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Yttrium Nitrate
Y(NO 3)3.xH2O
Product
Product Code
Order or Specifications
99% Yttrium Nitrate
Y-N-01
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99.9% Yttrium Nitrate
Y-N-03
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99.99% Yttrium Nitrate
Y-N-04
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99.999% Yttrium Nitrate
Y-N-05
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Yttrium Nitrate is a highly water soluble crystalline Yttrium source for uses compatible with nitrates and lower (acidic) pH. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Yttrium has the highest thermo-dynamic affinity for oxygen, useful in ceramics for crucibles for molten reactive metals, in florescent phosphors, computer displays and automotive fuel sensors. Yttria stabilized zirconia is used in high temperature applications and as an electrolyte in fuel cells. Yttrium Nitrate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Yttrium Nitrate Solution. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Yttrium is a Block D, Group 3, Period 5 element. The electronic configuration is [Kr] 4d1 5s2. In its elemental form yttrium's CAS number is 7440-65-5. The yttrium atom has a radius of 177.6.pm and it's Van der Waals radius is 200.pm. Yttrium has the highest thermo-dynamic affinity for oxygen of any element. This characteristic is the basis for many of its applications. While not part of the rare earth series, it resembles the heavy rare earths which are sometimes referred to as the “yttrics” for this reason. Another unique characteristic derives from its ability to form crystals with useful properties. Yttrium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Some of the many applications of yttrium include in ceramics for crucibles for molten reactive metals, in florescent lighting phosphors, computer displays and automotive fuel consumption sensors.Yttria stabilized zirconium oxide are used in high temperature applications, such as in thermal plasma sprays to protect aerospace high temperature surfaces and as an electrolyte in solid oxide fuel cells.

Formula CAS No. Appearance Molecular Weight Density Melting Point Boiling Point Solubility Stability
Y(NO3)3.xH2O 13494-98-9 White 274.92       Soluble in water, moderately soluble in strong mineral acids Slightly hygroscopic
PRODUCT CATALOG Yttrium Research, Properties, & Information Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. MSDS
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Recent Research & Development for Yttrium

  • Liver transplantation after radioembolization in a patient with unresectable HCC. Luna LE, Kwo PY, Roberts LR, Mettler TA, Gansen DN, Andrews JC, Wiseman GA, Misra VL. Nat Rev Gastroenterol Hepatol. 2009 Nov;6(11):679-83. PMID: 19881519 [PubMed - in process]

  • Assessment of Neodymium:Yttrium-Aluminum-Garnet (Nd:YAG) laser fiber wear and tear grade during visual laser ablation of prostatic adenoma. Rózanski W, Klimek L, Jablonowski Z, Sosnowski M. Photomed Laser Surg. 2009 Oct;27(5):799-805. PMID: 19878030 [PubMed - in process]

  • Yttrium-90 Radiotherapy for Unresectable Intrahepatic Cholangiocarcinoma: A Preliminary Assessment of This Novel Treatment Option. Saxena A, Bester L, Chua TC, Chu FC, Morris DL. Ann Surg Oncol. 2009 Oct 30. [Epub ahead of print] PMID: 19876691 [PubMed - as supplied by publisher]

  • Hepatic vein tumor thrombus as a risk factor for excessive pulmonary deposition of microspheres during TheraSphere therapy for unresectable hepatocellular carcinoma. Fleming CJ, Andrews JC, Wiseman GA, Gansen DN, Roberts LR. J Vasc Interv Radiol. 2009 Nov;20(11):1460-3. PMID: 19875064 [PubMed - in process]

  • Genotoxic effects of 1064-nm Nd:YAG and 532-nm KTP lasers on fibroblast cell cultures. Senturk N, Bedir A, Bilgici B, Aydin F, Okuyucu A, Ozmen ZC, Turanli AY. Clin Exp Dermatol. 2009 Oct 23. [Epub ahead of print] PMID: 19874333 [PubMed - as supplied by publisher]

