Zirconyl Chloride

ZrOCl2
CAS 7699-43-6


Product Product Code Order or Specifications
(2N) 99% Zirconyl Chloride ZROL-CL-02 Contact American Elements
(3N) 99.9% Zirconyl Chloride ZROL-CL-03 Contact American Elements
(4N) 99.99% Zirconyl Chloride ZROL-CL-04 Contact American Elements
(5N) 99.999% Zirconyl Chloride ZROL-CL-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
ZrOCl2 7699-43-6 24373 MFCD00011309 231-717-9 dichloro(oxo)zirconium N/A O=[Zr](Cl)Cl InChI=1S/2ClH.O.Zr
/h2*1H;;/q;;;+2/p-2
IPCAPQRVQMIMAN-UHFFFAOYSA-L

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
Cl2OZr 178.13 Solid 400 °C N/A N/A 178.129395 175.837326 0 Safety Data Sheet

Zirconyl Chloride is an excellent water soluble crystalline Zirconium source for uses compatible with chlorides. Chloride compounds can conduct electricity when fused or dissolved in water. Chloride materials can be decomposed by electrolysis to chlorine gas and the metal. They are formed through various chlorination processes whereby at least one chlorine anion (Cl-) is covalently bonded to the relevant metal or cation. Ultra high purity and proprietary formulations can be prepared. The chloride ion controls fluid equilibrium and pH levels in metabolic systems. They can form either inorganic or organic compounds. Zirconium Chloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. We also produce Zirconium Chloride Solution. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Zirconium (Zr) atomic and molecular weight, atomic number and elemental symbol Zirconium (atomic symbol: Zr, atomic number: 40) is a Block D, Group 4, Period 5 element with an atomic weight of 91.224. Zirconium Bohr ModelThe number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electron configuration is [Kr] 4d2 5s2. The zirconium atom has a radius of 160 pm and a Van der Waals radius of 186 pm. Zirconium was discovered by Martin Heinrich Klaproth in 1789 and first isolated by Jöns Jakob Berzelius in 1824. Elemental ZirconiumIn its elemental form, zirconium has a silvery white appearance that is similar to titanium. Zirconium's principal mineral is zircon (zirconium silicate). Zirconium is commercially produced as a by-product of titanium and tin mining and has many applications as a opacifier and a refractory material. It is not found in nature as a free element. The name of zirconium comes from the mineral zircon, the most important source of zirconium, and from the Persian word 'zargun' meaning gold-like. For more information on zirconium, including properties, safety data, research, and American Elements' catalog of zirconium products, visit the Zirconium Information Center.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H314
Hazard Codes C
Risk Codes 34
Safety Precautions 7/8-26-27-36/37/39-45
RTECS Number N/A
Transport Information UN 3260 8/PG 2
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Exploding Bomb: Explosive        

ZIRCONYL CHLORIDE SYNONYMS
Zirconium oxychloride; Chlorozirconyl, Dichlorooxozirconium, Zirconium oxydichloride, Zirconium chloride oxide, Zirconium dichloride oxide, basic zirconium chloride

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


Have a Question? Ask a Chemical Engineer or Material Scientist
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Recent Research & Development for Zirconium

