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Zirconium Arsenide
ZrAs
60909-47-9
Product Product Code Order or Specifications
(5N) 99.999% Zirconium Arsenide Powder ZR-AS-05-P Contact American Elements
(5N) 99.999% Zirconium Arsenide Ingot ZR-AS-05-I Contact American Elements
(5N) 99.999% Zirconium Arsenide Chunk ZR-AS-05-CK Contact American Elements
(5N) 99.999% Zirconium Arsenide Lump ZR-AS-05-L Contact American Elements
(5N) 99.999% Zirconium Arsenide Sputtering Target ZR-AS-05-ST Contact American Elements
(5N) 99.999% Zirconium Arsenide Wafer ZR-AS-05-WSX Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
ZrAs 60909-47-9 N/A 109033 N/A 262-524-8 arsanylidynezirconium N/A [As]#[Zr] InChI=1S/As.Zr FIJMPJIZAQHCBA-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
AsZr 166.15 N/A N/A 164.8263 164.8263 0 Safety Data Sheet



Arsenide IonZirconium Arsenide is a crystalline solid used as a semiconductor and in photo optic applications.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Zirconium(Zr) atomic and molecular weight, atomic number and elemental symbol Zirconium is a Block D, Group 4, Period 5 element. The number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electronic configuration is [Kr] 4d2 5s2. In its elemental form zirconium's CAS number is 7440-67-7. The zirconium atom has a radius of 159.pm and it's Van der Waals radius is 200.pm. Zirconium is non-toxic. Zirconium’s principal mineral is zircon (Zirconium Silicate) and is primarily used in its oxide or zirconia form. Zirconium dioxide has a high melting point (2,700° C) and a low thermal conductivity. Its polymorphism, however, restricts its widespread use in ceramic industry. During a heating process, zirconia will undergo a phase transformation process. The changeZirconium Bohr Model in volume associated with this transformation makes the usage of pure zirconia in many applications impossible. Addition of some oxides, such as CaO, MgO, and Y2O3, into the zirconia structure in a Elemental Zirconiumcertain degree results in a solid solution, which is a cubic form and has no phase transformation during heating and cooling. This solid solution material is termed as stabilized zirconia, a valuable refractory. Stabilized zirconia is used as a grinding media and engineering ceramics due to its increased hardness and high thermal shock resistivity. Stabilized zirconia is also used in applications such as oxygen sensors and solid oxide fuel cells due to its high oxygen ion conductivity.Zirconium was first discovered by William Gregor in 1791. The name Zirconium originated from the Persian word 'zargun' meaning gold color or gold-like. See Zirconium research below.

Arsenic(As) atomic and molecular weight, atomic number and elemental symbolArsenic is a Block P, Group 15, Period 4 element. The number of electrons in each of Arsenic's shells is 2, 8, 18, 5 and its electronic configuration is [Ar] 3d10 4s2 4p3. In its elemental form arsenic's CAS number is 1327-53-3.Elemental Arsenic The arsenic atom has a radius of 124.5.pm and it's Van der Waals radius is 185.pm. Arsenic in the organic form is not harmful but in the inorganic form it is extremely toxic even in very small amounts. Arsenic has numerous applications as a semiconductor and other electronic applications as Indium arsenide, silicon arsenide and tin arsenidea. Arsenic is finding increasing uses as a doping agent in solid-state devices such as transistors. Gallium arsenide is used as a laser material to convert electricity directly into coherent light. Arsenic is used in bronzing and for hardening and improving the sphericity of shot. Due to its toxicity, arsenic compounds are used in insecticides and wood preservation.Arsenic is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in Arsenic Bohr Modelthe form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Arsenic information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. See Arsenic research below.

An arsenide, an anion with the charge -3, is a rare mineral group consisting of compounds of one or more metals with arsenic (As). Arsenide anions have no existence in solution since they are extremely basic. These solid salts have very high lattice energies and are toxic due to the inherent toxicity of arsenic. Arsenides have applications in semiconductors, laser and light-emitting diodes, quantum dots, and optical and pressure sensors.

