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(3-Aminopropyl)trimethoxysilane

CAS #:

Linear Formula:

H2N(CH2)3Si(OCH3)3

MDL Number:

MFCD00008206

EC No.:

237-511-5

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% (3-Aminopropyl)trimethoxysilane
SI-OMX-02
Pricing > SDS > Data Sheet >
(3N) 99.9% (3-Aminopropyl)trimethoxysilane
SI-OMX-03
Pricing > SDS > Data Sheet >
(4N) 99.99% (3-Aminopropyl)trimethoxysilane
SI-OMX-04
Pricing > SDS > Data Sheet >
(5N) 99.999% (3-Aminopropyl)trimethoxysilane
SI-OMX-05
Pricing > SDS > Data Sheet >

(3-Aminopropyl)trimethoxysilane Properties (Theoretical)

Compound Formula C6H17NO3Si
Molecular Weight 179.29
Appearance Colorless Liquid
Melting Point N/A
Boiling Point 91-92 °C/15 mmHg
Density 1.027 g/mL
Solubility in H2O Soluble
Refractive Index n20/D 1.4240
Exact Mass 179.09777
Monoisotopic Mass 179.09777

(3-Aminopropyl)trimethoxysilane Health & Safety Information

Signal Word Danger
Hazard Statements H315-H318
Hazard Codes Xi
Flash Point 90 °C
Risk Codes 34
Safety Statements 26-36/37/39-45
RTECS Number N/A
Transport Information UN 1993 3/PG III
WGK Germany 1
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 06/19/2019
Date Revised: 05/15/2015

SECTION 1. IDENTIFICATION

Product Name: (3-Aminopropyl)trimethoxysilane

Product Number: All applicable American Elements product codes, e.g. SI-OMX-02 , SI-OMX-03 , SI-OMX-04 , SI-OMX-05

CAS #: 13822-56-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 4)
Skin irritation (Category 2)
Serious eye damage (Category 1)

Corrosion - GHS05

Signal word: Danger
Hazard statement(s):
Combustible liquid.
Causes skin irritation.
Causes serious eye damage.

Precautionary statement(s):
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wash skin thoroughly after handling.
Wear protective gloves/ eye protection/ face protection.
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
If skin irritation occurs: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
Store in a well-ventilated place. Keep cool.
Dispose of contents/ container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Synonyms : 3-(Trimethoxysilyl)propylamine
Formula : C6H17NO3Si
Molecular weight : 179.29 g/mol
CAS-No. : 13822-56-5
EC-No. : 237-511-5

Hazardous components
Flammable Liquid: 4
Skin Irritation: 2
Eye Damage: 1


SECTION 4. FIRST AID MEASURES

General advice:
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.

If inhaled:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact:
Wash off with soap and plenty of water. Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed:
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed:
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed:
No data available


SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture:
Carbon oxides, Nitrogen oxides (NOx), silicon oxides

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.

Further information:
Use water spray to cool unopened containers.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.

Environmental precautions:
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up:
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling:
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Moisture sensitive.
Storage class (TRGS 510): Combustible liquids

Specific end use(s):
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters:
Contains no substances with occupational exposure limit values.

Exposure controls
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.
If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure:
Prevent further leakage or spillage if safe to do so. Do not let product enter drains


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Form: liquid
Colour: colourless
Odour: No data available
Odour Threshold: No data available
pH: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range: 91 - 92 °C (196 - 198 °F) at 20 hPa (15 mmHg) - lit.
Flash point: 90 °C (194 °F) - closed cup
Evaporation rate: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Vapour pressure: No data available
Vapour density: No data available
Relative density: 1.027 g/cm3 at 25 °C (77 °F)
Water solubility: soluble
Partition coefficient: noctanol/water: No data available
Auto-ignition temperature: 295 °C (563 °F)
Decomposition temperature: No data available
Viscosity: No data available
Explosive properties: No data available
Oxidizing properties: No data available

Other safety information:
No data available


SECTION 10. STABILITY AND REACTIVITY

Reactivity:
No data available

Chemical stability:
May decompose on exposure to moist air or water.
Stable under recommended storage conditions.

