Zinc Arsenide is a crystalline solid used as a semiconductor and in photo optic applications.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Zinc is a Block D, Group 12, Period 4 element. The number of electrons in each of Zinc's shells is 2, 8, 18, 2, and its electronic configuration is [Ar] 3d10 4s2. In its elemental form zinc's CAS number is 7440-66-6. The zinc atom has a radius of 133.5.pm and it's Van der Waals radius is 139.pm. Zinc is considered non-toxic in healthy doses but can cause nausea if taken in excess. Zinc is a bluish-white, lustrous metal which we produce in Special High Grade (SHG) purities. It is brittle at ordinary temperatures but malleable at 100 to 150 o C. It is a fair conductor of electricity, and burns in air at high red heat with evolution of white clouds of the oxide. It has unusual electrical, thermal, optical, and solid-state properties that have not been fully investigated. The metal is employed to form numerous alloys with other metals. Brass, nickel, silver, commercial bronze, soft solder, and aluminum solder are some of the more important alloys. Large quantities of zinc are used to produce die castings, which are used extensively by the automotive, electrical, and hardware industries. Zinc is also used extensively togalvanize other metals such as iron to prevent corrosion. Zinc oxide is widely used in the manufacture of paints, rubber products, cosmetics, pharmaceuticals, floor coverings, plastics, printing inks, soap, storage batteries, textiles, electrical equipment, and other products. Zinc sulfide is used in making luminous dials, X-ray and TV screens, and fluorescent lights The chloride and chromate are also important compounds. Zinc is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Zinc was first discovered by Andreas Marggraf in 1746. The element name Zinc originates from the German word "zin" meaning tin. See Zinc research below.
Arsenic is a Block P, Group 15, Period 4 element. The number of electrons in each of Arsenic's shells is 2, 8, 18, 5 and its electronic configuration is [Ar] 3d10 4s2 4p3. In its elemental form arsenic's CAS number is 1327-53-3. The arsenic atom has a radius of 124.5.pm and it's Van der Waals radius is 185.pm. Arsenic in the organic form is not harmful but in the inorganic form it is extremely toxic even in very small amounts. Arsenic has numerous applications as a semiconductor and other electronic applications as Indium arsenide, silicon arsenide and tin arsenidea. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors. Gallium arsenide is used as a laser material to convert electricity directly into coherent light. Arsenic is used in bronzing and for hardening and improving the sphericity of shot. Arsenic is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Arsenic information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. See Arsenic research below.
An arsenide, an anion with the charge -3, is a rare mineral group consisting of compounds of one or more metals with arsenic (As). Arsenide anions have no existence in solution since they are extremely basic. These solid salts have very high lattice energies and are toxic due to the inherent toxicity of arsenic. Arsenides have applications in semiconductors, laser and light-emitting diodes, quantum dots, and optical and pressure sensors.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
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Crystal "pulling" by the Czochaiski method for production of semiconductor materials
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Flux growth and gradient freeze
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Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES |
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
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Recent Research & Development for Zinc
- The PHD Finger of Human UHRF1 Reveals a New Subgroup of Unmethylated Histone H3 Tail Readers.
Lallous N, Legrand P, McEwen AG, Ramón-Maiques S, Samama JP, Birck C.
PLoS One. 2011;6(11):e27599. Epub 2011 Nov 11.
PMID:
22096602
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- The Pharmacological Mechanism of Angiotensin-converting Enzyme Inhibition by Green Tea, Rooibos and Enalaprilat - A Study on Enzyme Kinetics.
Persson IA.
Phytother Res. 2011 Sep 8. doi: 10.1002/ptr.3588. [Epub ahead of print]
PMID:
22095883
[PubMed - as supplied by publisher]
- Chiral Nanoporous Metal-Organic Frameworks with High Porosity as Materials for Drug Delivery.
Sun CY, Qin C, Wang CG, Su ZM, Wang S, Wang XL, Yang GS, Shao KZ, Lan YQ, Wang EB.
Adv Mater. 2011 Nov 18. doi: 10.1002/adma.201102538. [Epub ahead of print]
PMID:
22095878
[PubMed - as supplied by publisher]
- Supramolecular Inclusion Complexes of Two Cyclic Zinc Bisporphyrins with C(60) and C(70) : Structural, Thermodynamic, and Photophysical Characterization.