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Toxicity
Safety & Handling
 
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
N/A N/A N/A N/A N/A N/A N/A N/A

 

Synonyms for Zirconium Arsenide Include:


Zirconium arsenide (zras)
arsanylidynezirconium

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 

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Recent Research & Development for Zirconium

  • Zirconium arsenate-modified silica nanoparticles for specific capture of phosphopeptides and direct analysis by matrix-assisted laser desorption/ionization mass spectrometry. Zhao PX, Guo XF, Wang H, Qi CB, Xia HS, Zhang HS. Anal Bioanal Chem. 2011 Nov 22. [Epub ahead of print] PMID: 22105300 [PubMed - as supplied by publisher]

  • A surface derivatization strategy for combinatorial analysis of cell response to mixtures of protein domains. Chiang C, Karuri SW, Kshatriya PP, Schwartz J, Schwarzbauer JE, Karuri NW. Langmuir. 2011 Nov 21. [Epub ahead of print] PMID: 22103809 [PubMed - as supplied by publisher]

  • Environmentally stable flexible metal-insulator-metal capacitors using zirconium-silicate and hafnium-silicate thin film composite materials as gate dielectrics. Meena JS, Chu MC, Wu CS, Ravipati S, Ko FH. J Nanosci Nanotechnol. 2011 Aug;11(8):6858-67. PMID: 22103091 [PubMed - in process]

  • Highly sensitive protein kinase activity assay based on electrochemiluminescence nanoprobes. Zhao Z, Zhou X, Xing D. Biosens Bioelectron. 2011 Oct 25. [Epub ahead of print] PMID: 22100765 [PubMed - as supplied by publisher]

  • Corrosion fatigue behavior of a biocompatible ultrafine-grained niobium alloy in simulated body fluid. Rubitschek F, Niendorf T, Karaman I, Maier HJ. J Mech Behav Biomed Mater. 2012 Jan;5(1):181-92. Epub 2011 Sep 8. PMID: 22100093 [PubMed - in process]

  • Fabrication and characterization of biocompatible nacre-like structures from ?-zirconium hydrogen phosphate hydrate and chitosan. Waraich SM, Hering B, Burghard Z, Bill J, Behrens P, Menzel H. J Colloid Interface Sci. 2011 Oct 29. [Epub ahead of print] PMID: 22099057 [PubMed - as supplied by publisher]

  • Wear resistance of experimental titanium alloys for dental applications. Faria AC, Rodrigues RC, Claro AP, de Mattos Mda G, Ribeiro RF. J Mech Behav Biomed Mater. 2011 Nov;4(8):1873-9. Epub 2011 Jun 15. PMID: 22098886 [PubMed - in process]

  • Carbon Fiber-Reinforced Cyanate Ester/Nano-ZrW(2)O(8) Composites with Tailored Thermal Expansion. Badrinarayanan P, Rogalski MK, Kessler MR. ACS Appl Mater Interfaces. 2011 Nov 18. [Epub ahead of print] PMID: 22098430 [PubMed - as supplied by publisher]

  • Single-step fabrication of nanolamellar structured oxide ceramic coatings by metal-organic chemical vapor deposition. Eils NK, Mechnich P, Keune H, Wahl G, Klages CP. J Nanosci Nanotechnol. 2011 Sep;11(9):8396-402. PMID: 22097592 [PubMed - in process]

  • Metalcones: hybrid organic-inorganic films fabricated using atomic and molecular layer deposition techniques. George SM, Lee BH, Yoon B, Abdulagatov AI, Hall RA. J Nanosci Nanotechnol. 2011 Sep;11(9):7948-55. PMID: 22097511 [PubMed - in process]

  • Reliability and fatigue failure modes of implant-supported aluminum-oxide fixed dental prostheses. Stappert CF, Baldassarri M, Zhang Y, Hänssler F, Rekow ED, Van P Thompson. Clin Oral Implants Res. 2011 Sep 5. doi: 10.1111/j.1600-0501.2011.02281.x. [Epub ahead of print] PMID: 22093019 [PubMed - as supplied by publisher]

  • Titanium-zirconium alloy narrow-diameter implants (Straumann Roxolid(®) ) for the rehabilitation of horizontally deficient edentulous ridges: prospective study on 18 consecutive patients. Chiapasco M, Casentini P, Zaniboni M, Corsi E, Anello T. Clin Oral Implants Res. 2011 Aug 18. doi: 10.1111/j.1600-0501.2011.02296.x. [Epub ahead of print] PMID: 22092806 [PubMed - as supplied by publisher]

  • Retention of implant-supported zirconium oxide ceramic restorations using different luting agents. Nejatidanesh F, Savabi O, Shahtoosi M. Clin Oral Implants Res. 2011 Nov 14. doi: 10.1111/j.1600-0501.2011.02358.x. [Epub ahead of print] PMID: 22092303 [PubMed - as supplied by publisher]

  • Tetra-kis(picolinato-?N,O)zirconium(IV) dihydrate. Steyn M, Visser HG, Roodt A, Muller TJ. Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1240-1. Epub 2011 Aug 17. PMID: 22065566 [PubMed]