Possibility of hazardous reactions:
No data available

Conditions to avoid:
Heat, flames and sparks.

Incompatible materials:
Strong acids, Strong oxidizing agents, Water, Bases, Alcohols, Peroxides

Hazardous decomposition products:
Other decomposition products - No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity:
LD50 Oral - Rat - 2,970 mg/kg
Inhalation: No data available
LD50 Dermal - Rat - 11,300 mg/kg
(OECD Test Guideline 402)
No data available

Skin corrosion/irritation:
Skin - Rabbit
Result: Skin irritation
(OECD Test Guideline 404)

Serious eye damage/eye irritation:
No data available

Respiratory or skin sensitisation:
No data available

Germ cell mutagenicity:
No data available

Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

Reproductive toxicity:
No data available

Specific target organ toxicity - single exposure:
No data available
Specific target organ toxicity - repeated exposure:
No data available

Aspiration hazard:
No data available

Additional Information:
RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.


SECTION 12. ECOLOGICAL INFORMATION

Toxicity:
No data available

Persistence and degradability:
No data available

Bioaccumulative potential:
No data available

Mobility in soil:
No data available

Results of PBT and vPvB assessment:
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects:
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

Product:
This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging:
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
NA-Number: 1993 Class: NONE Packing group: III
Proper shipping name: Combustible liquid, n.o.s. (3-(Trimethoxysilyl)propylamine)
Reportable Quantity (RQ):
Poison Inhalation Hazard: No

IMDG
Not dangerous goods

IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards:
Fire Hazard, Acute Health Hazard

Massachusetts Right To Know Components:
No components are subject to the Massachusetts Right to Know Act

Pennsylvania Right To Know Components:
3-(Trimethoxysilyl)propylamine
CAS-No.
13822-56-5

New Jersey Right To Know Components:
3-(Trimethoxysilyl)propylamine
CAS-No.
13822-56-5

California Prop. 65 Components:
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2018 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About (3-Aminopropyl)trimethoxysilane

(3-Aminopropyl)trimethoxysilane is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

(3-Aminopropyl)trimethoxysilane Synonyms

APTMS; 3-Aminopropyltrimethoxysilane; 3-(Trimethoxysilyl)propylamine; (γ-Aminopropyl)trimethoxysilane; 1-Propanamine, 3- (trimethoxysilyl)-

Chemical Identifiers

Linear Formula H2N(CH2)3Si(OCH3)3
MDL Number MFCD00008206
EC No. 237-511-5
Beilstein Registry No. 2038118
Pubchem CID 83756
IUPAC Name 3-trimethoxysilylpropan-1-amine
SMILES CO[Si](CCCN)(OC)OC
InchI Identifier InChI=1S/C6H17NO3Si/c1-8-11(9-2,10-3)6-4-5-7/h4-7H2,1-3H3
InchI Key SJECZPVISLOESU-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

See more Silicon products. Silicon (atomic symbol: Si, atomic number: 14) is a Block P, Group 14, Period 3 element with an atomic weight of 28.085. Silicon Bohr MoleculeThe number of electrons in each of Silicon's shells is 2, 8, 4 and its electron configuration is [Ne] 3s2 3p2. The silicon atom has a radius of 111 pm and a Van der Waals radius of 210 pm. Silicon was discovered and first isolated by Jöns Jacob Berzelius in 1823. Silicon makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, exceeded only by oxygen. The metalloid is rarely found in pure crystal form and is usually produced from the iron-silicon alloy ferrosilicon. Elemental SiliconSilica (or silicon dioxide), as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Ultra high purity silicon can be doped with boron, gallium, phosphorus, or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics industry.The name Silicon originates from the Latin word silex which means flint or hard stone.

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June 19, 2019
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