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Zirconium Aluminide
ZrAl3
12004-83-0
Product Product Code Order or Specifications
(2N) 99% Zirconium Aluminide ZR-ALI-02 Contact American Elements
(3N) 99.9% Zirconium Aluminide ZR-ALI-03 Contact American Elements
(4N) 99.99% Zirconium Aluminide ZR-ALI-04 Contact American Elements
(5N) 99.999% Zirconium Aluminide ZR-ALI-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
ZrAl3
12004-83-0 34179716 6336544 N/A 234-462-1 aluminum; zirconium N/A [AlH3].[AlH3].[AlH3].[Zr] InChI=1S/3Al.Zr PGLXYLYDLCVKEE-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
Al3Zr 172.168614 N/A g/cm3 170.849319 170.848999023438 Da 0 Safety Data Sheet


Aluminide IonZirconium Aluminide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. As aluminium is near the nonmetals, it bonds with metals differently than other metals, consequently the properties of aluminide compounds are intermediate between those of a metal alloy and an ionic compound.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Zirconium is a Block D, Group 4, Period 5 element. The number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electronic configuration is [Kr] 4d2 5s2. In its elemental form zirconium's CAS number is 7440-67-7. The zirconium atom has a radius of 159.pm and it'sVan der Waals radius is 200.pm. Zirconium is non-toxic. Zirconium is primarily used in it's oxide or zirconia form. Zirconium dioxide has a high melting point (2,700° C) and a low thermal conductivity. Its polymorphism, however, restricts its widespread use in ceramic industry. During a heating process, zirconia will undergo a phase transformation process. The change in volume associated with this transformation makes the usage of pure zirconia in many applications impossible. Addition of some oxides, such as CaO, MgO, and Y2O3, into the zirconia structure in a certain degree results in a solid solution, which is a cubic form and has no phase transformation during heating and cooling. This solid solution material is termed as stabilized zirconia, a valuable refractory. Stabilized zirconia is used as a grinding media and engineering ceramics due to its increased hardness and high thermal shock resistivity. Stabilized zirconia is also used in applications such as oxygen sensors and solid oxide fuel cells due to its high oxygen ion conductivity.Zirconium was first discovered by William Gregor in 1791. See Zirconium research below.

Aluminum(Al) atomic and molecular weight, atomic number and elemental symbolAluminum is a Block P, Group 13, Period 3 element. The number of electrons in each of Aluminum's shells is 2, 8, 3 and its electronic configuration is [Ne] 3s2 3p1. In its elemental form aluminum's CAS number is 7429-90-5. The aluminum atom has a radius of 143.2.pm and it's Van der Waals radius is 200.pm. Aluminum is the most abundant metal in the earth's crust. Aluminum is not known to be harmful but ingestion may cause Alzheimer's disease.Aluminum is a silvery-white metal that possesses many desirable characteristics. It is light, nonmagnetic and nonsparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in manyAluminum Bohr Model industrial applications where a strong, light, easily constructed material is needed. Although it's electrical conductivity is only about 60% that of copper, it is used in electrical transmission Elemental Aluminumlines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements impart a variety of useful properties. These alloys are of vital importance in the construction of modern aircraft and rockets. Aluminum, evaporated in a vacuum, forms a highly reflective coating for both visible light and radiant heat. They are used to coat telescope mirrors. Aluminum is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. See Aluminum research below.

An aluminide contains aluminium and one or more electropositive elements. Since aluminum is similar to the nonmetals, it forms compounds with properties intermediate between a metal alloy and an ionic compound. Aluminides have found applications in hydrogen storage technology, the aeronautical industry, and in coatings for furnaces and other high temperature applications.

