| Ytterbium doped Yttrium Aluminum Garnet (Yb:YAG) is a crystalline solid used in photo optic applications. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting frelevant units of measurement.
 Ytterbium has 2 valency state, +2 +3. The number of electrons in each of Ytterbium's shells is 2, 8, 18, 32, 8, 2 and its electronic configuration is [Xe]4f14 6s2. In its metallic form Ytterbium's CAS number is 7440-64-4 and its standard state at 20 ºC is a solid. The Ytterbium atom has a radius of 194 pm and it's Van der Waals radius is unknown. Ytterbium is considered to be fairly toxic. On the periodic table, Ytterbium is a Block F, Group 3, Period 6  element. Ytterbium is being applied to numerous fiber amplifier and fiber optic technologies and in various lasing applications. Ytterbium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It has a single dominant absorption band at 985 in the infra-red making it useful in silicon photocells to directly convert radiant energy to electricity. Ytterbium metal increases its electrical resistance when subjected to very high stresses. This property is used in stress gauges for monitoring ground deformations from earthquakes and nuclear explosions.The name Ytterbium originates after the name for the Swedish village of Ytterby. See Ytterbium research below.
 Yttrium is a Block D, Group 3, Period 5 element. The number of electrons in each of Yttrium's shells is 2, 8, 18, 9, 2 and its electronic configuration is [Kr] 4d1 5s2. In its elemental form Yttrium's CAS number is 7440-65-5. The yttrium atom has a radius of 177.6.pm and it's Van der Waals radius is 200.pm. Insoluble compounds of Yttrium are non-toxic, although water soluble compounds are somewhat toxic. Yttrium has the highest thermo-dynamic affinity for oxygen of any element. This characteristic is the basis for many of its applications. While not part of the rare earth series, it resembles the heavy rare earths which are sometimes referred to as the “yttrics” for this reason. Another unique characteristic derives from its ability to form crystals with useful properties.  Yttrium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Some of the many applications of yttrium include in ceramics for crucibles for molten reactive metals, in florescent lighting phosphors, computer displays and automotive fuel consumption sensors.Yttria stabilized zirconium oxide are used in high temperature applications, such as in thermal plasma sprays to protect aerospace high temperature surfaces and as an electrolyte in solid oxide fuel cells. The name Yttrium originated from a Swedish village near Vaxholm called Yttbery where Yttrium was discovered. Crystals of the yttrium-iron-garnet (YIG) variety are essential to microwave communication equipment. The phosphor Eu:Y2O2S creates the red color in televisions. Crystals of the yttrium-aluminum-garnet (YAG) variety are utilized with neodymium in a number of laser applications. Yttria can also increase the strength of metallic alloys. Yttrium was first discovered by Johann Gadolin in 1794. See Yttrium research below.
 Aluminum is a Block P, Group 13, Period 3 element. The number of electrons in each of Aluminum's shells is 2, 8, 3 and its electronic configuration is [Ne] 3s2 3p1. In its elemental form aluminum's CAS number is 7429-90-5. The aluminum atom has a radius of 143.2.pm and it's Van der Waals radius is 200.pm. Aluminum is not known to be harmful but ingestion may cause Alzheimer's disease.Aluminum is a silvery-white metal that possesses many desirable characteristics. It is light, nonmagnetic and nonsparking.
It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Although it's electrical conductivity is only about 60% that of copper, it is used in electrical transmission  lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements impart a variety of useful properties. These alloys are of vital importance in the construction of modern aircraft and rockets. Aluminum, evaporated in a vacuum, forms a highly reflective coating for both visible light and radiant heat. They are used to coat telescope mirrors. Aluminum is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. See Aluminum research below.
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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES |
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
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Recent Research & Development for Ytterbium
- Bis(?(2)-2-phen-oxy-propionato-?O:O')bis-[(1,10-phenanthroline-?N,N')bis-(2-phen-oxy-propionato-?O,O')ytterbium(III)].
Shen JB, Liu JL, Zhao GL.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1361. Epub 2011 Sep 14.
