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Yttrium
Yttrium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Yttrium has the highest thermo-dynamic affinity for oxygen of any element. This characteristic is the basis for many of its applications. While not part of the rare earth series, it resembles the heavy rare earths which are sometimes referred to as the “yttrics” for this reason. Another unique characteristic derives from its ability to form crystals with useful properties. Yttrium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Some of the many applications of yttrium include in ceramics for crucibles for molten reactive metals, in florescent lighting phosphors, computer displays and automotive fuel consumption sensors.Yttria stabilized zirconium oxide are used in high temperature applications, such as in thermal plasma sprays to protect aerospace high temperature surfaces and as an electrolyte in solid oxide fuel cells. Crystals of the yttrium-iron-garnet (YIG) variety are essential to microwave communication equipment. The phosphor Eu:Y2O2S creates the red color in televisions. Crystals of the yttrium-aluminum-garnet (YAG) variety are utilized with neodymium in a number of laser applications. Yttria can also increase the strength of metallic alloys.

Yttrium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Yttrium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Yttrium is a Block D, Group 3, Period 5 element. The electronic configuration is [Kr] 4d1 5s2. In its elemental form yttrium's CAS number is 7440-65-5. The yttrium atom has a radius of 177.6.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Yttrium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Yttrium was first discovered by Johann Gadolin in 1794.

French Yttrium German Yttrium Italian ittrio Portuguese Itrio Spanish Ytrio Swedish Yttrium

Abundance. The following table shows the abundance of yttrium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Y-89
88.905848
100

Safety Data. The safety data for yttrium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for yttrium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
599.86 kJ mol-1
2nd Ionization Energy
1180.99 kJ mol-1
3rd Ionization Energy
1979.89 kJ mol-1

Conductivity. As to yttrium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 57 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.22. The thermal conductivity of yttrium is 17.2 W m-1 K-1.

Thermal Properties. The melting point and boiling point for yttrium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
17.2 kJ mol-1
Heat of Vaporization
367.4 kJ mol-1
Heat of Atomization
420.45 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Y 39 88.9059 g.mol -1 1.2 4.47 g.cm-3 at 20 °C 1500 °C 3336 °C 200.pm Unknown 599.86 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Yttrium

  • Liver transplantation after radioembolization in a patient with unresectable HCC. Luna LE, Kwo PY, Roberts LR, Mettler TA, Gansen DN, Andrews JC, Wiseman GA, Misra VL. Nat Rev Gastroenterol Hepatol. 2009 Nov;6(11):679-83. PMID: 19881519 [PubMed - in process]

  • Assessment of Neodymium:Yttrium-Aluminum-Garnet (Nd:YAG) laser fiber wear and tear grade during visual laser ablation of prostatic adenoma. Rózanski W, Klimek L, Jablonowski Z, Sosnowski M. Photomed Laser Surg. 2009 Oct;27(5):799-805. PMID: 19878030 [PubMed - in process]

  • Yttrium-90 Radiotherapy for Unresectable Intrahepatic Cholangiocarcinoma: A Preliminary Assessment of This Novel Treatment Option. Saxena A, Bester L, Chua TC, Chu FC, Morris DL. Ann Surg Oncol. 2009 Oct 30. [Epub ahead of print] PMID: 19876691 [PubMed - as supplied by publisher]

  • Hepatic vein tumor thrombus as a risk factor for excessive pulmonary deposition of microspheres during TheraSphere therapy for unresectable hepatocellular carcinoma. Fleming CJ, Andrews JC, Wiseman GA, Gansen DN, Roberts LR. J Vasc Interv Radiol. 2009 Nov;20(11):1460-3. PMID: 19875064 [PubMed - in process]

  • Genotoxic effects of 1064-nm Nd:YAG and 532-nm KTP lasers on fibroblast cell cultures. Senturk N, Bedir A, Bilgici B, Aydin F, Okuyucu A, Ozmen ZC, Turanli AY. Clin Exp Dermatol. 2009 Oct 23. [Epub ahead of print] PMID: 19874333 [PubMed - as supplied by publisher]

  • Axillary hair removal with 1064-nm Nd:YAG laser increases sweat production. Aydin F, Pancar GS, Senturk N, Bek Y, Yuksel EP, Canturk T, Turanli AY. Clin Exp Dermatol. 2009 Oct 23. [Epub ahead of print] PMID: 19874331 [PubMed - as supplied by publisher]

  • The management of treatment-resistant biliary calculi using percutaneous endourologic techniques. Ray AA, Davies ET, Duvdevani M, Razvi H, Denstedt JD. Can J Surg. 2009 Oct;52(5):407-12. PMID: 19865576 [PubMed - in process]