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Toxicity
Safety & Handling
             
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
N/A N/A N/A N/A N/A N/A N/A N/A

 

Synonyms for Zirconium Aluminide Include:


Aluminium - zirconium (3:1)
Aluminium, compound with zirconium (3:1)
Zirconium aluminum
Aluminum, compd. with zirconium (3:1)

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 

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Recent Research & Development for Zirconium

  • The effect of ceramic thickness and number of firings on the color of a zirconium oxide based all ceramic system fabricated using CAD/CAM technology. Bachhav VC, Aras MA. J Adv Prosthodont. 2011 Jun;3(2):57-62. Epub 2011 Jun 30. PMID: 21814612 [PubMed - in process]

  • Implant-guided vertical bone growth in the mini-pig. Freilich M, Wen B, Shafer D, Schleier P, Dard M, Pendrys D, Ortiz D, Kuhn L. Clin Oral Implants Res. 2011 Aug 2. doi: 10.1111/j.1600-0501.2011.02199.x. [Epub ahead of print] PMID: 21810121 [PubMed - as supplied by publisher]

  • Absolute calibration method for laser megajoule neutron yield measurement by activation diagnostics. Landoas O, Yu Glebov V, Rosse´ B, Briat M, Disdier L, Sangster TC, Duffy T, Marmouget JG, Varignon C, Ledoux X, Caillaud T, Thfoin I, Bourgade JL. Rev Sci Instrum. 2011 Jul;82(7):073501. PMID: 21806179 [PubMed - as supplied by publisher]

  • Functionalizing porous zirconium terephthalate UiO-66(Zr) for natural gas upgrading: a computational exploration. Yang Q, Wiersum AD, Llewellyn PL, Guillerm V, Serre C, Maurin G. Chem Commun (Camb). 2011 Jul 29. [Epub ahead of print] PMID: 21799981 [PubMed - as supplied by publisher]

  • Effect of surface pre-treatments on the zirconia ceramic-resin cement microtensile bond strength. Casucci A, Monticelli F, Goracci C, Mazzitelli C, Cantoro A, Papacchini F, Ferrari M. Dent Mater. 2011 Jul 26. [Epub ahead of print] PMID: 21798589 [PubMed - as supplied by publisher]

  • Porous Interpenetrated Zirconium-Organic Frameworks (PIZOFs): A Chemically Versatile Family of Metal-Organic Frameworks. Schaate A, Roy P, Preuße T, Lohmeier SJ, Godt A, Behrens P. Chemistry. 2011 Aug 16;17(34):9320-9325. doi: 10.1002/chem.201101015. Epub 2011 Jul 27. PMID: 21796692 [PubMed - as supplied by publisher]

  • [Replacement of extracted tooth by means of implant-supported direct abutment. A case report]. Fazekas R, Fazekas A. Fogorv Sz. 2011 Jun;104(2):49-54. Hungarian. PMID: 21789935 [PubMed - in process]

  • The effect of different power outputs of carbon dioxide laser on bonding between zirconia ceramic surface and resin cement. Ural C, Kalyoncuoglu E, Balkaya V. Acta Odontol Scand. 2011 Jul 25. [Epub ahead of print] PMID: 21780979 [PubMed - as supplied by publisher]

  • Carbon nanotube-zirconium dioxide hybrid for defluoridation of water. Ramamurthy SS, Chen Y, Kalyan MK, Rao GN, Chelli J, Mitra S. J Nanosci Nanotechnol. 2011 Apr;11(4):3552-9. PMID: 21776736 [PubMed - in process]

  • Sulphur mustard degradation on zirconium doped Ti-Fe oxides. Stengl V, Grygar TM, Oplustil F, Nemec T. J Hazard Mater. 2011 Jul 1. [Epub ahead of print] PMID: 21775058 [PubMed - as supplied by publisher]

  • Designing Catalysts for Nitrene Transfer Using Early Transition Metals and Redox-Active Ligands. Heyduk AF, Zarkesh RA, Nguyen AI. Inorg Chem. 2011 Jul 20. [Epub ahead of print] PMID: 21774482 [PubMed - as supplied by publisher]

  • Temperature Rise during Resin Composite Polymerization under Different Ceramic Restorations. Yondem I, Altintas SH, Usumez A. Eur J Dent. 2011 Jul;5(3):305-9. PMID: 21769272 [PubMed - in process]

  • Development of a colorimetric colony-screening assay for detection of defluorination by micro-organisms. Davis CK, Denman SE, Sly LI, McSweeney CS. Lett Appl Microbiol. 2011 Jul 18. doi: 10.1111/j.1472-765X.2011.03123.x. [Epub ahead of print] PMID: 21767280 [PubMed - as supplied by publisher]