PMID:
22058692
[PubMed]
- "Covalency in the 4f Shell of tris-cyclopentadienyl Ytterbium (YbCp3) - a Spectroscopic Evaluation."
Denning RG, Harmer JR, Green JC, Irwin M.
J Am Chem Soc. 2011 Nov 4. [Epub ahead of print]
PMID:
22053917
[PubMed - as supplied by publisher]
- Fingermark detection on non-porous and semi-porous surfaces using YVO(4):Er,Yb luminescent upconverting particles.
Ma R, Shimmon R, McDonagh A, Maynard P, Lennard C, Roux C.
Forensic Sci Int. 2011 Oct 31. [Epub ahead of print]
PMID:
22047749
[PubMed - as supplied by publisher]
- Synthesis, Structure, and Reactivity of a Supramolecular Ytterbium(III)-Aqua Complex Featuring Infinite Stacks of C?C Bonds for Photocycloaddition Reactions.
Komori-Orisaku K, Yamashita S, Isozaki T, Sugiura K, Koide Y.
Chemistry. 2011 Oct 21. doi: 10.1002/chem.201102292. [Epub ahead of print] No abstract available.
PMID:
22021148
[PubMed - as supplied by publisher]
- Label-free in vivo fiber-based optical-resolution photoacoustic microscopy.
Hajireza P, Shi W, Zemp RJ.
Opt Lett. 2011 Oct 15;36(20):4107-9. doi: 10.1364/OL.36.004107.
PMID:
22002401
[PubMed - in process]
- Energy transfer and enhanced 1.54 ?m emission in Erbium-Ytterbium disilicate thin films.
Miritello M, Cardile P, Lo Savio R, Priolo F.
Opt Express. 2011 Oct 10;19(21):20761-72. doi: 10.1364/OE.19.020761.
PMID:
21997086
[PubMed - in process]
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Mattsson KE.
Opt Express. 2011 Oct 10;19(21):19797-812. doi: 10.1364/OE.19.019797.
PMID:
21996988
[PubMed - in process]
- Beam quality and noise properties of coherently combined ytterbium doped single frequency fiber amplifiers.
Tünnermann H, Pöld JH, Neumann J, Kracht D, Willke B, Wessels P.
Opt Express. 2011 Sep 26;19(20):19600-6. doi: 10.1364/OE.19.019600.
PMID:
21996901
[PubMed - in process]
- p-Wave Cold Collisions in an Optical Lattice Clock.
Lemke ND, von Stecher J, Sherman JA, Rey AM, Oates CW, Ludlow AD.
Phys Rev Lett. 2011 Sep 2;107(10):103902. Epub 2011 Aug 30.
PMID:
21981504
[PubMed - in process]
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Lhermite J, Lecaplain C, Machinet G, Royon R, Hideur A, Cormier E.
Opt Lett. 2011 Oct 1;36(19):3819-21. doi: 10.1364/OL.36.003819.
PMID:
21964108
[PubMed - in process]
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Samanta D, Sankar RM, Jaisankar SN, Alam MS, Mandal AB.
Chem Commun (Camb). 2011 Oct 25;47(43):11975-7. Epub 2011 Sep 30.
PMID:
21963934
[PubMed - in process]
- Electrochemical spectroscopic investigations on the interaction of an ytterbium complex with DNA and their analytical applications such as biosensor.
Ilkhani H, Ganjali MR, Arvand M, Hejazi MS, Azimi F, Norouzi P.
Int J Biol Macromol. 2011 Dec 1;49(5):1117-23. Epub 2011 Sep 16.
PMID:
21939686
[PubMed - in process]
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Feltham HL, Klöwer F, Cameron SA, Larsen DS, Lan Y, Tropiano M, Faulkner S, Powell AK, Brooker S.
Dalton Trans. 2011 Oct 25;40(43):11425-32. Epub 2011 Sep 21.
PMID:
21935549
[PubMed - in process]
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Lee WK, Park CY, Yu DH, Park SE, Lee SB, Kwon TY.
