. Clin Res Cardiol. 2010 Sep
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Reference region-based pharmacokinetic modeling in quantitative dynamic
contract-enhanced MRI allows robust treatment monitoring in a rat liver tumor
model despite cardiovascular changes. Steingoetter A, Svensson J, Kosanke Y, Botnar RM, Schwaiger M, Rummeny E,
Braren R. Magn Reson Med. 2010 Sep 24. [Epub ahead of
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Comparison of half-dose and full-dose
gadolinium MR contrast on the enhancement of bone and soft tissue tumors.
Costelloe CM, Murphy WA Jr, Haygood TM, Kumar R, McEnery KW, Stafford RJ, Roy
A, Bassett RL Jr, Harrell RK, Madewell JE. Skeletal Radiol. 2010 Sep 24. [Epub ahead of print] PubMed PMID: 20862469.
Gd-EOB-DTPA enhanced MR
imaging: Evaluation of biliary and renal excretion in normal and cirrhotic
livers. Tamada T, Ito K, Sone T, Kanki A, Sato T, Higashi H. Eur J Radiol. 2010 Sep 23. [Epub ahead of print] PubMed PMID: 20869827.
Increases
in the number of brain metastases detected at frame-fixed, thin-slice MRI for
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BOLD
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Revisiting an old friend: manganese-based MRI contrast agents. Pan D, Caruthers SD, Senpan A, Schmieder AH, Wickline SA, Lanza GM. Wiley Interdiscip
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Childhood cholesteatoma. Nevoux J, Lenoir M, Roger G, Denoyelle F, Ducou Le Pointe H, Garabédian EN.Eur Ann Otorhinolaryngol Head Neck Dis. 2010
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Comparison of portal venous and delayed phases of
gadolinium-enhanced magnetic resonance imaging study of cirrhotic liver for the
detection of contrast washout of hypervascular hepatocellular carcinoma. Cereser L, Furlan A, Bagatto D, Girometti R, Como G, Avellini C, Orsaria M,
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Three-dimensional multiphase time-resolved low-dose
contrast-enhanced magnetic resonance angiography using TWIST on a 32-channel coil
at 3 T: a quantitative and qualitative comparison of a conventional gadolinium
chelate with a high-relaxivity agent. Giesel FL, Runge V, Kirchin M, Mehndiratta A, Gerigk L, Corell B, von Gall C,
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[Accessory nerve schwannoma
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Use of cardiac magnetic resonance imaging to evaluate cardiac
structure, function and fibrosis in children with infantile Pompe disease on
enzyme replacement therapy. Barker PC, Pasquali SK, Darty S, Ing RJ, Li JS, Kim RJ, Dearmey S, Kishnani
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Distorted cubic tetranuclear vanadium(iv) phosphonate cages: double-four-ring (D4R) containing transition metal ion phosphonate cages.
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Bioavailability, tissue distribution and hypoglycaemic effect of vanadium in magnesium-deficient rats.
Sánchez C, Torres M, Bermúdez-Peńa MC, Aranda P, Montes-Bayón M, Sanz-Medel A, Llopis J.
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An alternative path for the evolution of biological nitrogen fixation.
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(4-Bromo-2-{[2-(morpholin-4-yl)ethyl-imino]-meth-yl}phenolato)dioxido-vanadium(V).
Wang CY, Wu X, Cao F, Yuan CJ.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1330. Epub 2011 Sep 14.
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A new mixed group 5 metal selenide, Nb(1.41)V(0.59)Se(9).
Lee E, Yun H.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):i50. Epub 2011 Aug 27.
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Catalytic dehydration of xylose to furfural: vanadyl pyrophosphate as source of active soluble species.
Sádaba I, Lima S, Valente AA, López Granados M.
Carbohydr Res. 2011 Oct 8. [Epub ahead of print]
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22055820
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Chemical speciation of vanadium in particulate matter emitted from diesel vehicles and urban atmospheric aerosols.
Shafer MM, Toner B, Overdier J, Schauer JJ, Fakra SC, Herner J, Hu S, Ayala A.