  • Laser ultrasonics detection of an embedded crack in a composite spherical particle. Amziane A, Amari M, Mounier D, Breteau JM, Joly N, Banchet J, Tisseur D, Gusev V. Ultrasonics. 2011 Jun 25. [Epub ahead of print] PMID: 21757213 [PubMed - as supplied by publisher]

  • Trichlorido(tetra-hydro-furan){(1,2,3,3a,7a-?)-1-[2-(1-trimethyl-silyl-1H-imidazol-2-yl-?N)-1-methyl-prop-yl]inden-yl}zirconium(IV). Guan S, Nie W, Borzov MV. Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m540-1. Epub 2011 Apr 7. PMID: 21754279 [PubMed]

  • cyclo-Tri-µ-oxido-tris-{[(?,?)-1,2-bis-(cyclo-penta-dien-yl)-1,1,2,2-tetra-methyl-disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene. Arnold T, Braunschweig H, Gruss K. Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m391. Epub 2011 Mar 2. PMID: 21753927 [PubMed]

  • Spectral and fluorescent kinetics features of Nd(3+) ion in Nb(2)O(5), Ta(2)O(5) and La(2)O(3) mixed lithium zirconium silicate glasses. Srikumar T, Brik MG, Srinivasa Rao C, Gandhi Y, Krishna Rao D, Ravi Kumar V, Veeraiah N. Spectrochim Acta A Mol Biomol Spectrosc. 2011 Jun 25. [Epub ahead of print] PMID: 21752699 [PubMed - as supplied by publisher]

  • Tailor-made three-dimensional hybrid scaffolds for cell cultures. Psycharakis S, Tosca A, Melissinaki V, Giakoumaki A, Ranella A. Biomed Mater. 2011 Aug;6(4):045008. Epub 2011 Jul 8. PMID: 21743121 [PubMed - in process]

  • MRI analysis of the component-bone interface after TKA. Heyse TJ, Chong LR, Davis J, Boettner F, Haas SB, Potter HG. Knee. 2011 Jul 7. [Epub ahead of print] PMID: 21741843 [PubMed - as supplied by publisher]

  • Ionothermal Synthesis and Structure Analysis of an Open-Framework Zirconium Phosphate with a High CO(2) /CH(4) Adsorption Ratio. Liu L, Yang J, Li J, Dong J, Sisak D, Luzzatto M, McCusker LB. Angew Chem Int Ed Engl. 2011 Jul 7. doi: 10.1002/anie.201102738. [Epub ahead of print] No abstract available. PMID: 21739548 [PubMed - as supplied by publisher]

 

Recent Research & Development for Aluminide

  • Nanostructure of vortex during explosion welding. Rybin VV, Greenberg BA, Ivanov MA, Patselov AM, Antonova OV, Elkina OA, Inozemtsev AV, Salishchev GA. J Nanosci Nanotechnol. 2011 Oct;11(10):8885-95. PMID: 22400276 [PubMed]

  • Microscopic origin of channeled flow in lamellar titanium aluminide. Katzarov IH, Paxton AT. Phys Rev Lett. 2010 Jun 4;104(22):225502. Epub 2010 Jun 2. PMID: 20867180 [PubMed]

  • In vitro evaluation of human osteoblast adhesion to a thermally oxidized gamma-TiAl intermetallic alloy of composition Ti-48Al-2Cr-2Nb (at.%). Bello SA, de Jesús-Maldonado I, Rosim-Fachini E, Sundaram PA, Diffoot-Carlo N. J Mater Sci Mater Med. 2010 May;21(5):1739-50. Epub 2010 Feb 17. PMID: 20162332 [PubMed - indexed for MEDLINE]

  • Li12Cu16+xAl26-x (x = 3.2): a new intermetallic structure type. Pavlyuk V, Dmytriv G, Tarasiuk I, Pauly H, Ehrenberg H. Acta Crystallogr C. 2008 Aug;64(Pt 8):i73-5. Epub 2008 Jul 26. PMID: 18682632 [PubMed]

  • Li8Cu12+xAl6-x (x = 1.16): a new structure type related to Laves phases. Pavlyuk V, Dmytriv G, Tarasiuk I, Pauly H, Ehrenberg H. Acta Crystallogr C. 2008 Feb;64(Pt 2):i15-7. Epub 2008 Jan 22. PMID: 18252986 [PubMed]