  • Axillary hair removal with 1064-nm Nd:YAG laser increases sweat production. Aydin F, Pancar GS, Senturk N, Bek Y, Yuksel EP, Canturk T, Turanli AY. Clin Exp Dermatol. 2009 Oct 23. [Epub ahead of print] PMID: 19874331 [PubMed - as supplied by publisher]

  • The management of treatment-resistant biliary calculi using percutaneous endourologic techniques. Ray AA, Davies ET, Duvdevani M, Razvi H, Denstedt JD. Can J Surg. 2009 Oct;52(5):407-12. PMID: 19865576 [PubMed - in process]

  • [Liver chemoembolization: an update.] Roche A. Bull Cancer. 2009 Oct 29. [Epub ahead of print] French. PMID: 19864205 [PubMed - as supplied by publisher]

  • Results of intraocular lens implantation with capsular tension ring in subluxated crystalline or cataractous lenses in children. Das P, Ram J, Brar GS, Dogra MR. Indian J Ophthalmol. 2009 Nov-Dec;57(6):431-6. PMID: 19861744 [PubMed - in process]

  • Quantitative PCR Analysis for Bcl-2/IgH in a Phase III Study of Yttrium-90 Ibritumomab Tiuxetan As Consolidation of First Remission in Patients With Follicular Lymphoma. Goff L, Summers K, Iqbal S, Kuhlmann J, Kunz M, Louton T, Hagenbeek A, Morschhauser F, Putz B, Lister A, Rohatiner A. J Clin Oncol. 2009 Oct 26. [Epub ahead of print] PMID: 19858392 [PubMed - as supplied by publisher]

  • Optimization of Radioembolic Effect with Extended-shelf-life Yttrium-90 Microspheres: Results from a Pilot Study. Lewandowski RJ, Riaz A, Ryu RK, Mulcahy MF, Sato KT, Kulik LM, Gates VL, Baker T, Omary R, Salem R. J Vasc Interv Radiol. 2009 Oct 23. [Epub ahead of print] PMID: 19854068 [PubMed - as supplied by publisher]

  • The Role of Tumor Vascularity in Predicting Survival after Yttrium-90 Radioembolization for Liver Metastases. Sato KT, Omary RA, Takehana C, Ibrahim S, Lewandowski RJ, Ryu RK, Salem R. J Vasc Interv Radiol. 2009 Oct 19. [Epub ahead of print] PMID: 19846320 [PubMed - as supplied by publisher]

  • Safety and Efficacy Assessment of Flow Redistribution by Occlusion of Intrahepatic Vessels Prior to Radioembolization in the Treatment of Liver Tumors. Bilbao JI, Garrastachu P, Herráiz MJ, Rodríguez M, Ińarrairaegui M, Rodríguez J, Hernández C, de la Cuesta AM, Arbizu J, Sangro B. Cardiovasc Intervent Radiol. 2009 Oct 20. [Epub ahead of print] PMID: 19841973 [PubMed - as supplied by publisher]

  • Radioimmunotherapy for stem cell transplantation in non-Hodgkin's lymphoma: in pursuit of a complete response. Gisselbrecht C, Vose J, Nademanee A, Gianni AM, Nagler A. Oncologist. 2009;14 Suppl 2:41-51. PMID: 19819923 [PubMed - in process]

  • Rationale for consolidation to improve progression-free survival in patients with non-Hodgkin's lymphoma: a review of the evidence. Morschhauser F, Dreyling M, Rohatiner A, Hagemeister F, Bischof Delaloye A. Oncologist. 2009;14 Suppl 2:17-29. PMID: 19819921 [PubMed - in process]

  • Harnessing the energy: development of radioimmunotherapy for patients with non-Hodgkin's lymphoma. Gregory SA, Hohloch K, Gisselbrecht C, Tobinai K, Dreyling M. Oncologist. 2009;14 Suppl 2:4-16. PMID: 19819920 [PubMed - in process]

  • Imaging in targeted delivery of therapy to cancer. Dancey G, Begent RH, Meyer T. Target Oncol. 2009 Oct 8. [Epub ahead of print] PMID: 19838639 [PubMed - as supplied by publisher]