Opt Express. 2011 Aug 29;19(18):17453-61. doi: 10.1364/OE.19.017453.
PMID:
21935111
[PubMed - in process]
- In vivo near-realtime volumetric optical-resolution photoacoustic microscopy using a high-repetition-rate nanosecond fiber-laser.
Shi W, Hajireza P, Shao P, Forbrich A, Zemp RJ.
Opt Express. 2011 Aug 29;19(18):17143-50. doi: 10.1364/OE.19.017143.
PMID:
21935076
[PubMed - in process]
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Pekarek S, Südmeyer T, Lecomte S, Kundermann S, Dudley JM, Keller U.
Opt Express. 2011 Aug 15;19(17):16491-7. doi: 10.1364/OE.19.016491.
PMID:
21935013
[PubMed - in process]
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Fan Y, He B, Zhou J, Zheng J, Liu H, Wei Y, Dong J, Lou Q.
Opt Express. 2011 Aug 1;19(16):15162-72. doi: 10.1364/OE.19.015162.
PMID:
21934878
[PubMed - in process]
- Background-free broadband CARS spectroscopy from a 1-MHz ytterbium laser.
Kumar V, Osellame R, Ramponi R, Cerullo G, Marangoni M.
Opt Express. 2011 Aug 1;19(16):15143-8. doi: 10.1364/OE.19.015143.
PMID:
21934875
[PubMed - in process]
- Fabrication and characterization of new Yb-doped zirconia-germano-alumino silicate phase-separated nano-particles based fibers.
Kir'yanov AV, Paul MC, Barmenkov YO, Das S, Pal M, Bhadra SK, Zarate LE, Guzman-Chavez AD.
Opt Express. 2011 Aug 1;19(16):14823-37. doi: 10.1364/OE.19.014823.
PMID:
21934843
[PubMed - in process]
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Strek W, Marciniak L, Bednarkiewicz A, Lukowiak A, Wiglusz R, Hreniak D.
Opt Express. 2011 Jul 18;19(15):14083-92. doi: 10.1364/OE.19.014083.
PMID:
21934770
[PubMed - in process]
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Recent Research & Development for Yttrium
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Lee Y, Choi EH, Lee SW.
Dermatol Surg. 2011 Sep 7. doi: 10.1111/j.1524-4725.2011.02147.x. [Epub ahead of print]
PMID:
22093176
[PubMed - as supplied by publisher]
- Successful Treatment of Cosmetic Mucosal Tattoos Via Q-Switched Laser.
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PMID:
22093036
[PubMed - as supplied by publisher]
- Letter: successful treatment of multiple miliary osteomas of the face using an erbium-doped yttrium aluminum garnet laser.
Ortiz AE, Ross EV.
Dermatol Surg. 2011 Oct;37(10):1548-50. doi: 10.1111/j.1524-4725.2011.02112.x.
PMID:
22092945
[PubMed - in process]
- Commentary on Treatment of Acne Scars in Asian Patients using a 2,790-nm Fractional Yttrium Scandium Gallium Garnet Laser.
Perez M.
Dermatol Surg. 2011 Oct;37(10):1470-2. doi: 10.1111/j.1524-4725.2011.02116.x. No abstract available.
PMID:
22092942
[PubMed - in process]
- Fractional Thermoablation Using an Erbium-Doped Yttrium Aluminum Garnet Fractionated Laser for the Treatment of Pulsed Dye Laser-Resistant Port Wine Stain Birthmarks.
Toren KL, Marquart JD.
Dermatol Surg. 2011 Sep 14. doi: 10.1111/j.1524-4725.2011.02160.x. [Epub ahead of print] No abstract available.
PMID:
22092921
[PubMed - as supplied by publisher]
- The effect of erbium-doped: yttrium, aluminium and garnet laser irradiation on the surface microstructure and roughness of double acid-etched implants.
Kim JH, Herr Y, Chung JH, Shin SI, Kwon YH.
