Zirconyl Nitrate

ZrO(NO3)2·xH2O
CAS 14985-18-3


Product Product Code Order or Specifications
(2N) 99% Zirconyl Nitrate ZR-NAT-02 Contact American Elements
(3N) 99.9% Zirconyl Nitrate ZR-NAT-03 Contact American Elements
(4N) 99.99% Zirconyl Nitrate ZR-NAT-04 Contact American Elements
(5N) 99.999% Zirconyl Nitrate ZR-NAT-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
ZrO(NO3)2·xH2O 14985-18-3 24854506 N/A MFCD00149896 237-529-3 N/A N/A Oxozirconium(2+) nitrate hydrate (1:2:1) InChI=1S/2NO
3.H2O.O.Zr/c2*2-1(3)4;;;/h;;1H2;;/q2*
-1;;;+2
BGMQNYCWAL
SARE-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
H2N2O7Zr 231.23 White Powder 1.415 g/cm3 N/A 231.891 g/mol 0 Safety Data Sheet

Nitrate IonZirconyl Nitrate is a highly water soluble crystalline Zirconium source for uses compatible with nitrates and lower (acidic) pH. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Zirconium Nitrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. We also produce Zirconium Nitrate Solution. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Zirconium (Zr) atomic and molecular weight, atomic number and elemental symbol Zirconium (atomic symbol: Zr, atomic number: 40) is a Block D, Group 4, Period 5 element with an atomic weight of 91.224. Zirconium Bohr ModelThe number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electron configuration is [Kr] 4d2 5s2. The zirconium atom has a radius of 160 pm and a Van der Waals radius of 186 pm. Zirconium was discovered by Martin Heinrich Klaproth in 1789 and first isolated by Jöns Jakob Berzelius in 1824. Elemental ZirconiumIn its elemental form, zirconium has a silvery white appearance that is similar to titanium. Zirconium's principal mineral is zircon (zirconium silicate). Zirconium is commercially produced as a by-product of titanium and tin mining and has many applications as a opacifier and a refractory material. It is not found in nature as a free element. The name of zirconium comes from the mineral zircon, the most important source of zirconium, and from the Persian word 'zargun' meaning gold-like. For more information on zirconium, including properties, safety data, research, and American Elements' catalog of zirconium products, visit the Zirconium Information Center.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Danger
H272-H314
O,C
8-34
17-26-28-36/37/39-45
N/A
UN 3085 5.1/PG 2
1
Flame Over Circle-Oxidizing gases and liquids Corrosion-Corrosive to metals      

ZIRCONYL NITRATE SYNONYMS
Zirconyl nitrate hydrate, Bis(nitrato)oxozirconium, Ketozirconium nitric acid, Zirconium(IV) oxynitrate hydrate, Zirconium dinitrate oxide, Nitric acid oxozirconium, Zirconyl dinitrate, Oxozirconium(2+) nitrate hydrate (1:2:1)