  • Biocompatibility studies of human fetal osteoblast cells cultured on gamma titanium aluminide. Rivera-Denizard O, Diffoot-Carlo N, Navas V, Sundaram PA. J Mater Sci Mater Med. 2008 Jan;19(1):153-8. Epub 2007 Jun 28. PMID: 17597368 [PubMed - indexed for MEDLINE]

  • Bone tissue reaction to Ti-48Al-2Cr-2Nb (at.%) in a rodent model: a preliminary SEM study. Castañeda-Muñoz DF, Sundaram PA, Ramírez N. J Mater Sci Mater Med. 2007 Jul;18(7):1433-8. Epub 2007 Mar 27. PMID: 17387593 [PubMed - indexed for MEDLINE]

  • Microstructural analysis of iron aluminide formed by self-propagating high-temperature synthesis mechanism in aluminium matrix composite. Olszówka-Myalska A, Maziarz W. J Microsc. 2006 Oct;224(Pt 1):1-3. PMID: 17100891 [PubMed]

  • A respiratory model for uranium aluminide based on occupational data. Leggett RW, Eckerman KF, Boice JD Jr. J Radiol Prot. 2005 Dec;25(4):405-16. Epub 2005 Dec 5. PMID: 16340069 [PubMed - indexed for MEDLINE]

  • Self-assembling of atomic vacancies at an oxide/intermetallic alloy interface. Maurice V, Despert G, Zanna S, Bacos MP, Marcus P. Nat Mater. 2004 Oct;3(10):687-91. Epub 2004 Sep 19. PMID: 15378049 [PubMed - indexed for MEDLINE]

  • Composition-structure relationships in polar intermetallics: experimental and theoretical studies of LaNi(1 + x)Al(6 - x) (x = 0.44). Gout D, Benbow E, Gourdon O, Miller GJ. Inorg Chem. 2004 Jul 26;43(15):4604-9. PMID: 15257588 [PubMed]

  • Treatment of compounds and alloys in radiation hydrodynamics simulations of ablative laser loading. Swift DC, Gammel JT, Clegg SM. Phys Rev E Stat Nonlin Soft Matter Phys. 2004 May;69(5 Pt 2):056401. Epub 2004 May 6. PMID: 15244945 [PubMed]

  • RE2MAl6Si4 (RE = Gd, Tb, Dy; M = Au, Pt): layered quaternary intermetallics featuring CaAl2Si2-type and YNiAl4Ge2-type slabs grown from aluminum flux. Latturner SE, Bilc D, Mahanti SD, Kanatzidis MG. Inorg Chem. 2003 Dec 1;42(24):7959-66. PMID: 14632514 [PubMed]

  • Investigations on field-ion image formation and field evaporation sequences of DO3-ordered Fe3Al. Frommeyer G, Liu ZG, Wesemann J, Wanderka N. Ultramicroscopy. 2002 Jul;92(2):57-66. PMID: 12138943 [PubMed]

  • EXAFS study of NiAl in thin films. Arcon I, Mozetic M, Kodre A, Jagielski J, Traverse A. J Synchrotron Radiat. 2001 Mar 1;8(Pt 2):493-5. PMID: 11512827 [PubMed]

  • A new stacking motif: complex alloy structures interpreted as modulated structures. Uchida M, Matsui Y. Acta Crystallogr B. 2000 Aug;56(Pt 4):654-8. PMID: 10944256 [PubMed - indexed for MEDLINE]

  • Strain-induced symmetry breakdown in HOLZ lines from L1(2) titanium tri-aluminides. Rossouw CJ, Tsuda K, Forwood CT, Gibson MA, Tanaka M. J Electron Microsc (Tokyo). 2000;49(5):589-98. PMID: 11110465 [PubMed]

  • [Experience in plasma-detonation coating of the working parts of medical instruments with nickel-aluminide-based alloys]. Matukhnov VM, Shmyreva TP, Altareva GI, Maksimov VK, Machuskaia ND. Med Tekh. 1984 Nov-Dec;(6):34-41. Russian. PMID: 6549405 [PubMed - indexed for MEDLINE]

     

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