Hernández-Eguía LP, Escudero-Adán EC, Pintre IC, Ventura B, Flamigni L, Ballester P.
Chemistry. 2011 Nov 17. doi: 10.1002/chem.201101511. [Epub ahead of print]
PMID:
22095593
[PubMed - as supplied by publisher]
- Clinical significance of zinc finger E-box binding homeobox 1 (ZEB1) in human gastric cancer.
Okugawa Y, Toiyama Y, Tanaka K, Matsusita K, Fujikawa H, Saigusa S, Ohi M, Inoue Y, Mohri Y, Uchida K, Kusunoki M.
J Surg Oncol. 2011 Nov 17. doi: 10.1002/jso.22142. [Epub ahead of print]
PMID:
22095522
[PubMed - as supplied by publisher]
- Convenient photooxidation of alcohols using dye sensitised zinc oxide in combination with silver nitrate and TEMPO.
Jeena V, Robinson RS.
Chem Commun (Camb). 2011 Nov 18. [Epub ahead of print]
PMID:
22095311
[PubMed - as supplied by publisher]
- Controlled delivery of basal level of insulin from chitosan-zinc-insulin-complex-loaded thermosensitive copolymer.
Oak M, Singh J.
J Pharm Sci. 2011 Nov 17. doi: 10.1002/jps.22823. [Epub ahead of print]
PMID:
22095295
[PubMed - as supplied by publisher]
- An important minority of prediabetic first-degree relatives of type 1 diabetic patients derives from seroconversion to persistent autoantibody positivity after 10 years of age.
Vermeulen I, Weets I, Costa O, Asanghanwa M, Verhaeghen K, Decochez K, Ruige J, Casteels K, Wenzlau J, Hutton JC, Pipeleers DG, Gorus FK; the Belgian Diabetes Registry.
Diabetologia. 2011 Nov 18. [Epub ahead of print]
PMID:
22095238
[PubMed - as supplied by publisher]
- Comparative kinome analysis to identify putative colon tumor biomarkers.
Hennig EE, Mikula M, Rubel T, Dadlez M, Ostrowski J.
J Mol Med (Berl). 2011 Nov 18. [Epub ahead of print]
PMID:
22095101
[PubMed - as supplied by publisher]
- Zinc and the ERK Kinases in the Developing Brain.
Nuttall JR, Oteiza PI.
Neurotox Res. 2011 Nov 18. [Epub ahead of print]
PMID:
22095091
[PubMed - as supplied by publisher]
- Exploring the microbial metalloproteome using MIRAGE.
Sevcenco AM, Pinkse MW, Wolterbeek HT, Verhaert PD, Hagen WR, Hagedoorn PL.
Metallomics. 2011 Nov 17. [Epub ahead of print]
PMID:
22094925
[PubMed - as supplied by publisher]
- Zinc and Copper Deficiency In The Microvillus Inclusion Disease.
Diamanti A, Basso MS, Candusso M, Panetta F, Gambarara M.
J Pediatr Gastroenterol Nutr. 2011 Nov 15. [Epub ahead of print] No abstract available.
PMID:
22094898
[PubMed - as supplied by publisher]
- Fortified juice drink improved iron and zinc status of schoolchildren.
Angeles-Agdeppa I, Magsadia CR, Capanzana MV.
Asia Pac J Clin Nutr. 2011;20(4):535-43.
PMID:
22094838
[PubMed - in process]
- In situ kinetic study of zinc sulfide activation using a quartz crystal microbalance with dissipation (QCM-D).
Teng F, Liu Q, Zeng H.
J Colloid Interface Sci. 2011 Oct 25. [Epub ahead of print]
PMID:
22093872
[PubMed - as supplied by publisher]
- Preparation and characterization of cobalt-substituted anthrax lethal factor.
Säbel CE, Carbone R, Dabous JR, Lo SY, Siemann S.
Biochem Biophys Res Commun. 2011 Nov 10. [Epub ahead of print]
PMID:
22093822
[PubMed - as supplied by publisher]
- Co-gasification of municipal solid waste and material recovery in a large-scale gasification and melting system.
Tanigaki N, Manako K, Osada M.