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Zirconium

  • Fei Li, Zhuang Kang, Xiao Huang, Xin-Gang Wang, Guo-Jun Zhang, Preparation of zirconium carbide foam by direct foaming method, Journal of the European Ceramic Society, Volume 34, Issue 15, December 2014
  • Xian Zhang, Zhijun Dong, Qing Huang, Yanjun Li, Xu Zhang, Guanming Yuan, Xuanke Li, Preparation of zirconium diboride powders by co-pyrolysis of a zirconium-containing organic precursor and polyborazine using a solution based method, Ceramics International, Volume 40, Issue 9, Part B, November 2014
  • Wanying Geng, Ge Zhu, Yurong Shi, Yuhua Wang, Luminescent characteristics of Dy3+ doped calcium zirconium phosphate CaZr4(PO4)6 (CZP) phosphor for warm-white LEDs, Journal of Luminescence, Volume 155, November 2014
  • I. Kratochvílová, R. Škoda, J. Škarohlíd, P. Ashcheulov, A. Jäger, J. Racek, A. Taylor, L. Shao, Nanosized polycrystalline diamond cladding for surface protection of zirconium nuclear fuel tubes, Journal of Materials Processing Technology, Volume 214, Issue 11, November 2014
  • R.F.L. Lorenzi, J.E. Zorzi, C.A. Perottoni, Effect of annealing on the elastic moduli of amorphous zirconium tungstate, Journal of Non-Crystalline Solids, Volume 403, 1 November 2014
  • P. Suresh, J. Judith Vijaya, L. John Kennedy, Photocatalytic degradation of textile-dyeing wastewater by using a microwave combustion-synthesized zirconium oxide supported activated carbon, Materials Science in Semiconductor Processing, Volume 27, November 2014
  • Yuliya S. Dzyazko, Ludmila N. Ponomaryova, Yurii M. Volfkovich, Vladimir V. Trachevskii, Alexey V. Palchik, Ion-exchange resin modified with aggregated nanoparticles of zirconium hydrophosphate. Morphology and functional properties, Microporous and Mesoporous Materials, Volume 198, 1 November 2014
  • Sangjoon Ahn, Sandeep Irukuvarghula, Sean M. McDeavitt, Thermophysical investigations of the uranium–zirconium alloy system, Journal of Alloys and Compounds, Volume 611, 25 October 2014
  • Moira Ambrosi, Sergio Santoni, Rodorico Giorgi, Emiliano Fratini, Nicola Toccafondi, Piero Baglioni, High-performance and anti-stain coating for porcelain stoneware tiles based on nanostructured zirconium compounds, Journal of Colloid and Interface Science, Volume 432, 15 October 2014
  • Céline Varvenne, Olivier Mackain, Emmanuel Clouet, Vacancy clustering in zirconium: An atomic-scale study, Acta Materialia, Volume 78, 1 October 2014
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  • M. Sattari, R.A. Holt, M.R. Daymond, Variant selection and transformation texture in zirconium alloy Excel, Journal of Nuclear Materials, Volume 453, Issues 1–3, October 2014
  • Tingshun Jiang, Jinlian Cheng, Wangping Liu, Lie Fu, Xuping Zhou, Qian Zhao, Hengbo Yin, Sulfuric acid functional zirconium (or aluminum) incorporated mesoporous MCM-48 solid acid catalysts for alkylation of phenol with tert-butyl alcohol, Journal of Solid State Chemistry, Volume 218, October 2014
  • Lucimara B. Panice, Elisangela A. de Oliveira, Ricardo A.D. Molin Filho, Daniela P. de Oliveira, Angélica M. Lazarin, Elza I.S. Andreotti, Rosana L. Sernaglia, Yoshitaka Gushikem, Electrochemical properties of the hexacyanoferrate(II)–ruthenium(III) complex immobilized on silica gel surface chemically modified with zirconium(IV) oxide, Materials Science and Engineering: B, Volume 188, October 2014
  • Lan Zhang, Shaoyu Zhu, Yong Han, Chengzhang Xiao, Wu Tang, Formation and bioactivity of HA nanorods on micro-arc oxidized zirconium, Materials Science and Engineering: C, Volume 43, 1 October 2014
  • Z. Amghouz, C. Ancín-Azpilicueta, K.K. Burusco, J.R. García, S.A. Khainakov, A. Luquin, R. Nieto, J.J. Garrido, Biogenic amines in wine: Individual and competitive adsorption on a modified zirconium phosphate, Microporous and Mesoporous Materials, Volume 197, October 2014
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Recent Research & Development for Nitrates

