A Cesium Rare-Earth Silicate Cs3RESi6O15 (RE = Dy-Lu, Y, In): The "Parent" of an Unusual Structural Class Featuring a Remarkable 57 Å Unit Cell Axis.

Title A Cesium Rare-Earth Silicate Cs3RESi6O15 (RE = Dy-Lu, Y, In): The "Parent" of an Unusual Structural Class Featuring a Remarkable 57 Å Unit Cell Axis.
Authors R. Terry; D. Vinton; C. McMillen; J. Kolis
Journal Angew Chem Int Ed Engl
DOI 10.1002/anie.201708798
Abstract

A new structural member of the broad class of A3RESi6O15 compounds has been discovered for the formula Cs3RESi6O15, where RE = Dy-Lu,Y,In. The structure is unusual in that it contains octahedrally coordinated rare earth ions whose relative orientation dictates the structure as they rotate about the c-axis supported by the cyclic Si6O15 framework. The repeat unit of the rotation is eight units generating a very long, ~57 Å, unit cell axis. This unusual repeat unit is created by the structural flexibility of the hexasilicate ring, which is in turn affected by the size of the rare earth ion as well as the size of alkali ion residing within the silicate layers. The products described here are prepared as large, high quality single crystals using a high temperature (650?C) hydrothermal method with CsOH and F- mineralizers. The presence of fluoride is essential to the formation of the product, as reactions without fluoride do not form these products.

Citation R. Terry; D. Vinton; C. McMillen; J. Kolis.A Cesium Rare-Earth Silicate Cs3RESi6O15 (RE = Dy-Lu, Y, In): The "Parent" of an Unusual Structural Class Featuring a Remarkable 57 Å Unit Cell Axis.. Angew Chem Int Ed Engl. 2017. doi:10.1002/anie.201708798

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