A low-crystalline ruthenium nano-layer supported on praseodymium oxide as an active catalyst for ammonia synthesis.

Title A low-crystalline ruthenium nano-layer supported on praseodymium oxide as an active catalyst for ammonia synthesis.
Authors K. Sato; K. Imamura; Y. Kawano; S.I. Miyahara; T. Yamamoto; S. Matsumura; K. Nagaoka
Journal Chem Sci
DOI 10.1039/c6sc02382g
Abstract

Ammonia is a crucial chemical feedstock for fertilizer production and is a potential energy carrier. However, the current method of synthesizing ammonia, the Haber-Bosch process, consumes a great deal of energy. To reduce energy consumption, a process and a substance that can catalyze ammonia synthesis under mild conditions (low temperature and low pressure) are strongly needed. Here we show that Ru/Pr2O3 without any dopant catalyzes ammonia synthesis under mild conditions at 1.8 times the rates reported with other highly active catalysts. Scanning transmission electron micrograph observations and energy dispersive X-ray analyses revealed the formation of low-crystalline nano-layers of ruthenium on the surface of Pr2O3. Furthermore, CO2 temperature-programmed desorption revealed that the catalyst was strongly basic. These unique structural and electronic characteristics are considered to synergistically accelerate the rate-determining step of NH3 synthesis, cleavage of the N 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 N bond. We expect that the use of this catalyst will be a starting point for achieving efficient ammonia synthesis.

Citation K. Sato; K. Imamura; Y. Kawano; S.I. Miyahara; T. Yamamoto; S. Matsumura; K. Nagaoka.A low-crystalline ruthenium nano-layer supported on praseodymium oxide as an active catalyst for ammonia synthesis.. Chem Sci. 2017;8(1):674679. doi:10.1039/c6sc02382g

Related Elements

Praseodymium

See more Praseodymium products. Praseodymium (atomic symbol: Pr, atomic number: 59) is a Block F, Group 3, Period 6 element with an atomic weight of 140.90765. Praseodymium Bohr Model The number of electrons in each of praseodymium's shells is 2, 8, 18, 21, 8, 2 and its electron configuration is [Xe]4f3 6s2. The praseodymium atom has a radius of 182 pm and a Van der Waals radius of 239 pm. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Elemental PraseodymiumUnlike other rare-earth metals, which show antiferromagnetic and / or ferromagnetic ordering at low temperatures, praseodymium is paramagnetic at any temperature above 1 K. Praseodymium is found in the minerals monazite and bastnasite. Praseodymium was discovered by Carl Auer von Welsbach in 1885. The origin of the element name comes from the Greek words prasios didymos, meaning green twin.

Ruthenium

See more Ruthenium products. Ruthenium (atomic symbol: Ru, atomic number: 44) is a Block D, Group 8, Period 5 element with an atomic weight of 101.07. Ruthenium Bohr ModelThe number of electrons in each of ruthenium's shells is [2, 8, 18, 15, 1] and its electron configuration is [Kr] 4d7 5s1. The ruthenium atom has a radius of 134 pm and a Van der Waals radius of 207 pm. Ruthenium was discovered by Jędrzej Śniadecki in 1807. It was first recognized as a distinct element by Karl Ernst Claus in 1844. Elemental RutheniumIn its elemental form, ruthenium has a silvery white metallic appearance. Ruthenium is a rare transition metal belonging to the platinum group of metals. It is found in pentlandite, pyroxenite, and platinum group metal ores. The name Ruthenium originates from the Latin word "Ruthenia," meaning Russia.

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