  • Wanying Geng, Ge Zhu, Yurong Shi, Yuhua Wang, Luminescent characteristics of Dy3+ doped calcium zirconium phosphate CaZr4(PO4)6 (CZP) phosphor for warm-white LEDs, Journal of Luminescence, Volume 155, November 2014
  • I. Kratochvílová, R. Škoda, J. Škarohlíd, P. Ashcheulov, A. Jäger, J. Racek, A. Taylor, L. Shao, Nanosized polycrystalline diamond cladding for surface protection of zirconium nuclear fuel tubes, Journal of Materials Processing Technology, Volume 214, Issue 11, November 2014
  • Sangjoon Ahn, Sandeep Irukuvarghula, Sean M. McDeavitt, Thermophysical investigations of the uranium–zirconium alloy system, Journal of Alloys and Compounds, Volume 611, 25 October 2014
  • Yueming Ren, Pingxin Liu, Xiaoli Liu, Jing Feng, Zhuangjun Fan, Tianzhu Luan, Preparation of zirconium oxy ion-imprinted particle for the selective separation of trace zirconium ion from water, Journal of Colloid and Interface Science, Volume 431, 1 October 2014
  • Tingshun Jiang, Jinlian Cheng, Wangping Liu, Lie Fu, Xuping Zhou, Qian Zhao, Hengbo Yin, Sulfuric acid functional zirconium (or aluminum) incorporated mesoporous MCM-48 solid acid catalysts for alkylation of phenol with tert-butyl alcohol, Journal of Solid State Chemistry, Volume 218, October 2014
  • Lucimara B. Panice, Elisangela A. de Oliveira, Ricardo A.D. Molin Filho, Daniela P. de Oliveira, Angélica M. Lazarin, Elza I.S. Andreotti, Rosana L. Sernaglia, Yoshitaka Gushikem, Electrochemical properties of the hexacyanoferrate(II)–ruthenium(III) complex immobilized on silica gel surface chemically modified with zirconium(IV) oxide, Materials Science and Engineering: B, Volume 188, October 2014
  • Z. Amghouz, C. Ancín-Azpilicueta, K.K. Burusco, J.R. García, S.A. Khainakov, A. Luquin, R. Nieto, J.J. Garrido, Biogenic amines in wine: Individual and competitive adsorption on a modified zirconium phosphate, Microporous and Mesoporous Materials, Volume 197, October 2014
  • Mario Casciola, Paula Cojocaru, Anna Donnadio, Stefano Giancola, Luca Merlo, Yannig Nedellec, Monica Pica, Surya Subianto, Zirconium phosphate reinforced short side chain perflurosulfonic acid membranes for medium temperature proton exchange membrane fuel cell application, Journal of Power Sources, Volume 262, 15 September 2014
  • Abubaker Abutartour, Yunjie Jia, Lotfia El Majdoub, Qinghong Xu, A new hierarchical porous zirconium phosphate membrane and its adsorption properties, Microporous and Mesoporous Materials, Volume 196, 15 September 2014
  • Hasan Gocmez, Mustafa Tuncer, Yavuz Selim Yeniceri, Low temperature synthesis and pressureless sintering of nanocrystalline zirconium diboride powders, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • W.J. Kelvin Chew, M. Amiriyan, A. Yaghoubi, S. Ramesh, J. Purbolaksono, R. Tolouei, W.D. Teng, D.K. Agrawal, Sintering properties and thermal depletion of boron in zirconia–zirconium diboride conductive ceramic, Ceramics International, Volume 40, Issue 8, Part B, September 2014
  • Mohammed Ibrahim Jamesh, Guosong Wu, Ying Zhao, Weihong Jin, David R. McKenzie, Marcela M.M. Bilek, Paul K. Chu, Effects of zirconium and nitrogen plasma immersion ion implantation on the electrochemical corrosion behavior of Mg–Y–RE alloy in simulated body fluid and cell culture medium, Corrosion Science, Volume 86, September 2014
  • S. Mukherjee, S. Kaity, M.T. Saify, S.K. Jha, P.K. Pujari, Evidence of zirconium nano-agglomeration in as-cast dilute U–Zr alloys, Journal of Nuclear Materials, Volume 452, Issues 1–3, September 2014
  • A. Rico, M.A. Martin-Rengel, J. Ruiz-Hervias, J. Rodriguez, F.J. Gomez-Sanchez, Nanoindentation measurements of the mechanical properties of zirconium matrix and hydrides in unirradiated pre-hydrided nuclear fuel cladding, Journal of Nuclear Materials, Volume 452, Issues 1–3, September 2014
  • Adrien Couet, Arthur T. Motta, Benoit de Gabory, Zhonghou Cai, Microbeam X-ray Absorption Near-Edge Spectroscopy study of the oxidation of Fe and Nb in zirconium alloy oxide layers, Journal of Nuclear Materials, Volume 452, Issues 1–3, September 2014
  • Haneul Yoo, Whangi Kim, Hyunchul Ju, A numerical comparison of hydrogen absorption behaviors of uranium and zirconium cobalt-based metal hydride beds, Solid State Ionics, Volume 262, 1 September 2014
  • Martynas Audronis, Allan Matthews, Kestutis Juškevicius, Ramutis Drazdys, Unlocking the potential of voltage control for high rate zirconium and hafnium oxide deposition by reactive magnetron sputtering, Vacuum, Volume 107, September 2014
  • G. Antou, M. Gendre, E. Laborde, A. Maître, G. Trolliard, High temperature compressive creep of spark plasma sintered zirconium (oxy-)carbide, Materials Science and Engineering: A, Volume 612, 26 August 2014
  • Fei Li, Zhuang Kang, Xiao Huang, Guo-Jun Zhang, Fabrication of zirconium carbide nanofibers by electrospinning, Ceramics International, Volume 40, Issue 7, Part A, August 2014
  • Cuiyan Li, Kezhi Li, Hejun Li, Yulei Zhang, Haibo Ouyang, Dongjia Yao, Lei Liu, Microstructure and ablation resistance of carbon/carbon composites with a zirconium carbide rich surface layer, Corrosion Science, Volume 85, August 2014