J Periodontal Implant Sci. 2011 Oct;41(5):234-41. Epub 2011 Oct 31.
PMID:
22087414
[PubMed - in process]
- 120-W 2-?m THULIUM:YTTRIUM-ALUMINIUM-GARNET VAPOENUCLEATION OF THE PROSTATE: 12-MONTH FOLLOW-UP.
Muir G.
BJU Int. 2011 Nov 15. doi: 10.1111/j.1464-410X.2011.10816.x. [Epub ahead of print] No abstract available.
PMID:
22085314
[PubMed - as supplied by publisher]
- 120-W 2-µm thulium:yttrium-aluminium-garnet vapoenucleation of the prostate: 12-month follow-up.
Netsch C, Pohlmann L, Herrmann TR, Gross AJ, Bach T.
BJU Int. 2011 Nov 15. doi: 10.1111/j.1464-410X.2011.10767.x. [Epub ahead of print]
PMID:
22085294
[PubMed - as supplied by publisher]
- An Unusual Organoyttrium Alkyl Complex Containing a [C(5) HMe(3) (?(3) -CH(2) )-C(5) H(4) N-?](-) Ligand and an Elusive Cyclopentadienide-Based Scandium Tuck-Over Zwitterion Obtained by C?H Bond Activation.
Jian Z, Cui D.
Chemistry. 2011 Nov 14. doi: 10.1002/chem.201102378. [Epub ahead of print]
PMID:
22083978
[PubMed - as supplied by publisher]
- Radioembolization versus Standard Care of Hepatic Metastases: Comparative Retrospective Cohort Study of Survival Outcomes and Adverse Events in Salvage Patients.
Bester L, Meteling B, Pocock N, Pavlakis N, Chua TC, Saxena A, Morris DL.
J Vasc Interv Radiol. 2011 Nov 11. [Epub ahead of print]
PMID:
22079516
[PubMed - as supplied by publisher]
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Elschot M, Nijsen JF, Dam AJ, de Jong HW.
PLoS One. 2011;6(11):e26174. Epub 2011 Nov 3.
PMID:
22073149
[PubMed - in process]
- Lasers or light sources for treating port-wine stains.
Faurschou A, Olesen AB, Leonardi-Bee J, Haedersdal M.
Cochrane Database Syst Rev. 2011 Nov 9;11:CD007152.
PMID:
22071834
[PubMed - in process]
- Treating and Downstaging Hepatocellular Carcinoma in the Caudate Lobe with Yttrium-90 Radioembolization.
Ibrahim SM, Kulik L, Baker T, Ryu RK, Mulcahy MF, Abecassis M, Salem R, Lewandowski RJ.
Cardiovasc Intervent Radiol. 2011 Nov 9. [Epub ahead of print]
PMID:
22069121
[PubMed - as supplied by publisher]
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Zhang J.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1206-7. Epub 2011 Aug 6.
PMID:
22065643
[PubMed]
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Kao YH, Tan EH, Ng CE, Goh SW.
Clin Nucl Med. 2011 Dec;36(12):e186-7.
PMID:
22064104
[PubMed - in process]
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Kaneko H, Nagae H, Tsurugi H, Mashima K.
J Am Chem Soc. 2011 Nov 7. [Epub ahead of print]
PMID:
22059504
[PubMed - as supplied by publisher]
- Catalytic, Enantioselective Intramolecular Hydroamination of Primary Amines Tethered to Di- and Tri-substituted Alkenes.
Chapurina Y, Ibrahim H, Guillot R, Kolodziej E, Collin J, Trifonov A, Schulz E, Hannedouche J.
J Org Chem. 2011 Nov 7. [Epub ahead of print]
PMID:
22059438
[PubMed - as supplied by publisher]
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Ma Y, Wang T, Wu J, Feng Y, Xu W, Jiang L, Zheng J, Shu C, Wang C.
Nanoscale. 2011 Nov 7. [Epub ahead of print]
PMID:
22057827
[PubMed - as supplied by publisher]
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Galizia MS, Töre HG, Chalian H, McCarthy R, Salem R, Yaghmai V.