  • 2,4-Pentanediolate as an Alkoxide/Diketonate "Hybrid" Ligand and the Formation of Aluminum and Zirconium Derivatives. Bierschenk EJ, Wilk NR, Hanusa TP. Inorg Chem. 2011 Nov 4. [Epub ahead of print] PMID: 22053749 [PubMed - as supplied by publisher]

  • Ultrasound-assisted synthesis of mesoporous zirconia-hydroxyapatite nanocomposites and their dual surface affinity for Cr3+/Cr2O72- ions. Achelhi K, Masse S, Laurent GP, Roux C, Laghzizil A, Saoiabi A, Coradin T. Langmuir. 2011 Nov 4. [Epub ahead of print] PMID: 22053732 [PubMed - as supplied by publisher]

  • Synthesis, Characterization, and Materials Chemistry of Group 4 Silylimides. Cosham SD, Johnson AL, Molloy KC, Kingsley AJ. Inorg Chem. 2011 Nov 4. [Epub ahead of print] PMID: 22053704 [PubMed - as supplied by publisher]

  • Influence of cement thickness on resin-zirconia microtensile bond strength. Lee TH, Ahn JS, Shim JS, Han CH, Kim SJ. J Adv Prosthodont. 2011 Sep;3(3):119-25. Epub 2011 Sep 25. PMID: 22053241 [PubMed]

  • Reliability of a new biokinetic model of zirconium in internal dosimetry: part ii, parameter sensitivity analysis. Li WB, Greiter M, Oeh U, Hoeschen C. Health Phys. 2011 Dec;101(6):677-92. PMID: 22048486 [PubMed - in process]

  • Reliability of a new biokinetic model of zirconium in internal dosimetry: part I, parameter uncertainty analysis. Li WB, Greiter M, Oeh U, Hoeschen C. Health Phys. 2011 Dec;101(6):660-76. PMID: 22048485 [PubMed - in process]

Recent Research & Development for Arsenide

  • Local quantum criticality of an iron-pnictide tetrahedron. Ong TT, Coleman P. Phys Rev Lett. 2012 Mar 9;108(10):107201. Epub 2012 Mar 5. PMID: 22463447 [PubMed - in process]

  • The effect of He-Ne and Ga-Al-As laser light on the healing of hard palate mucosa of mice. Fahimipour F, Mahdian M, Houshmand B, Asnaashari M, Sadrabadi AN, Farashah SE, Mousavifard SM, Khojasteh A. Lasers Med Sci. 2012 Mar 14. [Epub ahead of print] PMID: 22415572 [PubMed - as supplied by publisher]

  • Low-Level Laser Therapy Enhances the Stability of Orthodontic Mini-Implants via Bone Formation Related to BMP-2 Expression in a Rat Model. Omasa S, Motoyoshi M, Arai Y, Ejima KI, Shimizu N. Photomed Laser Surg. 2012 Mar 9. [Epub ahead of print] PMID: 22404559 [PubMed - as supplied by publisher]

  • Efficacy of low-intensity laser therapy in reducing treatment time and orthodontic pain: A clinical investigation. Doshi-Mehta G, Bhad-Patil WA. Am J Orthod Dentofacial Orthop. 2012 Mar;141(3):289-97. PMID: 22381489 [PubMed - in process]

  • Light-induced vasodilation of coronary arteries and its possible clinical implication. Plass CA, Loew HG, Podesser BK, Prusa AM. Ann Thorac Surg. 2012 Apr;93(4):1181-6. Epub 2012 Mar 3. PMID: 22381453 [PubMed - in process]

  • Wet Chemical Functionalization of III-V Semiconductor Surfaces: Alkylation of Gallium Arsenide and Gallium Nitride by a Grignard Reaction Sequence. Peczonczyk SL, Mukherjee J, Carim AI, Maldonado S. Langmuir. 2012 Mar 13;28(10):4672-82. Epub 2012 Feb 28. PMID: 22372474 [PubMed - in process]

  • Evaluation of low-level laser therapy in patients with acute and chronic temporomandibular disorders. Salmos-Brito JA, de Menezes RF, Teixeira CE, Gonzaga RK, Rodrigues BH, Braz R, Bessa-Nogueira RV, de Martínez Gerbi ME. Lasers Med Sci. 2012 Feb 25. [Epub ahead of print] PMID: 22367394 [PubMed - as supplied by publisher]