Waste Manag. 2011 Nov 15. [Epub ahead of print]
PMID:
22093706
[PubMed - as supplied by publisher]
- [The role of heme oxygenase 1 in hydrogen peroxide induced apoptosis and mitochondrial trans membrane potential change in rat primary typeII alveolar epithelium cells].
Wu Y, Chen M, Wu S, Wang HM, Qian MJ, Wang YH, Fu XY.
Zhongguo Wei Zhong Bing Ji Jiu Yi Xue. 2011 Nov;23(11):658-60. Chinese.
PMID:
22093310
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- Feed consumption, diet digestibility and mineral utilization in captive blackbuck (Antelope cervicapra) fed different levels of concentrates.
Das A, Katole S, Choubey M, Gupta SP, Saini M, Kumar V, Swarup D.
J Anim Physiol Anim Nutr (Berl). 2011 Nov 17. doi: 10.1111/j.1439-0396.2011.01245.x. [Epub ahead of print]
PMID:
22093070
[PubMed - as supplied by publisher]
- An explorative study of non-invasive ultra-weak photon emission and the anti-oxidative influence of oral zinc sulphate in light-sensitive patients with erythropoietic protoporphyria.
Petersen AB, Philipsen PA, Wulf HC.
Skin Res Technol. 2011 Nov 16. doi: 10.1111/j.1600-0846.2011.00586.x. [Epub ahead of print]
PMID:
22092997
[PubMed - as supplied by publisher]
- Metal-mediated affinity and orientation specificity in a computationally designed protein homodimer.
Der BS, Machius M, Miley MJ, Mills JL, Szyperski TA, Kuhlman B.
J Am Chem Soc. 2011 Nov 17. [Epub ahead of print]
PMID:
22092237
[PubMed - as supplied by publisher]
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Recent Research & Development for Arsenate
- Arsenic trioxide treatment decreases the oxygen consumption rate of tumor cells and radiosensitizes solid tumors.
Diepart C, Karroum O, Magat J, Feron O, Verrax J, Buc Calderon P, Grégoire V, Leveque P, Stockis J, Dauguet N, Jordan BF, Gallez B.
Cancer Res. 2011 Dec 2. [Epub ahead of print]
PMID:
22139377
[PubMed - as supplied by publisher]
- Arsenic-Induced Straighthead: An Impending Threat to Sustainable Rice Production in South and South-East Asia!
Azizur Rahman M, Mamunur Rahman M, Hasegawa H.
Bull Environ Contam Toxicol. 2011 Dec 4. [Epub ahead of print]
PMID:
22139332
[PubMed - as supplied by publisher]
- Comparative Soil Metal Analyses in Sudbury (Ontario, Canada) and Lubumbashi (Katanga, DR-Congo).
Narendrula R, Nkongolo KK, Beckett P.
Bull Environ Contam Toxicol. 2011 Dec 4. [Epub ahead of print]
PMID:
22139330
[PubMed - as supplied by publisher]
- Purification, crystallization and preliminary X-ray diffraction studies of the arsenic repressor ArsR from Corynebacterium glutamicum.
Santha S, Pandaranayaka EP, Rosen BP, Thiyagarajan S.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Dec 1;67(Pt 12):1616-8. Epub 2011 Nov 26.
PMID:
22139180
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- Arsenic contamination and speciation in surrounding waters of three old cinnabar mines.
Larios R, Fernández-Martínez R, Silva V, Loredo J, Rucandio I.
J Environ Monit. 2011 Dec 5. [Epub ahead of print]
PMID:
22139034
[PubMed - as supplied by publisher]
- Arsenic Exposure and Hypertension: A Systematic Review.
Abhyankar LN, Jones MR, Guallar E, Navas-Acien A.
Environ Health Perspect. 2011 Dec 2. [Epub ahead of print]
PMID:
22138666
[PubMed - as supplied by publisher]
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Metals in biology: defining metalloproteomes.
Yannone SM, Hartung S, Menon AL, Adams MW, Tainer JA.
Curr Opin Biotechnol. 2011 Dec 2. [Epub ahead of print]
PMID:
22138493
[PubMed - as supplied by publisher]
- Total and inorganic arsenic concentrations in different species of economically important algae harvested from coastal zones of Chile.