  • [Liver chemoembolization: an update.] Roche A. Bull Cancer. 2009 Oct 29. [Epub ahead of print] French. PMID: 19864205 [PubMed - as supplied by publisher]

  • Results of intraocular lens implantation with capsular tension ring in subluxated crystalline or cataractous lenses in children. Das P, Ram J, Brar GS, Dogra MR. Indian J Ophthalmol. 2009 Nov-Dec;57(6):431-6. PMID: 19861744 [PubMed - in process]

  • Quantitative PCR Analysis for Bcl-2/IgH in a Phase III Study of Yttrium-90 Ibritumomab Tiuxetan As Consolidation of First Remission in Patients With Follicular Lymphoma. Goff L, Summers K, Iqbal S, Kuhlmann J, Kunz M, Louton T, Hagenbeek A, Morschhauser F, Putz B, Lister A, Rohatiner A. J Clin Oncol. 2009 Oct 26. [Epub ahead of print] PMID: 19858392 [PubMed - as supplied by publisher]

  • Optimization of Radioembolic Effect with Extended-shelf-life Yttrium-90 Microspheres: Results from a Pilot Study. Lewandowski RJ, Riaz A, Ryu RK, Mulcahy MF, Sato KT, Kulik LM, Gates VL, Baker T, Omary R, Salem R. J Vasc Interv Radiol. 2009 Oct 23. [Epub ahead of print] PMID: 19854068 [PubMed - as supplied by publisher]

  • The Role of Tumor Vascularity in Predicting Survival after Yttrium-90 Radioembolization for Liver Metastases. Sato KT, Omary RA, Takehana C, Ibrahim S, Lewandowski RJ, Ryu RK, Salem R. J Vasc Interv Radiol. 2009 Oct 19. [Epub ahead of print] PMID: 19846320 [PubMed - as supplied by publisher]

  • Safety and Efficacy Assessment of Flow Redistribution by Occlusion of Intrahepatic Vessels Prior to Radioembolization in the Treatment of Liver Tumors. Bilbao JI, Garrastachu P, Herráiz MJ, Rodríguez M, Iñarrairaegui M, Rodríguez J, Hernández C, de la Cuesta AM, Arbizu J, Sangro B. Cardiovasc Intervent Radiol. 2009 Oct 20. [Epub ahead of print] PMID: 19841973 [PubMed - as supplied by publisher]

  • Radioimmunotherapy for stem cell transplantation in non-Hodgkin's lymphoma: in pursuit of a complete response. Gisselbrecht C, Vose J, Nademanee A, Gianni AM, Nagler A. Oncologist. 2009;14 Suppl 2:41-51. PMID: 19819923 [PubMed - in process]

  • Rationale for consolidation to improve progression-free survival in patients with non-Hodgkin's lymphoma: a review of the evidence. Morschhauser F, Dreyling M, Rohatiner A, Hagemeister F, Bischof Delaloye A. Oncologist. 2009;14 Suppl 2:17-29. PMID: 19819921 [PubMed - in process]

  • Harnessing the energy: development of radioimmunotherapy for patients with non-Hodgkin's lymphoma. Gregory SA, Hohloch K, Gisselbrecht C, Tobinai K, Dreyling M. Oncologist. 2009;14 Suppl 2:4-16. PMID: 19819920 [PubMed - in process]

  • Imaging in targeted delivery of therapy to cancer. Dancey G, Begent RH, Meyer T. Target Oncol. 2009 Oct 8. [Epub ahead of print] PMID: 19838639 [PubMed - as supplied by publisher]

  • Polymerization of Enantiopure Monomers Using Syndiospecific Catalysts: A New Approach To Sequence Control in Polymer Synthesis. Kramer JW, Treitler DS, Dunn EW, Castro PM, Roisnel T, Thomas CM, Coates GW. J Am Chem Soc. 2009 Oct 16. [Epub ahead of print] PMID: 19835375 [PubMed - as supplied by publisher]

  • [Minimally invasive tumor ablation in the liver] Wybranski C, Mohnike K, Ricke J. Anasthesiol Intensivmed Notfallmed Schmerzther. 2009 Oct;44(10):670-7; quiz 679. Epub 2009 Oct 15. German. PMID: 19834832 [PubMed - in process]

  • Intraarticular adalimumab in a patient with pigmented villonodular synovitis. Kobak S. Rheumatol Int. 2009 Oct 10. [Epub ahead of print] PMID: 19820943 [PubMed - as supplied by publisher]

 

 

 

 

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