  • L. Liu, J.P. Cheng, J. Zhang, F. Liu, X.B. Zhang, Effects of dodecyl sulfate and nitrate anions on the supercapacitive properties of a-Co(OH)2, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Baogang Zhang, Ye Liu, Shuang Tong, Maosheng Zheng, Yinxin Zhao, Caixing Tian, Hengyuan Liu, Chuanping Feng, Enhancement of bacterial denitrification for nitrate removal in groundwater with electrical stimulation from microbial fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Xu Wang, Dahai Pan, Qian Xu, Min He, Shuwei Chen, Feng Yu, Ruifeng Li, Synthesis of ordered mesoporous alumina with high thermal stability using aluminum nitrate as precursor, Materials Letters, Volume 135, 15 November 2014
  • Javad Baneshi, Mohammad Haghighi, Naeimeh Jodeiri, Mozaffar Abdollahifar, Hossein Ajamein, Urea–nitrate combustion synthesis of ZrO2 and CeO2 doped CuO/Al2O3 nanocatalyst used in steam reforming of biomethanol for hydrogen production, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Ian Y.Y. Bu, Sol–gel production of aluminium doped zinc oxide using aluminium nitrate, Materials Science in Semiconductor Processing, Volume 27, November 2014
  • N. Sivakumar, V. Jaisankar, G. Chakkaravarthi, G. Anbalagan, Synthesis, crystal structure, optical, thermal and mechanical characterization of poly bis(thiourea) silver(I) nitrate single crystals synthesized at room temperature, Materials Letters, Volume 132, 1 October 2014
  • Jing Cai, Ping Zheng, Mahmood Qaisar, Peide Sun, Effect of electrode types on simultaneous anaerobic sulfide and nitrate removal in microbial fuel cell, Separation and Purification Technology, Volume 134, 25 September 2014
  • Raka Mukherjee, Sirshendu De, Adsorptive removal of nitrate from aqueous solution by polyacrylonitrile–alumina nanoparticle mixed matrix hollow-fiber membrane, Journal of Membrane Science, Volume 466, 15 September 2014
  • Mircea Niculescu, Ionut Ledeti, Mihail Bîrzescu, New methods to obtain carboxylic acids by oxidation reactions of 1,2-ethanediol with metallic nitrates, Journal of Organometallic Chemistry, Volume 767, 15 September 2014
  • Bikshandarkoil R. Srinivasan, Comments on the paper: ‘Studies on structural, thermal and optical properties of novel NLO crystal bis l-glutamine sodium nitrate’, Materials Letters, Volume 131, 15 September 2014
  • Redrothu Hanumantharao, S. Kalainathan, Reply to “Comments on the paper: Studies on structural, thermal and optical properties of novel NLO crystal bis l-glutamine sodium nitrate”, Materials Letters, Volume 131, 15 September 2014
  • N. Hosseini, F. Karimzadeh, M.H. Abbasi, G.M. Choi, Microstructural characterization and electrical conductivity of CuxMn3-xO4 (0.9=x=1.3) spinels produced by optimized glycine–nitrate combustion and mechanical milling processes, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • J.L. Camas-Anzueto, A.E. Aguilar-Castillejos, J.H. Castañón-González, M.C. Lujpán-Hidalgo, H.R. Hernández de León, R. Mota Grajales, Fiber sensor based on Lophine sensitive layer for nitrate detection in drinking water, Optics and Lasers in Engineering, Volume 60, September 2014
  • Wattana Tuichai, Prasit Thongbai, Vittaya Amornkitbamrung, Teerapon Yamwong, Santi Maensiri, Na0.5Bi0.5Cu3Ti4O12 nanocrystalline powders prepared by a glycine–nitrate process: Preparation, characterization, and their dielectric properties, Microelectronic Engineering, Volume 126, 25 August 2014
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  • Lina Shi, Jianhua Du, Zuliang Chen, Mallavarapu Megharaj, Ravendra Naidu, Functional kaolinite supported Fe/Ni nanoparticles for simultaneous catalytic remediation of mixed contaminants (lead and nitrate) from wastewater, Journal of Colloid and Interface Science, Volume 428, 15 August 2014
  • Xinxin Jiang, Kaiqiang Wu, Lianyi Shao, Miao Shui, Xiaoting Lin, Mengmeng Lao, Nengbing Long, Yuanlong Ren, Jie Shu, Lithium storage mechanism in superior high capacity copper nitrate hydrate anode material, Journal of Power Sources, Volume 260, 15 August 2014
  • Inmaculada Pérez-Toro, Alicia Domínguez-Martín, Duane Choquesillo-Lazarte, Esther Vílchez-Rodríguez, Alfonso Castiñeiras, Juan Niclós-Gutiérrez, Synthesis, thermogravimetric study and crystal structure of an N-rich copper(II) compound with tren ligands and nitrate counter-anions, Thermochimica Acta, Available online 12 August 2014
  • Seung-Young Park, Chan Woong Na, Jee Hyun Ahn, Rak-Hyun Song, Jong-Heun Lee, Preparation of highly porous NiO–gadolinium-doped ceria nano-composite powders by one-pot glycine nitrate process for anode-supported tubular solid oxide fuel cells, Journal of Asian Ceramic Societies, Available online 4 August 2014
  • Laxman Singh, Uma Shanker Rai, Kamdeo Mandal, Byung Cheol Sin, Sang-Ick Lee, Youngil Lee, Dielectric, AC-impedance, modulus studies on 0.5BaTiO3·0.5CaCu3Ti4O12 nano-composite ceramic synthesized by one-pot, glycine-assisted nitrate-gel route, Ceramics International, Volume 40, Issue 7, Part A, August 2014