Díaz O, Tapia Y, Muñoz O, Montoro R, Velez D, Almela C.
Food Chem Toxicol. 2011 Nov 25. [Epub ahead of print]
PMID:
22138359
[PubMed - as supplied by publisher]
- Zamzam water: Concentration of trace elements and other characteristics.
Shomar B.
Chemosphere. 2011 Dec 2. [Epub ahead of print]
PMID:
22138338
[PubMed - as supplied by publisher]
- Removal of methylated arsenic using a nanostructured zirconia-based sorbent: Process performance and adsorption chemistry.
Zheng YM, Yu L, Chen JP.
J Colloid Interface Sci. 2011 Oct 12. [Epub ahead of print]
PMID:
22137855
[PubMed - as supplied by publisher]
- Humans seem to produce arsenobetaine and dimethylarsinate after a bolus dose of seafood.
Molin M, Ulven SM, Dahl L, Telle-Hansen VH, Holck M, Skjegstad G, Ledsaak O, Sloth JJ, Goessler W, Oshaug A, Alexander J, Fliegel D, Ydersbond TA, Meltzer HM.
Environ Res. 2011 Dec 1. [Epub ahead of print]
PMID:
22137101
[PubMed - as supplied by publisher]
- A modified batch reactor system to study equilibrium-reactive transport problems.
Jeppu GP, Clement TP, Barnett MO, Lee KK.
J Contam Hydrol. 2011 Oct 20. [Epub ahead of print]
PMID:
22136983
[PubMed - as supplied by publisher]
- Identification of the GST-T1 and GST-M1 Null Genotypes using High Resolution Melting Analysis.
Drobna Z, Del Razo LM, Garcia-Vargas G, Sanchez-Ramirez B, Gonzalez-Horta C, Ballinas ML, Loomis D, Styblo M.
Chem Res Toxicol. 2011 Dec 2. [Epub ahead of print]
PMID:
22136492
[PubMed - as supplied by publisher]
- Uranium and trace elements in phosphate fertilizers-saudi arabia.
Khater AE.
Health Phys. 2012 Jan;102(1):63-70.
PMID:
22134079
[PubMed - in process]
- Natural attenuation of arsenic in soils near a highly contaminated historical mine waste dump.
Drahota P, Filippi M, Ettler V, Rohovec J, Mihaljevic M, Sebek O.
Sci Total Environ. 2011 Nov 29. [Epub ahead of print]
PMID:
22134035
[PubMed - as supplied by publisher]
- Removing arsenic from synthetic groundwater with iron electrocoagulation: An Fe and As K-edge EXAFS study.
van Genuchten CM, Addy SE, Pena J, Gadgil A.
Environ Sci Technol. 2011 Dec 1. [Epub ahead of print]
PMID:
22132945
[PubMed - as supplied by publisher]
- Embryotoxicity assessment of developmental neurotoxicants using a neuronal endpoint in the embryonic stem cell test.
Baek DH, Kim TG, Lim HK, Kang JW, Seong SK, Choi SE, Lim SY, Park SH, Nam BH, Kim EH, Kim MS, Park KL.
J Appl Toxicol. 2011 Dec 1. doi: 10.1002/jat.1747. [Epub ahead of print]
PMID:
22131109
[PubMed - as supplied by publisher]
- Comparing different means of signal treatment for improving the detection power in HPLC-ICP-MS.
Prikler S, Pick D, Einax JW.
Anal Bioanal Chem. 2011 Dec 1. [Epub ahead of print]
PMID:
22130722
[PubMed - as supplied by publisher]
- Biological monitoring versus air monitoring strategies in assessing environmental-occupational exposure.
Jakubowski M.
J Environ Monit. 2011 Dec 1. [Epub ahead of print]
PMID:
22130625
[PubMed - as supplied by publisher]
- Overexpression of alfalfa mitochondrial HSP23 in prokaryotic and eukaryotic model systems confers enhanced tolerance to salinity and arsenic stress.
Lee KW, Cha JY, Kim KH, Kim YG, Lee BH, Lee SH.
Biotechnol Lett. 2011 Nov 30. [Epub ahead of print]
PMID:
22127759
[PubMed - as supplied by publisher]
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