Environ Sci Technol. 2011 Nov 3. [Epub ahead of print]
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Chemical Vapor Deposition Synthesis of Tunable Unsubstituted Polythiophene.
Nejati S, Lau KK.
Langmuir. 2011 Nov 2. [Epub ahead of print]
PMID:
22047472
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VCl(3) catalyzed imine-based multicomponent reactions for the facile access of functionalized tetrahydropyridines and ß-amino carbonyls.
Pal S, Choudhury LH, Parvin T.
Mol Divers. 2011 Nov 1. [Epub ahead of print]
PMID:
22042610
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Interplay between the structural and magnetic probes in the elucidation of the structure of a novel 2D layered [V(4)O(4)(OH)(2)(O(2)CC(6)H(4)CO(2))(4)]ˇDMF.
Djerdj I, Skapin SD, Ceh M, Jaglicic Z, Pajic D, Kozlevcar B, Orel B, Orel ZC.
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Interdigitating Organic Bilayers Direct the Short Interlayer Spacing in Hybrid Organic-Inorganic Layered Vanadium Oxide Nanostructures.
Gannon GT, O'Dwyer CP, Larsson JA, Thompson D.
J Phys Chem B. 2011 Oct 31. [Epub ahead of print]
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22040010
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Hepatic megalocytosis due to vanadium inhalation: participation of oxidative stress.
Cano-Gutiérrez G, Acevedo-Nava S, Santamaría A, Altamirano-Lozano M, Cano-Rodríguez MC, Fortoul TI.
Toxicol Ind Health. 2011 Oct 27. [Epub ahead of print]
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Recent perspectives into biochemistry of decavanadate.
Aureliano M, Fct, Algarve UO, Gambelas, Faro 8, Portugal.
World J Biol Chem. 2011 Oct 26;2(10):215-225.
PMID:
22031844
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Association between plate location and plate removal following facial fracture repair.
Kubota Y, Kuroki T, Akita S, Koizumi T, Hasegawa M, Rikihisa N, Mitsukawa N, Satoh K.
J Plast Reconstr Aesthet Surg. 2011 Oct 24. [Epub ahead of print]
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Vanadium Oxide Nanotube Spherical Clusters Prepared on Carbon Fabrics for Energy Storage Applications.
Perera SD, Patel B, Bonso J, Grunewald M, Ferraris JP, Balkus KJ.
ACS Appl Mater Interfaces. 2011 Nov 4. [Epub ahead of print]
PMID:
22029527
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Exchange Interactions Through p-p Stacking in the Lamellar Compound [{Cu(bipy)(en)}{Cu(bipy)(H(2)O)}{VO(3)}(4)](n).
Venegas-Yazigi D, Brown KA, Vega A, Calvo R, Aliaga C, Santana RC, Cardoso-Gil R, Kniep R, Schnelle W, Spodine E.
Inorg Chem. 2011 Oct 25. [Epub ahead of print]
PMID:
22026723
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MCM-41 supported oxo-vanadium(IV) complex: A highly selective heterogeneous catalyst for bromination of hydroxy aromatic compounds in water.
Bhunia S, Saha D, Koner S.
Langmuir. 2011 Oct 25. [Epub ahead of print]
PMID:
22026477
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Electronic Properties of Vanadium-Doped TiO(2).
Islam MM, Bredow T, Gerson A.
Chemphyschem. 2011 Oct 24. doi: 10.1002/cphc.201100557. [Epub ahead of print]
PMID:
22025455
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Design and Redox Function of Conjugated Complexes with Polyanilines or Quinonediimines.
Moriuchi T, Hirao T.
Acc Chem Res. 2011 Oct 24. [Epub ahead of print]
PMID:
22023138
[PubMed - as supplied by publisher]
The Tetrahydrometalate Species VH2(H2), NbH4, and TaH4: Matrix Infrared Spectra and Quantum Chemical Calculations.
Wang X, Andrews L.
J Phys Chem A. 2011 Oct 24. [Epub ahead of print]
PMID:
22017260
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