Acad Radiol. 2011 Nov 2. [Epub ahead of print]
PMID:
22054801
[PubMed - as supplied by publisher]
- Q-switched laser treatment of amiodarone pigmentation.
Bernstein EF.
J Drugs Dermatol. 2011 Nov 1;10(11):1316-9.
PMID:
22052315
[PubMed - in process]
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Recent Research & Development for Aluminum
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Material Safety Data Sheet |
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1 Identification of substance
- Product details
- Trade name Ytterbium (III) acetate
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2 Composition/Data on components:
- Chemical characterization:
Designation: (CAS#)
Ytterbium (III) acetate, hydrate (CAS# 15280-58-7), 100%
- Identification number(s):
- EINECS Number: 244-137-6
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3 Hazards identification
- Hazard designation: · void
- Information pertaining to particular dangers for man and environment
Not applicable
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4 First aid measures
- After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
- After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
- After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
- After swallowing Seek medical treatment.
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5 Fire fighting measures
- Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet.
- Special hazards caused by the material, its products of combustion or
flue gases:
Can be released in case of fire:
Carbon monoxide and carbon dioxide
- Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
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6 Accidental release measures
- Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
- Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
- Measures for cleaning/collecting: Collect mechanically.
- Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
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7 Handling and storage
- Handling
- Information for safe handling:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
No special precautions necessary if used correctly.
- Information about protection against explosions and fires:
No special measures required.
- Storage
- Requirements to be met by storerooms and containers:
No special requirements.
- Information about storage in one common storage facility:
Store away from oxidizing agents.
Store away from water.
- Further information about storage conditions:
This product is hygroscopic.
Protect from humidity and keep away from water.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
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8 Exposure controls and personal protection
- Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
- Components with critical values that require monitoring at the
workplace:
Not required.
- Additional information: No data
- Personal protective equipment
- General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
- Breathing equipment: Use breathing protection with high concentrations.
- Protection of hands: Impervious gloves
- Eye protection: Safety glasses
- Body protection: Protective work clothing.
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9 Physical and chemical properties:
- General Information
- Form: Crystalline aggregates
- Colour: White
- Smell: Odourless
- Value/Range Unit Method
- Change in condition
- Melting point/Melting range: 100 ° C (loses H2O)
- Boiling point/Boiling range: Not determined
- Sublimation temperature / start: Not determined
- Flash point: Not applicable
- Ignition temperature: Not determined
- Decomposition temperature: Not determined
- Danger of explosion: Product is not explosive.
- Critical values for explosion:
- Lower: Not determined
- Upper: Not determined
- Steam pressure: Not determined
- Density Not determined
- Solubility in / Miscibility with
- Water: Soluble
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10 Stability and reactivity
- Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
- Materials to be avoided:
Oxidizing agents
Water/moisture
- Dangerous reactions: No dangerous reactions known
- Dangerous products of decomposition:
Carbon monoxide and carbon dioxide
Metal oxide
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11 Toxicological information
- Acute toxicity:
- Primary irritant effect:
- on the skin: May cause irritation
- on the eye: May cause irritation
- Sensitization: No sensitizing effect known.
- Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
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12 Ecological information:
- General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
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13 Disposal considerations
- Product:
- Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
- Uncleaned packagings:
- Recommendation:
Disposal must be made according to official regulations.
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14 Transport information
- Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
- ADR/RID-GGVS/E Class: None
- Maritime transport IMDG/GGVSea:
- IMDG/GGVSea Class: None
- Air transport ICAO-TI and IATA-DGR:
- ICAO/IATA Class: None
- Transport/Additional information:
Not dangerous according to the above specifications.
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15 Regulatory information
- Designation according to EC guidelines:
Observe the normal safety regulations when handling chemicals
The product is not subject to identification regulations under EC Directives and the Ordinance on Hazardous Materials (GefStoffV).
- National regulations
- Information about limitation of use:
For use only by technically qualified individuals.
- Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
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16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
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