  • Polymerization of Enantiopure Monomers Using Syndiospecific Catalysts: A New Approach To Sequence Control in Polymer Synthesis. Kramer JW, Treitler DS, Dunn EW, Castro PM, Roisnel T, Thomas CM, Coates GW. J Am Chem Soc. 2009 Oct 16. [Epub ahead of print] PMID: 19835375 [PubMed - as supplied by publisher]

  • [Minimally invasive tumor ablation in the liver] Wybranski C, Mohnike K, Ricke J. Anasthesiol Intensivmed Notfallmed Schmerzther. 2009 Oct;44(10):670-7; quiz 679. Epub 2009 Oct 15. German. PMID: 19834832 [PubMed - in process]

  • Intraarticular adalimumab in a patient with pigmented villonodular synovitis. Kobak S. Rheumatol Int. 2009 Oct 10. [Epub ahead of print] PMID: 19820943 [PubMed - as supplied by publisher]

 

Material Safety Data Sheet
  • 1 Identification of substance

    • Product details

    • Trade name Yttrium nitrate
  • 2 Composition/Data on components:

    • Chemical characterization:
                 Designation: (CAS#)                                        
      Yttrium nitrate, hexahydrate (CAS# 13494-98-9), 100%
    • Identification number(s):
    • EINECS Number: 233-802-6
  • 3 Hazards identification

    • Hazard designation:
      Xi Irritant
      O  Oxidising
    • Information pertaining to particular dangers for man and environment
      R 8        Contact with combustible material may cause fire.
      R 36/37/38 Irritating to eyes, respiratory system and skin.
  • 4 First aid measures

    • After inhalation
      Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
      Seek immediate medical advice.
    • After skin contact
      Instantly wash with water and soap and rinse thoroughly.
      Seek immediate medical advice.
    • After eye contact
      Rinse opened eye for several minutes under running water. Then consult doctor.
    • After swallowing Seek immediate medical advice.
  • 5 Fire fighting measures

    • Suitable extinguishing agents
      CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
    • Special hazards caused by the material, its products of combustion or
        flue gases:
      This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
      Can be released in case of fire:
      Nitrogen oxides (NOx)
    • Protective equipment:
      Wear self-contained breathing apparatus.
      Wear full protective suit.
  • 6 Accidental release measures

    • Person-related safety precautions:
      Wear protective equipment. Keep unprotected persons away.
      Ensure adequate ventilation
    • Measures for environmental protection:
      Do not allow material to be released to the environment without proper governmental permits.
    • Measures for cleaning/collecting: Ensure adequate ventilation.
    • Additional information:
      See Section 7 for information on safe handling
      See section 8 for information on personal protection equipment.
      See Section 13 for information on disposal.
  • 7 Handling and storage


    • Handling
    • Information for safe handling:
      Keep containers tightly sealed.
      Store in cool, dry place in tightly closed containers.
      Ensure good ventilation/exhaustion at the workplace.
    • Information about protection against explosions and fires:
      Substance/product can reduce the ignition temperature of flammable substances.
      This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.

    • Storage
    • Requirements to be met by storerooms and containers:
      No special requirements.
    • Information about storage in one common storage facility:
      Store away from flammable substances.
      Store away from reducing agents.
    • Further information about storage conditions:
      This product is hygroscopic.
      Protect from humidity and keep away from water.
      Keep container tightly sealed.
      Store in cool, dry conditions in well sealed containers.
  • 8 Exposure controls and personal protection

    • Additional information about design of technical systems:
      Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

    • Components with critical values that require monitoring at the
      workplace:                                                             

      Yttrium and compounds, as Y
                             mg/m3
      ACGIH TLV             1
      Austria MAK           1
      Belgium TWA           1
      Denmark TWA           1
      Finland TWA           1
      France VME            1
      Germany TWA           5
      Korea TLV             1
      Netherlands MAC-TGG   1
      Norway TWA            1
      Poland TWA            1
      Switzerland MAK-W     1
      United Kingdom TWA    1; 3-STEL
      OSHA PEL              1
    • Additional information: No data