  • Effect of low-level laser therapy (LLLT) on orthodontic tooth movement. Genc G, Kocadereli I, Tasar F, Kilinc K, El S, Sarkarati B. Lasers Med Sci. 2012 Feb 18. [Epub ahead of print] PMID: 22350425 [PubMed - as supplied by publisher]

  • Cu(4.35)Cd(1.65)As(16): the first polyarsenic compound in the Cu-Cd-As system. Osters O, Nilges T. Acta Crystallogr Sect E Struct Rep Online. 2011 Nov 1;67(Pt 11):i62. Epub 2011 Oct 22. PMID: 22219727 [PubMed - in process]

  • Hole spin relaxation in Ge-Si core-shell nanowire qubits. Hu Y, Kuemmeth F, Lieber CM, Marcus CM. Nat Nanotechnol. 2011 Dec 18;7(1):47-50. doi: 10.1038/nnano.2011.234. PMID: 22179569 [PubMed - in process]

  • Analysis of optical absorption in GaAs nanowire arrays. Guo H, Wen L, Li X, Zhao Z, Wang Y. Nanoscale Res Lett. 2011 Dec 6;6:617. PMID: 22145699 [PubMed - in process]

  • GaAs 904-nm laser irradiation improves myofiber mass recovery during regeneration of skeletal muscle previously damaged by crotoxin. Silva LH, Silva MT, Gutierrez RM, Conte TC, Toledo CA, Aoki MS, Liebano RE, Miyabara EH. Lasers Med Sci. 2011 Dec 6. [Epub ahead of print] PMID: 22143119 [PubMed - as supplied by publisher]

  • Non-destructive clinical assessment of occlusal caries lesions using near-IR imaging methods. Staninec M, Douglas SM, Darling CL, Chan K, Kang H, Lee RC, Fried D. Lasers Surg Med. 2011 Dec;43(10):951-9. doi: 10.1002/lsm.21139. Epub 2011 Nov 22. PMID: 22109697 [PubMed - in process]

  • High speed InAs electron avalanche photodiodes overcome the conventional gain-bandwidth product limit. Marshall AR, Ker PJ, Krysa A, David JP, Tan CH. Opt Express. 2011 Nov 7;19(23):23341-9. doi: 10.1364/OE.19.023341. PMID: 22109211 [PubMed]

  • Effects of the combination of low-level laser irradiation and recombinant human bone morphogenetic protein-2 in bone repair. Rosa AP, de Sousa LG, Regalo SC, Issa JP, Barbosa AP, Pitol DL, de Oliveira RH, de Vasconcelos PB, Dias FJ, Chimello DT, Siéssere S. Lasers Med Sci. 2011 Nov 18. [Epub ahead of print] PMID: 22095190 [PubMed - as supplied by publisher]

  • Six-fold hexagonal symmetric nanostructures with various periodic shapes on GaAs substrates for efficient antireflection and hydrophobic properties. Leem JW, Song YM, Yu JS. Nanotechnology. 2011 Dec 2;22(48):485304. Epub 2011 Nov 9. PMID: 22071365 [PubMed]

  • Near-room-temperature mid-infrared quantum well photodetector. Hinds S, Buchanan M, Dudek R, Haffouz S, Laframboise S, Wasilewski Z, Liu HC. Adv Mater. 2011 Dec 8;23(46):5536-9. doi: 10.1002/adma.201103372. Epub 2011 Nov 3. PMID: 22052780 [PubMed - indexed for MEDLINE]

  • Effects of low-level laser therapy in combination with physiotherapy in the management of rotator cuff tendinitis. Eslamian F, Shakouri SK, Ghojazadeh M, Nobari OE, Eftekharsadat B. Lasers Med Sci. 2011 Nov 4. [Epub ahead of print] PMID: 22052627 [PubMed - as supplied by publisher]

  • High T(c) electron doped Ca10(Pt3As8)(Fe2As2)5 and Ca10(Pt4As8)(Fe2As2)5 superconductors with skutterudite intermediary layers. Ni N, Allred JM, Chan BC, Cava RJ. Proc Natl Acad Sci U S A. 2011 Nov 8;108(45):E1019-26. Epub 2011 Oct 31. PMID: 22042837 [PubMed]

  • Quantum confinement effects in nanoscale-thickness InAs membranes. Takei K, Fang H, Kumar SB, Kapadia R, Gao Q, Madsen M, Kim HS, Liu CH, Chueh YL, Plis E, Krishna S, Bechtel HA, Guo J, Javey A. Nano Lett. 2011 Nov 9;11(11):5008-12. Epub 2011 Oct 21. PMID: 22007924 [PubMed - indexed for MEDLINE]

     

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