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Yttrium
Yttrium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Yttrium has the highest thermo-dynamic affinity for oxygen of any element. This characteristic is the basis for many of its applications. While not part of the rare earth series, it resembles the heavy rare earths which are sometimes referred to as the “yttrics” for this reason. Another unique characteristic derives from its ability to form crystals with useful properties. Yttrium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Some of the many applications of yttrium include in ceramics for crucibles for molten reactive metals, in florescent lighting phosphors, computer displays and automotive fuel consumption sensors.Yttria stabilized zirconium oxide are used in high temperature applications, such as in thermal plasma sprays to protect aerospace high temperature surfaces and as an electrolyte in solid oxide fuel cells. Crystals of the yttrium-iron-garnet (YIG) variety are essential to microwave communication equipment. The phosphor Eu:Y2O2S creates the red color in televisions. Crystals of the yttrium-aluminum-garnet (YAG) variety are utilized with neodymium in a number of laser applications. Yttria can also increase the strength of metallic alloys.

Yttrium facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Hydrogen Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium    


(click on an element)
available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Yttrium is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Yttrium is a Block D, Group 3, Period 5 element. The electronic configuration is [Kr] 4d1 5s2. In its elemental form yttrium's CAS number is 7440-65-5. The yttrium atom has a radius of 177.6.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Yttrium compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Yttrium was first discovered by Johann Gadolin in 1794.

French Yttrium German Yttrium Italian ittrio Portuguese Itrio Spanish Ytrio Swedish Yttrium

Abundance. The following table shows the abundance of yttrium and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Y-89
88.905848
100

Safety Data. The safety data for yttrium metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Ionization Energy. The ionization energy for yttrium (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
599.86 kJ mol-1
2nd Ionization Energy
1180.99 kJ mol-1
3rd Ionization Energy
1979.89 kJ mol-1

Conductivity. As to yttrium's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 ºC is 57 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.22. The thermal conductivity of yttrium is 17.2 W m-1 K-1.

Thermal Properties. The melting point and boiling point for yttrium are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
17.2 kJ mol-1
Heat of Vaporization
367.4 kJ mol-1
Heat of Atomization
420.45 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Y 39 88.9059 g.mol -1 1.2 4.47 g.cm-3 at 20 °C 1500 °C 3336 °C 200.pm Unknown 599.86 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Yttrium



  • Yttrium pyrogermanate, Y(2)Ge(2)O(7). Acta Crystallogr C. 2007 Oct;63(Pt 10):i93-i95. Epub 2007 Sep 29.

  • Reduction of Arteriohepatovenous Shunting by Temporary Balloon Occlusion in Patients Undergoing Radioembolization. J Vasc Interv Radiol. 2007 Oct;18(10):1310-1314.

  • Tattoo removal - state of the art. J Dtsch Dermatol Ges. 2007 Oct;5(10):889-897.

  • Structural Varieties in Heterobimetallic Lanthanide Disiloxanediolates: "Inorganic Metallocenes" versus In-Plane Metallacrowns. Inorg Chem. 2007 Oct 2; [Epub ahead of print]

  • Steroidal and nonsteroidal antiinflammatory medications can improve photoreceptor survival after laser retinal photocoagulation. Ophthalmology. 2007 Oct;114(10):1876-83.

  • Synthesis and characterisation of yttrium complexes supported by the beta-diketiminate ligand {ArNC(CH3)CHC(CH3)NAr}- (Ar = 2,6-Pr(i)2C6H3). Dalton Trans. 2007 Aug 14;(30):3305-13. Epub 2007 Jun 20.

  • Visual Outcome and Rehabilitation in a Case of Bilateral Acanthamoeba Sclerokeratitis. Cornea. 2007 Oct;26(9):1150-1152.

  • Radioimmunotherapy and stem-cell transplantation in the treatment of aggressive B-cell lymphoma. Leuk Lymphoma. 2007 Sep 19;:1-11 [Epub ahead of print]

  • Computer-assisted evaluation of microleakage after apical resection with laser and conventional techniques. Lasers Med Sci. 2007 Sep 21; [Epub ahead of print]

  • Yttrium 90 ibritumomab tiuxetan (Zevalin(R)): A new bullet in the fight against malignant lymphoma? Biotechnol J. 2007 Sep 20; [Epub ahead of print]

  • Structures and Spectroscopic Properties of Bis(phthalocyaninato) Yttrium and Lanthanum Complexes: Theoretical Study Based on Density Functional Theory Calculations.
    J Phys Chem A Mol Spectrosc Kinet Environ Gen Theory. 2007 Jan 18;111(2):392-400.

  • Office-based and microlaryngeal applications of a fiber-based thulium laser.
    Ann Otol Rhinol Laryngol. 2006 Dec;115(12):891-6.

  • Treatment of cystic craniopharyngiomas with yttrium-90 colloid solution.
    Neurosurg Focus. 1997 Dec 15;3(6):e6.

  • Percutaneous lumbar discectomy with a working endoscope and laser assistance.
    Neurosurg Focus. 1998 Feb 15;4(2):e9.

  • Urinary yttrium excretion and effects of yttrium chloride on renal function in rats.
    Biol Trace Elem Res. 2006 Winter;114(1-3):225-36.

  • A multicentric phase II clinical trial on intra-arterial hepatic radiotherapy with 90yttrium SIR-spheres in unresectable, colorectal liver metastases refractory to i.v. chemotherapy: preliminary results on toxicity and response rates.
    In Vivo. 2006 Nov-Dec;20(6A):711-4.

  • Treatment of gingival hyperpigmentation by erbium-doped:yttrium, aluminum, and garnet laser for esthetic purposes.
    J Periodontol. 2007 Jan;78(1):177-84.

  • Evidence of the efficacy of radiation synovectomy with yttrium-90: Comment on the article by Jahangier et al.
    Arthritis Rheum. 2006 Dec 28;56(1):386 [Epub ahead of print] No abstract available.

  • An HPLC/mass spectrometry platform for the development of multimodality contrast agents and targeted therapeutics: prostate-specific membrane antigen small molecule derivatives.
    Contrast Media Mol Imaging. 2006 Sep;1(5):196-211.

  • Synthesis of yttria-based crystalline and lamellar nanostructures and their formation mechanism.
    Small. 2005 Jan;1(1):112-21.

 

 

 

 

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