    • Personal protective equipment
    • General protective and hygienic measures
      The usual precautionary measures should be adhered to in handling the chemicals.
      Keep away from foodstuffs, beverages and food.
      Instantly remove any soiled and impregnated garments.
      Wash hands during breaks and at the end of the work.
      Avoid contact with the eyes and skin.
    • Breathing equipment: Use breathing protection with high concentrations.
    • Protection of hands: Impervious gloves
    • Eye protection:
      Safety glasses
      Face protection
    • Body protection: Protective work clothing.
  • 9 Physical and chemical properties:

    • General Information

    • Form: Crystalline
    • Colour: Whitish
    • Smell: Odourless
    •   Value/Range  Unit    Method      
    • Change in condition
    • Melting point/Melting range:                   100 ° C     (-3H2O)
    • Boiling point/Boiling range:       Not determined
    • Sublimation temperature / start:   Not determined

    • Flash point:                       Not applicable

    • Ignition temperature:              Not determined

    • Decomposition temperature:         Not determined

    • Critical values for explosion:
    • Lower:                             Not determined
    • Upper:                             Not determined

    • Steam pressure:                    Not determined

    • Density                at   20 ° C            2.68 g/cm³

    • Solubility in / Miscibility with
    • Water:                 at   22 ° C            1347 g/l
  • 10 Stability and reactivity

    • Thermal decomposition / conditions to be avoided:
      No decomposition if used and stored according to specifications.
    • Materials to be avoided:
      Reducing agents, easily oxidized materials
      Organic materials
      Aluminum and aluminum alloys.
    • Dangerous reactions:
      Reacts with reducing agents
      Reacts with flammable substances
    • Dangerous products of decomposition: Nitrous vitriol gases
  • 11 Toxicological information

    • Acute toxicity:
    • Primary irritant effect:
    • on the skin: Irritant for skin and mucous membranes.
    • on the eye: Irritant effect.
    • Sensitization: No sensitizing effect known.
    • Additional toxicological information:
      To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
      No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
  • 12 Ecological information:

    • General notes:
      Do not allow material to be released to the environment without proper governmental permits.
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
      Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
  • 13 Disposal considerations


    • Product:
    • Recommendation
      Consult state, local or national regulations for proper disposal.
      Hand over to disposers of hazardous waste.
      Must be specially treated under adherence to official regulations.

    • Uncleaned packagings:
    • Recommendation:
      Disposal must be made according to official regulations.
    • Recommended cleaning agent: Water, if necessary with cleaning agent.
  • 14 Transport information


    • Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
    • ADR/RID-GGVS/E Class:     5.1 (O2) Oxidizing substances.
    • Kemler Number:            50
    • UN-Number:                1477
    • Packaging group:          III
    • Label                     5.1
    • Designation of goods:     1477 NITRATES, INORGANIC, N.O.S. (yttrium
                                 nitrate)

    • Maritime transport IMDG/GGVSea:
    • IMDG/GGVSea Class:        5.1
    • UN Number:                1477
    • Label                     5.1
    • Packaging group:          III
    • Correct technical name:   NITRATES, INORGANIC, N.O.S.

    • Air transport ICAO-TI and IATA-DGR:
    • ICAO/IATA Class:          5.1
    • UN/ID Number:             1477
    • Label                     5.1
    • Packaging group:          III
    • Correct technical name:   NITRATES, INORGANIC, N.O.S.
  • 15 Regulatory information


    • Designation according to EC guidelines:

    • Code letter and hazard designation of product:
      Xi Irritant O Oxidising

    • Risk phrases:
      8        Contact with combustible material may cause fire.
      36/37/38 Irritating to eyes, respiratory system and skin.

    • Safety phrases:
      17       Keep away from combustible material.
      26       In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
      36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

    • National regulations

    • Information about limitation of use:
      For use only by technically qualified individuals.
      Employment restrictions concerning young persons must be observed.

    • Water hazard class:
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
  • 16 Other information:

      Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees.  This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
  •  

     

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