Recent Research & Development for Chlorides

  • Qingli Li, Hongying Liu, Yiting Wang, Zhen Sun, Fangmin Guo, Jianzhong Zhu, Methyl green and nitrotetrazolium blue chloride co-expression in colon tissue: A hyperspectral microscopic imaging analysis, Optics & Laser Technology, Volume 64, December 2014
  • Ram Kripal, Manju Singh, EPR and optical study of Mn2+ doped monohydrated dipotassium stannic chloride, Journal of Alloys and Compounds, Volume 613, 15 November 2014
  • S. Imran U. Shah, Andrew L. Hector, John R. Owen, Redox supercapacitor performance of nanocrystalline molybdenum nitrides obtained by ammonolysis of chloride- and amide-derived precursors, Journal of Power Sources, Volume 266, 15 November 2014
  • N.S. Benerji, Bijendra Singh, Performance of axicon based conical resonator (ABCR) with a xenon chloride (XeCl) excimer laser, Optics Communications, Volume 331, 15 November 2014
  • M. Torres-Luque, E. Bastidas-Arteaga, F. Schoefs, M. Sánchez-Silva, J.F. Osma, Non-destructive methods for measuring chloride ingress into concrete: State-of-the-art and future challenges, Construction and Building Materials, Volume 68, 15 October 2014
  • Mickael Saillio, Véronique Baroghel-Bouny, Fabien Barberon, Chloride binding in sound and carbonated cementitious materials with various types of binder, Construction and Building Materials, Volume 68, 15 October 2014
  • Andrew J. Blok, Rinkubahen Chhasatia, Jessirie Dilag, Amanda V. Ellis, Surface initiated polydopamine grafted poly([2-(methacryoyloxy)ethyl]trimethylammonium chloride) coatings to produce reverse osmosis desalination membranes with anti-biofouling properties, Journal of Membrane Science, Volume 468, 15 October 2014
  • Hesam Madani, Alireza Bagheri, Tayebeh Parhizkar, Amirmaziar Raisghasemi, Chloride penetration and electrical resistivity of concretes containing nanosilica hydrosols with different specific surface areas, Cement and Concrete Composites, Volume 53, October 2014
  • Mathias Maes, Nele De Belie, Resistance of concrete and mortar against combined attack of chloride and sodium sulphate, Cement and Concrete Composites, Volume 53, October 2014
  • . Castañeda, A. Maldonado, J. Vega Pérez, M. de la L. Olvera, C. Torres-Torres, Electrical and optical properties of nanostructured indium doped zinc oxide thin films deposited by ultrasonic chemical spray technique, starting from zinc acetylacetonate and indium chloride, Materials Science in Semiconductor Processing, Volume 26, October 2014